The contribution of Spanish scientists to the rheology involved in polymer processing during the last 25 years is investigated. It is shown that the performed research covers, at different levels, all industrial polymeric materials: thermoplastics, t...
Any thermoset resin’s processing properties and end-use performance are heavily influenced by the gel time. The complicated viscosity of resin as a function of temperature is investigated in this work, with a particular emphasis on identifying...
The use of amine-based carbamates with their dual function, acting as amine curing agents and CO2 blowing agents after their decomposition without by-products, are promising for ecofriendly epoxy foams as high-performance materials. However, controll...
By understanding the effects of the physical properties of individual input materials (e.g., binding system) on the physical and thermal properties of a composite material, the latter can be engineered in advance according to the desired properties a...
Pultrusion is a highly efficient continuous process to manufacture advanced fiber-reinforced composites. The injection pultrusion variant permits a higher control of the resin flow, enabling the manufacturing of a high reinforcement volume fraction....
Furan/maleimide dynamic covalent chemistry has been extensively used to fabricate re-workable and self-healing thermosets. Understanding the relationship between crosslinker structure, network dynamics, and material final properties, however, remains...
The three-dimensional (3D) printing of a SiO2-filled thermosetting polyimide (SiO2@TSPI) composite with outstanding performance is realized via the direct ink writing (DIW) of polyamide acid (PAA) composite ink and thermal treatment conducted thereaf...
This study focuses first on the synthesis through an aza-Michael addition reaction of original linear diamine prepolymers and original amine/acrylate thermoset adhesives, and second on their thermal, mechanical and adhesion characterization. The majo...
This paper investigated the upcycling process of thermoplastic waste polystyrene (WPS) into thermosetting particleboard adhesive using two cross-linkers, namely methylene diphenyl diisocyanate (MDI) and maleic anhydride (MA). The WPS was dissolved in...
Considering the demand for the construction of a sustainable future, it is essential to endow the conventional thermoset silicone adhesive with reuse capability and recyclability. Although various research attempts have been made by incorporating rev...
The 50th annual conference of the North American Thermal Analysis Society is being held jointly with the 8th Baekeland Symposium to bring those communities together. NATAS offers scientists and practitioners the opportunity to explore the frontiers o...
The trend towards the utilization of bioresources for the manufacturing of polymers has led industry players to bring to the market new monomers. In this work, we studied 3 polyisocyanates and 2 polyols with high renewable carbon contents, namely L-l...
In recent work, the thermoreversible Diels–Alder reaction between furan and maleimide functional groups has been studied extensively in the context of self-healing elastomers and thermosets. To elaborate the influence of the stoichiometric ratio betw...
The need for sustainable practices in the processing chain of fiber-reinforced thermosets has led to the development of bio-based epoxy resins and curing agents. As a contribution to sustainable composites, this study focuses on the glass transition...
Thermosetting resins have good temperature resistance and high strength and have been widely used as plugging agents in oil fields. However, the current resin materials have high costs, and unmodified thermosetting resins are brittle or have deterior...
The North American Thermal Analysis Society (NATAS) is pleased to announce its 51st Annual Conference, held jointly with the IX International Baekeland Symposium. This premier event unites scientists, practitioners, and students from academia, indust...
Polymers crosslinked via furan/maleimide thermo-reversible chemistry have been extensively explored as reprocessable and self-healing thermosets and elastomers. For such applications, it is important that the thermo-reversible features are reproducib...
The article presents the results of modeling various modes of vacuum infusion molding of thin-walled polymer-composite structures of arbitrary geometry. The small thickness of the manufactured structures and the fixation of their back surface on the...
Despite the growing global interest in 3D printed carbon fiber reinforced polymers, most of the applications are still limited to high-performance sectors due to the low effectiveness–cost ratio of virgin carbon fibers. However, the use of recycled c...
Polyurethanes are gaining increasing interest for their use as structural components subjected to cyclic loads, such as leaf springs. Thermoset polyurethane (PUR) based technology offers some advantages, such as fatigue resistance, low viscosity, and...
When processing particular polymers, it may be necessary to increase the molecular weight, for example, during polymer recycling or foaming. Chemical additives such as chain extenders (CE) are often used to build up the molecular weight during reacti...
Thermoset-based polymer composites containing functional fillers are promising materials for a variety of applications, such as in the aerospace and medical fields. However, the resin viscosity is often unsuitably high and thus impedes a successful f...
This study describes the production of a new biobased epoxy thermoset and its use with long hemp fibres to produce high-performance composites that are totally biobased. The synthesis of BioIgenox, an epoxy resin derived from a lignin biorefinery, an...
This study provides a comprehensive quantitative comparison of three structurally distinct epoxy prepolymers—cycloaliphatic, novolac, and bis-aromatic (BADGE)—cured with a single hardener, methyl nadic anhydride (MNA), and catalyzed by 1-...