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17 pages, 11770 KiB  
Article
Landslide Prediction in Mountainous Terrain Using Weighted Overlay Analysis Method: A Case Study of Al Figrah Road, Al-Madinah Al-Munawarah, Western Saudi Arabia
by Talal Alharbi, Abdelbaset S. El-Sorogy and Naji Rikan
Sustainability 2025, 17(15), 6914; https://doi.org/10.3390/su17156914 - 30 Jul 2025
Viewed by 222
Abstract
This study applies the Weighted Overlay Analysis (WOA) method integrated with GIS to assess landslide susceptibility along Al Figrah Road in Al-Madinah Al-Munawarah, western Saudi Arabia. Seven key conditioning factors, elevation, slope, aspect, drainage density, lithology, soil type, and precipitation were integrated using [...] Read more.
This study applies the Weighted Overlay Analysis (WOA) method integrated with GIS to assess landslide susceptibility along Al Figrah Road in Al-Madinah Al-Munawarah, western Saudi Arabia. Seven key conditioning factors, elevation, slope, aspect, drainage density, lithology, soil type, and precipitation were integrated using high-resolution remote sensing data and expert-assigned weights. The output susceptibility map categorized the region into three zones: low (93.5 million m2), moderate (271.2 million m2), and high risk (33.1 million m2). Approximately 29% of the road corridor lies within the low-risk zone, 48% in the moderate zone, and 23% in the high-risk zone. Ten critical sites with potential landslide activity were detected along the road, correlating well with the high-risk zones on the map. Structural weaknesses in the area, such as faults, joints, foliation planes, and shear zones in both igneous and metamorphic rock units, were key contributors to slope instability. The findings offer practical guidance for infrastructure planning and geohazard mitigation in arid, mountainous environments and demonstrate the applicability of WOA in data-scarce regions. Full article
(This article belongs to the Special Issue Sustainable Assessment and Risk Analysis on Landslide Hazards)
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40 pages, 18210 KiB  
Article
Geological Significance of Bulk Density and Magnetic Susceptibility of the Rocks from Northwest Himalayas, Pakistan
by Fahad Hameed, Muhammad Rustam Khan, Jiangtao Tian, Muhammad Atif Bilal, Cheng Wang, Yongzhi Wang, Muhammad Saleem Mughal and Abrar Niaz
Minerals 2025, 15(8), 781; https://doi.org/10.3390/min15080781 - 25 Jul 2025
Viewed by 719
Abstract
The present study provides a detailed compilation and analysis of the bulk density and magnetic susceptibility of the rocks from the northwest Himalayas, Pakistan. The area is tectonically extremely complex and comprises sedimentary, metamorphic, and igneous rocks. These rocks range in age from [...] Read more.
The present study provides a detailed compilation and analysis of the bulk density and magnetic susceptibility of the rocks from the northwest Himalayas, Pakistan. The area is tectonically extremely complex and comprises sedimentary, metamorphic, and igneous rocks. These rocks range in age from Early Proterozoic to Recent. During the fieldwork, 476 rock samples were collected for density measurements and 410 for magnetic susceptibility measurements from the major rock units exposed in the study area. The measured physical parameters reveal a significant difference in the density and susceptibility of the rocks present in the investigated area. The sedimentary rock units belonging to the Indian Plate show the lowest mean values for bulk density, followed by metasedimentary rocks, Early Proterozoic rocks, igneous and metaigneous rock units of the Indian Plate, Indus Suture Melange Zone, and Kohistan Island Arc rocks, respectively. The magnetic susceptibility of sedimentary rock units of the Indian Plate has the lowest mean values, followed by metasedimentary rocks of the Indian Plate, igneous and metaigneous rock units of the Indian Plate, Early Proterozoic rocks of the Indian Plate, Kohistan Island Arc rocks, and Indus Suture Melange Zone. In brief, the sedimentary rocks of the Indian Plate have the lowest bulk density and magnetic susceptibility values, whereas the Kohistan Island Arc rocks have the highest values. Overall, the bulk density and magnetic susceptibility of rock units in the study area follow those predicted for different types of rocks. These measurements can be used to develop possible potential field models of the northwest Himalayas to better understand the tectonics of the ongoing continental-to-continental collision, as well as for many other geological analyses. Full article
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29 pages, 8706 KiB  
Article
An Integrated Risk Assessment of Rockfalls Along Highway Networks in Mountainous Regions: The Case of Guizhou, China
by Jinchen Yang, Zhiwen Xu, Mei Gong, Suhua Zhou and Minghua Huang
Appl. Sci. 2025, 15(15), 8212; https://doi.org/10.3390/app15158212 - 23 Jul 2025
Viewed by 216
Abstract
Rockfalls, among the most common natural disasters, pose risks such as traffic congestion, casualties, and substantial property damage. Guizhou Province, with China’s fourth-longest highway network, features mountainous terrain prone to frequent rockfall incidents annually. Consequently, assessing highway rockfall risks in Guizhou Province is [...] Read more.
Rockfalls, among the most common natural disasters, pose risks such as traffic congestion, casualties, and substantial property damage. Guizhou Province, with China’s fourth-longest highway network, features mountainous terrain prone to frequent rockfall incidents annually. Consequently, assessing highway rockfall risks in Guizhou Province is crucial for safeguarding the lives and travel of residents. This study evaluates highway rockfall risk through three key components: susceptibility, hazard, and vulnerability. Susceptibility was assessed using information content and logistic regression methods, considering factors such as elevation, slope, normalized difference vegetation index (NDVI), aspect, distance from fault, relief amplitude, lithology, and rock weathering index (RWI). Hazard assessment utilized a fuzzy analytic hierarchy process (AHP), focusing on average annual rainfall and daily maximum rainfall. Socioeconomic factors, including GDP, population density, and land use type, were incorporated to gauge vulnerability. Integration of these assessments via a risk matrix yielded comprehensive highway rockfall risk profiles. Results indicate a predominantly high risk across Guizhou Province, with high-risk zones covering 41.19% of the area. Spatially, the western regions exhibit higher risk levels compared to eastern areas. Notably, the Bijie region features over 70% of its highway mileage categorized as high risk or above. Logistic regression identified distance from fault lines as the most negatively correlated factor affecting highway rockfall susceptibility, whereas elevation gradient demonstrated a minimal influence. This research provides valuable insights for decision-makers in formulating highway rockfall prevention and control strategies. Full article
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17 pages, 2629 KiB  
Article
Recovery of High-Alkali-Grade Feldspar Substitute from Phonolite Tailings
by Savas Ozun, Semsettin Ulutas and Sema Yurdakul
Processes 2025, 13(8), 2334; https://doi.org/10.3390/pr13082334 - 23 Jul 2025
Viewed by 267
Abstract
Phonolite is a fine-grained, shallow extrusive rock rich in alkali minerals and containing iron/titanium-bearing minerals. This rock is widely used as a construction material for building exteriors due to its excellent abrasion resistance and insulation properties. However, during the cutting process, approximately 70% [...] Read more.
Phonolite is a fine-grained, shallow extrusive rock rich in alkali minerals and containing iron/titanium-bearing minerals. This rock is widely used as a construction material for building exteriors due to its excellent abrasion resistance and insulation properties. However, during the cutting process, approximately 70% of the rock is discarded as tailing. So, this study aims to repurpose tailings from a phonolite cutting and sizing plant into a high-alkali ceramic raw mineral concentrate. To enable the use of phonolite tailings in ceramic manufacturing, it is necessary to remove coloring iron/titanium-bearing minerals, which negatively affect the final product. To achieve this removal, dry/wet magnetic separation processes, along with flotation, were employed both individually and in combination. The results demonstrated that using dry high-intensity magnetic separation (DHIMS) resulted in a concentrate with an Fe2O3 + TiO2 grade of 0.95% and a removal efficiency of 85%. The wet high-intensity magnetic separation (WHIMS) process reduced the Fe2O3 + TiO2 grade of the concentrate to 1.2%, with 70% removal efficiency. During flotation tests, both pH levels and collector concentration impacted the efficiency and Fe2O3 + TiO2 grade (%) of the concentrate. The lowest Fe2O3 + TiO2 grade of 1.65% was achieved at a pH level of 10 with a collector concentration of 2000 g/t. Flotation concentrates processed with DHIMS achieved a minimum Fe2O3 + TiO2 grade of 0.90%, while those processed with WHIMS exhibited higher Fe2O3 + TiO2 grades (>1.1%) and higher recovery rates (80%). Additionally, studies on flotation applied to WHIMS concentrates showed that collector concentration, pulp density, and conditioning time significantly influenced the Fe2O3 + TiO2 grade of the final concentrate. Full article
(This article belongs to the Section Separation Processes)
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17 pages, 3791 KiB  
Article
Loading Response of Segment Lining with Pea-Gravel Grouting Defects for TBM Tunnel in Transition Zones of Surrounding Rocks
by Qixing Che, Changyong Li, Xiangfeng Wang, Zhixiao Zhang, Yintao He and Shunbo Zhao
Eng 2025, 6(7), 166; https://doi.org/10.3390/eng6070166 - 21 Jul 2025
Viewed by 252
Abstract
Pea-gravel grouting, which fills the gap between the lining of tunnels and the surrounding rock, is crucial for the structural stability and waterproofing of water delivery TBM tunnels. However, it is prone to defects due to complex construction conditions and geological factors. To [...] Read more.
Pea-gravel grouting, which fills the gap between the lining of tunnels and the surrounding rock, is crucial for the structural stability and waterproofing of water delivery TBM tunnels. However, it is prone to defects due to complex construction conditions and geological factors. To provide practical insights for engineers to evaluate grouting quality and take appropriate remedial action during TBM tunnel construction, this paper assesses four types of pea-gravel grouting defects, including local cavities, less density, rich rock powder and rich cement slurry. Detailed numerical simulation models comprising segment lining, pea-gravel grouting and surrounding rock were built using the 3D finite element method to analyze the displacement and stress of the segments at the transition zone between different classes of surrounding rocks, labeled V–IV, V–III and IV–III. The results indicate that a local cavity defect has the greatest impact on the loading response of segment lining, followed by less density, rich rock powder and rich cement slurry defects. Their impact will weaken with better self-support of the surrounding rocks in the order of V–IV, V–III and IV–III. The tensile stress of segment lining is within the limit of concrete cracking for combinations of all four defects when the surrounding rock is of the class IV–III, and it is within this limit for two-defect combinations when the surrounding rock is of classes V–III and V–IV. When three defects or all four defects are present in the pea-gravel grouting, the possibility of segment concrete cracking increases from the transition zone of class V–III surrounding rock to the transition zone of class V–IV surrounding rock. Full article
(This article belongs to the Topic Hydraulic Engineering and Modelling)
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32 pages, 23012 KiB  
Article
A DEM Study on the Macro- and Micro-Mechanical Characteristics of an Irregularly Shaped Soil–Rock Mixture Based on the Analysis of the Contact Force Skeleton
by Chenglong Jiang, Lingling Zeng, Yajing Liu, Yu Mu and Wangyi Dong
Appl. Sci. 2025, 15(14), 7978; https://doi.org/10.3390/app15147978 - 17 Jul 2025
Viewed by 253
Abstract
The mechanical characteristics of soil–rock mixtures (S-RMs) are essential for ensuring geotechnical engineering stability and are significantly influenced by the microstructure’s contact network configuration. Due to the irregularity of particle shapes and the variability in particle grading with S-RMs, their macro-mechanical characteristics and [...] Read more.
The mechanical characteristics of soil–rock mixtures (S-RMs) are essential for ensuring geotechnical engineering stability and are significantly influenced by the microstructure’s contact network configuration. Due to the irregularity of particle shapes and the variability in particle grading with S-RMs, their macro-mechanical characteristics and mesoscopic contact skeleton distribution exhibit increased complexity. To further elucidate the macro-mesoscopic mechanical behavior of S-RMs, this study employed the DEM to develop a model incorporating irregular specimens representing various states, based on CT scan outlines, and applied flexible boundary conditions. A main skeleton system of contact force chains is an effective methodology for characterizing the dominant structural features that govern the mechanical behavior of soil–rock mixture specimens. The results demonstrate that the strength of S-RMs was significantly influenced by gravel content and consolidation state; however, the relationship is not merely linear but rather intricately associated with the strength and distinctiveness of the contact force chain skeleton. In the critical state, the mechanical behavior of S-RMs was predominantly governed by the characteristics of the principal contact force skeleton: the contact force skeleton formed by gravel–gravel, despite having fewer contact forces, exhibits strong contact characteristics and an exceptionally high-density distribution of weak contacts, conferring the highest shear strength to the specimens. Conversely, the principal skeleton formed through gravel–sand exhibits contact characteristics that are less distinct compared to those associated with strong contacts. Simultaneously, the probability density distribution of weak contacts diminishes, resulting in reduced shear strength. The contact skeleton dominated by sand–sand contact forces displays similar micro-mechanical characteristics yet possesses the weakest macroscopic behavior strength. Consequently, the concept of the main skeleton of contact force chains utilized in this study presents a novel research approach for elucidating the macro- and micro-mechanical characteristics of multiphase media. Full article
(This article belongs to the Section Civil Engineering)
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21 pages, 5158 KiB  
Article
Genesis of the Erentaolegai Silver Deposit, Inner Mongolia, Northeast China: Evidence from Fluid Inclusion and H-O-S Isotopes
by Yushan Zuo, Xintong Dong, Zhengxi Gao, Liwen Wu, Zhao Liu, Jiaqi Xu, Shanming Zhang and Wentian Mi
Minerals 2025, 15(7), 748; https://doi.org/10.3390/min15070748 - 17 Jul 2025
Viewed by 303
Abstract
The Erentaolegai silver deposit is located within the Derbugan metallogenic belt in the eastern segment of the Central Asia–Mongolia giant orogenic belt. The ore bodies are primarily hosted in the volcanic rocks of the Middle Jurassic Tamulangou Formation of the Mesozoic. The mineralization [...] Read more.
The Erentaolegai silver deposit is located within the Derbugan metallogenic belt in the eastern segment of the Central Asia–Mongolia giant orogenic belt. The ore bodies are primarily hosted in the volcanic rocks of the Middle Jurassic Tamulangou Formation of the Mesozoic. The mineralization process of the deposit is divided into three stages: Stage I: Pyrite–Quartz Stage; Stage II: Sulfide–Quartz Stage; Stage III: Quartz–Manganese Carbonate Stage. This paper discusses the ore-forming fluids, ore-forming materials, and deposit genesis of the Erentaolegai silver deposits using fluid inclusions microthermometry, laser Raman spectroscopy, and H-O-S isotope analyses. Fluid inclusion microthermometry and laser Raman spectroscopy analyses indicate that the Erentaolegai silver deposit contains exclusively fluid-rich two-phase fluid inclusions, all of which belong to the H2O-NaCl system. Homogenization temperatures of fluid inclusions in the three stages (from early to late) ranged from 257 to 311 °C, 228 to 280 °C, and 194 to 238 °C, corresponding to salinities of 1.91 to 7.86 wt%, 2.07 to 5.41 wt%, and 0.70–3.55 wt% NaCl equivalent, densities of 0.75 to 0.83 g/cm−3, 0.80 to 0.86 g/cm−3 and 0.85 to 0.89 g/cm−3. The mineralization pressure ranged from 12.2 to 29.5 MPa, and the mineralization depth was 0.41 to 0.98 km, indicating low-pressure and shallow-depth mineralization conditions. H-O isotope results indicate that the ore-forming fluid is a mixture of magmatic fluids and meteoric water, with meteoric contribution dominating in the late stage. The δ34S values of metallic sulfides ranged from −1.8 to +4.0‰, indicating that the metallogenic material of the Erentaolegai silver deposit was dominated by a deep magmatic source. This study concludes that meteoric water mixing and subsequent fluid cooling served as the primary mechanism for silver mineral precipitation. The Erentaolegai silver deposit is classified as a low-sulfidation epithermal silver deposit. Full article
(This article belongs to the Special Issue Recent Developments in Rare Metal Mineral Deposits)
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23 pages, 6440 KiB  
Article
A Gravity Data Denoising Method Based on Multi-Scale Attention Mechanism and Physical Constraints Using U-Net
by Bing Liu, Houpu Li, Shaofeng Bian, Chaoliang Zhang, Bing Ji and Yujie Zhang
Appl. Sci. 2025, 15(14), 7956; https://doi.org/10.3390/app15147956 - 17 Jul 2025
Viewed by 269
Abstract
Gravity and gravity gradient data serve as fundamental inputs for geophysical resource exploration and geological structure analysis. However, traditional denoising methods—including wavelet transforms, moving averages, and low-pass filtering—exhibit signal loss and limited adaptability under complex, non-stationary noise conditions. To address these challenges, this [...] Read more.
Gravity and gravity gradient data serve as fundamental inputs for geophysical resource exploration and geological structure analysis. However, traditional denoising methods—including wavelet transforms, moving averages, and low-pass filtering—exhibit signal loss and limited adaptability under complex, non-stationary noise conditions. To address these challenges, this study proposes an improved U-Net deep learning framework that integrates multi-scale feature extraction and attention mechanisms. Furthermore, a Laplace consistency constraint is introduced into the loss function to enhance denoising performance and physical interpretability. Notably, the datasets used in this study are generated by the authors, involving simulations of subsurface prism distributions with realistic density perturbations (±20% of typical rock densities) and the addition of controlled Gaussian noise (5%, 10%, 15%, and 30%) to simulate field-like conditions, ensuring the diversity and physical relevance of training samples. Experimental validation on these synthetic datasets and real field datasets demonstrates the superiority of the proposed method over conventional techniques. For noise levels of 5%, 10%, 15%, and 30% in test sets, the improved U-Net achieves Peak Signal-to-Noise Ratios (PSNR) of 59.13 dB, 52.03 dB, 48.62 dB, and 48.81 dB, respectively, outperforming wavelet transforms, moving averages, and low-pass filtering by 10–30 dB. In multi-component gravity gradient denoising, our method excels in detail preservation and noise suppression, improving Structural Similarity Index (SSIM) by 15–25%. Field data tests further confirm enhanced identification of key geological anomalies and overall data quality improvement. In summary, the improved U-Net not only delivers quantitative advancements in gravity data denoising but also provides a novel approach for high-precision geophysical data preprocessing. Full article
(This article belongs to the Special Issue Applications of Machine Learning in Earth Sciences—2nd Edition)
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16 pages, 5222 KiB  
Article
Rock Physics Characteristics and Modeling of Deep Fracture–Cavity Carbonate Reservoirs
by Qifei Fang, Juntao Ge, Xiaoqiong Wang, Junfeng Zhou, Huizhen Li, Yuhao Zhao, Tuanyu Teng, Guoliang Yan and Mengen Wang
Energies 2025, 18(14), 3710; https://doi.org/10.3390/en18143710 - 14 Jul 2025
Viewed by 299
Abstract
The deep carbonate reservoirs in the Tarim Basin, Xinjiang, China, are widely developed with multi-scale complex reservoir spaces such as fractures, pores, and karst caves under the coupling of abnormal high pressure, diagenesis, karst, and tectonics and have strong heterogeneity. Among them, fracture–cavity [...] Read more.
The deep carbonate reservoirs in the Tarim Basin, Xinjiang, China, are widely developed with multi-scale complex reservoir spaces such as fractures, pores, and karst caves under the coupling of abnormal high pressure, diagenesis, karst, and tectonics and have strong heterogeneity. Among them, fracture–cavity carbonate reservoirs are one of the main reservoir types. Revealing the petrophysical characteristics of fracture–cavity carbonate reservoirs can provide a theoretical basis for the log interpretation and geophysical prediction of deep reservoirs, which holds significant implications for deep hydrocarbon exploration and production. In this study, based on the mineral composition and complex pore structure of carbonate rocks in the Tarim Basin, we comprehensively applied classical petrophysical models, including Voigt–Reuss–Hill, DEM (Differential Effective Medium), Hudson, Wood, and Gassmann, to establish a fracture–cavity petrophysical model tailored to the target block. This model effectively characterizes the complex pore structure of deep carbonate rocks and addresses the applicability limitations of conventional models in heterogeneous reservoirs. The discrepancies between the model-predicted elastic moduli, longitudinal and shear wave velocities (Vp and Vs), and laboratory measurements are within 4%, validating the model’s reliability. Petrophysical template analysis demonstrates that P-wave impedance (Ip) and the Vp/Vs ratio increase with water saturation but decrease with fracture density. A higher fracture density amplifies the fluid effect on the elastic properties of reservoir samples. The Vp/Vs ratio is more sensitive to pore fluids than to fractures, whereas Ip is more sensitive to fracture density. Regions with higher fracture and pore development exhibit greater hydrocarbon storage potential. Therefore, this petrophysical model and its quantitative templates can provide theoretical and technical support for predicting geological sweet spots in deep carbonate reservoirs. Full article
(This article belongs to the Special Issue New Progress in Unconventional Oil and Gas Development: 2nd Edition)
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23 pages, 6106 KiB  
Article
Seismic Multi-Parameter Full-Waveform Inversion Based on Rock Physical Constraints
by Cen Cao, Deshan Feng, Jia Tang and Xun Wang
Appl. Sci. 2025, 15(14), 7849; https://doi.org/10.3390/app15147849 - 14 Jul 2025
Viewed by 211
Abstract
Seismic multi-parameter full-waveform inversion (FWI) integrating velocity and density parameters can fully use the kinematic and dynamic information of observed data to reconstruct underground models. However, seismic multi-parameter FWI is a highly ill-posed problem due to the strong dependence on the initial model. [...] Read more.
Seismic multi-parameter full-waveform inversion (FWI) integrating velocity and density parameters can fully use the kinematic and dynamic information of observed data to reconstruct underground models. However, seismic multi-parameter FWI is a highly ill-posed problem due to the strong dependence on the initial model. An inaccurate initial model often leads to cycle skipping and convergence to local minima, resulting in poor inversion results. The introduction of prior information can regularize the inversion problem, not only improving the crosstalk phenomenon between parameters, but also effectively constraining the inversion parameters, enhancing the inversion efficiency. Multi-parameter FWI based on rock physical constraints can introduce prior information of underground media into the objective function of FWI. Taking a simple layered model as an example, the results show that the inversion strategy based on rock physical constraints can enhance the stability of inversion and obtain high-precision inversion results. Application to the international standard 1994BP model further confirms that the proposed inversion strategy has good applicability to complex geological models. Full article
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27 pages, 9385 KiB  
Article
Comparative Analysis of Studies of Geological Conditions at the Planning and Construction Stage of Dam Reservoirs: A Case Study of New Facilities in South-Western Poland
by Maksymilian Połomski, Mirosław Wiatkowski and Gabriela Ługowska
Appl. Sci. 2025, 15(14), 7811; https://doi.org/10.3390/app15147811 - 11 Jul 2025
Viewed by 259
Abstract
Geological surveys have vital importance at the planning stage of dammed reservoir construction projects. The results of these surveys determine the majority of the technical solutions adopted in the construction design to ensure the proper safety and stability parameters of the structure during [...] Read more.
Geological surveys have vital importance at the planning stage of dammed reservoir construction projects. The results of these surveys determine the majority of the technical solutions adopted in the construction design to ensure the proper safety and stability parameters of the structure during water damming. Where the ground type is found to be different from what is expected, the construction project may be delayed or even cancelled. This study analyses issues and design modifications caused by the identification of different soil conditions during the construction of four new flood control reservoirs in the Nysa Kłodzka River basin in south-western Poland. The key findings are as follows: (1) a higher density of exploratory boreholes in areas with potentially fractured rock mass is essential for selecting the appropriate anti-filtration protection; (2) when deciding to apply deep piles, it is reasonable to verify, at the planning stage, whether they can be installed using the given technology directly at the planned site; (3) inaccurate identification of foundation soils under the dam body can lead to significant design modifications—in contrast, a denser borehole grid helps to determine the precise elevation of the base layer, which is essential for reliably estimating the volume of material required for the embankment; (4) in order to correctly assess the soil deposits located, for instance, in the reservoir basin area, it is more effective to use test excavations rather than relying solely on borehole-based investigations—as a last resort, test excavations can be used to supplement the latter. Full article
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21 pages, 2440 KiB  
Article
Dual-Purpose Utilization of Sri Lankan Apatite for Rare Earth Recovery Integrated into Sustainable Nitrophosphate Fertilizer Manufacturing
by D. B. Hashini Indrachapa Bandara, Avantha Prasad, K. D. Anushka Dulanjana and Pradeep Wishwanath Samarasekere
Sustainability 2025, 17(14), 6353; https://doi.org/10.3390/su17146353 - 11 Jul 2025
Viewed by 1177
Abstract
Rare earth elements (REEs) have garnered significant global attention due to their essential role in advanced technologies. Sri Lanka is endowed with various REE-bearing minerals, including the apatite-rich deposit in the Eppawala area, commonly known as Eppawala rock phosphate (ERP). However, direct extraction [...] Read more.
Rare earth elements (REEs) have garnered significant global attention due to their essential role in advanced technologies. Sri Lanka is endowed with various REE-bearing minerals, including the apatite-rich deposit in the Eppawala area, commonly known as Eppawala rock phosphate (ERP). However, direct extraction of REEs from ERP is technically challenging and economically unfeasible. This study introduces a novel, integrated approach for recovering REEs from ERP as a by-product of nitrophosphate fertilizer production. The process involves nitric acid-based acidolysis of apatite, optimized at 10 M nitric acid for 2 h at 70 °C with a pulp density of 2.4 mL/g. During cooling crystallization, 42 wt% of calcium was removed as Ca(NO3)2.4H2O while REEs remained in the solution. REEs were then selectively precipitated as REE phosphates via pH-controlled addition of ammonium hydroxide, minimizing the co-precipitation with calcium. Further separation was achieved through selective dissolution in a sulfuric–phosphoric acid mixture, followed by precipitation as sodium rare earth double sulfates. The process achieved over 90% total REE recovery with extraction efficiencies in the order of Pr > Nd > Ce > Gd > Sm > Y > Dy. Samples were characterized for their phase composition, elemental content, and morphology. The fertilizer results confirmed the successful production of a nutrient-rich nitrophosphate (NP) with 18.2% nitrogen and 13.9% phosphorus (as P2O5) with a low moisture content (0.6%) and minimal free acid (0.1%), indicating strong agronomic value and storage stability. This study represents one of the pioneering efforts to valorize Sri Lanka’s apatite through a novel, dual-purpose, and circular approach, recovering REEs while simultaneously producing high-quality fertilizer. Full article
(This article belongs to the Special Issue Technologies for Green and Sustainable Mining)
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22 pages, 4046 KiB  
Article
Research on the Adsorption Characteristics and Adsorption Capacity Predictions of Supercritical Methane in Deep Coal Seams
by Xuan Chen, Chao Wu, Hua Zhang, Shiqi Liu, Xinggang Wang, Hongwei Li, Zongsen Yao, Kaisaer Wureyimu, Fansheng Huang and Zhongliang Cao
Processes 2025, 13(7), 2186; https://doi.org/10.3390/pr13072186 - 8 Jul 2025
Viewed by 289
Abstract
In the development of deep coalbed methane (CBM) resources, the adsorption behavior of supercritical methane is a key factor restricting reserve evaluation and development efficiency. This study integrates scanning electron microscopy (SEM), low-temperature CO2 adsorption (LTCO2A), mercury intrusion porosimetry (MIP), [...] Read more.
In the development of deep coalbed methane (CBM) resources, the adsorption behavior of supercritical methane is a key factor restricting reserve evaluation and development efficiency. This study integrates scanning electron microscopy (SEM), low-temperature CO2 adsorption (LTCO2A), mercury intrusion porosimetry (MIP), high-temperature and high-pressure CH4 adsorption experiments (HTHP-CH4A), and theoretical models to reveal the pore–fracture structure of deep coal seams and the adsorption characteristics of supercritical methane. Based on a predictive model for supercritical methane adsorption capacity, the adsorption capacity of deep methane was predicted. Results show that micro-pores are well-developed in deep coal rocks, but pore connectivity is generally poor, predominantly consisting of fine bottleneck pores and semi-closed pores, with a certain proportion of open pores. The fractal dimension (Dm) of micro-pore structures in deep coal samples ranges from 2.0447 to 2.2439, indicating high micro-pore surface roughness and a large specific surface area, which provide favorable sites for methane adsorption. Pores larger than 100 nm exhibit fractal values between 2.6459 and 2.8833, suggesting that the pore surfaces in deep coal seams approach a three-dimensional pore space with rough surfaces and complex pore structures. As temperature and pressure enter the supercritical region, the adsorption capacity shows an abnormal trend of “first increasing and then decreasing” with increasing pressure. The deep coal rock–supercritical methane adsorption system exhibits two scenarios in low-pressure and high-pressure regions, corresponding to self-adsorption driven by strong methane adsorption potential and external force adsorption or overpressure micro-pore adsorption, respectively. The supercritical adsorption prediction model considering temperature and methane adsorption phase density has extremely low deviation (1.11–1.25%) and high accuracy. The average dispersion between predicted and actual values ranges from 0.44 cm3/g to 0.48 cm3/g, with small error fluctuations and no significant deviation. This study provides theoretical support for the recoverability evaluation and efficient development of deep CBM resources. Full article
(This article belongs to the Section Energy Systems)
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18 pages, 5336 KiB  
Article
Comparative Flexural Response of Mineralized Massive Sulfides and Meta-Rhyolitic Rocks
by Haitham M. Ahmed and Essam B. Moustafa
Geosciences 2025, 15(7), 263; https://doi.org/10.3390/geosciences15070263 - 8 Jul 2025
Viewed by 236
Abstract
An experimental study was conducted to investigate the flexural mechanical properties of mineralized (massive sulfides) and non-mineralized (meta-rhyolitic tuff) rock samples using a three-point bending test. Mineralogical analysis was conducted on samples from both rock categories, followed by the determination of physical properties [...] Read more.
An experimental study was conducted to investigate the flexural mechanical properties of mineralized (massive sulfides) and non-mineralized (meta-rhyolitic tuff) rock samples using a three-point bending test. Mineralogical analysis was conducted on samples from both rock categories, followed by the determination of physical properties (P-wave velocity and density). In the massive sulfide zones, there are three distinctive zones of mineralization, each exhibiting varying degrees of pyritization: the intense pyritization zone (formerly Zone A) exhibited extensive pyrite replacement of sphalerite and chalcopyrite, the transitional zone (Zone B) displays intergrowths of pyrite and sphalerite, and the coarse sulfide zone (Zone C) features coarser, less altered sulfides—polyphase hydrothermal alteration, including sericitization, silicification, and amphibole veining. Mineralized rocks showed a 35.18% increase in density (3.65 ± 0.17 kg/m3 vs. 2.72 ± 0.014 kg/m3) attributed to dense sulfide content. The flexural strength more than doubled (99.02 ± 4.42 GPa vs. 43.17 ± 6.45 GPa), experiencing a 129% increase, due to homogeneous chalcopyrite distribution and fine-grained sulfide networks. Despite strength differences, deflection rates showed a non-significant 4% variation (0.373 ± 0.083 mm for mineralized vs. 0.389 ± 0.074 mm for metamorphic rocks), indicating comparable ductility. Full article
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25 pages, 8033 KiB  
Article
Research on the Damage Evolution Law of Branch Wellbore Based on Damage Mechanics
by Qizhong Tian, Chao Han, Yang Meng, Rongdong Dai, Haocai Huang, Jiaao Chen and Chuanliang Yan
Processes 2025, 13(7), 2172; https://doi.org/10.3390/pr13072172 - 8 Jul 2025
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Abstract
Multilateral wells can effectively develop complex reservoirs at a lower cost, which, in turn, enhances the overall efficiency of oilfield exploitation. However, drilling branch wells from the main wellbore can disrupt the surrounding formation stresses, leading to secondary stress concentration at the junctions, [...] Read more.
Multilateral wells can effectively develop complex reservoirs at a lower cost, which, in turn, enhances the overall efficiency of oilfield exploitation. However, drilling branch wells from the main wellbore can disrupt the surrounding formation stresses, leading to secondary stress concentration at the junctions, which, in turn, causes wellbore instability. This study established a coupled analysis model for wellbore stability in branch wells by integrating seepage, stress, and damage. The model explained the instability mechanisms of branch wellbores under multi-physics coupling conditions. The results showed that during drilling, the thin, interwall section of branch wells had weak resistance to external loads, with significant stress concentration and a maximum damage factor of 0.267, making it prone to instability. As drilling time progressed, fractures in the surrounding rock mass of the wellbore continuously formed, propagated, and interconnected, causing a sharp increase in the permeability of the damaged area. The seepage direction of drilling fluid in the wellbore tended towards the severely damaged interwall section, leading to a rapid increase in pore pressure there. With increasing distance from the interwall tip, the resistance to external loads strengthened, and the formation damage factor, permeability, pore pressure, and equivalent plastic strain all gradually decreased. When the drilling fluid density increased from 1.0 g/cm3 to 1.5 g/cm3, the maximum equivalent plastic strain around the wellbore decreased from 0.041 to 0.014, a reduction of 65.8%, indicating that appropriately increasing the drilling fluid density can effectively reduce the risk of wellbore instability. Full article
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