Search Results (30)

The P(IA-HBP-AA-AM)/MMT composite was successfully synthesized via in situ polymerization and characterized using FTIR, XRD, TGA, and other techniques. The material was then applied as an adsorbent for the removal of heavy metals from simulated mining-contaminated water (prepared based on the typical ionic composition of real mining wastewater). Static adsorption experiments revealed that P(IA-HBP-AA-AM)/MMT composite could efficiently remove Pb(II) from contaminated water, and the adsorption behavior was well described by the pseudo-second-order kinetic model and the Langmuir isotherm model. Thermodynamic analysis indicated that the adsorption of Pb(II) onto the P(IA-HBP-AA-AM)/MMT composite was an endothermic and spontaneous process. At pH = 4.5 and T = 45 °C, the maximum adsorption capacity obtained from model fitting was 249.38 mg/g. The material exhibited strong selectivity for Pb(II), even in the presence of competing metal ions such as Cd(II), Zn(II), Al(III), Fe(III), K(I), and Na(I). Moreover, after five adsorption–desorption cycles, it still retained approximately 90% of its Pb(II) removal efficiency. Furthermore, dynamic adsorption experiments showed that the saturation adsorption capacity of Pb(II) reached 178.7 mg/g, with a column utilization efficiency of approximately 41%. These findings demonstrate the promising potential of P(IA-HBP-AA-AM)/MMT composite for the removal of Pb(II) from mining-contaminated water. Full article

Coal mining has generated a large amount of underground space, which has traditionally been reused mostly as mine wastewater storage. Given the excellent thermal insulation properties of these mine reservoirs, their potential for seasonal energy storage is considerable. However, research on cross-seasonal thermal energy storage utilizing coal mine underground reservoirs remains limited, and the thermal storage characteristics of such systems throughout their entire operational cycle are not yet fully understood. This study employs numerical simulation methods to analyze the thermal storage performance of a cross-seasonal thermal storage system based on a coal mine underground reservoir throughout a fully operation cycle. Based on the actual geological conditions of the Daliuta Coal Mine in the Shendong Mining Area, we established a thermal-fluid coupling model for a coal mine underground reservoir. Using this model, we analyzed the entire process of the heat injection stage, heat storage stage, and heat production stage within the cross-seasonal thermal energy storage system. Based on the model, the feasibility of utilizing a coal mine underground reservoir for cross-seasonal thermal energy storage was evaluated, and the system’s thermal storage performance was assessed. Results indicate that under current geological conditions of the Daliuta Coal Mine and designed operating parameters, the effective heat storage rate of the cross-seasonal system can reach 78.16%. Through investigation of the thermal storage process, the distribution evolution of hot water and heat dissipation mechanisms were thoroughly analyzed. This study identified the heat storage phase as the primary stage controlling heat loss and discussed key influencing factors affecting the thermal storage process. These findings provide novel insights for utilizing coal mine goafs and residual underground spaces, offering a reference for developing and designing novel energy storage facilities. Full article

The removal of copper–cyanide complexes from cyanide gold leaching tail water poses a significant challenge, as they are difficult to eliminate and risk causing secondary pollution. This study developed a synergistic flocculation–flotation process using the bio-collector sodium cocoyl glycinate (SCG) and the coagulant polyferric sulfate (PFS) for purification. Simulated wastewater, prepared based on actual gold mine effluent, was treated under optimized conditions of reagent dosage, a solution pH of 6–10, and a flotation time of 1–5 min, achieving high removal efficiencies of 96.48% for copper and 94.68% for total cyanide. Mechanistic studies via FT-IR, Zeta potential, and XPS revealed that Fe³⁺ from PFS formed Fe-CN complexes with both free and copper-complexed cyanide. Simultaneously, copper ions coordinated with SCG to generate a hydrophobic Fe-CN-Cu-SCG ternary complex, which was subsequently removed by adsorption onto air bubbles via the hydrophobic chains of SCG. This work provides a novel, efficient, and mechanistically clear strategy for the advanced treatment of cyanide-containing tailing water with a gold content of 0.021 mg/L. Full article

This study focuses on the Lujiang Alum Mine, analyzing sources of acid mine drainage (AMD) generated during remediation activities. A numerical model of groundwater flow was constructed to simulate and predict the causes of AMD under the influence of remediation measures. Concurrently, hydrogen and oxygen stable-isotope-tracing techniques were employed to elucidate the pathways through which AMD occurred and the mechanisms underlying water acidification. A fully mixed model was established to quantify the rates of contribution from different water sources. The results indicate that the annual amount of acidic wastewater produced under the influence of disturbance via remediation is approximately 3.29 × 10⁵ m³. The fully mixed model based on environmental isotopes further revealed that the discharge of water from the first branch of the +85 m adit serves as the primary cause of AMD during the wet, normal, and dry seasons, with a contribution exceeding 50%. This is followed by recharge from Tianchi Lake, accounting for approximately 20–30%. In contrast, the contributions from seepage water from the roof of the +85 m adit and water from the Xiaofanshan Inclined Shaft are relatively minor. Based on these findings, we propose targeted strategies for source prevention and end-of-pipe treatment of AMD in the mining area. This work provides scientific support for the ongoing ecological restoration project at the Lujiang Alum Mine and offers valuable insights for AMD management in similar mines. Full article

Prior research has proposed a basic configuration for a deep-sea mining system integrating slurry transport and wastewater discharge, and examined the operational characteristics of water-driven diaphragm pumps. Against the backdrop of commercial deep-sea polymetallic nodule exploitation, this study focuses on the technical design of seabed diaphragm pump groups and hydraulic parameter matching for a coupled slurry transport-wastewater discharge system. The solid–liquid two-phase output characteristics of the water-driven diaphragm pump were analyzed, leading to the proposal of a four-pump staggered configuration to ensure continuous particulate discharge throughout the full operating cycle. To meet commercial mining capacity requirements, the system consists of two sets (each with four pumps) operating with a phase offset to reduce fluctuations in slurry output concentration. A centralized output device was developed for the pump group, and a centralized mixing tank was designed based on analyses of outlet pipe length and positional effects. CFD-DEM simulations show that the combined effects of phased pump operation and centralized mixing tank mixing result in the slurry concentration delivered to the riser pipeline staying within ±1% of the mean for up to 57.8% of the system’s operational time. Considering the characteristics of both diaphragm and centrifugal pumps, the system is designed to output high-concentration slurry from the seabed diaphragm pumps, driven solely by wastewater, while centrifugal pumps provide lower-concentration transport by adding supplementary water from a buffer—thus reducing the risk of clogging. Under the constraints of centrifugal pump capacity, the system’s hydraulic parameters were optimized to maximize overall slurry transport efficiency while minimizing the energy consumption from wastewater discharge. The resulting configuration defines the flow rate and slurry concentration of the diaphragm pump group. Compared with conventional centrifugal pump-based transport schemes, the proposed system increases the slurry pipeline efficiency from 53.14% to 55.43% and reduces wastewater discharge-related pipeline resistance losses from 475.9 mH₂O to 361.7 mH₂O. Full article

The development of advanced photocatalysts that are efficient, recyclable and sustainable represents a significant challenge in the face of the growing presence of persistent organic contaminants in industrial wastewaters. This paper presents a novel approach based on the design of new heterostructures synthesized from BiOI and magnetic materials, using not only synthetic magnetite, but also magnetic compounds extracted from mine tailings, transforming environmental liabilities in active supporting materials through valorization strategies in line with the circular economy. Through precise control of composition, it was established that a proportion of 6% by mass of the magnetic phase allows the formation of a heterostructure that is highly photocatalytically efficient. These compounds were evaluated using caffeic acid, an organic contaminant of agroindustrial origin, as a target compound. Experiments were carried out under simulated solar radiation for 120 min. Among the materials synthesized, the BiOI/MMA heterostructure, derived from industrial tailing A, displayed an outstanding photodegradation efficiency of over 89.4 ± 0.25%, attributed to an effective separation of photoinduced charges, a broad active surface and a synergic interface interaction between its constituent phases. Furthermore, BiOI/MMA exhibited excellent structural stability and magnetic recovery capacity, which allowed for its reuse through two consecutive cycles without any significant losses to its photocatalytic performance. Thus, this study constitutes a significant contribution to the design of functional photocatalysts derived from industrial tailings, thus promoting clean, technological solutions for the treatment of wastewater and reinforcing the link between environmental remediation and circular economy. Full article

Mining discharge, namely acid mine drainage (AMD), is a significant environmental issue due to mining activities and site-specific factors. These pose challenges in choosing and executing suitable treatment procedures that are both sustainable and effective. Ceramic membranes, with their durability, long lifespan, and ease of maintenance, are increasingly used in industrial wastewater treatment due to their superior features. This review provides an overview of current remediation techniques for mining effluents, focusing on the use of ceramic membrane technology. It examines pressure-driven ceramic membrane systems like microfiltration, ultrafiltration, and nanofiltration, as well as the potential of vacuum membrane distillation for mine drainage treatment. Research on ceramic membranes in the mining sector is limited due to challenges such as complex effluent composition, low membrane packing density, and poor ion separation efficiency. To assess their effectiveness, this review also considers studies conducted on simulated water. Future research should focus on enhancing capital costs, developing more effective membrane configurations, modifying membrane outer layers, evaluating the long-term stability of the membrane performance, and exploring water recycling during mineral processing. Full article

Chlorella sp. was cultivated in a closed system using PET bottles (5 L) and with the continuous injection of air and commercial gas (98% CO₂) and in simulated conditions (15% CO₂, 73% N₂, and 12% O₂). The culture medium was prepared using well water and mining wastewater, the cultivation period occurred in a 10-day cycle, and the cell growth curves were evaluated through cell counting using a Neubauer chamber. The cultivation was carried out under the following conditions: temperature at 22 °C to 25 °C; aeration rate with commercial and simulated CO₂ gas at 0.01 vvm; and synthetic air containing 0.042% CO₂. The dry biomass productivity was 0.81 g·L⁻¹·day⁻¹ and the maximum CO₂ fixation rate was 0.90 g·L⁻¹·day⁻¹ when the microalgae were cultivated with a continuous flow of simulated waste gas and a culture medium composed of wastewater. The percentages of macromolecules obtained in the biomass cultivated in wastewater reached 20.95%, 26.48%, and 9.3% for lipids, proteins, and carbohydrates, respectively. Full article

Tailings ponds can recycle water resources through the water recirculation system by clarifying and purifying the wastewater discharged from the mining production process. Due to factors such as flooding and heavy rainfall, once a tailings dams burst, the spread of heavy metals in the tailings causes underground and surface water pollution, endangering the lives and properties of people downstream. To effectively assess the potential impact of tailings dams bursting, many problems such as the difficulty of taking values in predicting the volume of silt penetration through empirical formulae, model testing, and numerical simulation need to be solved. In this study, 65 engineering cases were collected to develop a sample dataset containing dam height and storage capacity. The Support Vector Machine (SVM) algorithm was used to develop a nonlinear regression model for tailings discharge volume after tailings dam failure. In addition, the model penalty parameter C and kernel function g were optimized using the powerful global search capability of the Slime Mold Algorithm (SMA) to develop an SMA–SVM prediction model for tailings discharge volume. The results indicate that the volume of tailings discharged increases nonlinearly with increasing dam height and tailings storage capacity. The SMA-SVM model showed higher prediction accuracy compared to the predictions made by the Random Forest (RF), Radial Basis Function (RBF), and Least Squares SVM (LS-SVM) algorithms. The average absolute error in tailings discharge volume compared to actual values was 30,000 m³, with an average relative error of less than 25%. This is very close to practical engineering scenarios. The ability of the SMA-SVM optimization algorithm to produce predictions with minimal error relative to actual values was further confirmed by the combination of numerical simulations. In addition, the numerical simulations revealed the flow characteristics and inundation area of the discharged sediment during tailings dam failure, and the research results can provide reference for water resource protection and downstream safety prevention and control of tailings ponds. Full article

Biological treatment processes at low or neutral pH are ineffective for gold mine wastewater treatment. The aim of this study was to develop a new cyanide-rich gold mine wastewater treatment system using alkaliphilic microbial consortia from the Ethiopian Rift Valley soda lake, Lake Chitu. The treatment setup incorporates aerobic and anoxic reactors connected in series and operated for about 200 treatment days. Simulated gold mine wastewater was formulated in the laboratory. Colorimetry was used to measure residual cyanide and reactive nitrogen molecules derived from cyanide biodegradation. Flocks and biofilms developed in the reactors during the acclimatization process. Using sodium cyanide at 200 mg/L as an initial concentration, the consortia degraded to 99.74 ± 0.08% of cyanide, with no significant variation (p > 0.05) occurring when the dose was increased to 800 mg/L. However, changes were observed (p < 0.05) at 1000 mg/L. Acetate was the preferred carbon source for the consortia. The established consortia effectively degraded cyanide to levels below the permissible discharge limit set by the International Cyanide Management Institute (ICMI). This study provides insights into the effectiveness of alkaliphilic microbial consortia derived from soda lakes for treating cyanide-polluted wastewater. Full article

Mining industries have long relied on cyanidation as the primary method for gold extraction, but this process generates thiocyanates as a problematic byproduct, posing challenges for wastewater treatment and recycling. The stability of thiocyanates makes their reduction or elimination in mining wastewater difficult. In this study, a p-n heterojunction of ZnO and BiOI was created and evaluated for its ability to photodegrade thiocyanate ions under simulated solar conditions. Various analytical techniques revealed a highly porous structure with a sponge-like morphology and agglomeration in the synthesized heterojunction. The compound exhibited crystalline patterns without impurity peaks, a slight red shift in absorbance, and Type IV isotherm adsorption. The synthesized heterostructure achieved the complete destruction of thiocyanate ions in less than 30 min. The investigation of different process parameters indicated that the destruction of the contaminant by the heterostructure was influenced by the initial thiocyanate concentration, which decreased as the thiocyanate concentration increased. The peak photodestruction reaction was observed at pH 7. By applying a pseudo-first-order kinetic model, it was found that increasing the catalyst mass to 15 mg raised the rate constant from 0.188 to 0.420 min⁻¹, while increasing the pH to 10 led to a 3.5-fold reduction. The strong correlation between the observed data and the predicted values of the pseudo-first-order kinetic model was indicated by the observed (R²) values. The findings of this study hold potential significance for mining industries, as it offers a potential solution for eliminating cyanide and thiocyanates from mining wastewater. The elimination of thiocyanate generation in the cyanidation process is crucial for mining companies, making this study valuable for the industry. Full article

The secondary waste produced by NdFeB waste after rare earth recycling, with an annual output of more than tens of thousands of tons, is the largest solid waste emission source in the rare earth industry, and long-term storage causes land resource occupation and environmental pollution. Arsenic-containing mine wastewater has serious harm, wide distribution, and long duration of pollution. In this study, the mechanical ball milling method was used to activate NdFeB secondary waste to prepare micro-nano magnetic composite materials, the main components of which are Fe₂O₃, Fe₃O₄, and C. Under mechanical mechanochemical action, the particles are more dispersed, the particle size decreases, the specific surface area increases significantly, the crystal structure changes to amorphous structure, the degree of amorphous shape increases, and the content of Fe-OH increases. Applied to the treatment of As (V) in simulated mine water, it was found that the removal of As (V) by this material was mainly based on chemisorption and monolayer adsorption, and the maximum adsorption amount reached 10.477 mg/g. Zeta, FT-IT, and XPS characterization confirmed that the removal of As (V) was a coordination exchange reaction between the material and As (V) to form an inner sphere complex. The removal rate of As (V) decreased from 94.33% to 73.56% when the initial concentration of solution was 10 mg/L, pH value was 3.0, and material dosage was 1 g/L after 5 times of regrowth. This study provides a new way for the application of NdFeB secondary waste, which has low cost, green environmental protection, and wide application prospects. Full article

Sulfate is a typical characteristic pollutant in mine water. Because of its high concentration and large discharge of mine water, it has become a difficult problem in mineral exploitation. Capacitive deionization (CDI) is an innovative and economical removal technology. There are few reports on the use of CDI to remove SO₄²⁻ from mine water. In this study, a CeO₂ activated carbon electrode with good wettability, excellent electrochemical performance, and suitable pore structure was prepared by the sol-gel method. The application of the CeO₂ activated carbon electrode to the capacitive method for treating high SO₄²⁻ mine water was investigated using simulated wastewater and actual mine water. The study structure shows that CeO₂:activated carbon (AC) has the best wettability, the highest specific capacitance, and the lowest electrical conductivity when the mass ratio of CeO₂ is 5%. At 100 mg/L, the electrode has the maximum SO₄²⁻ ion specific adsorption capacity (SAC). At 1 V and 20 mL/min, this value is measured. The electrode has a SAC value of 9.36 mg/g, far higher than the AC electrode’s 4.1 mg/g. The effect of CDI process factors such the voltage, flow rate, and initial concentration was studied to find the best treatment method. SAC retention is 91% after 10 adsorption–desorption cycles, demonstrating outstanding electrode performance. Under the best CDI process (1.4 volts, 30 mL/min), mine water was treated. After 20 cycles of treatment, the concentration of SO₄²⁻ in mine water decreased from 1170 mg/L to 276.46 mg/L, and the removal rate was 76.37%. This study proved that the CeO₂ modified activated carbon electrode capacitance method can effectively remove sulfate ions and other ions from mine water. Full article

Acid mine drainage was utilized to catalyze the solar photo-Fenton treatment of wastewater coming from a sludge dewatering system. Acid mine drainage in the form of iron-rich liquid or synthesized minerals (namely magnetite, hematite, and goethite) was added in the wastewater, which was treated by means of the solar photo-Fenton process. The effects of operational parameters such as the amount of acid mine drainage, the wastewater matrix (i.e., synthetic and real wastewater), and the initial H₂O₂ concentration municipal wastewater’s organic content were explored. The results showed that using acid mine drainage (liquid phase) for wastewater treatment was more efficient than using the acid-mine-drainage-recovered minerals. Moreover, it was observed that the addition of acid mine drainage above 10.7 mL/L wastewater, which is equivalent to 50 mg/L iron, could substantially reduce the removal percentage of the chemical oxygen demand (COD). At the best conditions assayed, COD removal reached 99% after 90 min of photo-Fenton treatment under simulated solar light, in the presence of 30 mg/L Fe (i.e., 6.4 mL drainage/L of real wastewater) and 1000 mg/L H₂O₂ at a pH of 2.8. Therefore, the solar photo-Fenton treatment of municipal wastewater catalyzed by acid mine drainage may appear to be a promising method to effectively improve wastewater management, especially in areas with high solar energy potential. Full article

Mining wastewater (MWW) can contain mercury in high concentrations. In this study, four autochthonous aquatic plant species (Eichhornia Crassipes—EC, Marsilea Quadrifolia—MQ, Ludwigia Helminthorrhiza—LH, and Lemna Minor—LM) were identified and tested for phytoaccumulation of total mercury (THg). To better study the accumulation phenomenon and macrophyte responses, this work has been divided into three phases, and pilot-scale reactors have been used to simulate real conditions. The results highlighted that, in case of 15 µg_THg,fed, the bioconcentration factor (BCF) was significantly higher in EC (19.04) and LH (18.41) with respect to MQ and LM (almost six times and two times higher, respectively). EC granted the best results in terms of THg accumulation (50.90%) and lower evapotranspiration of THg phenomenon with respect to LH. A significant decrease of the BCF (from 23.45 to 21.98) and an increase of the TF (from 0.23 up to 0.73) after 42 d highlighted that a breaking-time in terms of THg accumulation was reached due to the deterioration of the roots. In terms of the kinetics of THg removal by bioaccumulation, an HLT of 69.31 d was found, which is more than the breaking-time of the EC system, proving that a periodic replacement of exhausted macrophytes is required to obtain a higher percentage of THg removal. Full article