Search Results (3,086)

This study systematically investigates the microstructural evolution and mechanical properties of GH2787 superalloy following solution treatment at 1140 °C and subsequent aging within the temperature range of 770 °C to 920 °C. The results indicate that aging at 770 °C and 820 °C promotes the precipitation of a high density of finely dispersed γ′ precipitates with minimal interparticle spacing. In contrast, a significant coarsening of the γ′ particles, accompanied by a sparse distribution and a notable increase in interparticle spacing, was observed at the higher aging temperatures of 870 °C and 920 °C. Mechanical characterization reveals that the ultimate tensile strength (UTS) and yield strength (YS) experienced a moderate decrease as the aging temperature increased from 770 °C to 820 °C, followed by a pronounced drop at 870 °C and 920 °C. Conversely, the impact toughness exhibited a non-monotonic trend: it gradually decreased, reaching a minimum at 820 °C, before rapidly increasing with further rises in aging temperature. Quantitative analysis of the strengthening contributions demonstrates that solid-solution and precipitation strengthening are the dominant mechanisms. The marked decline in yield strength at elevated aging temperatures is primarily attributed to the diminished precipitation strengthening effect due to γ′ coarsening. Furthermore, the variation in impact toughness can be linked to the proportion and size of dimples observed on the fracture surfaces, indicating a transition in the fracture mechanism driven by microstructural evolution. Full article

This experimental study comparatively investigates flow boiling performance and mechanisms in open and closed rectangular microchannels (ORMs/CRMs) with a high aspect ratio of 4. Fabricated on a copper substrate and sealed with a transparent window for visualization, the systems were tested using refrigerant R245fa. Experiments spanned mass fluxes from 89 to 545 kg/m²·s and heat fluxes from 6.3 to 218.5 W/cm² at an inlet temperature of 14 °C. Flow visualization reveals that the ORM configuration accelerates the transition from bubbly to slug and churn flow regimes and facilitates a unique stratified flow pattern absent in the CRM. Quantitatively, the ORM enhances the heat transfer coefficient by 4.2–14.1% while reducing the system pressure drop by 11.5–58.6% within the low mass flux range (89–269 kg/m²·s). Conversely, at a high mass flux of 545 kg/m²·s, the ORM’s pressure drop increases substantially by 29.9–246.8%, attributed to significant two-phase losses in the top-gap region. As heat flux increases, inertial forces dominate over gravitational effects, shifting the primary heat transfer contribution from nucleate to flow boiling. The figure of merit (FOM) confirms the overall performance superiority of the ORM at low mass fluxes. This work provides valuable insights and design guidelines for high-performance, high-aspect-ratio microchannel heat sinks in advanced thermal management systems. Full article

Clonal propagation often must incorporate heaters to warm stock plants and stabilize growth. This study investigates the impact that different temperature regimes for stock plants have on the rooting capacity of mini-cuttings derived therefrom. Experiments were conducted in growth chambers using two clones of Eucalyptus dunnii Maiden, with clone A’s rooting being moderately better that that of clone B in commercial production. Root primordia differentiation and elongation were faster in clone A than clone B. Stock plants were maintained for one month under two temperature conditions: Δ0 (26/26 °C day/night) and Δ10 (26/16 °C). The main results indicate that rooting significantly decreased with the reduction in nocturnal temperature. Clone A exhibited a 38% reduction in rooting, whereas clone B showed a more pronounced decrease of 65%. In cold nights, soluble carbohydrates at the cutting bases dropped by approximately 25% considering both clones, and overall foliar nutrients also decreased. Cutting base transcript profiles revealed that cold nights decreased the expression of efflux auxin transporter PIN1, increased expression of auxin catabolism-related enzyme DAO, and that expression of auxin nuclear receptor TIR1 remained stable. Fine management of clonal gardens by adjusting thermal conditions can optimize the physiological status of donor plants and enhance the rooting potential and establishment of the derived cuttings. Full article

This study investigated the effect of fermentation time (24 and 48 h) on the pH, titratable acidity (TTA), phytochemicals, antioxidants, phenolic compounds, colour, functional, pasting, and thermal properties of flours from selected legumes (mung beans, haricot beans, butter beans, and black beans). The pH dropped significantly (p ≤ 0.05) after 48 h (6.61–4.91) of fermentation, with a corresponding increase in TTA, which ranged from 0.3 to 1.28 g lactic acid/100 g sample. Colour analysis showed that fermentation caused a decrease in L* values (2.97–23.86% reduction), with the highest reduction observed in black bean flour (23.86% at 24 h), along with an increase in the browning index. The total phenolic content increased significantly (p ≤ 0.05) in all the samples, with the most pronounced increase observed in mung bean 24 h (6.85 mg GAE/g). Similarly, the values for total flavonoid increased from 2.26 to 6.48 mg QE/g, and antioxidant activities such as DPPH ranged from 45.04 to 74.51%, FRAP from 1.65 to 8.03 Mm TE/g, and ABTS from 60.86 to 90.01%. Ultra-high performance liquid chromatography–photodiode array quantification of the targeted phenolic compounds showed a significant increase, with the highest notable increase for trans-ferulic acid in mung bean (330% after 48 h). Water absorption capacity generally showed an increase, whereas bulk density ranged from 0.55 to 0.91 g/cm³ and decreased in all legumes. There were differences in the pasting properties of the selected legumes. The peak time of unfermented butter bean was 33.08 min and remained constant at 33.15 min at 24 and 48 h of fermentation. Thermal analysis indicated the alteration of gelatinization parameters, with a decrease in peak temperature, whereas higher gelatinization enthalpy was observed. Findings from this study show that fermentation with the starter cultures can significantly improve the bioactive compound and functional properties of legume flours and thus act as potential ingredients in functional food development. Full article

This paper presents a pressure-driven liquid transfer system for laboratory automation, along with a physics-based model and calibration method. The device maintains near-isothermal transport by storing reagents at a prescribed temperature and routing the flow through a single PTFE tube enclosed within a heated jacket. The pressure-drop model accounts for temperature-dependent viscosity and the thermal expansion of PTFE. Residual deviations from the no-slip prediction in submillimeter tubing are represented by an effective slip length, which is identified through linear regression. This parameter is subsequently used to calculate the pressure required to achieve a target flow rate. Experimental results compare unheated and heated operating conditions and characterize the dependence of slip length on temperature and flow rate. Under heated operation with slip-compensated pressure commands, the system achieved dispensing accuracy within $\pm 4\%$ over the tested range, whereas unheated operation exhibited larger errors due to axial temperature gradients. These results demonstrate that effective thermal management and slip compensation are critical for accurate pressure-based metering under temperature-sensitive conditions, as validated using water-based tests. Full article

In the current climate change context and the potential to extend exotic crops in Romania, sweet potato could become an option for extensive areas with optimum ecophysiological conditions to provide economic and ecological benefits and assure food security. This study aimed to validate the suitability, photosynthetic performance, yield productivity, and sugar content of three sweet potato cultivars, KSC, Koretta, and Hayanmi, in Central Romania. Three key phenophases were selected: the beginning of flowering (P1), 50% tuber formation/full flowering (P2), and total tuber formation/leaves and stems bleached and dry (P3), respectively. At the beginning of flowering, extreme heat and moisture stress showed a reduced effect on the sweet potato development and photosynthetic parameters. The only exception was the assimilation rate for Hayanmi, which was markedly lower, with the highest relative chlorophyll content and leaf dry biomass. Koretta registered increased values for stomatal features. A higher tuber weight was registered for Hayanmi in P2 due to slightly increased rainfall and elevated evapotranspiration. In P3, the temperatures dropped sharply, rainfall exceeded evapotranspiration, and KSC accumulated a seven times higher value for tuber weight. The total biomass was 2–3 times higher for KSC in P3. Sugar content was negatively correlated with tuber weight, and Hayanmi had 1% higher values compared with KSC and Koretta. Sweet potato showed a variety-specific response to ecophysiological conditions, and for each variety, these physiological features suggest potential advantages for different cropping scenarios. Full article

In this study, we have investigated heterostructural TiO₂/BiVO₄ anodes to determine the effect of the amount and form of BiVO₄ nanoparticles on TiO₂ on the response of photoanodes under UV and visible illumination. BiVO₄ nanopowders were prepared and annealed at temperatures ranging from 200 to 500 °C. Structural and optical characterization indicates that as the annealing temperature is increased, a phase transition from a weakly ordered to a dominant monoclinic BiVO₄ phase is observed, which is accompanied by an increase in visible light absorption. Subsequently, the most crystalline powder was utilized to deposit BiVO₄ on nanostructured TiO₂ either as a compact overlayer (drop-casting) or as a progressively grown nanoparticle (TiO₂@S series) in the successive ionic layer adsorption and reaction process (SILAR). Photoelectrochemical measurements were performed, revealing a morphology-dependent photocurrent response under UV and visible illumination. A further increase in the number of cycles systematically increases the photocurrent in the visible light range while limiting the response to UV radiation. The TiO₂@d photoanode demonstrates the highest relative activity within the visible range; however, it also generates the lowest absolute photocurrent, indicating the presence of significant transport and recombination losses within the thick BiVO₄ layer. The results demonstrate that the presence of BiVO₄ nanoparticles on TiO₂ exerts a substantial influence on the separation of charge between semiconductors and the synergistic utilization of photons from the UV and visible ranges. This research yielded a proposed scheme of mutual band arrangement and charge carrier transfer mechanism in TiO₂@BiVO₄ heterostructures. Full article

With the industry development of sea cucumber Apostichopus japonicus aquaculture, the indoor high cost and low survival rate have become serious problems. Therefore, it is necessary to optimize substrate selection for seedling protection in outdoor pond net cages. This study explores the succession of periphyton on the different substrate surface types, including a curvimurate net (CU), nylon mesh (NM), and ground cages (including a ground cage net (CN) and ground cage plate (CP)), and their effects on the seedling protection of sea cucumbers. In addition, we monitored the substrates’ dry weight, chlorophyll-a, and the community composition of substrates, alongside seedling growth, yield, and survival rate. The results show that a total of 7 phyla, 23 genera, and 31 species were detected on the substrates, with diatoms dominating (19 species) and Chlorophyta (4 species) being the main species. The CU had the highest total number of alga species attached, significantly higher than the other substrates in week 13 (p < 0.05). In week 9, the diatom density dropped to its lowest point, and, after September, it rose with the decrease in water temperature. In terms of dry weight with and without ash, CP increased rapidly in the early stage, with NM, CU, and CP being significantly higher than CN in week 13 (p < 0.05). The chlorophyll-a content showed a decreasing–increasing–decreasing trend, with CU reaching 3.62 ± 0.48 μg/cm² in the 13th week, significantly higher than other substrates (p < 0.05). Finally, the A. japonicus survival rate and yield in the CU group at week 12 were significantly higher than those in the NM and ground cage groups (p < 0.05). At week 17, the average weight, yield, and survival rate in the CU group were still optimal, with the yield 5.76 times that in the initial dosage. These results suggest that the CU has a suitable mesh size, has good permeability, and may stably support sediment, which is conducive to the growth of benthic diatoms. In addition, it can provide sufficient natural feed and a good habitat environment and is the preferred substrate for A. japonicus seedling protection in outdoor pond net cages. Full article

Thermochromic VO₂ crystalline domains have been formed in amorphous nanocolumnar VO_x films by means of a low-temperature oxidation process. The oxidation of an amorphous film with [O]/[V] below 1.9 favors the formation of VO₂, V₃O₇, and V₂O₅ crystalline domains in the material for temperatures as low as 260 °C, while values above 1.9 lead to the sole formation of the V₂O₅ phase. It is found that the absorption of oxygen also causes a relevant film volume expansion that makes pores shrink. Under some specific conditions, low-temperature oxidation causes the near disappearance of the amorphous regions, clearly improving the overall transparency and optimizing the optical and electrical modulation capabilities associated with the presence of crystalline VO₂ domains. The best thermochromic performance was found when the original stoichiometry was [O]/[V] = 1.5 and the oxidation temperature was 280 °C. These conditions yield a relatively transparent coating in the visible range that presents an optical modulation in the near-infrared range of nearly 50% and a drop of electrical resistivity of more than two orders of magnitude, with a transition temperature of 50.3 °C. A tentative model based on the volume expansion experienced by the film upon oxidation is proposed, which links the structural/chemical features of the material and the formation of the crystalline domains at such relatively low temperatures. Full article

As a reliable peak-shaving power source, coal-fired boilers’ flexible operation technology has become a key support for achieving the low-carbon transition. To enhance the peak-shaving capacity of the boiler, it is urgent to explore the transient mechanisms of flow, combustion, and heat transfer under dynamic conditions. In this study, the heat transfer characteristics of the burner under varying load conditions and the combustion characteristics in boilers under low and dynamic load conditions are investigated by CFD numerical simulation technology based on a 10 MW coal-fired test bench. The results indicate that at load rates of 2%/min and 4%/min, heat flux density remains mostly consistent across the upper wall of the furnace. At 6%/min, the heat flux near dense pulverized coal flow exceeds that near fresh coal flow. At 60% load, the flow fields are symmetrical, optimizing flame filling and distribution. As the load drops to 40%, the upper flow field begins to distort, and by 20% load, turbulence and uneven temperature distribution arise. At 20% load, the one-layer burner demonstrates superior flow field stabilization compared to the two-layer configuration, with particle concentration remaining lower near the wall above the burner but higher in the cold ash hopper, while high-temperature zones predominantly concentrate in the furnace center with minimal areas exceeding 1900 K. A boiler designed for concentration separation enhances airflow and decreases wall particle concentration at 20% load, resulting in a more uniform temperature distribution with high-temperature zones further from the walls. Full article

Twenty years of MODIS satellite data (2002–2022), TROPOMI glyoxal observations (2018–2022), and ground-based isoprene measurements were used to examine vegetation greenness (NDVI) and atmospheric glyoxal over Houston, Texas. Biogenically produced glyoxal grew by 51% between 2018 and 2022, despite a 2% per decade decrease in summer vegetation greenness and continued urbanization. Ambient mixing ratios of isoprene, the main biogenic glyoxal precursor, paradoxically dropped by 14% within the same time frame. Temperature (+0.68 °C/year), ozone (+28%), and photochemical oxidants all significantly increased over this time, according to analysis of concurrent environmental data. The results indicate that higher temperature-driven isoprene emissions (+35%) and accelerated photochemical oxidation (+10%) overcame the declining vegetation signal, resulting in net increases in atmospheric glyoxal. This suggests that Houston’s remaining flora is experiencing temperature-driven changes in biogenic volatile organic compound (VOC) emissions per unit area, even while its greenness has reduced. Full article

Fermented forest litter (FFL) is a biofertilizer obtained by anaerobic fermentation of forest litter combined with agricultural by-products. Its production involves an initial one-month solid-state fermentation of oak litter mixed with whey, molasses and wheat bran, followed by a one-week submerged fermentation-called the “activation” phase-during which the solid FFL is fermented with sugarcane molasses diluted in water. This study aimed to evaluate the effects storage duration (6, 18 and 30 months), and temperature (ambient and 29 °C) on the activation phase. For this purpose, pH, sugar consumption and metabolite production dynamics were monitored. Under all experimental conditions, the pH dropped to values close to 3.5, sucrose was rapidly hydrolyzed, and glucose was preferentially consumed over fructose. Fructose was metabolized only after glucose was depleted, suggesting the involvement of fructophilic microorganisms. The time-course evolution of lactic acid (LA) concentration was adequately fitted by the Gompertz model (R² > 0.970). The highest LA_max concentration (6.30 g/L) and production rate (2.16 g/L·d) were obtained with FFL stored for 6 months. Acetic acid (AA) and ethanol were also detected reaching maxima values of 1.19 g/L and 0.96 g/L, respectively. Their profiles varied depending on the experimental conditions. Notably, the AA/LA ratio increased with the age of the FFL. Overall, sugar consumption and metabolite production were significantly slower at ambient temperature, than at 29 °C. These results contribute to a better understanding of the metabolic dynamics during FFL activation and highlight key parameters that should be considered to optimize future biofertilizer production processes. Full article

Freezing and thawing affect the structural integrity and quality of meat, yet these processes remain difficult to monitor due to spatial temperature gradients and non-uniform phase transitions. This study investigates the ability of ultrasound to detect dynamic freezing and thawing events in pork tissues with different fat contents. Specimens of water, lean meat, marbled meat, layered lean–fat structures, and lard were subjected to controlled freeze–thaw cycles while ultrasonic signals and internal temperatures were continuously monitored. Consistent amplitude drops in the megahertz range at entering the freezing phase formed characteristic signal patterns that differed sharply between lean and fatty tissues. Lean meat, dominated by water content, exhibited rapid signal loss at the onset of ice crystallization and a clear recovery of amplitude once fully frozen. Fat-rich tissues demonstrated prolonged attenuation and near disappearance of high-frequency signals, with incomplete recovery even at deep-frozen states. A jump of ultrasound velocity from 1.4–1.6 km/s in a warm state to 2.6–3.7 km/s in a frozen state indicated complete freezing. Hysteresis between temperature readings and actual phase transition moments was found. Distinct ultrasonic freeze–thaw signatures reflecting tissue composition suggest a novel approach for monitoring the true onset and completion of freezing and thawing in meat. Full article

In Proton Exchange Membrane Water Electrolysis (PEMWE), the two-phase flow distribution in the anode field significantly affects overall electrolysis performance. Based on visualized experimental data, in this paper, the reaction kinetics equations were theoretically revised, and a three-dimensional, two-phase, non-isothermal, multi-physics coupled model of the electrolysis was developed and experimentally validated. Four different configurations of rectangular turbulence promoters were designed within the anode serpentine flow field and compared with a conventional serpentine flow field (SFF) in terms of their multi-physics distribution characteristics. The results showed that, in the double-row rectangular block serpentine flow field (DRB SFF), the uniformity of liquid water saturation, temperature, and current density improved by 16.6%, 0.49% and 40.8%, respectively. The normal mass transfer coefficient increased by a factor of 6.3, and polarization performance improved by 6.98%. A cross-arranged turbulence promoter structure was further proposed. This design maintains effective turbulence while reducing flow resistance and pressure drop, thereby enhancing mass transfer efficiency and overall electrolysis performance through improved bubble fragmentation. Full article

Interactions between surface water and groundwater in arid regions regulate their response to climate and human impacts. In the salar systems of the Altiplano-Puna plateau (Bolivia, Chile, Argentina), understanding how surface waters connect to groundwater is crucial for accurate modeling and assessment. This study introduces new data and analysis using subsurface thermal profiles and modeling to identify flow patterns and possible surface water links. We document, to our knowledge, for the first time in the literature, deep-seated cooling of the subsurface caused by extreme evaporation rates. The subsurface is cooled by 4–5 degrees Celsius below the mean annual air temperature to depths greater than 50 m, even though groundwater inflow waters are elevated by 10 degrees °C due to geothermal heating. Three thermal zones are observed along the southern edge of Salar de Atacama, with temperature dropping from 28 °C to about 12 °C over 2.5 km. A 2D numerical model of groundwater and heat flow was developed to test various hydrological scenarios and understand the factors controlling the thermal regime. Two flow scenarios at the southern margin were examined: a diffuse flow model with uniform flow and flux to the surface and a focused flow model with preferential discharge at a topographic slope break. Results indicate that the focused flow scenario matches thermal data, with warm inflow water discharging into a transition zone between freshwater and brine, cooling through evaporation, re-infiltration, and surface flow, then re-emerging near lagoons at the halite nucleus margin. This research offers valuable insights into the groundwater hydraulics in the Salar de Atacama and can aid in monitoring environmental changes causally linked to lithium mining and upgradient freshwater extraction. Full article