Search Results (240)

Thermal analysis (TA) has been a valuable tool for controlling the carbon equivalent (CE) of cast irons. Additionally, this technique can provide enhanced control over melt quality, allowing for the avoidance of defects such as undesirable graphite morphology and the formation of carbides. To obtain the most valuable information from the TA, it is necessary to minimize the variations in the filling operation of the TA cups. However, the mass and pouring temperature of TA cups can vary in TA’s typical foundry operations. A design of experiments was performed to determine whether specific parameters of cooling curves used for quality control can distinguish the inoculation effect in the melt when the mass and the pouring temperature of TA cups are varied. The minimum temperature of the eutectic arrest proved to be a robust inoculation potential control parameter when variations in the cup’s mass were within a range of 268–390 g and were filled at any pouring temperature between 1235 and 1369 °C. Lighter cups under 268 g and poured at a low temperature are not suitable for controlling inoculation potential by TA; however, they remain helpful in controlling CE. These later cups are related to cooling times of less than 180 s, which can serve as a criterion for discarding unsuitable samples. A bimodal population of cell surfaces was revealed in the samples, with the population of small cells being proportionally more numerous in samples with lower TE_min values. Full article

The in situ emulsification synergistic self-profile control system has wide application prospects for efficient development on offshore oil reservoirs. During water flooding in Bohai heavy oil reservoirs, random emulsification occurs with superimposed Jamin effects. Effectively utilizing this phenomenon can enhance the efficient development of offshore oilfields. This study addresses the challenges hindering water flooding development in offshore oilfields by investigating the emulsification mechanism and key influencing factors based on oil–water emulsion characteristics, thereby proposing a novel in situ emulsification flooding method. Based on a fundamental analysis of oil–water properties, key factors affecting emulsion stability were examined. Core flooding experiments clarified the impact of spontaneous oil–water emulsification on water flooding recovery. Two-dimensional T1–T2 NMR spectroscopy was employed to detect pure fluid components, innovating the method for distinguishing oil–water distribution during flooding and revealing the characteristics of in situ emulsification interactions. The results indicate that emulsions formed between crude oil and formation water under varying rheometer rotational speeds (500–2500 r/min), water cuts (30–80%), and emulsification temperatures (40–85 °C) are all water-in-oil (W/O) type. Emulsion viscosity exhibits a positive correlation with shear rate, with droplet sizes primarily ranging between 2 and 7 μm and a viscosity amplification factor up to 25.8. Emulsion stability deteriorates with increasing water cut and temperature. Prolonged shearing initially increases viscosity until stabilization. In low-permeability cores, spontaneous oil–water emulsification occurs, yielding a recovery factor of only 30%. For medium- and high-permeability cores (water cuts of 80% and 50%, respectively), recovery factors increased by 9.7% and 12%. The in situ generation of micron-scale emulsions in porous media achieved a recovery factor of approximately 50%, demonstrating significantly enhanced oil recovery (EOR) potential. During emulsification flooding, the system emulsifies oil at pore walls, intensifying water–wall interactions and stripping wall-adhered oil, leading to increased T2 signal intensity and reduced relaxation time. Oil–wall interactions and collision frequencies are lower than those of water, which appears in high-relaxation regions (T1/T2 > 5). The two-dimensional NMR spectrum clearly distinguishes oil and water distributions. Full article

In order to elucidate the high-temperature reaction process of solid waste-based high belite sulphoaluminate cement containing residual gypsum in clinker (NHBSAC) and obtain the formation laws of each mineral in clinker, this article studied its high-temperature reaction kinetics. Through QXRD analysis and numerical fitting methods, the formation of C₄A₃$\overline{\mathrm{S}}$, β-C₂S, and CaSO₄ in clinker under different calcination systems was quantitatively characterized, the corresponding high-temperature reaction kinetics models were established, and the reaction activation energies of each mineral were obtained. The results indicate that the content of C₄A₃$\overline{\mathrm{S}}$ and β-C₂S increases with the prolongation of holding time and the increase in calcination temperature, while CaSO₄ is continuously consumed. Under the control mechanism of solid-state reaction, the formation and consumption of minerals follow the kinetic equation. C₄A₃$\overline{\mathrm{S}}$ and β-C₂S satisfy the D₄ equation under diffusion mechanism control, and CaSO₄ satisfies the R₃ equation under interface chemical reaction mechanism control. The activation energy required for mineral formation varies with different temperature ranges. The activation energies required to form C₄A₃$\overline{\mathrm{S}}$ at 1200–1225 °C, 1225–1275 °C, and 1275–1300 °C are 166.28 kJ/mol, 83.14 kJ/mol, and 36.58 kJ/mol, respectively. The activation energies required to form β-C₂S at 1200–1225 °C and 1225–1300 °C are 374.13 kJ/mol and 66.51 kJ/mol, respectively. This study is beneficial for achieving flexible control of the mineral composition of NHBSAC clinker, providing a theoretical basis and practical experience for the preparation of low-carbon cement and the optimization design of its mineral composition. Full article

Stephanopodium engleri Baill. is an endangered tree species from the Dichapetalaceae family and endemic to the Iron Quadrangle region of Brazil. Recalcitrance and low seed viability limit conventional seedling production, making vegetative propagation a crucial alternative for conservation efforts. This study evaluated the rooting and sprouting potential of different cutting types (apical, middle, and basal segments from the main stem, as well as the tip and the herbaceous and woody segments from the lateral branches) treated with Indole-3-Butyric Acid (IBA) at varying concentrations (0, 1, 2, 3, and 4 g L⁻¹) and immersion durations (5 s to 10 min). Cuttings were collected from 12-month-old plants grown under controlled conditions and planted in Carolina Soil^® substrate after treatment. Sprouting and rooting rates varied significantly between cutting types, with basal main stem cuttings showing the highest rooting success, particularly at 3 g L⁻¹ of IBA. These cuttings also exhibited more and longer roots and enhanced sprouting-related biometric traits. Shorter immersion times (15 s and 1 min) were the most effective, promoting root formation while avoiding the potential inhibitory effects of prolonged exposure. Our findings provide a practical protocol for large-scale seedling production of S. engleri while minimizing impacts on wild populations. The effective use of vegetative propagation could facilitate the expansion of S. engleri populations in their natural habitats, enhancing conservation efforts and ensuring sustainable species management. Full article

Asphaltene deposition remains a critical challenge in water-injected reservoirs, where pressure and compositional variations destabilize the oil phase, triggering precipitation and formation damage. This study explores the application of intermittent waterflooding (IWF) as a practical mitigation strategy, combining alternating injection and well shut-in times to stabilize fluid conditions. A synthetic reservoir model was developed in Eclipse 300 to evaluate how key parameters such as shut-in time, injection rate, and injection timing affect asphaltene behavior under varying operational regimes. Comparative simulations against traditional continuous waterflooding reveal that IWF can significantly suppress near-wellbore deposition, preserve permeability, and improve overall oil recovery. The results show that early injections and optimized cycling schedules maintain reservoir pressure above the bubble point, thereby reducing the extent of destabilization. This study offers a simulation-based framework for IWF design, providing insights into asphaltene control mechanisms and contributing to more efficient reservoir management in fields prone to flow assurance issues. Full article

The galvanostatic electrodeposition of zinc on carbon paper from mildly acidic solutions (ZnCl₂: 0.05–0.1 M; H₃BO₃: 0.05 M) was investigated. The deposits’ growth mechanisms were analyzed through the study of the electrodeposition potential transients and the physical characterization of the electrodes synthesized by varying the current density, transferred charge, and zinc precursor concentration. The analysis reveals that the transition from crystalline to amorphous mossy deposits takes place via the electrodeposition of metallic zinc followed by the formation of oxidized zinc structures. The time required for this transition can be controlled by varying the zinc precursor concentration and electrodeposition current density, allowing for the synthesis of composite zinc/oxidized zinc electrodes with varying ratios of the oxidized to underlying metallic phases. The impact of this ratio on the electrode activity for CO₂ electroreduction is analyzed, highlighting that composite zinc/oxidized zinc electrodes can achieve a faradaic efficiency to CO equal to 82% at −1.8 V vs. Ag/AgCl. The mechanisms behind the variations in the catalytic activity with varying morphologies and structures are discussed, providing guidelines for the synthesis of composite zinc/oxidized zinc electrodes for CO₂ electroreduction. Full article

This paper resolves the predefined-time control problem for multi-agent systems under predefined performance metrics and state constraints, addressing critical limitations of traditional methods—notably their inability to enforce strict user-specified deadlines for mission-critical operations, coupled with difficulties in simultaneously guaranteeing transient performance bounds and state constraints while suffering prohibitive stability proof complexity. To overcome these challenges, we propose a predefined performance control methodology that integrates Barrier Lyapunov Functions command-filtered backstepping. The framework rigorously ensures exact convergence within user-defined time independent of initial conditions while enforcing strict state constraints through time-varying BLF boundaries and further delivers quantifiable performance such as overshoot below 5% and convergence within 10 s. By eliminating high-order derivative continuity proofs via command-filter design, stability analysis complexity is reduced by 40% versus conventional backstepping. Stability proofs and dual-case simulations (UAV formation/smart grid) demonstrate over 95% tracking accuracy under disturbances and constraints, validating broad applicability in safety-critical multi-agent systems. Full article

The article investigates the development of local scour downstream of a damming structure, emphasizing the dynamic equilibrium of river morphology influenced by both natural processes and human interventions like the construction of weirs. It distinguishes between clear-water and live-bed conditions, discussing how sediment transport interacts with hydraulic forces to shape the riverbed. The introduction of a damming structure disrupts sediment flow and initiates local scour formation, which varies depending on stream conditions. In the experimental section, a physical model of a damming weir was tested under controlled conditions. The laboratory model was inspired by an existing damming weir on the Radomka River in Poland. Granulometric analysis and eleven flow series were conducted to assess scour evolution over time. The results showed the fastest erosion in the first hours, followed by stabilization in scour depth but continued elongation of the scour hole. The analysis identified four phases of scour development: initiation, intensive growth, stabilization, and equilibrium. Despite depth stabilization, scour length continued to increase, indicating that full equilibrium had not been reached. The study highlights the complexity of predicting scour behavior and recommends incorporating both depth and length evolution into design analyses to improve the resilience of such damming structures. The innovative aspect of the present study lies in the inclusion of coarse sediment transport, previously accumulated in the upstream reach due to the weir’s impoundment effect, into the scour development process. This specific effect has not been addressed in the studies cited by other authors. This research provides crucial insights for the sustainable design of hydraulic structures and effective sediment management strategies, contributing to the long-term stability and safety of riverine infrastructure. Full article

Recently, morphing quadcopters have gained an unprecedented popularity due to their nature of flexibility, self-controlled arm management and diversified application. It has been established that in morphing quadcopter control, aerial morphing generally introduces time-varying parameters into the dynamic model, thereby increasing the complexity of the control problem, in addition to the non-linearity, coupling dynamics, and external disturbances present in the model. Thus, to address those challenges, this research aimed at developing a robust backstepping sliding mode controller (BSMC) for morphing quadcopter position and orientation control. to achieve the stated aim, mathematical model of an active morphing quadcopter (a foldable drone) was presented considering five morphing formations (X, H, T, O, and Y). Following the development of the system model, the proposed control method was designed in two stages: a high-performance sliding mode controller (HSMC) for attitude control to ensure chattering-free and fast convergence of the orientation angles and a backstepping controller for position control. The robustness and effectiveness of the proposed controller were investigated and benchmarked against a backstepping control approach. The simulation results obtained show the effectiveness of the developed controller against the backstepping approach in the presence of parameter variations and external disturbances. Full article

This paper studies the robust $H_{\infty }$ time-varying formation tracking (TVFT) problem for heterogeneous nonlinear multi-agent systems (MASs) with parameter uncertainties, external disturbances, and unknown leader inputs. The objective is to ensure that follower agents track the leader’s trajectory while achieving a desired time-varying formation, even under unmodeled dynamics and disturbances. Unlike existing methods that rely on global topology information or homogeneous system assumptions, an adaptive control protocol is proposed in full distribution, requiring no global topology information, and integrates nonlinear compensation terms to handle unknown leader inputs and parameter uncertainties. Based on the Lyapunov theory and laplacian matrix, a robust $H_{\infty }$ TVFT criterion is developed. Finally, a numerical example is given to verify the theory. Full article

This paper studies the problem of time-varying formation-tracking control for a class of nonlinear multi-agent systems. A distributed adaptive controller that avoids the global non-zero minimum eigenvalue is designed for heterogeneous systems in which leaders and followers contain different nonlinear terms, and which relies only on the relative errors between adjacent agents. By adopting the Riccati inequality method, the adaptive adjustment factor in the controller is designed to solve the problem of automatically adjusting relative errors based solely on local information. Unlike existing research on time-varying formations with fixed and switching topologies, the method of jointly connected topological graphs is adopted to enable nonlinear followers to track the trajectories of leaders with different nonlinear terms and simultaneously achieve the control objective of the desired time-varying formation. The stability of the system under the jointly connected graph is proved by the Lyapunov stability proof method. Finally, numerical simulation experiments confirm the effectiveness of the proposed control method. Full article

In this article, we present a nonlocal Cahn–Hilliard (nCH) equation incorporating a space-dependent parameter to model microphase separation phenomena in diblock copolymers. The proposed model introduces a modified formulation that accounts for spatially varying average volume fractions and thus captures nonlocal interactions between distinct subdomains. Such spatial heterogeneity plays a critical role in determining the morphology of the resulting phase-separated structures. To efficiently solve the resulting partial differential equation, a Fourier spectral method is used in conjunction with a linearly stabilized splitting scheme. This numerical approach not only guarantees stability and efficiency but also enables accurate resolution of spatially complex patterns without excessive computational overhead. The spectral representation effectively handles the nonlocal terms, while the stabilization scheme allows for large time steps. Therefore, this method is suitable for long-time simulations of pattern formation processes. Numerical experiments conducted under various initial conditions demonstrate the ability of the proposed method to resolve intricate phase separation behaviors, including coarsening dynamics and interface evolution. The results show that the space-dependent parameters significantly influence the orientation, size, and regularity of the emergent patterns. This suggests that spatial control of average composition could be used to engineer desirable microstructures in polymeric materials. This study provides a robust computational framework for investigating nonlocal pattern formation in heterogeneous systems, enables simulations in complex spatial domains, and contributes to the theoretical understanding of morphology control in polymer science. Full article

To address the interception problem against maneuvering targets, this paper proposes a multi-agent cooperative guidance law based on a multi-directional interception formation. A three-dimensional agent–target engagement kinematics model is established, and a fixed-time observer is designed to estimate the target acceleration. By utilizing the agent-to-agent communication network, real-time exchange of motion state information among the agents is realized. Based on this, a control input along the line-of-sight (LOS) direction is designed to directly regulate the agent–target relative velocity, effectively driving the agent swarm to achieve time-to-go consensus within a fixed-time boundary. Furthermore, adaptive variable-power sliding mode control inputs are designed for both elevation and azimuth angles. By adjusting the power of the control inputs according to a preset sliding threshold, the proposed method achieves fast convergence in the early phase and smooth tracking in the latter phase under varying engagement conditions. This ensures that the elevation and azimuth angles of each agent–target pair converge to the desired values within a fixed-time boundary, forming a multi-directional interception formation and significantly improving the interception performance against maneuvering targets. Simulation results demonstrate that the proposed cooperative guidance law exhibits fast convergence, strong robustness, and high accuracy. Full article

Fabricating eutectic high-entropy alloys (EHEAs) via selective laser melting (SLM) presents significant potential for advanced structural applications. This study explores the microstructural evolution of Fe₃₂Cr₃₃Ni₂₉Al₃Ti₃ EHEAs fabricated by SLM under varying laser powers. Electron backscatter diffraction (EBSD) analysis revealed that samples fabricated at 200 W exhibited approximately 70% face-centered-cubic (FCC) and 30% body-centered-cubic (BCC) phases. In comparison, those processed at 160 W showed an increased FCC fraction of 85% with a corresponding reduction in BCC content. Grain size measurements indicated that BCC grains were consistently finer than their FCC counterparts. Thermal simulations demonstrated that higher laser power produced deeper melt pools and broader temperature gradients. By correlating thermal history with phase diagram data, the spatial variation in BCC content was attributed to the differential residence time in the 1350–1100 °C range. This study represents one of the first attempts to quantitatively link local thermal histories with the evolution of dual-phase (FCC + BCC) microstructures in EHEAs during SLM. The findings contribute to the improved understanding and control of phase formation in complex alloy systems, providing valuable guidance for tailoring SLM parameters to optimize the phase composition and microstructure of EHEAs. Full article

This study presents a novel capillary microgripper for manipulating micrometer-sized objects directly within aqueous environments. The system features dynamic, vision-based feedback control of a non-volatile silicone oil droplet volume, enabling precise adjustment of the capillary bridge force for the adaptable capture of varying object sizes. This approach ensures extended working time and stable operation in water, mitigating the issues associated with evaporation common in other systems. COMSOL Multiphysics simulations analyzed capillary bridge formation. Experimental validation demonstrated successful different object shapes and sizes capture in an aqueous environment and further explored active release strategies necessary due to the non-volatile fluid, confirming the system potential for robust underwater micromanipulation. Full article