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Keywords = space-charge suppression

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14 pages, 3047 KiB  
Article
Investigation on the Underlying Mechanisms of the Mechanical and Electrical Enhancement of Nano-SiO2-Doped Epoxy Resins: A Molecular Simulation Study
by Kunqi Cui, Yang Wang, Wenchao Yan, Teng Cao, Yan Du, Kai Wu and Li Guo
Molecules 2025, 30(14), 2960; https://doi.org/10.3390/molecules30142960 - 14 Jul 2025
Viewed by 236
Abstract
As a key insulating material in power equipment, epoxy resins (EP) are often limited in practical applications due to space charge accumulation and mechanical degradation. This study systematically investigates the effects of SiO2 nanoparticle doping on the electrical and mechanical properties of [...] Read more.
As a key insulating material in power equipment, epoxy resins (EP) are often limited in practical applications due to space charge accumulation and mechanical degradation. This study systematically investigates the effects of SiO2 nanoparticle doping on the electrical and mechanical properties of SiO2/EP composites through molecular dynamics simulations and first-principles calculations. The results demonstrate that SiO2 doping enhances the mechanical properties of EP, with notable improvements in Young’s modulus, bulk modulus, and shear modulus, while maintaining excellent thermal stability across different temperatures. Further investigations reveal that SiO2 doping effectively modulates the interfacial charge behavior between EP and metals (Cu/Fe) by introducing shallow defect states and reconstructing interfacial dipoles. Density of states analysis indicates the formation of localized defect states at the interface in doped systems, which dominate the defect-assisted hopping mechanism for charge transport and suppress space charge accumulation. Potential distribution calculations show that doping reduces the average potential of EP (1 eV for Cu layer and 1.09 eV for Fe layer) while simultaneously influencing the potential distribution near the polymer–metal interface, thereby optimizing the interfacial charge injection barrier. Specifically, the hole barrier at the maximum valence band (VBM) after doping significantly increased, rising from the initial values of 0.448 eV (Cu interface) and 0.349 eV (Fe interface) to 104.02% and 209.46%, respectively. These findings provide a theoretical foundation for designing high-performance epoxy-based composites with both enhanced mechanical properties and controllable interfacial charge behavior. Full article
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15 pages, 4864 KiB  
Article
The Systematic Design of Voice Coil Motor Structures for Rapid Zoom Optical Lens
by Junqiang Gong, Dameng Liu and Jianbin Luo
Actuators 2025, 14(7), 332; https://doi.org/10.3390/act14070332 - 2 Jul 2025
Viewed by 276
Abstract
In order to solve the zoom delay issue for high-magnification zoom optical systems, a voice coil motor (VCM) is used to achieve rapid zooming. In this paper, the structural design of VCMs is systematically analyzed through magnetic field numerical computations. Firstly, finite element [...] Read more.
In order to solve the zoom delay issue for high-magnification zoom optical systems, a voice coil motor (VCM) is used to achieve rapid zooming. In this paper, the structural design of VCMs is systematically analyzed through magnetic field numerical computations. Firstly, finite element method (FEM) is used to analyze magnetic field of single magnets, and simulations correspond to experimental results. Both FEM and equivalent magnetic charge (EMC) results confirm that increasing magnet thickness while reducing its lateral dimensions will contribute to magnetic enhancement. Furthermore, the influence of structural parameters VCM is analyzed, validating the yoke’s critical role in suppressing edge effects and optimizing magnetic circuit efficiency, and optimal yoke thickness and magnet width range are determined. Moreover, a simple EMC calculation method is proposed for rapid and accurate determination of the magnetic field distribution in the VCM air gap. Optimal structural parameters of VCM are determined for a 40× rapid zoom lens with cost and space limitations. Driving force Fdrive = 5.58 N is about 5 times the demand force Fd = 1.06 N, and the prototype fabrication of the rapid zoom lens is successfully accomplished. Moving group reaches 35.4 mm destination within 0.18 s, and photographs confirm that the rapid zoom system achieves 100-ms-level short/long-focus transition. Rapid zoom lens shows great potential in applications including security surveillance, industrial visual inspection, and intelligent logistics management. Full article
(This article belongs to the Special Issue Actuators in 2025)
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13 pages, 4395 KiB  
Article
WRTU-16T: Write-Enhanced Low-Power Radiation-Tolerant SRAM for Space Applications
by Seung-Hyun Lee and Sung-Hun Jo
Appl. Sci. 2025, 15(13), 7295; https://doi.org/10.3390/app15137295 - 28 Jun 2025
Viewed by 291
Abstract
In space, high-energy particle radiation poses a serious threat to the data stability and reliability of SRAM. Existing radiation-tolerant techniques, such as Triple Modular Redundancy (TMR) and Error Correction Code (ECC), have disadvantages such as large area, high power consumption, and additional delay, [...] Read more.
In space, high-energy particle radiation poses a serious threat to the data stability and reliability of SRAM. Existing radiation-tolerant techniques, such as Triple Modular Redundancy (TMR) and Error Correction Code (ECC), have disadvantages such as large area, high power consumption, and additional delay, making them unsuitable for small satellite systems. To overcome these limitations, this paper proposes a 16-transistor-based radiation-tolerant SRAM cell, WRTU-16T, which applies a read-decoupled structure and a charge-sharing suppression mechanism. The proposed structure effectively isolates the storage node from external disturbances and improves the recovery capability for single-event inversion (SEU) and multiple-node inversion (SEMNU) by reducing charge loss. WRTU-16T shows superior performance in terms of write delay, charge recovery capability (Qc), hold power, and word line write threshold voltage (WWTV) compared to existing radiation-tolerant SRAM designs. The integrated circuit is implemented using a 90 nm CMOS process and has an operating voltage of 1V. Full article
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27 pages, 10012 KiB  
Article
Beam Emittance and Bunch Length Diagnostics for the MIR-FEL Beamline at Chiang Mai University
by Kittipong Techakaew, Kanlayaporn Kongmali, Siriwan Pakluea and Sakhorn Rimjaem
Particles 2025, 8(3), 64; https://doi.org/10.3390/particles8030064 - 21 Jun 2025
Viewed by 1092
Abstract
The generation of high-quality mid-infrared free-electron laser (MIR-FEL) radiation depends critically on precise control of electron beam parameters, including energy, energy spread, transverse emittance, bunch charge, and bunch length. At the PBP-CMU Electron Linac Laboratory (PCELL), effective beam diagnostics are essential for optimizing [...] Read more.
The generation of high-quality mid-infrared free-electron laser (MIR-FEL) radiation depends critically on precise control of electron beam parameters, including energy, energy spread, transverse emittance, bunch charge, and bunch length. At the PBP-CMU Electron Linac Laboratory (PCELL), effective beam diagnostics are essential for optimizing FEL performance. However, dedicated systems for direct measurement of transverse emittance and bunch length at the undulator entrance have been lacking. This paper addresses this gap by presenting the design, simulation, and analysis of diagnostic stations for accurate characterization of these parameters. A two-quadrupole emittance measurement system was developed, enabling independent control of beam-focusing in both transverse planes. An analytical model was formulated specifically for this configuration to enhance emittance reconstruction accuracy. Systematic error analysis was conducted using ASTRA beam dynamics simulations, incorporating 3D field maps from CST Studio Suite and fully including space-charge effects. Results show that transverse emittance values as low as 0.15 mm·mrad can be measured with less than 20% error when the initial RMS beam size is under 2 mm. Additionally, quadrupole misalignment effects were quantified, showing that alignment within ±0.95 mm limits systematic errors to below 33.3%. For bunch length measurements, a transition radiation (TR) station coupled with a Michelson interferometer was designed. Spectral and interferometric simulations reveal that transverse beam size and beam splitter properties significantly affect measurement accuracy. A 6% error due to transverse size was identified, while Kapton beam splitters introduced additional systematic distortions. In contrast, a 6 mm-thick silicon beam splitter enabled accurate, correction-free measurements. The finite size of the radiator was also found to suppress low-frequency components, resulting in up to 10.6% underestimation of bunch length. This work provides a practical and comprehensive diagnostic framework that accounts for multiple error sources in both transverse emittance and bunch length measurements. These findings contribute valuable insight for the beam diagnostics community and support improved control of beam quality in MIR FEL systems. Full article
(This article belongs to the Special Issue Generation and Application of High-Power Radiation Sources 2025)
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18 pages, 5136 KiB  
Article
Beam Dynamics Design of a Multi-Ion RFQ for Medical Application
by Xinran Wang, Guiling Cao and Wenzhi Zhang
Appl. Sci. 2025, 15(11), 6182; https://doi.org/10.3390/app15116182 - 30 May 2025
Viewed by 394
Abstract
Particle radiotherapy based on the medical accelerator is emerging as a major treatment for cancer. To enhance the clinical flexibility of particle radiotherapy and further promote the use of medical accelerators, the Shanghai Institute of Applied Physics (SINAP) has presented a new linear [...] Read more.
Particle radiotherapy based on the medical accelerator is emerging as a major treatment for cancer. To enhance the clinical flexibility of particle radiotherapy and further promote the use of medical accelerators, the Shanghai Institute of Applied Physics (SINAP) has presented a new linear accelerator plan for medical application. The new plan utilizes a 200 MHz Radio Frequency Quadrupole (RFQ) as the injector. The RFQ is designed to accelerate ions with charge-to-mass ratios of 1/3 to 1/2 from 8 keV/u to 750 keV/u. For the beam dynamics design, a new design strategy is presented to enhance the suppression of space charge effects and improve beam capture efficiency by optimizing the modulation, synchronous phase, and focusing strength. The simulation results demonstrate that the multi-ion RFQ can operate at a maximum beam current of 3.2 mA while maintaining a transmission efficiency above 95% with a compact length of 2.5 m. Multi-particle simulations confirm the high reliability of the design. Additionally, input and mechanical error analyses evaluate the RFQ’s tolerance and stability. The research results demonstrate the feasibility of a compact, high-efficiency RFQ for multi-ion acceleration in medical applications, contributing to the advancement of particle therapy. Full article
(This article belongs to the Special Issue Advances in Diagnostic and Therapeutic Radiology — 2nd Edition)
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14 pages, 2546 KiB  
Article
Hollow-Structured Carbon-Coated CoxNiySe2 Assembled with Ultrasmall Nanoparticles for Enhanced Sodium-Ion Battery Performance
by Chao Wang, Weijie Si and Xiongwu Kang
Inorganics 2025, 13(3), 96; https://doi.org/10.3390/inorganics13030096 - 20 Mar 2025
Viewed by 508
Abstract
Transition metal selenides are considered one of the most promising materials for sodium-ion battery anodes due to their excellent theoretical capacity. However, it remains challenging to suppress the volume variation and the resulted capacity decay during the charge–discharge process. Herein, hollow-structured CoNiSe2 [...] Read more.
Transition metal selenides are considered one of the most promising materials for sodium-ion battery anodes due to their excellent theoretical capacity. However, it remains challenging to suppress the volume variation and the resulted capacity decay during the charge–discharge process. Herein, hollow-structured CoNiSe2 dual transition metal selenides wrapped in a carbon shell (HS-CoxNiySe2@C) were deliberately designed and prepared through sequential coating of polyacrylonitrile (PAN), ion exchange of ZIF-67 with Ni2+ metal ions, and carbonization/selenization. The hollow structure was evidenced by transmission electron microscopy, and the crystalline structure was confirmed by X-ray diffraction. The ample internal space of HS-CoxNiySe2@C effectively accommodated volume expansion during the charge and discharge processes, and the large surface area enabled sufficient contact between the electrode and electrolyte and shortened the diffusion path of sodium ions for a feasible electrochemical reaction. The surface area and ionic conductivity of HS-CoxNiySe2@C were strongly dependent on the ratio of Co to Ni. The synergistic effect between Co and Ni enhanced the conductivity and electron mobility of HS-CoxNiySe2@C, thereby improving charge transfer efficiency. By taking into account the structural advantages and rational metal selenide ratios, significant improvements can be achieved in the cycling performance, rate performance, and overall electrochemical stability of sodium-ion batteries. The optimized HS-CoxNiySe2@C demonstrated excellent performance, and the reversible capacity remained at 334 mAh g−1 after 1000 cycles at a high current of 5.0 A g−1. Full article
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21 pages, 7210 KiB  
Article
Improved Electric Eel Foraging Algorithm for Shielding Optimization of Wireless Power Transfer Systems
by Wencong Huang, Cheng Shu, Aoli Wang, Yufang Chang and Huaicheng Yan
Electronics 2025, 14(5), 906; https://doi.org/10.3390/electronics14050906 - 25 Feb 2025
Viewed by 634
Abstract
There is a problem of magnetic leakage in the charging process of wireless power transfer systems, which can threaten human safety and affect the normal operation of electronic equipment. In this paper, the wireless power transfer system adopts a bilateral LCCS hybrid topology [...] Read more.
There is a problem of magnetic leakage in the charging process of wireless power transfer systems, which can threaten human safety and affect the normal operation of electronic equipment. In this paper, the wireless power transfer system adopts a bilateral LCCS hybrid topology to address this problem. It proposes a magnetic field shielding suppression method based on the improved electric eel foraging optimization algorithm. Firstly, the Fuch infinite folding chaos strategy and the Cauchy–Gauss variation strategy are introduced to optimize the electric eel foraging optimization algorithm, which further improves the global optimal parameter search capability of the improved electric eel foraging optimization algorithm. Then, the improved electric eel foraging optimization algorithm is proposed to perform a parameter search for the inductance of the shielded coil. Finally, simulation and experimental verification show that when the shielding coil inductance is optimal, the method proposed in this paper can effectively shield and suppress the magnetic leakage of the system, reducing the magnetic leakage field by 67.05%. The magnetic induction intensity in the space region meets the international safety standards, which verifies the effectiveness and feasibility of the method. Full article
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15 pages, 6869 KiB  
Article
Study on the Space Charge Characteristics of Polypropylene Insulation Material Under a Polarity Reversal Electric Field
by Xinhua Dong, Guodong Bao and Wei Wang
Polymers 2025, 17(3), 430; https://doi.org/10.3390/polym17030430 - 6 Feb 2025
Cited by 1 | Viewed by 807
Abstract
High-voltage (HV) cables may experience voltage polarity reversal during power adjustment, leading to the accumulation of space charges inside the insulation material and causing distortion of the internal electric field. To characterize the effect of grafting modification on the insulation properties of polypropylene [...] Read more.
High-voltage (HV) cables may experience voltage polarity reversal during power adjustment, leading to the accumulation of space charges inside the insulation material and causing distortion of the internal electric field. To characterize the effect of grafting modification on the insulation properties of polypropylene (PP), various electrical properties were characterized. The results show that grafting modification can significantly improve the electrical properties of PP, with PPG-2 exhibiting the best electrical properties. Compared with PP, the breakdown strength of PPG-2 is increased by 39.27%, and the critical electric field is increased by 36.52%. Meanwhile, the charge accumulation inside the PPG-2 is extremely small after voltage polarity reversal. The mechanism of grafting modification to enhance the electrical properties of PP was explained by analyzing the trap characteristics of the samples. This indicates that grafting modification introduces a large number of deep traps within PP, suppressing the injection and migration of charge carriers. The presence of deep traps weakens the charge accumulation and electric field distortion at the interface. In this paper, the optimal monomer and content of grafted PP were determined, and the insulation properties of the cable under operating conditions were analyzed. The research results offer practical guidance for the development of high-performance grafted PP cable insulation materials and the reliability of cable operation. Full article
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13 pages, 3309 KiB  
Article
Improved Ferroelectric and Magnetic Properties of Bismuth Ferrite-Based Ceramics by Introduction of Non-Isovalent Ions and Grain Engineering
by Ting Wang, Huojuan Ye, Xiaoling Wang, Yuhan Cui, Haijuan Mei, Shenhua Song, Zhenting Zhao, Meng Wang, Pitcheri Rosaiah and Qing Ma
Nanomaterials 2025, 15(3), 215; https://doi.org/10.3390/nano15030215 - 29 Jan 2025
Cited by 2 | Viewed by 1199
Abstract
Single-phase multiferroics exhibiting ferroelectricity and ferromagnetism are considered pivotal for advancing next-generation multistate memories, spintronic devices, sensors, and logic devices. In this study, the magnetic and electric characteristics of bismuth ferrite (BiFeO3) ceramics were enhanced through compositional design and grain engineering. [...] Read more.
Single-phase multiferroics exhibiting ferroelectricity and ferromagnetism are considered pivotal for advancing next-generation multistate memories, spintronic devices, sensors, and logic devices. In this study, the magnetic and electric characteristics of bismuth ferrite (BiFeO3) ceramics were enhanced through compositional design and grain engineering. BiFeO3 ceramic was co-substituted by neodymium (Nd) and niobium (Nb), two non-isovalent elements, via the spark plasma sintering process using phase-pure powder prepared via sol-gel as the precursor. The symmetry of the sintered Nd–Nb co-doped samples changed from R3c to Pnma, accompanied by a decrease in the loss tangent, grain size, and leakage current density. The reduction in the leakage current density of the co-doped samples was ~three orders of magnitude. Moreover, ferroelectric, dielectric, and magnetic properties were substantially improved. The remanent polarization and magnetization values of the optimized Nd–Nb co-doped BiFeO3 sample were 3.12 μC cm−2 and 0.15 emu g−1, respectively. The multiferroic properties were enhanced based on multiple factors such as structural distortion caused by co-doping, grain size reduction, suppression of defect charges via donor doping, space-modulated spin structure disruption, and an increase in magnetic ions. The synergistic approach of composition design and grain engineering sets a paradigm for the advancement of multiferroic materials. Full article
(This article belongs to the Special Issue Design and Applications of Heterogeneous Nanostructured Materials)
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15 pages, 13240 KiB  
Article
Finite Element Analysis of Electrostatic Coupling in LISA Pathfinder Inertial Sensors
by Wenyan Zhang, Jungang Lei, Zuolei Wang, Cunhui Li, Shijia Yang, Jian Min and Xuan Wen
Sensors 2024, 24(19), 6189; https://doi.org/10.3390/s24196189 - 24 Sep 2024
Cited by 2 | Viewed by 1163
Abstract
In the LISA Pathfinder (LPF) mission, electrostatic noise can reach the femto-Newtonian level despite the fact that the LPF’s sensors are equipped with potential shielding. Most of the existing simulation studies focus on the electrostatic edge effect and related fields, while the simulation [...] Read more.
In the LISA Pathfinder (LPF) mission, electrostatic noise can reach the femto-Newtonian level despite the fact that the LPF’s sensors are equipped with potential shielding. Most of the existing simulation studies focus on the electrostatic edge effect and related fields, while the simulation study of the patch effect is neglected. For that reason, this paper analyzes the basic principle of electrostatic noise and constructs a simulation model for studying the coupling effects of a TM’s residual charge and stray bias voltage. The patch effect and other perturbation factors are simulated by the simulation model with finite element operation, focusing on the suppression effect of the protective ring on the edge effect, the realization of the patch effect in the simulation model, and the possible influence. The results show that electrode area and the spacing between the electrode and the TM together limit the suppression effect of the protective ring on the edge effect. The spatial and temporal variations of the patch effect significantly affect the distributed electric field between the electrodes and the TM, as well as the charge distribution density of the TM. In the worst-case scenario of LPF electrostatic input parameters, the electrostatic noise is about 1.03 × 10−15 m/s2/√Hz at 1 mHz, which is about 6% different from the expected performance estimate. Finally, considering the limitations of multiple environmental factors on the inertial sensors, the present model will be useful to explore the interactive effects of multi-field coupling and to further investigate the impact of low-energy electron charging on the performance of the inertial sensors. Full article
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9 pages, 6506 KiB  
Article
Influence of the Experimental Setup on Electromagnetic Pulses in the VHF Band at Relativistic High-Power Laser Facilities
by Michael Ehret, Luca Volpe, Jon Imanol Apiñaniz, Maria Dolores Rodríguez-Frías and Giancarlo Gatti
Photonics 2024, 11(5), 459; https://doi.org/10.3390/photonics11050459 - 14 May 2024
Cited by 2 | Viewed by 1727
Abstract
We present experimental results for the controlled mitigation of the electromagnetic pulses (EMPs) produced in the interactions of a 1 PW high-power 30 fs Ti:Sa laser VEGA-3 with solid-density targets transparent to laser-forward-accelerated relativistic electrons. This study aims at the band of very [...] Read more.
We present experimental results for the controlled mitigation of the electromagnetic pulses (EMPs) produced in the interactions of a 1 PW high-power 30 fs Ti:Sa laser VEGA-3 with solid-density targets transparent to laser-forward-accelerated relativistic electrons. This study aims at the band of very high frequencies (VHFs), i.e., those in the hundreds of MHz, which comprise the fundamental cavity modes of the rectangular VEGA-3 vacuum chamber. We demonstrate mode suppression by a tailoring of the laser-produced space charge distribution. Full article
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17 pages, 9158 KiB  
Article
The Effect of SiO2 Particle Size on Crystallization Behavior and Space Charge Properties for SiO2/MMT/LDPE Composites
by Hongtao Jiang, Hong Yuan, Qunguang Yu and Jing Xie
Materials 2024, 17(7), 1605; https://doi.org/10.3390/ma17071605 - 31 Mar 2024
Cited by 1 | Viewed by 1477
Abstract
The matrix material used in this paper was low-density polyethene (LDPE), and the added particles selected were silicon oxide (SiO2) particles and montmorillonite (MMT) particles. The sizes of the SiO2 particles were 1 µm, 30 nm, and 100 nm, respectively; [...] Read more.
The matrix material used in this paper was low-density polyethene (LDPE), and the added particles selected were silicon oxide (SiO2) particles and montmorillonite (MMT) particles. The sizes of the SiO2 particles were 1 µm, 30 nm, and 100 nm, respectively; three kinds of SiO2/MMT/LDPE multi-component composites were prepared based on MMT/LDPE composites doped with MMT particles. The effect of the SiO2 particle size on the crystallization behavior and space charge properties of SiO2/MMT/LDPE composites was studied. The crystalline behaviors and crystallinity of the materials were analyzed. At the same time, the changes in the relative dielectric constant εr and loss factor tanδ for each material with the influence of frequency were studied, and the space charge accumulation, residual characteristics, and apparent charge mobility of each material were explored. The results show that the smaller the size of the added particles, the smaller the grain size and the clearer the grain outline for the multi-composite material. After adding 30 nm SiO2 particles, the crystallinity of the material increases significantly. The microstructure formed by the addition of 100 nm SiO2 particles effectively restricts molecular chain movement and makes it difficult to establish the polarization of the composite. The incorporation of large-size particles can reduce the proportion of the crystalline structure for the material as a whole, resulting in the formation of a new structure to promote charge transfer. Among the three kinds of SiO2 particles, the addition of 30 nm SiO2 particles can effectively suppress the space charge, and the composite material has the lowest residual space charge after depolarization. The addition of 100 nm SiO2 particles can cause the accumulation of many homopolar charges near the anode. Full article
(This article belongs to the Special Issue Advanced Polymer Matrix Nanocomposite Materials (2nd Edition))
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15 pages, 5453 KiB  
Article
Improved Electrical Properties of Organic Modified Thermoplastic Insulation Material for Direct Current Cable Application
by Yunpeng Zhan, Xu Yang, Jiaming Yang, Shuai Hou and Mingli Fu
Polymers 2024, 16(1), 46; https://doi.org/10.3390/polym16010046 - 22 Dec 2023
Cited by 7 | Viewed by 2161
Abstract
To achieve exceptional recyclable DC cable insulation material using thermoplastic polypropylene (PP), we have introduced the organic polar molecule styrene-maleic anhydride copolymer (SMA) into PP-based insulation materials following the principles of deep trap modification. PP, PP/SMA, PP/ethylene-octene copolymer (POE), and PP/POE/SMA insulating samples [...] Read more.
To achieve exceptional recyclable DC cable insulation material using thermoplastic polypropylene (PP), we have introduced the organic polar molecule styrene-maleic anhydride copolymer (SMA) into PP-based insulation materials following the principles of deep trap modification. PP, PP/SMA, PP/ethylene-octene copolymer (POE), and PP/POE/SMA insulating samples were prepared, and their meso-morphology, crystalline morphology, and molecular structure were comprehensively characterized. The results indicate that SMA can be uniformly dispersed in PP with minimal impact on the crystalline morphology of PP. The DC electrical properties of the materials were tested at temperatures of 30, 50, and 70 °C. The findings demonstrate that the introduction of SMA can improve the DC properties of the material in both PP and PP/POE. The thermal stimulated depolarization current results reveal that SMA can introduce deep traps into the material, thereby improving its DC properties, which is in agreement with the quantum chemical calculation results. Subsequently, a bipolar carrier transport model was employed for coaxial cables to simulate the space charge distribution in the insulation layer of the four sets of insulation samples as well as the actual cable in service. The results highlight that SMA can significantly suppress space charge in PP and PP/POE systems, and it exhibits excellent electric field distortion resistance. In summary, the results illustrate that SMA is expected to be used as an organic deep trap modifier in PP-based cable insulation materials. Full article
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18 pages, 5670 KiB  
Article
Insight into the Role of Conductive Polypyrrole Coated on Rice Husk-Derived Nanosilica-Reduced Graphene Oxide as the Anodes: Electrochemical Improvement in Sustainable Lithium-Ion Batteries
by Natthakan Ratsameetammajak, Thanapat Autthawong, Kittiched Khunpakdee, Mitsutaka Haruta, Torranin Chairuangsri and Thapanee Sarakonsri
Polymers 2023, 15(24), 4638; https://doi.org/10.3390/polym15244638 - 7 Dec 2023
Cited by 9 | Viewed by 2245
Abstract
Polypyrrole (PPy) is a type of conducting polymer that has garnered attention as a potential electrode material for sustainable energy storage devices. This is mostly attributed to its mechanical flexibility, ease of processing, and ecologically friendly nature. Here, a polypyrrole-coated rice husk-derived nanosilica-reduced [...] Read more.
Polypyrrole (PPy) is a type of conducting polymer that has garnered attention as a potential electrode material for sustainable energy storage devices. This is mostly attributed to its mechanical flexibility, ease of processing, and ecologically friendly nature. Here, a polypyrrole-coated rice husk-derived nanosilica-reduced graphene oxide nanocomposite (SiO2-rGO@PPy) as an anode material was developed by a simple composite technique followed by an in situ polymerization process. The architecture of reduced graphene oxide offers a larger electrode/electrolyte interface to promote charge-transfer reactions and provides sufficient space to buffer a large volume expansion of SiO2, maintaining the mechanical integrity of the overall electrode during the lithiation/delithiation process. Moreover, the conducting polymer coating not only improves the capacity of SiO2, but also suppresses the volume expansion and rapid capacity fading caused by serious pulverization. The present anode material shows a remarkable specific reversible capacity of 523 mAh g−1 at 100 mA g−1 current density and exhibits exceptional discharge rate capability. The cycling stability at a current density of 100 mA g−1 shows 81.6% capacity retention and high Coulombic efficiency after 250 charge–discharge cycles. The study also pointed out that this method might be able to be used on a large scale in the lithium-ion battery industry, which could have a big effect on its long-term viability. Creating sustainable nanocomposites is an exciting area of research that could help solve some of the biggest problems with lithium-ion batteries, like how easy they are to make and how big they can be used in industry. This is because they are sustainable and have less of an impact on the environment. Full article
(This article belongs to the Special Issue Advances in Polymer/Graphene Composites and Nanocomposites)
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11 pages, 3200 KiB  
Article
In Situ Growth of Mg-Fe Layered Double Hydroxides (LDH) Film on Titanium Dental Implant Substrates for pH Regulation in Oral Environments
by Yuliu Li, Francesco Gianfreda, Carlotta Danesi, Patrizio Bollero, Anita Ermini, Roberto Pizzoferrato and Eleonora Nicolai
Crystals 2023, 13(12), 1636; https://doi.org/10.3390/cryst13121636 - 26 Nov 2023
Cited by 1 | Viewed by 1692
Abstract
Layered double hydroxides (LDHs) consist of two-dimensional, positively charged lamellar structures with the ability to host various anions in the interlayer spaces, which grants them unique properties and tunable characteristics. LDHs, a class of versatile inorganic compounds, have recently emerged as promising candidates [...] Read more.
Layered double hydroxides (LDHs) consist of two-dimensional, positively charged lamellar structures with the ability to host various anions in the interlayer spaces, which grants them unique properties and tunable characteristics. LDHs, a class of versatile inorganic compounds, have recently emerged as promising candidates for enhancing osseointegration. A suitable alkaline microenvironment is thought to be beneficial for stimulating osteoblasts’ differentiation (responsible for bone matrix formation) while suppressing osteoclast generation (responsible for bone matrix disintegration). LDHs are prone to adjusting their alkalinity and thus offering us the chance to study how pH affects cellular behavior. LDHs can indeed modulate the local pH, inflammatory responses, and oxidative stress levels, factors that profoundly influence the behavior of osteogenic cells and their interactions with the implant surface. Herein, we deposited Mg–Fe LDH films on titanium substrates for dental implants. The modified Ti substrates was more alkaline in comparison to the bare ones, with a pH higher than 8 after hydrolysis in an aqueous environment. Full article
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