Search Results (1,681)

Polyoxometalate (POM)-type supramolecular materials have unique structures and hold immense potential for development in the fields of biomedicine, information storage, and electrocatalysis. In this study, (NH₄)₃ [AlMo₆O₂₄H₆]·7H₂O was employed as a polyacid anion template, pentacyclic imidazole molecules served as organic ligands, and the moderate-temperature hydrothermal and natural evaporation methods were used in combination for the design and synthesis of two octamolybdenum-oxo cluster (homopolyacids containing molybdenum-oxygen structures as the main small-molecular structures)-based organic–inorganic hybrid compounds, [(C₃N₂H₅)(C₃N₂H₄)][(β-Mo₈O₂₆H₂)]_0.5 (1) and {Zn(C₃N₂H₄)₄}{[(γ-Mo₈O₂₆)(C₃N₂H₄)₂]_0.5}·2H₂O (2). Structural and property characterization revealed that both compounds crystallized in the P-1 space group with relatively stable three-dimensional structures under the action of hydrogen bonding. Upon temperature stimulation, the [Zn(C₃N₂H₄)₄]²⁺ cation and water molecules in 2 exhibited obvious oscillations, leading to significant dielectric anomalies at approximately 250 and 260 K when dielectric testing was conducted under heating conditions. Full article

Under global warming, persistent extreme heat events (PHEs) in China have increased significantly in both frequency and intensity, posing severe threats to agriculture and socioeconomic development. Combining observational analysis (1961–2019) and numerical simulations, this study investigates the distinct impacts of Northwest Pacific (NWP) and North Atlantic (NA) sea surface temperature (SST) anomalies on PHEs over China. Key findings include the following: (1) PHEs exhibit heterogeneous spatial distribution, with the Yangtze-Huai River Valley as the hotspot showing the highest frequency and intensity. A regime shift occurred post-2000, marked by a threefold increase in extreme indices (+3σ to +4σ). (2) Observational analyses reveal significant but independent correlations between PHEs and SST anomalies in the tropical NWP and mid-high latitude NA. (3) Numerical experiments demonstrate that NWP warming triggers a meridional dipole response (warming in southern China vs. cooling in the north) via the Pacific–Japan teleconnection pattern, characterized by an eastward-retreated and southward-shifted sub-tropical high (WPSH) coupled with an intensified South Asian High (SAH). In contrast, NA warming induces uniform warming across eastern China through a Eurasian Rossby wave train that modulates the WPSH northward. (4) Thermodynamically, NWP forcing dominates via asymmetric vertical motion and advection processes, while NA forcing primarily enhances large-scale subsidence and shortwave radiation. This study elucidates region-specific oceanic drivers of extreme heat, advancing mechanistic understanding for improved heatwave predictability. Full article

In order to provide a theoretical basis for the thermal analysis and management of spacecraft/payload interstellar pointing attitudes, which are used for inter-satellite communication, this paper develops an analytical method for solar heat flux under pointing attitudes. The key to solving solar heat flux is calculating the angle between the sun vector and the normal vector of the object surface. Therefore, a method for calculating the included angle is proposed. Firstly, a coordinate system was constructed based on the pointing attitude. Secondly, the angle between the coordinate axis vector and solar vector variation with a true anomaly was calculated. Finally, the reaching direct solar heat flux was obtained using an analytical method or commercial software. Based on the proposed method, the direct solar heat flux of relay satellites in commonly used lunar orbits, including Halo orbits and highly elliptic orbits, was calculated. Thermal analysis on the payload of interstellar laser communication was also conducted in this paper. The calculated temperatures of each mirror ranged from 16.6 °C to 21.2 °C. The highest temperature of the sensor was 20.9 °C, with a 2.3 °C difference from the in-orbit data. The results indicate that the external heat flux analysis method proposed in this article is realistic and reasonable. Full article

In recent years, China has experienced growing impacts from extreme weather events, emphasizing the importance of understanding regional atmospheric moisture dynamics, particularly Precipitable Water Vapor (PWV), to support sustainable environmental and urban planning. This study utilizes ten years (2013–2022) of Global Navigation Satellite System (GNSS) observations in typical cities in eastern China and proposes a comprehensive multiscale frequency-domain analysis framework that integrates the Fourier transform, Bayesian spectral estimation, and wavelet decomposition to extract the dominant PWV periodicities. Time-series analysis reveals an overall increasing trend in PWV across most regions, with notably declining trends in Beijing, Wuhan, and southern Taiwan, primarily attributed to groundwater depletion, rapid urban expansion, and ENSO-related anomalies, respectively. Frequency-domain results indicate distinct latitudinal and coastal–inland differences in the PWV periodicities. Inland stations (Beijing, Changchun, and Wuhan) display annual signals alongside weaker semi-annual components, while coastal stations (Shanghai, Kinmen County, Hong Kong, and Taiwan) mainly exhibit annual cycles. High-latitude stations show stronger seasonal and monthly fluctuations, mid-latitude stations present moderate-scale changes, and low-latitude regions display more diverse medium- and short-term fluctuations. In the short-term frequency domain, GNSS stations in most regions demonstrate significant PWV periodic variations over 0.5 days, 1 day, or both timescales, except for Changchun, where weak diurnal patterns are attributed to local topography and reduced solar radiation. Furthermore, ERA5-derived vertical temperature profiles are incorporated to reveal the thermodynamic mechanisms driving these variations, underscoring region-specific controls on surface evaporation and atmospheric moisture capacity. These findings offer novel insights into how human-induced environmental changes modulate the behavior of atmospheric water vapor. Full article

Digital Twins (DTs) are transforming manufacturing by bridging the physical and digital worlds, enabling real-time insights, predictive analytics, and enhanced decision making. In Industry 4.0, DTs facilitate automation and data integration, while Industry 5.0 emphasizes human-centric, resilient, and sustainable production. However, implementing DTs in robotic metal additive manufacturing (AM) remains challenging because of the complexity of the wire-based laser metal deposition (LMD) process, the need for real-time monitoring, and the demand for advanced defect detection to ensure high-quality prints. This work proposes a structured DT architecture for a robotic wire-based LMD cell, following a standard framework. Three DT implementations were developed. First, a real-time 3D simulation in RoboDK, integrated with a 2D Node-RED dashboard, enabled motion validation and live process monitoring via MQTT (message queuing telemetry transport) telemetry, minimizing toolpath errors and collisions. Second, an Industrial IoT-based system using KUKA iiQoT (Industrial Internet of Things Quality of Things) facilitated predictive maintenance by analyzing motor loads, joint temperatures, and energy consumption, allowing early anomaly detection and reducing unplanned downtime. Third, the Meltio dashboard provided real-time insights into the laser temperature, wire tension, and deposition accuracy, ensuring adaptive control based on live telemetry. Additionally, a prescriptive analytics layer leveraging historical data in FireStore was integrated to optimize the process performance, enabling data-driven decision making. Full article

The Qiubudong silver deposit on the western margin of the Fuping ore cluster in the central North China Craton is a representative breccia-type deposit characterized by relatively high-grade ores, thick mineralized zones, and extensive alteration, indicating considerable potential for economic resource development and further exploration. Previous studies on this deposit have not addressed its genetic mineralogical characteristics. This study focuses on pyrite and quartz to investigate their typomorphic features, such as crystal morphology, trace element composition, thermoelectric properties, and luminescence characteristics, and their implications for ore-forming processes. Pyrite crystals are predominantly cubic in early stages, while pentagonal dodecahedral and cubic–dodecahedral combinations peak during the main mineralization stage. The pyrite is sulfur-deficient and iron-rich, enriched in Au, and relatively high in Ag, Cu, Pb, and Bi contents during the main ore-forming stage. Rare earth element (REE) concentrations are low, with weak LREE-HREE fractionation and a strong negative Eu anomaly. The thermoelectric coefficient of pyrite ranges from −328.9 to +335.6 μV/°C, with a mean of +197.63 μV/°C; P-type conduction dominates, with an occurrence rate of 58%–100% and an average of 88.78%. A weak–low temperature and a strong–high temperature peak characterize quartz thermoluminescence during the main mineralization stage. Fluid inclusions in quartz include liquid-rich, vapor-rich, and two-phase types, with salinities ranging from 10.11% to 12.62% NaCl equiv. (average 11.16%) and densities from 0.91 to 0.95 g/cm³ (average 0.90 g/cm³). The ore-forming fluids are interpreted as F-rich, low-salinity, low-density hydrothermal fluids of volcanic origin at medium–low temperatures. The abundance of pentagonal dodecahedral pyrite, low Co/Ni ratios, high Cu contents, and complex quartz thermoluminescence signatures are key mineralogical indicators for deep prospecting. Combined with thermoelectric data and morphological analysis, the depth interval around 800 m between drill holes ZK3204 and ZK3201 has high mineralization potential. This study fills a research gap on the genetic mineralogy of the Qiubudong deposit and provides a scientific basis for deep exploration. Full article

The Moxi area in the Sichuan Basin hosts abundant deep geothermal resources, but their thermal regime and accumulation mechanisms remain poorly understood. Using 2D/3D seismic data, drilling records, and temperature measurements (DST), we analyze deep thermal fields, reservoir–caprock systems, and structural features. The following are our key findings: (1) Heat transfer is conduction-dominated, with thermal anomalies in Late Permian–Early Cambrian strata. Four mudstone/shale caprocks and three carbonate reservoirs occur, with the Longtan Formation as the key seal. Reservoir geothermal gradients (25.05–32.55 °C/km) exceed basin averages. (2) Transtensional strike-slip faults form E-W/NE/NW networks; most terminate at the Permian Longtan Formation, with few extending into the Lower Triassic while penetrating the Archean–Lower Proterozoic basement. (3) Structural highs positively correlate with higher geothermal gradients. (4) The deep geothermal reservoirs and thermal accumulation mechanisms in the Moxi area are jointly controlled by crustal thinning, basement uplift, and structural architecture. Mantle-derived heat converges at basement uplift cores, generating localized thermal anomalies. Fault networks connect these deep heat sources, facilitating upward fluid migration. Thick Longtan Formation shale seals these rising thermal fluids, causing anomalous heating in underlying strata and concentrated thermal accumulation in reservoirs—enhanced by thermal focusing effects from uplift structures. This study establishes a theoretical framework for target selection and industrial-scale geothermal exploitation in sedimentary basins, highlighting the potential for repurposing oil/gas infrastructure. Full article

Industrial maintenance has shifted from reactive repairs and calendar-based servicing toward data-driven predictive strategies. This paper presents a non-intrusive, low-cost IoT hardware platform for sustainable predictive maintenance of rotating machinery. The system integrates an ESP32-S3 sensor node that captures vibration (100 kHz) and temperature data, performs local logging, and communicates wirelessly. An automated spectral band segmentation framework is introduced, comparing equal-energy, linear-width, nonlinear, clustering, and peak–valley partitioning methods, followed by a weighted feature scheme that emphasizes high-value bands. Three unsupervised one-class classifiers—transformer autoencoders, GANomaly, and Isolation Forest—are evaluated on these weighted spectral features. Experiments conducted on a custom pump test bench with controlled anomaly severities demonstrate strong anomaly classification performance across multiple configurations, supported by detailed threshold-characterization metrics. Among 150 model–segmentation configurations, 25 achieved perfect classification (100% precision, recall, and F1 score) with ROC-AUC = 1.0, 43 configurations achieved ≥90% accuracy, and the lowest-performing setup maintained 81.8% accuracy. The proposed end-to-end solution reduces the downtime, lowers maintenance costs, and extends the asset life, offering a scalable, predictive maintenance approach for diverse industrial settings. Full article

Oceanic mesoscale activity influences the atmosphere in the southwestern and southern sectors of the Atlantic Ocean. However, the influence of high latitudes, specifically sea ice, on mid-latitudes and a better understanding of mesoscale ocean–atmosphere thermodynamic interactions still require further study. To quantify the effects of oceanic mesoscale activity during the periods of maximum and minimum Antarctic sea ice extent (September 2019 and February 2020), numerical experiments were conducted using a coupled regional model and an online two-dimensional spatial filter to remove high-frequency sea surface temperature (SST) oscillations. The largest SST anomalies were observed in the Brazil–Malvinas Confluence and along oceanic fronts in September, with maximum SST anomalies reaching 4.23 °C and −3.71 °C. In February, the anomalies were 2.18 °C and −3.06 °C. The influence of oceanic mesoscale activity was evident in surface atmospheric variables, with larger anomalies also observed in September. This influence led to changes in the vertical structure of the atmosphere, affecting the development of the marine atmospheric boundary layer (MABL) and influencing the free atmosphere above the MABL. Modulations in precipitation patterns were observed, not only in oceanic regions, but also in adjacent continental areas. This research provides a novel perspective on ocean–atmosphere thermodynamic coupling, highlighting the mesoscale role and importance of its representation in the study region. Full article

Marine heatwaves (MHWs) and Marine cold spells (MCSs) are oceanic events characterized by prolonged periods of anomalously warm or cold sea surface temperatures, which pose significant ecological and socio-economic threats on a global scale. These extreme temperature events exhibit an asymmetric trend under ongoing climate change in recent decades: MHWs have increased markedly in both frequency and intensity, whereas MCSs have shown an overall decline. Among the potential drivers, mesoscale eddies play a critical role in modulating sea surface temperature anomalies (SSTAs). Anticyclonic eddies (AEs) promote downwelling, generating positive SSTAs that potentially favor MHWs, while cyclonic eddies (CEs) enhance upwelling and negative anomalies that are potentially related to MCSs. In this paper, we investigate the relationship between mesoscale eddies and MHWs/MCSs using global satellite-derived datasets from 2010 to 2019. By analyzing the spatial overlap and intensity correlation between eddies and MHWs/MCSs, it is found that 12.2% of MHWs are accompanied by AEs, and 13.4% of MCSs by CEs, with a high degree of spatial containment where approximately 90.2% of MHW events are found within the mean eddy contour of AEs, and about 93.1% of MCS events fall inside the mean eddy contour of CEs. Stronger eddies tend to be associated with more intense MHWs/MCSs. This study provides new insights into the role of mesoscale eddies in regulating extreme oceanic temperature events, offering valuable information for future predictions in the context of climate change. Full article

Solar power generation is rapidly emerging within renewable energy due to its cost-effectiveness and ease of deployment. However, improper inspection and maintenance lead to significant damage from unnoticed solar hotspots. Even with inspections, factors like shadows, dust, and shading cause localized heat, mimicking hotspot behavior. This study emphasizes interpretability and efficiency, identifying key predictive features through feature-level and What-if Analysis. It evaluates model training and inference times to assess effectiveness in resource-limited environments, aiming to balance accuracy, generalization, and efficiency. Using Unmanned Aerial Vehicle (UAV)-acquired thermal images from five datasets, the study compares five Machine Learning (ML) models and five Deep Learning (DL) models. Explainable AI (XAI) techniques guide the analysis, with a particular focus on MPEG (Moving Picture Experts Group)-7 features for hotspot discrimination, supported by statistical validation. Medium Gaussian SVM achieved the best trade-off, with 99.3% accuracy and 18 s inference time. Feature analysis revealed blue chrominance as a strong early indicator of hotspot detection. Statistical validation across datasets confirmed the discriminative strength of MPEG-7 features. This study revisits the assumption that DL models are inherently superior, presenting an interpretable alternative for hotspot detection; highlighting the potential impact of domain mismatch. Model-level insight shows that both absolute and relative temperature variations are important in solar panel inspections. The relative decrease in “blueness” provides a crucial early indication of faults, especially in low-contrast thermal images where distinguishing normal warm areas from actual hotspot is difficult. Feature-level insight highlights how subtle changes in color composition, particularly reductions in blue components, serve as early indicators of developing anomalies. Full article

Snow water equivalent (SWE), an essential parameter of snow, is largely studied to understand the impact of climate regime effects on snowmelt patterns. This study developed a Siamese Attention U-Net (Si-Att-UNet) model to detect daily change events in the winter season. The daily SWE change event detection task is treated as an image content comparison problem in which the Si-Att-UNet compares a pair of SWE maps sampled at two temporal windows. The model detected SWE similarity and dissimilarity with an F1 score of 99.3% at a 50% confidence threshold. The change events were derived from the model’s prediction of SWE similarity using the 50% threshold. Daily SWE change events increased between 1979 and 2018. However, the SWE change events were significant in March and April, with a positive Mann–Kendall test statistic (tau = 0.25 and 0.38, respectively). The highest frequency of zero-change events occurred in February. A comparison of the SWE change events and mean change segments with those of the northern hemisphere’s climate anomalies revealed that low temperature and low precipitation anomalies reduced the frequency of SWE change events. The findings highlight the influence of climate variables on daily changes in snow-related water storage in March and April. Full article

This research addresses urban heat island intensification driven by urbanization using Dianchi Lake in Kunming, China, as a case study, aiming to quantitatively evaluate the spatial extent, intensity, and land cover sensitivity differences in the cooling effects of large urban water bodies across dry/wet seasons and complex urban landscapes (forest, cropland, and impervious surfaces) to provide a scientific basis for optimizing thermal environments in low-latitude plateau cities. Based on Landsat 8/9 satellite data from dry (January) and wet (May) seasons in 2020 and 2023 used for land surface temperature (LST) retrieval combined with land use data, buffer zone gradient analysis was adopted to quantify the spatial heterogeneity of key cooling indicators within 0–1500 m lakeshore buffers. The results demonstrated significant seasonal differences. The wet season showed a greater cooling extent (600 m) and higher intensity (6.0–6.6 °C) compared with the dry season (400 m; 2.4–3.9 °C). The land cover responses varied substantially, with cropland having the largest influence (600 m), followed by impervious surfaces (400 m), while forest exhibited a minimal effective cooling range (100 m) but localized warming anomalies at 200–400 m. Sensitivity analysis confirmed that impervious surfaces were the most sensitive to water-cooling, followed by cropland, whereas forest showed the lowest sensitivity. Full article

Extreme air temperatures along with the synoptic conditions leading to their appearance are examined for the Mediterranean region for the 85-year period of 1940–2024. The data used are daily (04UTC and 12UTC) grid point (1° × 1°) values of 2 m air temperature, 850 hPa air temperature, and 1000 hPa and 500 hPa geopotential heights, obtained from the ERA5 database. For 12UTC and 04UTC, the 2 m air temperature anomalies are calculated and are used for the definition of Extremely High Temperature Days (EHTDs) and Extremely Low Temperature Days (ELTDs), respectively. Overall, 3787 EHTDs and 4872 ELTDs are defined. It is found that EHTDs are evidently more frequent in recent years (increased by 305% since the 1980s) whereas ELTDs are less frequent (decreased by 41% since the 1980s), providing a clear sign of warming of the Mediterranean climate. A multivariate statistical analysis combining factor analysis and k-means clustering, known as spectral clustering, is applied to the data resulting in the definition of nine EHTD and seven ELTD clusters. EHTDs are mainly associated with intense solar heating, blocking anticyclones and warm air advection. ELTDs are connected to intense radiative cooling of the Earth’s surface, cold air advection and Arctic outbreaks. This is a unique study for the Mediterranean region utilizing the high-resolution ERA5 data collected since the 1940s to define and investigate the variability of both high and low temperature extremes using a validated methodology. Full article

Over the past few decades, occurrences of extreme climatic events have escalated significantly, with severe repercussions for global ecosystems and socio-economics. northern China (NC), characterized by its complex topography and diverse climatic conditions, represents a typical ecologically vulnerable region where vegetation is highly sensitive to climate change. Therefore, monitoring vegetation dynamics and analyzing the influence of extreme climatic events on vegetation are crucial for ecological conservation efforts in NC. Based on extreme climate indicators and the Normalized Difference Vegetation Index (NDVI), this study employed trend analysis, Ensemble Empirical Mode Decomposition, all subsets regression analysis, and random forest to quantitatively investigate the spatiotemporal variations in historical and projected future NDVI trends in NC, as well as their responses to extreme climatic conditions. The results indicate that from 1982 to 2018, the NDVI in NC generally exhibited a recovery trend, with an average growth rate of 0.003/a and a short-term variation cycle of approximately 3 years. Vegetation restoration across most areas was primarily driven by short-term high temperatures and long-term precipitation patterns. Future projections under different emission scenarios (SSP245 and SSP585) suggest that extreme climate change will continue to follow historical trends. However, increased radiative forcing is expected to constrain both the rate of vegetation growth and its spatial expansion. These findings provide a scientific basis for mitigating the impacts of climate anomalies and improving ecological quality in NC. Full article