Search Results (40)

Toughening modification of epoxy resin (EP) matrices is important for advancing high-performance fiber-reinforced composites. A promising strategy involves the use of multi-component additive systems. However, synergistic effects in such additive systems are difficult to achieve for multidimensional performance optimization due to insufficient interfacial interactions and competing toughening mechanisms. Herein, a “hard–soft” biphasic synergistic toughening system was engineered for epoxy resin, composed of furan-ring-grafted polyhedral oligomeric silsesquioxane (FPOSS) and liquid polysulfide rubber. The hybrid toughening agent significantly enhanced the integrated performance of the epoxy system: Young’s modulus, tensile strength, and elongation at break increased by 13%, 56%, and 101%, respectively. These improvements are attributed to the formation of enriched molecular chain entanglement sites and optimized dispersion, facilitated by nucleophilic addition reactions between flexible rubber segments and rigid FPOSS units with the epoxy matrix. The marked enhancement in toughness primarily stems from the synergistic toughening mechanism involving “crazing pinning” and “crazing-shear band”. Concurrently, FPOSS incorporation effectively modulated the curing reaction kinetics, rendering the process more gradual while substantially elevating the glass transition temperature (T_g) of the cured system by 16.82 °C and endowing it with superior thermal degradation stability. This work provides a simple and unique strategy to leverage multi-scale mechanisms for the construction of epoxy-based composites with good toughness and strength, and enhanced heat resistance. Full article

Mid-infrared (MIR) supercontinuum (SC) sources are critical for spectroscopy, biomedical imaging, and environmental monitoring. However, conventional generation methods based on free-space experiments using optical parametric amplifiers (OPAs) and difference frequency generation (DFG) lasers suffer from narrow bandwidth and low power distribution in the MIR region. This paper presents a cascaded pumping technique using two soft-glass fibers. A picosecond thulium-doped fiber amplifier (TDFA) pumps a Germania-doped fiber (GDF) to generate an intermediate broadband spectrum, which then pumps a fluorotellurite fiber (TBY) with higher nonlinearity and a wider transmission window. Using this configuration, we achieved an Octave-Spanning SC generation covering 1–4 μm with 7.20 W output power. Notably, 32.8% of total power lies above 3.0 μm, with 11.2% beyond 3.5 μm, demonstrating excellent long-wavelength performance. In addition, we applied numerical simulation methods to investigate SC generation in GDF and TBY by solving the nonlinear Schrödinger equation. The close match between simulated and experimental results facilitates theoretical examination of how SC broadening occurs. This cascaded approach offers a feasible solution in terms of spectral band matching, material compatibility, and system integration potential. Full article

Dy³⁺:InF₃ fiber shows promise for 4.4 μm mid-infrared lasing, but the much shorter lifetime of its upper laser level compared to the lower level causes inevitable self-termination. While cascade 4.4 μm/3 μm lasing has been proposed as a potential solution, this method faces complex configuration and an extremely high pump threshold (>30 W under continuous-wave operation), rendering it impractical for high-power use, especially given InF₃’s soft-glass nature. To address the self-termination challenge and enable the low-threshold, high-efficiency lasing, this study proposes, for the first time to our knowledge, a dual-wavelength cascade-pumping scheme utilizing 2.8 μm and 2.4 μm pumps. Numerical simulations demonstrate that the dual-wavelength cascade-pumped Dy³⁺:InF₃ fiber laser exhibits an optical-to-optical efficiency of up to 18.4% and a maximum slope efficiency of 38.5%. The total pump threshold is as low as 5.4 W, remarkably lower than that required by the cascade lasing approach. This work provides a viable solution and design guidelines for the development of 4 μm-class mid-infrared fiber lasers. Full article

We conducted a comprehensive experimental investigation of dual-wavelength switching of 1560 nm, 75 fs pulses (referred to as signal) driven by 1030 nm, 270 fs pulses (referred to as control) using two dual-core fibers with high refractive index contrast and different levels of asymmetry. The study explores the influence of fiber length, control pulse energy, and control-signal pulse delay on switching performance. For the fiber with higher dual-core asymmetry, we achieved an exceptional switching contrast of 41.6 dB at a 14 mm fiber length, exhibiting a homogeneous character within the spectral range of 1450–1650 nm. In contrast, the study of the weaker dual-core asymmetry fiber revealed a maximum switching contrast of 10.7 dB at a 22 mm fiber length, albeit under lower control pulse energy. These observations confirm that the switching mechanism is based on the nonlinear balancing of dual-core asymmetry, wherein the control pulse induces an enhancement of the effective refractive index in the fast fiber core, facilitating the switching of the signal pulse. This work demonstrates high switching contrasts with only a 0.4–0.6 nJ control pulse energy requirement, providing experimental confirmation of a previously reported theoretical model. For the first time, the dual-wavelength switching performance of dual-core fibers with varying levels of asymmetry is compared. The results reveal key directions for the further development of dual-core fibers in view of their potential applications. Full article

Keratoconus is a potentially blinding condition characterized by progressive thinning and steepening of the cornea, leading to visual impairment due to irregular astigmatism and myopia. While the exact pathophysiology is still unknown, it is believed to involve genetic, environmental, and cellular factors. Treatment options for keratoconus have significantly expanded over the past few decades. Historically, glasses were the primary means of managing mild cases, whereas rigid gas permeable contact lenses were used in moderate to advanced diseases; yet the latter were rarely tolerated by patients with steep cones, in which full-thickness corneal transplantation was often performed. However, a variety of innovative treatments have been introduced in the past decades. Corneal collagen cross-linking (CXL) has revolutionized the field by halting the progression of keratoconus through creating new covalent bonds between individual corneal fibers. Custom, soft, and scleral contact lenses have improved visual outcomes for many patients. Additionally, surgical interventions such as intrastromal ring segments and Bowman layer transplantation have provided alternatives for visual restoration and postponing a potential keratoplasty. Furthermore, innovative cellular and pharmacological KCN treatments are on the horizon, awaiting clinical trials. This review article aims to provide a comprehensive overview of the current treatment options for keratoconus. Full article

Recycled aggregate concrete (RAC) holds significant promise for reducing the environmental impact of the construction industry. However, the poor mechanical properties of RAC compared to conventional concrete are mainly due to the porous and soft nature of recycled aggregates. While fiber reinforcement has been proposed as a promising method to address this issue, existing studies primarily focus on steel and polypropylene fibers, with limited systematic comparison of alternative fiber types and dosages. In particular, the mechanical enhancement mechanisms of basalt and glass fibers in RAC remain underexplored, and there is a lack of predictive models for strength behavior. This study evaluates the effects of basalt and glass fibers on RAC through uniaxial compression, splitting tensile, and three-point bending tests. Nine mixtures with varying fiber types and volume fractions (1.0–2.5%) were tested, and results were compared to plain RAC. Key properties such as strength, energy absorption, toughness, and flexibility were analyzed using load–displacement curves and advanced toughness indices. Both fiber types improved tensile and flexural properties, with glass fibers showing superior performance, particularly at 1.5% content, where the splitting tensile strength increased by up to 40% and the flexural strength improved by 42.19%. Basalt fibers dispersed more uniformly but were less effective in enhancing toughness and crack resistance. Excessive fiber content reduced matrix homogeneity and mechanical performance. Optimal fiber dosages were identified as 1–1.5% for glass fibers and 1–2% for basalt fibers, depending on the targeted property. Predictive formulas for the flexural strength of fiber-reinforced RAC are also proposed, offering guidance for the design of structural RAC elements. Full article

Background: Polymerization shrinkage of composite resins affects the marginal closure of direct dental restorations. It is responsible for developing secondary caries and indirectly affects the survival rate of restorations. This study aims to investigate the null hypothesis, which states that there are no significant differences in the marginal microleakage of Class II restorations when examined in vitro using different dental adhesives, whether the restoration material used is a composite with glass fiber reinforcement or not. Methods: Class II cavities were prepared on both proximal surfaces of thirty-six extracted human molars. A single-component (Universal VivaPen) and a two-component (Futurabond DC) self-etch adhesive system were used for the restorations in the control group (Charisma Classic) and the experimental group (Charisma Classic with Interlig glass fiber strip). An oblique layering technique and a 40-s soft-start light-curing polymerization were used. After selective pre-isolation, the specimens were placed in a 0.2% methylene blue solution and incubated at 37 °C for 24 h. The teeth were sectioned in the mesiodistal direction, and two examiners examined and graded the extent of dye penetration. Statistical analysis was conducted using the Mann–Whitney U and chi-square tests (p < 0.05). Results: All the composite restorations reinforced with glass fiber showed significantly reduced dye infiltration compared to the control group (p < 0.05). A significant difference (p < 0.05) was also observed between the two adhesives. Conclusions: The null hypothesis was rejected. Glass fiber strips significantly reduced composite restoration microleakage regardless of the adhesive. The marginal fit of the restoration was also influenced by the adhesive system used. Full article

The purpose of this study was to determine the effect of fiber reinforcement materials on the magnitude of stresses in a critical part of the maxillary denture base under thermal and occlusal load. Thermal stress analyses of the models were carried out using the finite element method. The models consisted of bone, soft tissue, interface gap, and maxillary dentures with and without reinforcements. A concentrated occlusal load of 230 N was applied bilaterally on the molar teeth. A 36 °C reference and 0 °C, 36 °C, and 70 °C variable ambient temperatures were applied to the models. CrCo, unidirectional and woven carbon/epoxy, unidirectional and woven glass/epoxy, and unidirectional and woven Kevlar/epoxy were used as reinforcing materials in the maxillary denture base made of PMMA (polymethyl methacrylate). Stress distributions on the maxillary denture’s midline and lateral line direction were evaluated. Maximum stresses in the incisal notch and the labial frenal notch of the maxillary denture were determined. Failure analysis of reinforcement materials used in maxillary dentures was carried out using the Tsai-Wu index criterion. The results obtained show that the thermal properties of reinforcement materials should be considered as an important criterion in their selection. Full article

Materials with a soft tissue regenerative capacity can be produced using biopolymer scaffolds and nanomaterials, which allow injured tissue to recover without any side effects or limitations. Four formulations were prepared using polyvinyl alcohol (PVA) and chitosan (CS), with silicon dioxide nanoparticles (NPs-SiO₂) incorporated using the freeze-drying method at a temperature of −50 °C. TGA and DSC showed no change in thermal degradation, with glass transition temperatures around 74 °C and 77 °C. The interactions between the hydroxyl groups of PVA and CS remained stable. Scanning electron microscopy (SEM) indicated that the incorporation of NPs-SiO₂ complemented the freeze-drying process, enabling the dispersion of the components on the polymeric matrix and obtaining structures with a small pore size (between 30 and 60 μm) and large pores (between 100 and 160 μm). The antimicrobial capacity analysis of Gram-positive and Gram-negative bacteria revealed that the scaffolds inhibited around 99% of K. pneumoniae, E. cloacae, and S. aureus ATCC 55804. The subdermal implantation analysis demonstrated tissue growth and proliferation, with good biocompatibility, promoting the healing process for tissue restoration through the simultaneous degradation and formation of type I collagen fibers. All the results presented expand the boundaries in tissue engineering and regenerative medicine by highlighting the crucial role of nanoparticles in optimizing scaffold properties. Full article

Several therapeutic approaches have been developed to promote bone regeneration, including guided bone regeneration (GBR), where barrier membranes play a crucial role in segregating soft tissue and facilitating bone growth. This study emphasizes the importance of considering specific tissue requirements in the design of materials for tissue regeneration, with a focus on the development of a double-layered membrane to mimic both soft and hard tissues within the context of GBR. The hard tissue-facing layer comprises collagen and zinc-doped bioactive glass to support bone tissue regeneration, while the soft tissue-facing layer combines collagen and chitosan. The electrospinning technique was employed to achieve the production of nanofibers resembling extracellular matrix fibers. The production of nano-sized (~116 nm) bioactive glasses was achieved by microemulsion assisted sol-gel method. The bioactive glass-containing layers developed hydroxyapatite on their surfaces starting from the first week of simulated body fluid (SBF) immersion, demonstrating that the membranes possessed favorable bioactivity properties. Moreover, all membranes exhibited distinct degradation behaviors in various mediums. However, weight loss exceeding 50% was observed in all tested samples after four weeks in both SBF and phosphate-buffered saline (PBS). The double-layered membranes were also subjected to mechanical testing, revealing a tensile strength of approximately 4 MPa. The double-layered membranes containing zinc-doped bioactive glass demonstrated cell viability of over 70% across all tested concentrations (0.2, 0.1, and 0.02 g/mL), confirming the excellent biocompatibility of the membranes. The fabricated polymer bioactive glass composite double-layered membranes are strong candidates with the potential to be utilized in tissue engineering applications. Full article

Calcium phosphate (CaP) glass has recently gained popularity as a promising material for a wide range of biomedical applications. Recent developments have seen CaP glasses moving from a passive implant material to an active degradable material, particularly as a major constituent of bioresorbable photonic devices. This holds great promise in advanced biomedical applications, since the main constituents of CaP glasses are present in the human body. In this review, the progressive advancements in the biomedical applications of calcium phosphate glass-based devices over the past 50 years are discussed. An overview of their role as reinforcing agents and the studies on doping their matrices for ion releasing and drug and gene delivery are reviewed. Recent applications of CaP glass and fibers in soft-tissue engineering and their potential for optical quality bioresorbable devices are then discussed along with the current challenges and potential future directions, emphasizing the promising role of CaP glass in the next generation of biomaterials. Considering their progress and potential in performing several biomedical functionalities over time, CaP glass-based devices hold promise for becoming enabling tools as an implantable, bioresorbable, multifunctional class of devices in future biomedicine. Full article

Marine soft clays are prevalent in coastal regions of China, giving rise to engineering challenges such as salt swelling, corrosion, and load bearing in foundations with soft soil. This study is dedicated to enhancing the mechanical properties of fiber-reinforced cement-stabilized soft clay (FCSSC) and revealing its strengthening mechanism. Uniaxial compression tests are performed to explore the impact of fiber length, fiber amount, and curing ages on mechanical behavior. The stabilization mechanisms of cement and glass fibers are explored through damage analyses and microscopy. Based on the experimental results, a damage constitutive model is formulated for FCSSC, and its validity is established by comparing fitting curves with testing curves. The results demonstrate a significant improvement in the mechanical properties of the stabilized soil, attributed to the synergistic effects of the cement and glass fibers. The growth rate of the unconfined compressive strength decreased with increasing curing ages. Notably, the fiber length significantly impacted the strength index, with short-chopped fibers playing a crucial role in strength enhancement. The compressive strength exhibited an initial increase followed by a decrease with rising fiber content, reaching a maximum between 0.3% and 0.4%. The bridging effect of the glass fibers proved effective in inhibiting compression crack expansion and mitigating structural damage of the soil sample. However, excessive fiber content or length led to improved local porosity, resulting in the deterioration of strength and deformation properties. The stress–strain curves fitted using the proposed damage constitutive model accurately reflected the stress–strain relationship and deformation characteristics of the FCSSC. Full article

This research investigates the visible upconversion luminescence which is induced by multiphoton absorption of soft glass fiber defects. The study of this phenomenon has thus far been restricted to standard silica fibers. We observed the emission of green and cyan light as a consequence of fiber material ionization. We investigate both the commercial ZBLAN step index and in-house-made tellurite nanostructured graded-index fibers. For the latter, the analysis of the luminescence signal permits us to determine the core and cladding refractive index difference. Upconversion luminescence is a powerful tool for characterizing soft glass fibers and a promising platform for innovative photonic technologies and mid-IR applications. Full article

Microplastic contamination is a global concern due to its conspicuous presence in aquatic ecosystems and its toxic nature to environmental and human health. False mussels are among the most notable fresh- and brackish water invaders. The invasive Mytilopsis leucophaeata in Rodrigo de Freitas Lagoon-RFL (Rio de Janeiro, Brazil) is the most abundant macrofaunal invertebrate, widely established and distributed throughout the lagoon. This study aimed to assess microplastic contamination in this invasive filter feeder and evaluate its potential use as a bioindicator. Agglomerates (~100 mussels) were manually collected using a stainless-steel spatula in ten sampling areas distributed throughout the whole lagoon and kept frozen. In the laboratory, 60 individuals were sorted by area for soft-tissue digestion. Each pool of 10 soft-tissue mussels (n = 6 by area) was wet-weighted and then placed in a 150-mL decontaminated glass beaker with 50 mL of 10% KOH. Samples were heated (40 °C) for 48 h, and digested samples were filtered in glass-fiber membranes. Microplastics were found in all samples of mussels (n = 60) from RFL; the particles were mostly lower than 100 µm with a mean concentration (±SD) of 35.96 ± 47.64 MPs g wet-weight⁻¹. Microplastics were distinguished in seven shapes with different occurrences in samples (%): fiber (43.3%); fragment (34.3%); film (16.3%); sponge/foam (4.9%); pellet (0.57%), rope/filaments (0.17%); and undefined (0.4%). Thirteen colors of microplastics were found, but transparent (54.94%), black (10.77%), and white (9.36%) were the most common. Mytilopsis leucophaeata were useful to assess microplastic contamination in RFL and might be preferentially used in other invaded brackish systems instead of native and often threatened bivalves. Our results confirm the effective application of bivalves as an indicator of coastal microplastic pollution. Full article

Poor interlaminar fracture toughness has been a major issue in glass fiber-reinforced epoxy resin (GF/EP) laminate composites. In this paper, soft carboxy-terminated nitrile (CTBN) rubber particles and rigid nano-SiO₂ are used to toughen the epoxy resin (EP) matrix to improve the interlayer properties of GF/EP laminate composites. The effects of adding two toughening agents on the mechanical and interlayer properties of GF/EP laminates were studied. The results showed that adding the two kinds of particles improved the mechanical properties of the epoxy matrix. When the additional amount of flexible CTBN rubber particles was 8 wt%, and the rigid nano-SiO₂ was 0.5 wt%, the fracture toughness of the matrix resin was increased by 215.8%, and the tensile strength was only decreased by 2.3% compared with the pure epoxy resin. On this basis, the effects of two kinds of particles on the interlayer properties of GF/EP composites were studied. Compared with the unmodified GF/EP laminates, the interlayer shear strength and mode I interlayer fracture toughness is significantly improved by a toughening agent, and the energy release rate G_IC of interlayer shear strength and interlayer fracture toughness is increased by 109.2%, and 86.8%, respectively. The flexible CTBN rubber particles and rigid nano-SiO₂ improve the interfacial adhesion between GF and EP. The cavitation of the two particles and the plastic deformation of the matrix is the toughening mechanism of the interlayer properties of the composite. Such excellent interlaminar mechanical properties make it possible for GF/EP laminates to be widely used as engineering materials in various industries (e.g., aerospace, hydrogen energy, marine). Full article