Search Results (60)

We present a whole-rock geochemical dataset of late Variscan intrusive rocks and residual anatectic melts from the mid- and lower continental crust exposed in the Serre Massif of Calabria (southern Italy). A total of 74 samples were collected from the main plutonic units and from leucosomes of associated migmatitic metasediments. The composition of intrusive rocks varies from tonalites and quartz-diorites at deeper structural levels, to peraluminous granites at shallower levels. The dataset includes major, trace and rare earth element (REE) analyses obtained using X-ray fluorescence (XRF) and inductively coupled plasma mass spectrometry (ICP-MS). The dataset integrates new and previously published geochemical data into a consistent and reusable format, including sample locations (WGS84), lithological classification and lithostratigraphic attribution. Sampling sites are also provided as a downloadable geospatial (.kmz) file for visualization in GIS platforms. The data are intended to support a wide range of applications, including studies on granitoid magmatism, water–rock interaction processes in crystalline aquifers and raw materials exploration. Therefore, the dataset represents a valuable resource for both fundamental and applied geoscientific research. Full article

The Abitagua batholith is a 120 km long plutonic body located in the northern sub-Andean zone of Ecuador. Despite its size, previous studies have focused on its northern and southern sectors, leaving the central sector uncharacterized. This study presents the first petrographic and geochemical evidence from a single outcrop exposed along the Jatunyacu River, in the central part of the Abitagua Batholith, in order to understand its magmatic evolution and tectonic affinity. Petrographically, the dominant lithology is an equigranular monzogranite. The fractured zones show localized hydrothermal alteration, including epidote, sericitization of plagioclase, and chloritization of biotite. Subordinate bodies include tonalitic enclaves, felsic dikes, and an andesitic dike. Geochemically, the studied sector shows a calc-alkaline affinity, peraluminous character, and a volcanic arc granite (VAG) signature broadly consistent with I-type granitoids formed in a continental arc related to subduction. Samples from fractured zones show small shifts toward the S-type field in the K₂O vs. Na₂O diagram, attributed to hydrothermal alkali mobility rather than primary magmatic variation, as supported by petrographic evidence. Multi-element normalized diagrams reveal distinct signatures among subordinate bodies: tonalitic enclaves show strong enrichment in mafic components and Nb, suggesting a primitive mafic source; felsic dikes display enrichment in incompatible elements (Nb, Rb) consistent with evolved residual melts; and the andesitic dike exhibits the most primitive composition with apparent minimal interaction with the felsic host. These are interpreted as evidence of a complex magmatic evolution involving mafic recharge, magma mixing, late injection of residual melts, and localized hydrothermal alteration. Comparison with previous studies suggest that the studied outcrop records an arc signature similar to that reported for the northern and southern sectors, although further work is needed to confirm the extent of this affinity across the central sector. Full article

The Arco Verde Complex, exposed in the Serra do Inajá region of the Rio Maria Domain (Carajás Province, Amazonian Craton), represents one of the oldest TTG granitoid association of the province (3.00–2.92 Ga). While TTG magmatism is well constrained in the northern domain, its southern sector lacks precise geochronological data. This study integrates petrographic, geochemical, U–Pb zircon geochronology, and Nd–Hf isotopes to constrain the age, source, and crustal significance of these granitoids. Uranium–Pb zircon dating of two granodiorites yielded ages of 2979 ± 8 and 2979 ± 11 Ma, extending the 2.98 Ga TTG magmatic episode to the southern sector of the Rio Maria Domain. Geochemical data indicate dominant tonalites formed by partial melting of a similar mafic source at different crustal depths, whereas subordinate granodioritic and monzogranitic rocks show transitional TTG affinities. These features indicate coeval mafic and felsic crust rapidly reworked after formation. Hf and Nd model ages of 3.0–3.2 Ga, with positive ε_Hf–Nd at 2.98 Ga, reinforce the Early Mesoarchean as the main crustal growth period in the province. In addition, we propose that the differentiation of the depleted mantle (DM) beneath the Carajás Province may have initiated around 3.8 Ga. Full article

Focusing on the West African Craton (WAC) as a test bed, this protocol-oriented scoping review synthesizes indicators for orogenic gold and translates them into an auditable, map-first checklist that separates Fertility and Preservation, while deliberately deferring any performance estimation to a blinded, out-of-sample evaluation. There is a need for a transparent, auditable, and field-ready framework that integrates geological, structural, geophysical, and geochemical evidence. We (i) synthesize the state of knowledge into a map-first, reproducible targeting checklist, (ii) formalize an indicator decision matrix that separates Fertility from Preservation factors, and (iii) specify a deferred, out-of-sample evaluation protocol to quantify performance. We conduct a Preferred Reporting Items for Systematic Reviews and Meta-Analyses extension for Scoping Reviews (PRISMA-ScR)-style scoping review (2010–2025) and codify commonly used indicators (e.g., transpressional jogs, lineament density, proximity to tonalite-trondhjemite-granodiorite (TTG)/tonalite contacts, Sr/Y proxies). Indicators are operationalized as auditable pass/fail rules and assembled into a decision matrix with explicit uncertainty handling and risk logging. We further define a deferred evaluation protocol using classification and ranking metrics (receiver operating characteristic (ROC) and precision–recall (PR) curves, odds ratios), ablation/sensitivity tests, and district-level threshold calibration. We deliver (1) a unified, auditable checklist with default (tunable) thresholds; (2) an indicator decision matrix that disentangles Fertility vs. Preservation signals; and (3) a deferred evaluation protocol enabling a reproducible, out-of-sample assessment without inflating apparent performance. All numerical thresholds reported here are explicit placeholders that facilitate transparency and auditability; they are not optimized. A properly blocked train/validation/test scheme, operating-point selection criteria, null models, and uncertainty procedures are prespecified for future evaluation. By publishing the checklist, data lineage, and audit-log schema now—without performance claims—we enable reproducible adoption and stress-test the framework ahead of calibration. Full article

The origin of intermediate rocks within large igneous provinces (LIPs), which often exhibit a bimodal compositional distribution, remains poorly understood. To investigate the petrogenesis of such intermediate magmas within the Early Cretaceous Tethyan Himalaya igneous province in Tibet, we present a comprehensive study of zircon U–Pb geochronology, whole-rock geochemistry, and Nd isotopes for the tonalites from the Zhegucuo area. Zircon U–Pb dating yields a crystallization age of 130.81 ± 0.55 Ma. The rocks exhibit low Mg# and compatible element contents, indicating significant fractional crystallization of ferromagnesian minerals, plagioclase, and accessory minerals. Their homogeneous, near-chondritic ε_Nd(t) values (−0.34 to +0.01) preclude significant crustal contamination. Based on field relationships, geochemistry, and isotopic evidence, we conclude that the Zhegucuo tonalites were generated by extensive fractional crystallization of basaltic magmas. FC3MS and FCKANTMS systematics reveal a peridotitic component in the mantle source of the Zhegucuo mafic rocks. The exceptionally high values of these proxies of the Zhegucuo tonalites are attributed to extensive fractional crystallization of evolved magmas. Full article

The development of the continental crust during the Archean era is one of the key issues of geoscience. Determining the geological nature of the Archean terrane of the southern Liaoning Province (SLP) is fundamental to decipher the tectonic framework of the eastern North China Craton (NCC) from the late Neoarchean to Paleoproterozoic. The Archean assemblage of the SLP is composed of metabasalt, deformed diorite, TTG, and granite. Zircon U-Pb and Lu-Hf data constrain that the metabasalt formed at 2.52 Ga and was metamorphosed at 2.49 Ga. Dioritic rocks, TTG (tonalite-trondhjemite-granodiorite) and granite formed between 2.53 and 2.48 Ga. More than 85% of analyzed zircon grains yield ε_Hf(t) values intermediate between coeval CHUR and depleted mantle (DM). Their single-stage (T_DM) Hf model ages are dominantly between 2.90 and 2.58 Ga with a peak at 2.76–2.66 Ga, suggesting that the Archean assemblages of the SLP were derived from short-lived crustal sources with limited contributions from older materials. Geochemistry and zircon Lu-Hf systems indicate that these metamafic rocks have N-MORB and island arc-like tholeiitic affinities. Similar basaltic associations were identified from the Wutai greenstone belt. Intra-oceanic subduction and back arc basin extension can be ascribed to the generation of associated MORB-like and arc-related basalt. Along with the closure of the SLP back arc basin, an unknown terrane accreted to the south of the Longgang block at the end of the Neoarchean. Full article

The consistency between geochemical discrimination diagrams and the modal Quartz–Alkali feldspar–Plagioclase (QAP) classification scheme was investigated by evaluating the accuracy of three diagrams—the Quartz–Plagioclase coordinates (P-Q), the SiO₂–CaO/(CaO + K₂O) (SCK), and the Silica–Total Alkali (TAS) diagrams—for granitoid rocks. A global dataset of 1981 samples, each containing both whole-rock geochemical data and quantitative modal mineralogy, was employed. The results indicate that the P-Q and SCK diagrams have relatively low overall accuracy (~50%–55%) in reproducing the QAP classification. Their accuracy is acceptable for granites but notably lower for basic and intermediate rock types. The SCK diagram achieves higher accuracy (~80%) for tonalite but exhibits considerable dispersion for other lithologies. Despite the IUGS recommending the TAS diagram for volcanic rocks only, it is commonly used for intrusive rocks; this study, however, finds that it yields low accuracy rates for most common plutonic rocks and is therefore unsuitable for their reliable classification. This limited accuracy is attributed to the use of only three or four oxides to estimate major mineral proportions, a practice equivalent to dimensionality reduction that results in substantial information loss. Full article

The article provides a comprehensive analysis of the Magal Gebreel granitic suites (MGGs) using petrological (fieldwork, petrography, mineral chemistry, and bulk rock analysis) aspects to infer their petrogenesis and emplacement setting. Our understanding of the development of the northern portion of the Arabian Nubian Shield is significantly improved by the Neoproterozoic granitic rocks of the seldom studied MGGs in Egypt’s south Eastern Desert. According to detailed field, mineralogical, and geochemical assessments, they comprise syn-collision (granodiorites) and post-collision (monzogranites, syenogranites, and alkali feldspar rocks). Granodiorite has strong positive Pb, notable negative P, Ti, and Nb anomalies, and is magnesian in composition. They have high content of LREEs (light rare-earth elements) compared to HREEs (heavy rare-earth elements) and clear elevation of LFSEs (low-field strength elements; K Rb, and Ba) compared to HFSEs (high-field strength elements; Zr and Nb), which are in accord with the contents of I-type granites from the Eastern Desert. In this context, the granodiorites are indicative of an early magmatic phase that probably resulted from the partial melting of high K-mafic sources in the subduction zone. Conversely, the post-collision rocks have low contents of Mg#, CaO, P₂O₅, MgO, Fe₂O₃, Sr, and Ti, and high SiO₂, Fe₂O₃/MgO, Nb, Ce, and Ga/Al, suggesting A-type features with ferroan affinity. Their P, Nb, Sr, Ba, and Ti negative anomalies are in accord with the findings for Eastern Desert granites of the A2-type. Furthermore, they exhibit a prominent negative anomaly in Eu and a small elevation of LREEs in relation to HREEs. The oxygen fugacity (fO₂) for the rocks under investigation can be calculated using the biotite chemistry. The narrow Fe/(Fe + Mg) ratio range (0.6–0.75) indicates that they crystallized under moderately oxidizing conditions between ~QFM +0.1 and QFM +1. The A-type rocks were formed by the partial melting of a tonalite source (underplating rocks) in a post-collisional environment during the late period of extension via slab delamination. The lithosphere became somewhat impregnated with particular elements as a result of the interaction between the deeper crust and the upwelling mantle. Full article

Potentially toxic elements such as cadmium (Cd) in agricultural soils represent a global concern due to their toxicity and potential accumulation in the food chain. However, our understanding of cadmium’s complex sources and the mechanisms controlling its spatial distribution across diverse edaphic and geological contexts remains limited, particularly in underexplored agricultural regions. Our study aimed to assess the total accumulated Cd content in soils under avocado cultivation and its association with edaphic, geochemical, and geomorphological variables. To this end, we considered the total concentrations of other metals and explored their associations to gain a better understanding of Cd’s spatial distribution. We analyzed 26 physicochemical properties, the total concentrations of 22 elements (including heavy and trace metals such as As, Ba, Cr, Cu, Hg, Ni, Pb, Sb, Se, Sr, Tl, V, and Zn and major elements such as Al, Ca, Fe, K, Mg, and Na), and six geospatial variables in 410 soil samples collected from various avocado-growing regions in Peru in order to identity potential associations that could help explain the spatial patterns of Cd. For data analysis, we applied (1) univariate statistics (skewness, kurtosis); (2) multivariate methods such as Spearman correlations and principal component analysis (PCA); (3) spatial modeling using the Geodetector tool; and (4) non-parametric testing (Kruskal–Wallis test with Dunn’s post hoc test). Our results indicated (1) the presence of hotspots with Cd concentrations exceeding 3 mg·kg⁻¹, displaying a leptokurtic distribution (skewness = 7.3); (2) dominant accumulation mechanisms involving co-adsorption and cation competition (Na⁺, Ca²⁺), as well as geogenic co-accumulation with Zn and Pb; and (3) significantly higher Cd concentrations in Leptosols derived from Cretaceous intermediate igneous rocks (diorites/tonalites), averaging 1.33 mg kg⁻¹ compared to 0.20 mg·kg⁻¹ in alluvial soils (p < 0.0001). The factors with the greatest explanatory power (q > 15%, Geodetector) were the Zn content, parent material, geological age, and soil taxonomic classification. These findings provide edaphogenetic insights that can inform soil cadmium (Cd) management strategies, including recommendations to avoid establishing new plantations in areas with a high risk of Cd accumulation. Such approaches can enhance the efficiency of mitigation programs and reduce the risks to export markets. Full article

The Huoqiu Group is located in the southern margin of the North China Craton and is considered an Archean geologic body. Its supracrustal rocks are divided into the Huayuan, Wuji, and Zhouji formations in ascending order. The Wuji and Zhouji formations contain large BIF-type iron deposits. The BIFs show geological and geochemical features of Paleoproterozoic Lake Superior-type rather than Archean Algoma-type. The study of the formation ages and evolutionary history of the Huoqiu Terrane will provide significant guidance for the mineralization and exploration of the Huoqiu iron deposits. In this paper, we collected all available isotopic ages and Hf isotopic compositions obtained from the Huoqiu Terrane and reassessed their accuracy and geological meanings. We conclude that the Wuji and Zhouji formations were not older than 2343 Ma. Therefore, the BIFs hosted in the Wuji and Zhouji formations must be of Paleoproterozoic age. The magmatic zircons from the TTG gneisses and granite yield U-Pb ages of Neoarchean Era, indicating that the Wuji and Zhouji formations of the Huoqiu Group were deposited on an Archean granitic basement that mainly comprises the trondhjemite-tonalite-granodiorite (TTG) gneisses and granites of the “Huayuan Formation”. The Early Precambrian crystalline basement in the Huoqiu area can be divided into the Huayuan Gneiss Complex and the Huoqiu Group, comprising the Wuji and Zhouji formations. The tectonic scenario of granitic complexes overlain by supracrustal rocks in the Huoqiu Terrane has been recognized in the Songshan, Zhongtiao, Xiaoshan, and Lushan Early Precambrian terranes in the southern margin of the North China Craton. As indicated by the zircon U-Pb ages and εHf(t) data, the crustal growth of the Huoqiu Terrane occurred mainly at ~2.9 Ga and ~2.7 Ga. Based on the sedimentary age, environment, and rhythm, the BIFs in the Huoqiu region are considered to be of Lake Superior type and of great potential for Fe ore exploration. Full article

Digital image correlation (DIC) is a non-contact optical method that can provide high-resolution strain and displacement measurements, but its effectiveness depends on surface texture contrast. This study investigates the effects of surface characteristics on the quality of DIC results in tonalite and marble samples under Brazilian tests. Tonalite samples have a coarse texture with a heterogeneous mineral composition; therefore, DIC analysis was conducted without artificial speckle patterns. Marble, instead, poses a challenge due to its uniform fine texture and composition. Thus, using point and line grids to enhance surface contrast, artificial speckle patterns were applied to marble samples. A total of 39 disk samples (12 tonalite and 27 marble) were tested with video frames recorded during loading and analyzed using Ncorr software. The results confirmed that tonalite’s natural texture allows accurate strain mapping without artificial speckle patterns. In contrast, marbles without speckles are not effective in strain evolution mapping due to a lack of surface contrast. Marble with both point- and line-speckled patterns effectively mapped the strain evolution except for some distortion and directionality along speckles in displacement fields. This result suggests that the preparation of speckled surfaces need special attention for effective deformation evolution mapping in homogeneous materials. Full article

The connection between crustal anatexis and magmatism is key to understanding the mechanisms that drive the evolution of the continental crust. Isotope geology and lithochemistry are important tools for reconstructing links between these processes, as field evidence of their connection is often obliterated by deformation in high-grade terrains. Thus, this study proposes new insights into the connection between the Mesoarchean regional metamorphism, crustal anatexis, and plutonism in the northern sector of the Carajás Province (i.e., Carajás Domain), in the Amazonian Craton, around 2.89 to 2.83 Ga. The widespread crustal anatexis in the Carajás Domain involved the water-fluxed melting of banded orthogneisses of the Xingu Complex and Xicrim-Cateté Orthogranulite (crystallization age at ca. 3.06–2.93 Ga), producing metatexites and diatexites with stromatic, net, schollen, and schlieren morphologies and coeval syntectonic leucosomes with composition similar to tonalites, trondhjemites, and granites. These leucosomes yielded crystallization ages of 2853 ± 5 Ma (MSWD: 0.61), 2862 ± 13 Ma (MSWD: 0.1), and 2867 ± 7 Ma (MSWD: 1.3). Their lithochemical data are similar to those of several diachronous Mesoarchean granitoids of the Carajás Domain in terms of major, minor, and trace elements and magmatic affinity. In addition, binary log–log vector diagrams (e.g., La vs. Yb; Rb vs. Yb), Sr/Y vs. Y, and Eu/Eu* vs. Yb plots indicate that plagioclase fractionation preceded melt extraction, establishing evolving source-to-sink trends between leucosomes and granites. These results show that the interplay between high-grade metamorphism, crustal anatexis, and magmatism may have shaped the evolution of the Mesoarchean continental crust in the Carajás Province, developing a petrotectonic assemblage associated with collisional orogens. The Mesoarchean geodynamic setting played a critical role in the development of coeval ca. 2.89 Ga magmatic–hydrothermal copper deposits in the Carajás Province, as well as Neoarchean world-class iron oxide–copper–gold deposits linked to post-orogenic extensional rebound. Full article

Characterizing alteration and its geochemical signature provides critical information relevant to ore-deposit genesis and its related footprint; for porphyry-type deposits, zoned potassic-phyllic-propylitic alteration and metal enrichment are critical features. Here we integrate earlier lithological and mineralogical studies of the (10+ Moz Au) Archean Côté Gold porphyry-type Au(-Cu) deposit (Ontario, Canada) with identified alteration types to provide exploration vectors. The ca. 2740 tonalite-quartz diorite-diorite intrusive complex and co-temporal Au(-Cu) mineralization as disseminations, breccias and veins are co-spatial with ore-related alteration types (amphibole, biotite, muscovite). An early, locally developed amphibole event coring the deposit is followed by emplacement of a Au(-Cu) mineralized biotite-rich magmatic-hydrothermal breccia body and broad halo of disseminated biotite and quartz veining. These rocks record gains via mass balance calculations of K, Fe, Mg, LILE, and LREE with Au, Cu, Mo, Ag, Se and Bi. Later muscovite alteration is enriched in K, Rb, Cs, Ba, CO₂, and LOI with varied Au, Cu, Mo, Te, As, and Bi values. A strong albite overprint records extreme Na gains with the loss of most other elements, including ore metals (i.e., Au, Cu). Together these data define an Au-Cu-Mo-Ag-Te-Bi-Se core co-spatial with biotite breccia versus a peripheral stockwork and sheeted vein zone with a Te-Se-Zn-Pb-As association. These features further support the posited porphyry-type model for the Côté Gold Au(-Cu) deposit. Full article

The Neoarchean diorite- and tonalite-dominated Chibougamau pluton (Canada) is ideal for case studies dedicated to the petrogenesis and timing of emplacement of fertile magmatic systems and associated Cu-Au porphyry systems. Using whole-rock analyses, geochronology, and zircon chemistry, it is determined that an early magmatic phase (pre-2714 Ma) is derived from a dioritic magma with a moderate ƒO₂ (ΔFMQ 0 to +1), which is optimal for transporting Au and Cu, and that diorite is a potentially fertile magma. Field descriptions indicate that the main mineralizing style consists of sulfide-filled hairline fractures and quartz–carbonate veins. This is likely the consequence of fluid circulation facilitated by a well-developed diaclase network formed following the intrusion of magma at about 4–7 km depth in a competent hosting material. The petrographic features of fluid inclusions (FIs), considered with their microthermometric data and evaporate mound chemistry, suggest the exsolution of early CO₂-rich fluids followed by the unmixing of later aqueous saline fluids characterized by a magmatic signature (i.e., Na-, Ca-, Fe-, Mn-, Ba-, and Cl-F). The type of magmatism and its oxidation state, age relationships, the nature of mineralization, and fluid chemistry together support a model whereby metalliferous fluids are derived from an intermediate hydrous magma. This therefore enforces a porphyry-type metallogenic model for this Archean setting. Full article

The Las Cruces intrusive suite is located at the southern extent of the Baja California Peninsula in northwestern Mexico. The suite constitutes the northern part of the Los Cabos Batholitic Complex. It is correlated with extensive Cretaceous magmatic activity extending across California and the Baja Peninsula, known as the Peninsular Ranges Batholith. Despite its significance for understanding the regional tectonic and magmatic evolution, detailed information to fully support this correlation remains limited. This work provides new cartographic and structural data of the units comprising the intrusive suite and the temporal relationships between lithological units, supported by U-Pb zircon geochronology. The suite consists of granite in its central part, tonalite displaying magmatic foliation at its NW and SE margins, and two gabbro apophyses along the western edge. The host rocks consist of intercalations of hornblende and biotite schists, forming screens and roof pendants. Late magmatic felsic dikes, derived from the granite, intrude into the suite units. Five new U-Pb zircon age determinations indicate that the suite has a normal crystallization history with ages from 103.5 ± 1.2 to 97.6 ± 0.8 Ma for the tonalite and from 93.6 ± 0.7 to 95.0 ± 0.9 Ma for the granite. The gabbro is the oldest intrusive unit, with previous U-Pb zircon ages reported near 109 ± 2.3 and 102.3 ± 2.9 Ma. Structural analysis indicates that the gabbro and tonalite were emplaced during an E–W synmagmatic compressional event, evidenced by N–S oriented magmatic foliation, aligning subparallel to the granite and metasedimentary screens contacts. Later, the granite was emplaced during a compressional stress relaxation phase, causing the tonalite dissection and forming the current suite margins. The calculated U-Pb ages for the Las Cruces intrusive suite and reported geochemical and geophysical data from the northern Baja California Peninsula support its correlation with the Peninsular Ranges batholith. Full article