Search Results (266)

The coupled factors of high temperature, high humidity, and high salinity in tropical marine atmospheres severely threaten the long-term service performance of power transmission and transformation infrastructure. This paper establishes an accelerated cyclic testing protocol (salt spray → drying → damp heat → drying) to evaluate performance and elucidate the dynamic corrosion failure mechanisms of the organic Zn14Al1.4 composite coating. By integrating multiphysical characterization techniques (SEM, EDS, XPS) with electrochemical analysis, this study for the first time elucidates the dynamic transformation of corrosion products: initially dominated by Zn(OH)₂, progressing to complex passive phases such as Zn₅(OH)₈Cl₂·H₂O, Zn₅(OH)₆(CO₃)₂, and Zn₆Al₂(OH)₁₆CO₃ in the mid-term, and ultimately dominated by Fe-based products (FeO, Fe₂O₃, Fe₃O₄, FeOOH) that drive interfacial failure. And a four-stage corrosion evolution model was defined: incubation period, accelerated degradation phase, substrate nucleation stage, and catastrophic failure phase. The investigation reveals a shift in the coating/substrate interface failure mechanism from purely physical barrier effects to electrochemical synergy, providing a theoretical framework for the optimized design and service-life prediction of anticorrosive coatings for transmission and transformation equipment in tropical environments. Full article

Subsea pipelines, operating in high-pressure and high-salinity conditions, face ongoing risks of leakage. Pipeline leaks can pollute the marine environment and, in severe cases, cause safety incidents, endangering human lives and property. Regular integrity inspections of subsea pipelines are critical to prevent corrosion-related leaks. This study develops a magnetic flux leakage (MFL)-based pig for detecting corrosion in subsea pipelines. Using a three-dimensional finite element model, this study analyzes the effects of defect geometry, lift-off distance, and operating speed on MFL signals. It proposes a defect estimation method based on axial peak-to-valley values and radial peak spacing, with inversion accuracy validated against simulation results. This study establishes a theoretical and practical framework for subsea pipeline integrity management, providing an effective solution for corrosion monitoring. Full article

This study systematically investigated the corrosion evolution and protective mechanisms of X80 pipeline steel in Xinjiang’s saline soil environments under freeze–thaw cycling conditions. Combining regional soil characterization with laboratory-constructed corrosion systems, we employed electrochemical impedance spectroscopy, potentiodynamic polarization, and surface analytical techniques to quantify temporal–spatial corrosion behavior across 30 freeze–thaw cycles. Experimental results revealed a distinctive corrosion resistance pattern: initial improvement (cycles 1–10) attributed to protective oxide layer formation, followed by accelerated degradation (cycles 10–30) due to microcrack propagation and chloride accumulation. Synchrotron X-ray diffraction analyses identified sulfate–chloride ion synergism as the primary driver of localized corrosion disparities in heterogeneous soil matrices. A comparative evaluation of asphalt-coated specimens demonstrated a 62%–89% corrosion rate reduction, with effectiveness directly correlating with coating integrity and thickness (200–500 μm range). Molecular dynamics simulations using Materials Studio revealed atomic-scale ion transport dynamics at coating–substrate interfaces, showing preferential Cl⁻ permeation through coating defects. These multiscale findings establish quantitative relationships between environmental stressors, coating parameters, and corrosion kinetics, providing a mechanistic framework for optimizing protective coatings in cold-region pipeline applications. Full article

RC piers in mountainous coastal or saline areas face the dual threats of rockfall impacts and chloride-induced steel corrosion, but their combined effects on dynamic response and residual bearing capacity remain unquantified. This study aims to investigate these combined effects over a 90-year service time and propose a damage assessment formula. A validated numerical model (relative error ≤14.7%) of corroded RC columns under impact is developed using ABAQUS, based on which the dynamic response and residual bearing capacity of an actual RC pier subjected to rockfall impacts during the service time of 90 years incorporating corrosion initiation (via Life-365 software 2.2) and propagation are analyzed, with the consideration of various impact energies (1–5 t mass, 5–15 m/s velocity). Results show that (1) increasing impact mass/velocity expands damage and increases displacement (e.g., the velocity of increases peak displacement by 33.41 mm in comparison to 5 m/s); (2) a 90-year service time leads to >50% severe surface damage and 47.1% residual capacity loss; and (3) the proposed and validated damage formula assessment formula for the residual bearing capacity enables lifecycle maintenance guidance. This work provides a validated framework for assessing combined corrosion-rockfall effects, aiding design and maintenance of structures. Full article

Leveraging the sensitivity of long-period fiber grating (LPFG) to changes in the environmental refractive index, an LPFG-based seawater concentration monitoring sensor is proposed. Considering the highly saltine and alkali characteristics of the sensor’s operating environment, the proposed sensor is packaged by basalt fiber-reinforced polymer (BFRP), and the sensor’s sensitivities were studied by sodium chloride and calcium chloride solution concentration experiments and one real-time sodium chloride solution concentration monitoring experiment. The test results show the wavelength of LPFG, a 3 dB bandwidth and a peak loss of LPFG’s spectrogram change with changes in the concentration of sodium chloride or calcium chloride solutions, but only the wavelength has a good linear relationship with the change in solution concentration, and the sensing coefficient is −0.160 nm/% in the sodium chloride solution and −0.225 nm/% in the calcium chloride solution. The real-time monitoring test further verified the sensor’s sensing performance, with an absolute measurement error of less than 1.8%. The BFRP packaged sensor has good corrosion resistance and a simple structure, and it has a certain application value in the monitoring of salinity in the marine environment and coastal soil. Full article

This study addresses the microbial corrosion of cement-based materials in coastal urban sewer networks, systematically investigating the kinetic mechanisms of sulfur biogeochemical cycling under seawater infiltration conditions. Through dynamic monitoring of sulfide concentrations and environmental parameter variations in anaerobic pipelines, a multiphase coupled kinetic model integrating liquid-phase, gas-phase, and biofilm metabolic processes was developed. The results demonstrate that moderate salinity enhances the activity of sulfate-reducing bacteria (SRB) and accelerates sulfate reduction rates, whereas excessive sulfide accumulation inhibits SRB activity. At 35 °C, the mathematical model coefficient “a” for sulfate reduction in the reactor with 3 g/L salinity was significantly higher than those in reactors with 19 g/L and 35 g/L salinities, with no significant difference observed between the latter two. Overall, high sulfate concentrations do not act as limiting factors for sulfide oxidation under anaerobic conditions; instead, they enhance the reaction within specific concentration ranges. The refined kinetic model enables prediction of sulfur speciation in tropical coastal urban sewer pipelines, providing a scientific basis for corrosion risk assessment. Full article

The increasing demand for sustainable energy and clean water has prompted the exploration of alternative solutions to reduce reliance on fossil fuels. In this context, hydrogen production through water electrolysis powered by solar energy presents a promising pathway toward a zero-carbon footprint. This study investigates the potential of copper slag, an abundant industrial waste, as a low-cost electrocatalyst for the hydrogen evolution reaction (HER) in contact with saline water such as 0.5 M NaCl and seawater, comparing the electrochemical response when in contact with geothermal water from El Tatio (Atacama Desert). The physicochemical characterisation of copper slag was performed using XRD, Raman, and SEM-EDS to determine its surface properties. Electrochemical evaluations were conducted in 0.5 M NaCl and natural seawater using polarisation techniques to assess the corrosion behaviour and catalytic efficiency of the copper slag electrodes. The results indicate that copper slag exhibits high stability and promising HER kinetics, particularly in seawater, where its mesoporous structure facilitates efficient charge transfer processes. The key novelty of this manuscript lies in the direct revalorisation of untreated copper slag as a functional electrode for HER in real seawater and geothermal water, avoiding the use of expensive noble metals and aligning with circular economy principles. This innovative combination of recycled material and natural saline electrolyte enhances both the technical and economic viability of electrolysis, while reducing environmental impact and promoting green hydrogen production in coastal regions with high solar potential. This research contributes to the value of industrial waste, offering a viable pathway for advancing sustainable hydrogen technologies in real-world environments. Full article

Human development has led to increased production of oil and gas, mainly as energy sources, which, however, are responsible for contamination and metal corrosion in industrial, marine, and terrestrial environments. Lubricating oil, in particular, is widely used in generators and industrial machines in the electric sector and is responsible for contamination not only in industrial environments but also in many terrestrial and aquatic ecosystems. In this context, this study aimed to apply the Starmerella bombicola ATCC 222214 biosurfactant to inhibit metal corrosion in seawater and in an Accelerated Corrosion Chamber (ACC). For this purpose, its toxicity against the microcrustacean Artemia salina, its dispersion capacity, and its ability to promote oil biodegradation in a saline environment were investigated. The biosurfactant, when applied at twice its Critical Micellar Concentration (CMC), caused low mortality (30.0%) of microcrustaceans in a saline environment, and, in its crude form, the biosurfactant ensured the dispersion of no less than 77.56% of residual engine oil in seawater. Oil biodegradation by autochthonous microorganisms reached 94.39% in the presence of the biosurfactant in seawater. Furthermore, the biosurfactant, when used at twice its CMC, acted satisfactorily as a corrosion inhibitor by reducing the mass loss of galvanized iron specimens (plates) in seawater in a static system to only 0.36%. On the other hand, when the biosurfactant was added at the CMC as an atmospheric corrosion inhibitor, the reduction in mass loss of carbon steel plates treated in the ACC was 17.38% compared to the control containing only a biodegradable matrix based on vegetable resin. When the biosurfactant was incorporated into different paints applied to galvanized iron plates placed in contact with the salt spray produced in the ACC, the best result was obtained using the biomolecule at a concentration of 3% in the satin paint, ensuring a plate mass loss (29.236 g/m²) that was almost half that obtained without surfactant (52.967 g/m²). The study indicated the use of yeast biosurfactant as a sustainable alternative in combating the contamination of marine environments and metal corrosion, with the aim of preserving the environment and improving the quality of life in aquatic and terrestrial ecosystems. Full article

This study investigates the tribo-corrosion behavior of Ti6Al4V biomedical alloy, when sliding against fused filament fabrication (FFF) 3D-printed polyether ether ketone (PEEK) pins in a phosphate-buffered saline (PBS) solution. This research aims to evaluate wear mechanisms and electrochemical responses under simulated physiological conditions, providing critical insights for enhancing the durability and performance of biomedical implants. Potentiodynamic polarization tests demonstrate that the Ti6Al4V alloy possesses excellent corrosion resistance, which is further enhanced under sliding conditions compared to the test without sliding. When tested against 3D-printed PEEK, the alloy exhibits a mixed wear mechanism characterized by both abrasive and adhesive wear. Open-circuit potential (OCP) measurement of Ti6Al4V demonstrates the alloy’s superior electrochemical stability, indicating high corrosion resistance and a favorable coefficient of friction. These findings highlight the potential of 3D-printed PEEK as a viable alternative for biomedical applications, offering rapid patient-specific prototyping, tunable mechanical properties, and improved surface adaptability compared to conventional materials. Full article

The current paper examines the sustainable possibility for recycling unused or expired Metoprolol (MET), a benzodiazepine derivative, as an effective corrosion inhibitor for carbon steel in saline solutions. Repurposing expired medicinal drugs aligns with green chemistry concepts and supports circular economy initiatives by reducing pharmaceutical waste and averting the production of new synthetic inhibitors. The technical benefit of recycling expired MET drugs pertains to the elimination of costs associated with organic inhibitor manufacturing and the decrease in disposal expenses for the expired medication. A combination of electrochemical techniques (potentiodynamic polarization and electrochemical impedance spectroscopy) and quantum chemical calculations was employed to evaluate the inhibitory mechanism and efficacy of MET. At a concentration of 10⁻³ M, MET reduced the corrosion current density from 19.38 to 5.97 μA cm⁻², achieving a maximum IE of 69.1%. Adsorption Gibbs free energy, determined using different adsorption isotherms, revealed that interactions between metal atoms and MET adsorbed molecules have a chemical character with a ∆G^o_ads value of −50.7 kJ·mol⁻¹. Furthermore, quantum chemistry calculations indicate that the investigated drug, owing to its molecular structure (E_HOMO = −9.12 eV, E_LUMO = 0.21 eV, µ = 3.95 D), possesses the capacity to establish an adsorption layer on the metal surface, thereby impeding the diffusion of molecules and ions involved in the overall corrosion process. The results obtained using the different techniques were in good agreement and highlighted the effectiveness of MET in the corrosion inhibition of carbon steel. Full article

The corrosion within photovoltaic (PV) systems has become a critical challenge to address, significantly affecting the efficiency of solar-to-electric energy conversion, longevity, and economic viability. This review provides a comprehensive analysis of electrochemical corrosion mechanisms affecting solar panels and environmental factors that accelerate material degradation, including (i) humidity, (ii) temperature fluctuations, (iii) ultraviolet radiation, and (iv) exposure to saline environments, leading to reduced performance and premature failures. The role of encapsulation materials, solder interconnections, and conductive coatings in the corrosion formation process is examined. Various electrochemical and surface characterization techniques provide insights into material degradation and corrosion mechanisms within panels. Essential parameters are presented and discussed, including materials used, geographical location of analysis, environmental considerations, and corrosion characterization techniques, to enhance the assessment of solar panels. This review emphasizes the importance of corrosion management for sustainable PV systems and proposes future research directions for developing more durable materials and advanced coatings. Full article

This study prepared epoxy–clay nanocomposites (ECNs) by incorporating organophilic clays modified with either non-redox cetyltrimethylammonium bromide (CTAB) or redox-active aniline pentamer (AP), then compared their anticorrosion performance on metal substrates in saline environments. The test solution contained 2 wt% alkaline copper quaternary (ACQ) wood preservatives. Cold-rolled steel (CRS) panels coated with the ECNs were evaluated via electrochemical impedance spectroscopy (EIS) in saline media both with and without ACQ. For CRS coated with unmodified epoxy, the Nyquist plot showed impedance dropping from 255 kΩ to 121 kΩ upon adding 2 wt% ACQ—indicating that Cu²⁺ ions accelerate iron oxidation. Introducing 1 wt% CTAB–clay into the epoxy increased impedance from 121 kΩ to 271 kΩ, while 1 wt% AP–clay raised it to 702 kΩ. This improvement arises because the organophilic clay platelets create a more tortuous path for Cu²⁺ and O₂ diffusion, as confirmed by ICP–MS measurements of Cu²⁺ after EIS and oxygen permeability tests (GPA), thereby slowing iron oxidation. Moreover, ECN coatings containing AP–clay outperformed those with CTAB–clay in corrosion resistance, suggesting that AP not only enhances platelet dispersion but also promotes formation of a dense, passive metal oxide layer at the coating–metal interface, as shown by TEM, GPA, and XRD analyses. Finally, accelerated salt-spray exposure following ASTM B-117 yielded corrosion behavior consistent with the EIS results. Full article

Asphalt binder aging under natural exposure critically determines pavement durability, though current research inadequately captured performance evolution across diverse regional climates. This study investigated climate-driven degradation mechanisms through 12-month all-weather aging (AWA) tests in Gansu, Shandong, and Beijing via rheological (G-R parameter, stiffness modulus S-value) and chemical analyses (carbonyl index I_C=O, sulfoxide index I_S=O). The results demonstrated significant region-dependent aging disparities beyond laboratory simulation. In Gansu, extreme thermal fluctuations and UV radiation accelerated hardening via thermal stress cycles and photo-oxidation, yielding 52.4% higher G-R parameter than PAV. In Shandong, humid saline environments triggered sulfur oxidation-driven electrochemical corrosion, increasing I_S=O by 4.2% compared to PAV. In Beijing, synergistic UV–thermal oxidation elevated I_C=O and S-value by 8% and 40.7%, respectively versus PAV. Critically, I_C=O exhibited strong positive correlations with rheological degradation across regions (r > 0.90, p < 0.01). Based on I_C=O, the 12-month all-weather aging rate in Beijing exceeded Gansu and Shandong by 18.5% and 68%, revealing UV–thermal coupling as the most severe degradation pattern. Novelty lies in quantifying region-specific multi-factor coupling effects (UV–thermal, hygrothermal–salt, etc.) and demonstrating their superior severity over PAV (Beijing > Gansu > Shandong). Dominant environmental factors showed distinct regional variations: UV radiation and temperature difference dominated in Gansu (I_C=O, r = 0.76) and Beijing (0.74), while precipitation—I_C=O correlation prevailed in Shandong (0.76), yet multi-factor coupling ultimately governed aging. These findings provide theoretical foundations for region-tailored and climate-resilient asphalt pavement design. Full article

In recent years, the concept of reusing expired pharmaceuticals as corrosion inhibitors has attracted considerable attention due to the increasing demand for sustainable and eco-friendly solutions. This paper investigates the potential of an expired drug, called Fluimucil, containing N-acetylcysteine (NAC, 300 mg/3 mL), as a green corrosion inhibitor of bronze exposed to 3.5 wt.% NaCl solution and simulated acid rain (pH = 3.4). Potentiodynamic polarization measurements revealed that the drug acted mainly as a cathodic-type inhibitor in both electrolytes. Inhibition efficiency increased with drug concentration, reaching the maximum values of 86.7% in the presence of 36 mM NAC in the saline solution and 90.2% in the presence of 6 mM NAC in simulated acid rain. The anticorrosive effect of the drug was likely due to the adsorption of NAC on the bronze surface, which hindered to some extent the charge transfer reaction and corrosion product formation, thereby offering enhanced protection. Disregarding the nature of the corrosive electrolyte, NAC adsorption on the bronze followed the Langmuir isotherm model, involving a combination of physisorption and chemisorption processes. Surface examination by SEM-EDX confirmed that expired Fluimucil significantly mitigated the surface degradation and the corrosion products on the bronze. Full article

The application of rebar reinforced ultra-high-performance concrete (R-UHPC) has been increasingly adopted in engineering structures due to its exceptional mechanical performance and durability characteristics. Nevertheless, when subjected to combined saline and stray current conditions, R-UHPC remains vulnerable to severe corrosion degradation. This investigation examined the corrosion performance and tensile behavior evolution of R-UHPC containing 2.0 vol% copper-coated steel fiber content and HRB400 steel rebar with a reinforcement ratio of 3.1%. The accelerated corrosion process was induced through an impressed current method, followed by direct tensile tests at varying exposure periods. The findings revealed that the embedding of rebar in UHPC led to the formation of fiber-to-rebar (F-R) conductive pathways, generating radial cracks besides laminar cracks. The bonding between rebar and UHPC degraded as corrosion progressed, leading to the loss of characteristic multiple-cracking behavior of R-UHPC in tension. Meanwhile, R-UHPC load-bearing capacity, transitioning from gradual to accelerated deterioration phases with prolonged corrosion, aligns with steel fibers temporally. During the initial 4 days of corrosion, the specimens displayed surface-level corrosion features with negligible steel fiber loss, showing less than 4.0% reduction in ultimate bearing capacity. At 8 days of corrosion, the steel fiber decreased by 22.6%, accompanied by an 18.3% reduction in bearing capacity. By 16 days of corrosion, the steel fiber loss reached 41.5%, with a corresponding bearing capacity reduction of 29.1%. During the corrosion process, corrosion cracks and load-bearing degradation in R-UHPC could be indicated by the ultrasonic damage factor. Full article