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Search Results (637)

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Keywords = printed electronic technology

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24 pages, 569 KiB  
Systematic Review
Artificial Intelligence Approach for Waste-Printed Circuit Board Recycling: A Systematic Review
by Muhammad Mohsin, Stefano Rovetta, Francesco Masulli and Alberto Cabri
Computers 2025, 14(8), 304; https://doi.org/10.3390/computers14080304 - 27 Jul 2025
Viewed by 205
Abstract
The rapid advancement of technology has led to a substantial increase in Waste Electrical and Electronic Equipment (WEEE), which poses significant environmental threats and increases pressure on the planet’s limited natural resources. In response, Artificial Intelligence (AI) has emerged as a key enabler [...] Read more.
The rapid advancement of technology has led to a substantial increase in Waste Electrical and Electronic Equipment (WEEE), which poses significant environmental threats and increases pressure on the planet’s limited natural resources. In response, Artificial Intelligence (AI) has emerged as a key enabler of the Circular Economy (CE), particularly in improving the speed and precision of waste sorting through machine learning and computer vision techniques. Despite this progress, to our knowledge, no comprehensive, systematic review has focused specifically on the role of AI in disassembling and recycling Waste-Printed Circuit Boards (WPCBs). This paper addresses this gap by systematically reviewing recent advancements in AI-driven disassembly and sorting approaches with a focus on machine learning and vision-based methodologies. The review is structured around three areas: (1) the availability and use of datasets for AI-based WPCB recycling; (2) state-of-the-art techniques for selective disassembly and component recognition to enable fast WPCB recycling; and (3) key challenges and possible solutions aimed at enhancing the recovery of critical raw materials (CRMs) from WPCBs. Full article
(This article belongs to the Special Issue Advanced Image Processing and Computer Vision (2nd Edition))
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15 pages, 734 KiB  
Article
The Influence of Electrostatic Separation Parameters on the Recovery of Metals from Pre-Crushed PCBs
by Antonio Manuel Lopez-Paneque, Victoria Humildad Gallardo García-Orta, Jose Maria Gallardo, Ranier Enrique Sepúlveda-Ferrer and Ernesto Chicardi
Metals 2025, 15(8), 826; https://doi.org/10.3390/met15080826 - 23 Jul 2025
Viewed by 198
Abstract
Electrostatic separation is a promising technology for the recovery of valuable metals from electronic waste, particularly from printed circuit boards (PCBs). This study explores the application of electrostatic separation for the selective recovery of metallic and non-metallic fractions from crushed PCBs (PCBs). The [...] Read more.
Electrostatic separation is a promising technology for the recovery of valuable metals from electronic waste, particularly from printed circuit boards (PCBs). This study explores the application of electrostatic separation for the selective recovery of metallic and non-metallic fractions from crushed PCBs (PCBs). The process exploits the differences in electrical properties between conductive metals and non-conductive polymers and ceramics, facilitating their separation through applied electric fields. The raw materials were pre-treated via mechanical comminution using shredders and hammer mills to achieve an optimal particle size distribution (<3 mm), which enhances separation efficiency. Ferrous materials were removed prior to electrostatic separation to improve process selectivity. Key operational parameters, including particle size, charge accumulation, environmental conditions, and separation efficiency, were systematically analysed. The results demonstrate that electrostatic separation effectively recovers high-value metals such as copper and gold while minimizing material losses. Additionally, the process contributes to the sustainability of e-waste recycling by enabling the recovery of non-metallic fractions for potential secondary applications. This work underscores the significance of electrostatic separation as a viable technique for e-waste management and highlights optimization strategies for enhancing its performance in large-scale recycling operations. Full article
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50 pages, 15545 KiB  
Review
Synergies in Materials and Manufacturing: A Review of Composites and 3D Printing for Triboelectric Energy Harvesting
by T. Pavan Rahul and P. S. Rama Sreekanth
J. Compos. Sci. 2025, 9(8), 386; https://doi.org/10.3390/jcs9080386 - 23 Jul 2025
Viewed by 359
Abstract
Sophisticated energy-harvesting technologies have swiftly progressed, expanding energy supply distribution and leveraging advancements in self-sustaining electronic devices. Despite substantial advancements in friction nanomotors within the last decade, a considerable technical obstacle remains for their flawless incorporation using printed electronics and autonomous devices. Integrating [...] Read more.
Sophisticated energy-harvesting technologies have swiftly progressed, expanding energy supply distribution and leveraging advancements in self-sustaining electronic devices. Despite substantial advancements in friction nanomotors within the last decade, a considerable technical obstacle remains for their flawless incorporation using printed electronics and autonomous devices. Integrating advanced triboelectric nanogenerator (TENG) technology with the rapidly evolving field of composite material 3D printing with has resulted in the advancement of three-dimensionally printed TENGs. Triboelectric nanogenerators are an important part of the next generation of portable energy harvesting and sensing devices that may be used for energy harvesting and artificial intelligence tasks. This paper systematically analyzes the continual development of 3D-printed TENGs and the integration of composite materials. The authors thoroughly review the latest material combinations of composite materials and 3D printing techniques for TENGs. Furthermore, this paper showcases the latest applications, such as using a TENG device to generate energy for electrical devices and harvesting energy from human motions, tactile sensors, and self-sustaining sensing gloves. This paper discusses the obstacles in constructing composite-material-based 3D-printed TENGs and the concerns linked to research and methods for improving electrical output performance. The paper finishes with an assessment of the issues associated with the evolution of 3D-printed TENGs, along with innovations and potential future directions in the dynamic realm of composite-material-based 3D-printed TENGs. Full article
(This article belongs to the Special Issue Advancements in Composite Materials for Energy Storage Applications)
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18 pages, 3220 KiB  
Article
High-Throughput Microfluidic Electroporation (HTME): A Scalable, 384-Well Platform for Multiplexed Cell Engineering
by William R. Gaillard, Jess Sustarich, Yuerong Li, David N. Carruthers, Kshitiz Gupta, Yan Liang, Rita Kuo, Stephen Tan, Sam Yoder, Paul D. Adams, Hector Garcia Martin, Nathan J. Hillson and Anup K. Singh
Bioengineering 2025, 12(8), 788; https://doi.org/10.3390/bioengineering12080788 - 22 Jul 2025
Viewed by 396
Abstract
Electroporation-mediated gene delivery is a cornerstone of synthetic biology, offering several advantages over other methods: higher efficiencies, broader applicability, and simpler sample preparation. Yet, electroporation protocols are often challenging to integrate into highly multiplexed workflows, owing to limitations in their scalability and tunability. [...] Read more.
Electroporation-mediated gene delivery is a cornerstone of synthetic biology, offering several advantages over other methods: higher efficiencies, broader applicability, and simpler sample preparation. Yet, electroporation protocols are often challenging to integrate into highly multiplexed workflows, owing to limitations in their scalability and tunability. These challenges ultimately increase the time and cost per transformation. As a result, rapidly screening genetic libraries, exploring combinatorial designs, or optimizing electroporation parameters requires extensive iterations, consuming large quantities of expensive custom-made DNA and cell lines or primary cells. To address these limitations, we have developed a High-Throughput Microfluidic Electroporation (HTME) platform that includes a 384-well electroporation plate (E-Plate) and control electronics capable of rapidly electroporating all wells in under a minute with individual control of each well. Fabricated using scalable and cost-effective printed-circuit-board (PCB) technology, the E-Plate significantly reduces consumable costs and reagent consumption by operating on nano to microliter volumes. Furthermore, individually addressable wells facilitate rapid exploration of large sets of experimental conditions to optimize electroporation for different cell types and plasmid concentrations/types. Use of the standard 384-well footprint makes the platform easily integrable into automated workflows, thereby enabling end-to-end automation. We demonstrate transformation of E. coli with pUC19 to validate the HTME’s core functionality, achieving at least a single colony forming unit in more than 99% of wells and confirming the platform’s ability to rapidly perform hundreds of electroporations with customizable conditions. This work highlights the HTME’s potential to significantly accelerate synthetic biology Design-Build-Test-Learn (DBTL) cycles by mitigating the transformation/transfection bottleneck. Full article
(This article belongs to the Section Cellular and Molecular Bioengineering)
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14 pages, 2149 KiB  
Article
Polymer Prosthetic Hand with Finger Copies for Persons with Congenital Defects or After Amputation Using 3D Printing Technology
by Anna Włodarczyk-Fligier, Magdalena Polok-Rubiniec, Aneta Kania, Sebastian Jakubik, Jakub Painta, Justyna Ryś, Jakub Wieczorek, Marta Marianek, Agata Ociepka, Mikołaj Micuła and Jakub Osuch
Polymers 2025, 17(14), 1983; https://doi.org/10.3390/polym17141983 - 19 Jul 2025
Viewed by 389
Abstract
The research presented in this paper focuses on the utilization of 3D printing technology in the design and manufacture of a prosthetic hand, equipped with a digit replicator. The subject of this study was a young man who had undergone the amputation of [...] Read more.
The research presented in this paper focuses on the utilization of 3D printing technology in the design and manufacture of a prosthetic hand, equipped with a digit replicator. The subject of this study was a young man who had undergone the amputation of two fingers on his right hand. The electronic control of the movement of the finger copy was developed using Arduino language. A concept and outline drawings were developed in ProCreate. Three-dimensional scan of the hand and forearm was made using an EinScan PRO HD SHINING 3D scanner. Using CAD software—Autodesk Inventor and Autodesk Meshmixer, the prosthesis was designed. Printing was carried out on a 3D printer of the i3 MK3 and MK3+ series using a PLA (polylactic acid) filament. It was determined that PLA is an optimal material for printing, as it is considered to be safe for future patients’ skin. Work on the electronic circuitry started in Autodesk TinkerCad simulation software, allowing the code to be verified and ensuring the safety of the control system. The prosthesis’s design demonstrates the potential to reach as many people in need as possible by using readily available, low-cost, and easy-to-use components. Full article
(This article belongs to the Special Issue 3D Printing Polymer Materials and Their Biomedical Applications)
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26 pages, 2731 KiB  
Review
Recent Advances in PEEK for Biomedical Applications: A Comprehensive Review of Material Properties, Processing, and Additive Manufacturing
by Samreen Dallal, Babak Eslami and Saeed Tiari
Polymers 2025, 17(14), 1968; https://doi.org/10.3390/polym17141968 - 17 Jul 2025
Viewed by 680
Abstract
Polyetheretherketone (PEEK) is a high-performance thermoplastic polymer widely recognized for its distinct mechanical strength, chemical resistance, and biocompatibility. These characteristics make it suitable for a wide range of applications, particularly in medical, aerospace, chemical, and electronics fields. Conventional processing techniques, such as 3D [...] Read more.
Polyetheretherketone (PEEK) is a high-performance thermoplastic polymer widely recognized for its distinct mechanical strength, chemical resistance, and biocompatibility. These characteristics make it suitable for a wide range of applications, particularly in medical, aerospace, chemical, and electronics fields. Conventional processing techniques, such as 3D printing, molding, and extrusion, are widely employed for PEEK fabrication. This review critically examines recent advancements in PEEK research, with an emphasis on additive manufacturing techniques that are expanding its applications in the medical field. We provide an in-depth analysis of PEEK’s intrinsic properties, diverse processing methods, and current challenges that hinder its wider adoption. In addition to evaluating PEEK’s performance, this review compares it with alternative biomaterials—such as titanium and ultra-high molecular weight polyethylene (UHMWPE)—to explore its advantages and limitations in biomedical applications. Furthermore, this review discusses cost considerations, regulatory constraints, long-term clinical performance challenges, and failure modes that are essential for validating and ensuring the reliability of PEEK in clinical use. By synthesizing the recent literature, particularly from the last decade, this review highlights the significant potential of PEEK and underscores ongoing research efforts aimed at overcoming its limitations, paving the way for its broader implementation in advanced technological applications. Full article
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17 pages, 6691 KiB  
Article
Antibiotic-Coated Melt Electrowritten Polycaprolactone Meshes: Fabrication and In Vitro Antibacterial Evaluation
by Joana Pinheiro Martins, Ana Sofia de Sousa, Sofia Costa de Oliveira, António Augusto Fernandes and Elisabete Teixeira da Silva
Macromol 2025, 5(3), 33; https://doi.org/10.3390/macromol5030033 - 16 Jul 2025
Viewed by 275
Abstract
In recent years, pelvic organ prolapse (POP) cases have been rising, affecting women’s quality of life. Synthetic surgical transvaginal meshes used for POP treatment were withdrawn from the United States market in 2019 due to high risks, including infection, vaginal mesh erosion, and [...] Read more.
In recent years, pelvic organ prolapse (POP) cases have been rising, affecting women’s quality of life. Synthetic surgical transvaginal meshes used for POP treatment were withdrawn from the United States market in 2019 due to high risks, including infection, vaginal mesh erosion, and POP reoccurrence. Biodegradable mesh implants with three-dimensional printing technology have emerged as an innovative alternative. In this study, polycaprolactone (PCL) meshes for POP repair were fabricated using melt electrospinning writing (MEW) and mechanically evaluated through uniaxial tensile tests. Following this, they were coated with antibiotics—azithromycin, gentamicin sulfate, and ciprofloxacin—commonly used for genitourinary tract infections. Zone inhibition and biofilm assays evaluated antibiotic effectiveness in preventing mesh infections by Escherichia coli, and methicillin-susceptible (MSSA) and methicillin-resistant (MRSA) Staphylococcus aureus. The meshes presented a mechanical behavior closer to vaginal tissue than commercially available meshes. Fourier transform infrared analysis confirmed antibiotic incorporation. Ciprofloxacin demonstrated antibacterial activity against MRSA, with a 92% reduction in metabolic activity and a 99% biomass reduction. Gentamicin and ciprofloxacin displayed inhibitory activity against MSSA and E. coli. Scanning electron microscopy images support these conclusions. This methodology may offer a more effective, patient-friendly solution for POP repair, improving healing and the quality of life for affected women. Full article
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19 pages, 1293 KiB  
Review
Customized 3D-Printed Scaffolds for Alveolar Ridge Augmentation: A Scoping Review of Workflows, Technology, and Materials
by Saeed A. Elrefaei, Lucrezia Parma-Benfenati, Rana Dabaja, Paolo Nava, Hom-Lay Wang and Muhammad H. A. Saleh
Medicina 2025, 61(7), 1269; https://doi.org/10.3390/medicina61071269 - 14 Jul 2025
Viewed by 292
Abstract
Background and Objectives: Bone regeneration (BR) is a cornerstone technique in reconstructive dental surgery, traditionally using either barrier membranes, titanium meshes, or perforated non-resorbable membranes to facilitate bone regeneration. Recent advancements in 3D technology, including CAD/CAM and additive manufacturing, have enabled the development [...] Read more.
Background and Objectives: Bone regeneration (BR) is a cornerstone technique in reconstructive dental surgery, traditionally using either barrier membranes, titanium meshes, or perforated non-resorbable membranes to facilitate bone regeneration. Recent advancements in 3D technology, including CAD/CAM and additive manufacturing, have enabled the development of customized scaffolds tailored to patient needs, potentially overcoming the limitations of conventional methods. Materials and Methods: A scoping review was conducted according to the PRISMA guidelines. Electronic searches were performed in MEDLINE (PubMed), the Cochrane Library, Scopus, and Web of Science up to January 2025 to identify studies on digital technologies applied to bone augmentation. Eligible studies encompassed randomized controlled trials, cohort studies, case series, and case reports, all published in English. Data regarding digital workflows, software, materials, printing techniques, and sterilization methods were extracted from 23 studies published between 2015 and 2024. Results: The review highlights a diverse range of digital workflows, beginning with CBCT-based DICOM to STL conversion using software such as Mimics and Btk-3D®. Customized titanium meshes and other meshes like Poly Ether-Ether Ketone (PEEK) meshes were produced via techniques including direct metal laser sintering (DMLS), selective laser melting (SLM), and five-axis milling. Although titanium remained the predominant material, studies reported variations in mesh design, thickness, and sterilization protocols. The findings underscore that digital customization enhances surgical precision and efficiency in BR, with several studies demonstrating improved bone gain and reduced operative time compared to conventional approaches. Conclusions: This scoping review confirms that 3D techniques represent a promising advancement in BR. Customized digital workflows provide superior accuracy and support for BR procedures, yet variability in protocols and limited high-quality trials underscore the need for further clinical research to standardize techniques and validate long-term outcomes. Full article
(This article belongs to the Section Dentistry and Oral Health)
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44 pages, 7563 KiB  
Review
Green Batteries: A Sustainable Approach Towards Next-Generation Batteries
by Annu, Bairi Sri Harisha, Manesh Yewale, Bhargav Akkinepally and Dong Kil Shin
Batteries 2025, 11(7), 258; https://doi.org/10.3390/batteries11070258 - 10 Jul 2025
Viewed by 840
Abstract
The rising demand for sustainable energy storage has fueled the development of green batteries as alternatives to conventional systems. However, a major research gap lies in the unified integration of environmentally friendly materials and processes across all battery components—electrodes, electrolytes, and separators—without compromising [...] Read more.
The rising demand for sustainable energy storage has fueled the development of green batteries as alternatives to conventional systems. However, a major research gap lies in the unified integration of environmentally friendly materials and processes across all battery components—electrodes, electrolytes, and separators—without compromising performance or scalability. This review addresses this gap by highlighting recent advances in eco-conscious battery technologies, focusing on green electrode fabrication using water-based methods, electrophoretic deposition, solvent-free dry-press coating, 3D printing, and biomass-derived materials. It also examines the shift toward safer electrolytes, including ionic liquids, deep eutectic solvents, water-based systems, and solid biopolymer matrices, which improve both environmental compatibility and safety. Additionally, biodegradable separators made from natural polymers such as cellulose and chitosan offer enhanced thermal stability and ecological benefits. The review emphasizes the importance of lifecycle considerations like recyclability and biodegradability, aligning battery design with circular economy principles. While significant progress has been made, challenges such as standardization, long-term stability, and industrial scalability remain. By identifying key strategies and future directions, this article contributes to the foundation for next-generation green batteries, promoting their adoption in environmentally sensitive applications ranging from wearable electronics to grid storage. Full article
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15 pages, 5527 KiB  
Article
Screen Printing Conductive Inks on Textiles: Impact of Plasma Treatment
by Julia Guérineau, Jollan Ton and Mariia Zhuldybina
Sensors 2025, 25(13), 4240; https://doi.org/10.3390/s25134240 - 7 Jul 2025
Viewed by 372
Abstract
Textile-based wearable devices are rapidly gaining traction in the Internet of Things paradigm and offer distinct advantages for data collection and analysis across a wide variety of applications. Seamlessly integrating electronics in textiles remains a technical challenge, especially when the textiles’ essential properties, [...] Read more.
Textile-based wearable devices are rapidly gaining traction in the Internet of Things paradigm and offer distinct advantages for data collection and analysis across a wide variety of applications. Seamlessly integrating electronics in textiles remains a technical challenge, especially when the textiles’ essential properties, such as comfort, breathability, and flexibility, are meant to be preserved. This article investigates screen printing as a textile post-processing technique for electronic integration, and highlights its versatility, cost-effectiveness, and adaptability in terms of design and customization. The study examines two silver-based inks screen-printed on an Oxford polyester textile substrate with a focus on substrate preparation and treatment. Before printing, the textile samples were cleaned with nitrogen gas and then subjected to low-pressure oxygen plasma treatment. For comparative analysis, two samples printed on polyethylene terephthalate (PET) serve as a reference. The findings highlight the importance of plasma treatment in optimizing the printability of textiles and demonstrate that it notably improves the electrical properties of conductive inks. Despite some remaining challenges, the study indicates that screen-printed electronics show promising potential for advancing the development of e-textiles and sensor-integrated wearables. Full article
(This article belongs to the Section Sensors Development)
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21 pages, 2197 KiB  
Review
Aerosol Jet Printing for Neuroprosthetic Device Development
by Lander De Waele, Massimo Di Pietro, Stefano Perilli, Emanuele Mantini, Giulio Trevisan, Michela Simoncini, Massimo Panella, Viviana Betti, Matteo Laffranchi and Dante Mantini
Bioengineering 2025, 12(7), 707; https://doi.org/10.3390/bioengineering12070707 - 28 Jun 2025
Viewed by 541
Abstract
Aerosol jet printing (AJP) technology has emerged as a transformative tool in neuroprosthetic device development, offering high accuracy and versatility in fabricating complex and miniaturized structures, which are essential for advanced neural interfaces. This review explores the fundamental principles of AJP, highlighting its [...] Read more.
Aerosol jet printing (AJP) technology has emerged as a transformative tool in neuroprosthetic device development, offering high accuracy and versatility in fabricating complex and miniaturized structures, which are essential for advanced neural interfaces. This review explores the fundamental principles of AJP, highlighting its unique aerosol generation and concentrated deposition mechanisms, which facilitate the use of different materials on a variety of substrates. The advantages of AJP, including its device scalability, ability to print on flexible and stretchable substrates, and compatibility with a wide range of biocompatible materials, are examined in the context of neuroprosthetic applications. Key implementations, such as the fabrication of neural interfaces, the development of microelectrode arrays, and the integration with flexible electronics, are discussed, showcasing the potential of AJP to revolutionize neuroprosthetic devices. Additionally, this review addresses the challenges of biocompatibility and technical limitations, such as the long-term stability of electroconductive traces. The review concludes with a discussion of future directions and innovations, emphasizing the realization of sensorized prosthetic limbs through the incorporation of tactile sensors, the integration of biosensors for monitoring physiological parameters, and the development of intelligent prostheses. These prospects underscore the role of AJP in the advancement of neuroprosthetic applications and its pathway toward clinical translation and commercialization. Full article
(This article belongs to the Special Issue The Application of Additive Manufacturing in the Biomedical Field)
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23 pages, 4929 KiB  
Article
Low Phase Noise, Dual-Frequency Pierce MEMS Oscillators with Direct Print Additively Manufactured Amplifier Circuits
by Liguan Li, Di Lan, Xu Han, Tinghung Liu, Julio Dewdney, Adnan Zaman, Ugur Guneroglu, Carlos Molina Martinez and Jing Wang
Micromachines 2025, 16(7), 755; https://doi.org/10.3390/mi16070755 (registering DOI) - 26 Jun 2025
Cited by 1 | Viewed by 380
Abstract
This paper presents the first demonstration and comparison of two identical oscillator circuits employing piezoelectric zinc oxide (ZnO) microelectromechanical systems (MEMS) resonators, implemented on conventional printed-circuit-board (PCB) and three-dimensional (3D)-printed acrylonitrile butadiene styrene (ABS) substrates. Both oscillators operate simultaneously at dual frequencies (260 [...] Read more.
This paper presents the first demonstration and comparison of two identical oscillator circuits employing piezoelectric zinc oxide (ZnO) microelectromechanical systems (MEMS) resonators, implemented on conventional printed-circuit-board (PCB) and three-dimensional (3D)-printed acrylonitrile butadiene styrene (ABS) substrates. Both oscillators operate simultaneously at dual frequencies (260 MHz and 437 MHz) without the need for additional circuitry. The MEMS resonators, fabricated on silicon-on-insulator (SOI) wafers, exhibit high-quality factors (Q), ensuring superior phase noise performance. Experimental results indicate that the oscillator packaged using 3D-printed chip-carrier assembly achieves a 2–3 dB improvement in phase noise compared to the PCB-based oscillator, attributed to the ABS substrate’s lower dielectric loss and reduced parasitic effects at radio frequency (RF). Specifically, phase noise values between −84 and −77 dBc/Hz at 1 kHz offset and a noise floor of −163 dBc/Hz at far-from-carrier offset were achieved. Additionally, the 3D-printed ABS-based oscillator delivers notably higher output power (4.575 dBm at 260 MHz and 0.147 dBm at 437 MHz). To facilitate modular characterization, advanced packaging techniques leveraging precise 3D-printed encapsulation with sub-100 μm lateral interconnects were employed. These ensured robust packaging integrity without compromising oscillator performance. Furthermore, a comparison between two transistor technologies—a silicon germanium (SiGe) heterojunction bipolar transistor (HBT) and an enhancement-mode pseudomorphic high-electron-mobility transistor (E-pHEMT)—demonstrated that SiGe HBT transistors provide superior phase noise characteristics at close-to-carrier offset frequencies, with a significant 11 dB improvement observed at 1 kHz offset. These results highlight the promising potential of 3D-printed chip-carrier packaging techniques in high-performance MEMS oscillator applications. Full article
(This article belongs to the Section E:Engineering and Technology)
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22 pages, 5030 KiB  
Article
Flexible Screen-Printed Gold Electrode Array on Polyimide/PET for Nickel(II) Electrochemistry and Sensing
by Norica Godja, Saied Assadollahi, Melanie Hütter, Pooyan Mehrabi, Narges Khajehmeymandi, Thomas Schalkhammer and Florentina-Daniela Munteanu
Sensors 2025, 25(13), 3959; https://doi.org/10.3390/s25133959 - 25 Jun 2025
Viewed by 438
Abstract
Nickel’s durability and catalytic properties make it essential in the aerospace, automotive, electronics, and fuel cell technology industries. Wastewater analysis typically relies on sensitive but costly techniques such as ICP-MS, AAS, and ICP-AES, which require complex equipment and are unsuitable for on-site testing. [...] Read more.
Nickel’s durability and catalytic properties make it essential in the aerospace, automotive, electronics, and fuel cell technology industries. Wastewater analysis typically relies on sensitive but costly techniques such as ICP-MS, AAS, and ICP-AES, which require complex equipment and are unsuitable for on-site testing. This study introduces a novel screen-printed electrode array with 16 chemically and, optionally, electrochemically coated Au electrodes. Its electrochemical response to Ni2+ was tested using Na2SO3 and ChCl-EG deep eutectic solvents as electrolytes. Ni2+ solutions were prepared from NiCl2·6H2O, NiSO4·6H2O, and dry NiCl2. In Na2SO3, the linear detection ranges were 20–196 mM for NiCl2·6H2O and 89–329 mM for NiSO4·6H2O. High Ni2+ concentrations (10–500 mM) were used to simulate industrial conditions. Two linear ranges were observed, likely due to differences in electrochemical behaviour between NiCl2·6H2O and NiSO4·6H2O, despite the identical Na2SO3 electrolyte. Anion effects (Cl vs. SO42−) may influence response via complexation or ion pairing. In ChCl-EG, a linear range of 0.5–10 mM (R2 = 0.9995) and a detection limit of 1.6 µM were achieved. With a small electrolyte volume (100–200 µL), nickel detection in the nanomole range is possible. A key advantage is the array’s ability to analyze multiple analytes simultaneously via customizable electrode configurations. Future research will focus on nickel detection in industrial wastewater and its potential in the multiplexed analysis of toxic metals. The array also holds promise for medical diagnostics and food safety applications using thiol/Au-based capture molecules. Full article
(This article belongs to the Section Chemical Sensors)
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16 pages, 5373 KiB  
Article
Design and Development of an Electronic Interface for Acquiring Signals from a Piezoelectric Sensor for Ultrasound Imaging Applications
by Elizabeth Espitia-Romero, Adriana Guzmán-López, Micael Gerardo Bravo-Sánchez, Juan José Martínez-Nolasco, José Alfredo Padilla Medina and Francisco Villaseñor-Ortega
Technologies 2025, 13(7), 270; https://doi.org/10.3390/technologies13070270 - 25 Jun 2025
Viewed by 1263
Abstract
The increasing demand for accurate and accessible medical imaging has driven efforts to develop technologies that overcome limitations associated with conventional imaging techniques, such as MRI and CT scans. This study presents the design and implementation of an electronic interface for acquiring signals [...] Read more.
The increasing demand for accurate and accessible medical imaging has driven efforts to develop technologies that overcome limitations associated with conventional imaging techniques, such as MRI and CT scans. This study presents the design and implementation of an electronic interface for acquiring signals from a piezoelectric ultrasound sensor with the aim of improving image reconstruction quality by addressing electromagnetic interference and speckle noise, two major factors that degrade image fidelity. The proposed interface is installed between the ultrasound transducer and acquisition system, allowing real-time signal capture without altering the medical equipment’s operation. Using a printed circuit board with 110-pin connectors, signals from individual piezoelectric elements were analyzed using an oscilloscope. Results show that noise amplitudes occasionally exceed those of the acoustic echoes, potentially compromising image quality. By enabling direct observation of these signals, the interface facilitates the future development of analog filtering solutions to mitigate high-frequency noise before digital processing. This approach reduces reliance on computationally expensive digital filtering, offering a low-cost, real-time alternative. The findings underscore the potential of the interface to enhance diagnostic accuracy and support further innovation in medical imaging technologies. Full article
(This article belongs to the Special Issue Image Analysis and Processing)
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11 pages, 2330 KiB  
Article
Separations of Strategic Metals from Spent Electronic Waste Using “Green Methods”
by Urszula Domańska, Anna Wiśniewska and Zbigniew Dąbrowski
Separations 2025, 12(6), 167; https://doi.org/10.3390/separations12060167 - 18 Jun 2025
Viewed by 437
Abstract
Next-generation recycling technologies must be urgently innovated to tackle huge volumes of spent batteries, photovoltaic panels or printed circuit boards (WPCBs). Current e-waste recycling industrial technology is dominated by traditional recycling technologies. Herein, ionic liquids (ILs), deep eutectic solvents (DESs) and promising oxidizing [...] Read more.
Next-generation recycling technologies must be urgently innovated to tackle huge volumes of spent batteries, photovoltaic panels or printed circuit boards (WPCBs). Current e-waste recycling industrial technology is dominated by traditional recycling technologies. Herein, ionic liquids (ILs), deep eutectic solvents (DESs) and promising oxidizing additives that can overcome some traditional recycling methods of metal ions from e-waste, used in our works from last year, are presented. The unique chemical environments of ILs and DESs, with the application of low-temperature extraction procedures, are important environmental aspects known as “Green Methods”. A closed-loop system for recycling zinc and manganese from the “black mass” (BM) of waste, Zn-MnO2 batteries, is presented. The leaching process achieves a high efficiency and distribution ratio using the composition of two solvents (Cyanex 272 + diethyl phosphite (DPh)) for Zn(II) extraction. High extraction efficiency with 100% zinc and manganese recovery is also achieved using DESs (cholinum chloride/lactic acid, 1:2, DES 1, and cholinum chloride/malonic acid, 1:1, DES 2). New, greener recycling approaches to metal extraction from the BM of spent Li-ion batteries are presented with ILs ([N8,8,8,1][Cl], (Aliquat 336), [P6,6,6,14][Cl], [P6,6,6,14][SCN] and [Benzet][TCM]) eight DESs, Cyanex 272 and D2EHPA. A high extraction efficiency of Li(I) (41–92 wt%) and Ni(II) (37–52 wt%) using (Cyanex 272 + DPh) is obtained. The recovery of Ni(II) and Cd(II) from the BM of spent Ni-Cd batteries is also demonstrated. The extraction efficiency of DES 1 and DES 2, contrary to ILs ([P6,6,6,14][Cl] and [P6,6,6,14][SCN]), is at the level of 30 wt% for Ni(II) and 100 wt% for Cd(II). In this mini-review, the option to use ILs, DESs and Cyanex 272 for the recovery of valuable metals from end-of-life WPCBs is presented. Next-generation recycling technologies, in contrast to the extraction of metals from acidic leachate preceded by thermal pre-treatment or from solid material only after thermal pre-treatment, have been developed with ILs and DESs using the ABS method, as well as Cyanex 272 (only after the thermal pre-treatment of WPCBs), with a process efficiency of 60–100 wt%. In this process, four new ILs are used: didecyldimethylammonium propionate, [N10,10,1,1][C2H5COO], didecylmethylammonium hydrogen sulphate, [N10,10,1,H][HSO4], didecyldimethylammonium dihydrogen phosphate, [N10,10,1,1][H2PO4], and tetrabutylphosphonium dihydrogen phosphate, [P4,4,4,4][H2PO4]. The extraction of Cu(II), Ag(I) and other metals such as Al(III), Fe(II) and Zn(II) from solid WPCBs is demonstrated. Various additives are used during the extraction processes. The Analyst 800 atomic absorption spectrometer (FAAS) is used for the determination of metal content in the solid BM. The ICP-OES method is used for metal analysis. The obtained results describe the possible application of ILs and DESs as environmental media for upcycling spent electronic wastes. Full article
(This article belongs to the Section Materials in Separation Science)
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