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58 pages, 10593 KiB  
Article
Statistical Physics of Fissure Swarms and Dike Swarms
by Agust Gudmundsson
Geosciences 2025, 15(8), 301; https://doi.org/10.3390/geosciences15080301 - 4 Aug 2025
Abstract
Fissure swarms and dike swarms in Iceland constitute the main parts of volcanic systems that are 40–150 km long, 5–20 km wide, extend to depths of 10–20 km, and contain 2 × 1014 outcrop-scale (≥0.1 m) and 1022–23 down to grain-scale [...] Read more.
Fissure swarms and dike swarms in Iceland constitute the main parts of volcanic systems that are 40–150 km long, 5–20 km wide, extend to depths of 10–20 km, and contain 2 × 1014 outcrop-scale (≥0.1 m) and 1022–23 down to grain-scale (≥1 mm) fractures, suggesting that statistical physics is an appropriate method of analysis. Length-size distributions of 565 outcrop-scale Holocene fissures (tension fractures and normal faults) and 1041 Neogene dikes show good to excellent fits with negative power laws and exponential laws. Here, the Helmholtz free energy is used to represent the energy supplied to the swarms and to derive the Gibbs–Shannon entropy formula. The calculated entropies of 12 sets and subsets of fissures and 3 sets and subsets of dikes all show strong positive correlations with sets/subsets length ranges and scaling exponents. Statistical physics considerations suggest that, at a given time, the probability of the overall state of stress in a crustal segment being heterogeneous is much greater than the state of stress being homogeneous and favourable to the propagation of a fissure or a dike. In a heterogeneous stress field, most fissures/dikes become arrested after a short propagation—which is a formal explanation of the observed statistical size-length distributions. As the size of the stress-homogenised rock volume increases larger fissures/dikes can form, increasing the length range of the distribution (and its entropy) which may, potentially, transform from an exponential distribution into a power-law distribution. Full article
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18 pages, 6915 KiB  
Article
Strength Mobilisation in Karlsruhe Fine Sand
by Jinghong Liu, Yi Pik Cheng and Min Deng
Geotechnics 2025, 5(3), 52; https://doi.org/10.3390/geotechnics5030052 - 4 Aug 2025
Abstract
The strength mobilisation framework was adopted for the first time to describe the stress–strain responses for three different types of sands, including a total of 30 published drained triaxial tests—25 for Karlsruhe Fine Sand, 2 for Ottawa sands and 3 for Fontainebleau sand, [...] Read more.
The strength mobilisation framework was adopted for the first time to describe the stress–strain responses for three different types of sands, including a total of 30 published drained triaxial tests—25 for Karlsruhe Fine Sand, 2 for Ottawa sands and 3 for Fontainebleau sand, under confining pressures ranging from 50 to 400 kPa. The peak shear strength τpeak obtained from drained triaxial shearing of these sands was used to normalise shear stress. Shear strains normalised at peak strength γpeak and at half peak of shear strength γM=2 were taken as the normalised reference strains, and the results were compared. Power–law functions were then derived when the mobilised strength was between 0.2τpeak and 0.8τpeak. Exponents of the power–law functions of these sands were found to be lower than in the published undrained shearing data of clays. Using γM=2 as the reference strain shows a slightly better power–law correlation than using γpeak. Linear relationships between the reference strains and variables, such as relative density, relative dilatancy index, and dilatancy, are identified. Full article
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15 pages, 3175 KiB  
Article
Creep Deformation Mechanisms of Gas-Bearing Coal in Deep Mining Environments: Experimental Characterization and Constitutive Modeling
by Xiaolei Sun, Xueqiu He, Liming Qiu, Qiang Liu, Limin Qie and Qian Sun
Processes 2025, 13(8), 2466; https://doi.org/10.3390/pr13082466 - 4 Aug 2025
Abstract
The impact mechanism of long-term creep in gas-containing coal on coal and gas outbursts has not been fully elucidated and remains insufficiently understood for the purpose of disaster engineering control. This investigation conducted triaxial creep experiments on raw coal specimens under controlled confining [...] Read more.
The impact mechanism of long-term creep in gas-containing coal on coal and gas outbursts has not been fully elucidated and remains insufficiently understood for the purpose of disaster engineering control. This investigation conducted triaxial creep experiments on raw coal specimens under controlled confining pressures, axial stresses, and gas pressures. Through systematic analysis of coal’s physical responses across different loading conditions, we developed and validated a novel creep damage constitutive model for gas-saturated coal through laboratory data calibration. The key findings reveal three characteristic creep regimes: (1) a decelerating phase dominates under low stress conditions, (2) progressive transitions to combined decelerating–steady-state creep with increasing stress, and (3) triphasic decelerating–steady–accelerating behavior at critical stress levels. Comparative analysis shows that gas-free specimens exhibit lower cumulative strain than the 0.5 MPa gas-saturated counterparts, with gas presence accelerating creep progression and reducing the time to failure. Measured creep rates demonstrate stress-dependent behavior: primary creep progresses at 0.002–0.011%/min, decaying exponentially to secondary creep rates below 0.001%/min. Steady-state creep rates follow a power law relationship when subject to deviatoric stress (R2 = 0.96). Through the integration of Burgers viscoelastic model with the effective stress principle for porous media, we propose an enhanced constitutive model, incorporating gas adsorption-induced dilatational stresses. This advancement provides a theoretical foundation for predicting time-dependent deformation in deep coal reservoirs and informs monitoring strategies concerning gas-bearing strata stability. This study contributes to the theoretical understanding and engineering monitoring of creep behavior in deep coal rocks. Full article
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28 pages, 3973 KiB  
Article
A Neural Network-Based Fault-Tolerant Control Method for Current Sensor Failures in Permanent Magnet Synchronous Motors for Electric Aircraft
by Shuli Wang, Zelong Yang and Qingxin Zhang
Aerospace 2025, 12(8), 697; https://doi.org/10.3390/aerospace12080697 - 4 Aug 2025
Abstract
To enhance the reliability of electric propulsion in electric aircraft and address power interruptions caused by current sensor failures, this study proposes a current sensorless fault-tolerant control strategy for permanent magnet synchronous motors (PMSMs) based on a long short-term memory (LSTM) network. First, [...] Read more.
To enhance the reliability of electric propulsion in electric aircraft and address power interruptions caused by current sensor failures, this study proposes a current sensorless fault-tolerant control strategy for permanent magnet synchronous motors (PMSMs) based on a long short-term memory (LSTM) network. First, a hierarchical architecture is constructed to fuse multi-phase electrical signals in the fault diagnosis layer (sliding mode observer). A symbolic function for the reaching law observer is designed based on Lyapunov theory, in order to generate current predictions for fault diagnosis. Second, when a fault occurs, the system switches to the LSTM reconstruction layer. Finally, gating units are used to model nonlinear dynamics to achieve direct mapping of speed/position to phase current. Verification using a physical prototype shows that the proposed method can complete mode switching within 10 ms after a sensor failure, which is 80% faster than EKF, and its speed error is less than 2.5%, fully meeting the high speed error requirements of electric aircraft propulsion systems (i.e., ≤3%). The current reconstruction RMSE is reduced by more than 50% compared with that of the EKF, which ensures continuous and reliable control while maintaining the stable operation of the motor and realizing rapid switching. The intelligent algorithm and sliding mode control fusion strategy meet the requirements of high real-time performance and provide a highly reliable fault-tolerant scheme for electric aircraft propulsion. Full article
(This article belongs to the Section Aeronautics)
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17 pages, 438 KiB  
Article
Analytic Solutions and Conservation Laws of a 2D Generalized Fifth-Order KdV Equation with Power Law Nonlinearity Describing Motions in Shallow Water Under a Gravity Field of Long Waves
by Chaudry Masood Khalique and Boikanyo Pretty Sebogodi
AppliedMath 2025, 5(3), 96; https://doi.org/10.3390/appliedmath5030096 (registering DOI) - 31 Jul 2025
Viewed by 77
Abstract
The Korteweg–de Vries (KdV) equation is a nonlinear evolution equation that reflects a wide variety of dispersive wave occurrences with limited amplitude. It has also been used to describe a range of major physical phenomena, such as shallow water waves that interact weakly [...] Read more.
The Korteweg–de Vries (KdV) equation is a nonlinear evolution equation that reflects a wide variety of dispersive wave occurrences with limited amplitude. It has also been used to describe a range of major physical phenomena, such as shallow water waves that interact weakly and nonlinearly, acoustic waves on a crystal lattice, lengthy internal waves in density-graded oceans, and ion acoustic waves in plasma. The KdV equation is one of the most well-known soliton models, and it provides a good platform for further research into other equations. The KdV equation has several forms. The aim of this study is to introduce and investigate a (2+1)-dimensional generalized fifth-order KdV equation with power law nonlinearity (gFKdVp). The research methodology employed is the Lie group analysis. Using the point symmetries of the gFKdVp equation, we transform this equation into several nonlinear ordinary differential equations (ODEs), which we solve by employing different strategies that include Kudryashov’s method, the (G/G) expansion method, and the power series expansion method. To demonstrate the physical behavior of the equation, 3D, density, and 2D graphs of the obtained solutions are presented. Finally, utilizing the multiplier technique and Ibragimov’s method, we derive conserved vectors of the gFKdVp equation. These include the conservation of energy and momentum. Thus, the major conclusion of the study is that analytic solutions and conservation laws of the gFKdVp equation are determined. Full article
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14 pages, 863 KiB  
Article
The Effect of the Extraction Temperature on the Colligative, Hydrodynamic and Rheological Properties of Psyllium Husk Mucilage Raw Solutions
by Anna Ptaszek, Marta Liszka-Skoczylas and Urszula Goik
Molecules 2025, 30(15), 3219; https://doi.org/10.3390/molecules30153219 - 31 Jul 2025
Viewed by 161
Abstract
The aim of the research was to analyse the effect of different extraction temperatures on the colligative, hydrodynamic, and rheological properties of a water-soluble AXs fractions. The research material consisted of raw water extracts of arabinoxylans obtained from the husk at the following [...] Read more.
The aim of the research was to analyse the effect of different extraction temperatures on the colligative, hydrodynamic, and rheological properties of a water-soluble AXs fractions. The research material consisted of raw water extracts of arabinoxylans obtained from the husk at the following temperatures: 40 °C (AX40), 60 °C (AX60), 80 °C (AX80), and 100 °C (AX100). These were characterised in terms of their hydrodynamic, osmotic, and rheological properties, as well as the average molecular mass of the polysaccharide fractions. An increase in extraction temperature resulted in an increase in weight-average molecular mass, from 2190 kDa (AX40) to 3320 kDa (AX100). The values of the osmotic average molecular mass were higher than those obtained from GPC, and decreased with increasing extraction temperature. The dominance of biopolymer–biopolymer interactions was evident in the shape of the autocorrelation function, which did not disappear as the extraction temperature and concentration increased. Furthermore, the values of the second virial coefficient were negative, which is indicative of the tendency of biopolymer chains to aggregate. The rheological properties of the extracts changed from being described by a power-law model (AX40 and AX60) to being described by the full non-linear De Kee model (AX80 and AX100). Full article
(This article belongs to the Section Physical Chemistry)
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17 pages, 3995 KiB  
Article
Nonlinear Vibration and Post-Buckling Behaviors of Metal and FGM Pipes Transporting Heavy Crude Oil
by Kamran Foroutan, Farshid Torabi and Arth Pradeep Patel
Appl. Sci. 2025, 15(15), 8515; https://doi.org/10.3390/app15158515 (registering DOI) - 31 Jul 2025
Viewed by 84
Abstract
Functionally graded materials (FGMs) have the potential to revolutionize the oil and gas transportation sector, due to their increased strengths and efficiencies as pipelines. Conventional pipelines frequently face serious problems such as extreme weather, pressure changes, corrosion, and stress-induced pipe bursts. By analyzing [...] Read more.
Functionally graded materials (FGMs) have the potential to revolutionize the oil and gas transportation sector, due to their increased strengths and efficiencies as pipelines. Conventional pipelines frequently face serious problems such as extreme weather, pressure changes, corrosion, and stress-induced pipe bursts. By analyzing the mechanical and thermal performance of FGM-based pipes under various operating conditions, this study investigates the possibility of using them as a more reliable substitute. In the current study, the post-buckling and nonlinear vibration behaviors of pipes composed of FGMs transporting heavy crude oil were examined using a Timoshenko beam framework. The material properties of the FGM pipe were observed to change gradually across the thickness, following a power-law distribution, and were influenced by temperature variations. In this regard, two types of FGM pipes are considered: one with a metal-rich inner surface and ceramic-rich outer surface, and the other with a reverse configuration featuring metal on the outside and ceramic on the inside. The nonlinear governing equations (NGEs) describing the system’s nonlinear dynamic response were formulated by considering nonlinear strain terms through the von Kármán assumptions and employing Hamilton’s principle. These equations were then discretized using Galerkin’s method to facilitate the analytical investigation. The Runge–Kutta method was employed to address the nonlinear vibration problem. It is concluded that, compared with pipelines made from conventional materials, those constructed with FGMs exhibit enhanced thermal resistance and improved mechanical strength. Full article
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11 pages, 2887 KiB  
Article
INTEGRAL/ISGRI Post 2024-Periastron View of PSR B1259-63
by Aleksei Kuzin, Denys Malyshev, Maria Chernyakova, Brian van Soelen and Andrea Santangelo
Universe 2025, 11(8), 254; https://doi.org/10.3390/universe11080254 - 31 Jul 2025
Viewed by 110
Abstract
PSR B1259-63/LS 2883 is a well-studied gamma-ray binary hosting a pulsar in a 3.4-year eccentric orbit around a Be-type star. Its non-thermal emission spans from radio to TeV energies, exhibiting a significant increase near the periastron passage. This paper is dedicated to the [...] Read more.
PSR B1259-63/LS 2883 is a well-studied gamma-ray binary hosting a pulsar in a 3.4-year eccentric orbit around a Be-type star. Its non-thermal emission spans from radio to TeV energies, exhibiting a significant increase near the periastron passage. This paper is dedicated to the analysis of INTEGRAL observations of the system following its last periastron passage in June 2024. We aim to study the spectral evolution of this gamma-ray binary in the soft (0.3–10 keV) and hard (30–300 keV) X-ray energy bands. We performed a joint analysis of the data taken by INTEGRAL/ISGRI in July–August 2024 and quasi-simultaneous Swift/XRT observations. The spectrum of the system in the 0.3–300 keV band is well described by an absorbed power law with a photon index of Γ=1.42±0.03. We place constraints on potential spectral curvature, limiting the break energy Eb>30 keV for ΔΓ>0.3 and cutoff energy Ecutoff>150 keV at a 95% confidence level. For one-zone leptonic emission models, these values correspond to electron distribution spectral parameters of Eb,e>0.8 TeV and Ecutoff,e>1.7 TeV, consistent with previous constraints derived by H.E.S.S. Full article
(This article belongs to the Section Compact Objects)
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20 pages, 2321 KiB  
Article
Electric Vehicle Energy Management Under Unknown Disturbances from Undefined Power Demand: Online Co-State Estimation via Reinforcement Learning
by C. Treesatayapun, A. J. Munoz-Vazquez, S. K. Korkua, B. Srikarun and C. Pochaiya
Energies 2025, 18(15), 4062; https://doi.org/10.3390/en18154062 - 31 Jul 2025
Viewed by 251
Abstract
This paper presents a data-driven energy management scheme for fuel cell and battery electric vehicles, formulated as a constrained optimal control problem. The proposed method employs a co-state network trained using real-time measurements to estimate the control law without requiring prior knowledge of [...] Read more.
This paper presents a data-driven energy management scheme for fuel cell and battery electric vehicles, formulated as a constrained optimal control problem. The proposed method employs a co-state network trained using real-time measurements to estimate the control law without requiring prior knowledge of the system model or a complete dataset across the full operating domain. In contrast to conventional reinforcement learning approaches, this method avoids the issue of high dimensionality and does not depend on extensive offline training. Robustness is demonstrated by treating uncertain and time-varying elements, including power consumption from air conditioning systems, variations in road slope, and passenger-related demands, as unknown disturbances. The desired state of charge is defined as a reference trajectory, and the control input is computed while ensuring compliance with all operational constraints. Validation results based on a combined driving profile confirm the effectiveness of the proposed controller in maintaining the battery charge, reducing fluctuations in fuel cell power output, and ensuring reliable performance under practical conditions. Comparative evaluations are conducted against two benchmark controllers: one designed to maintain a constant state of charge and another based on a soft actor–critic learning algorithm. Full article
(This article belongs to the Special Issue Forecasting and Optimization in Transport Energy Management Systems)
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22 pages, 645 KiB  
Article
Asymptotic Solution for Skin Heating by an Electromagnetic Beam at an Incident Angle
by Hongyun Wang, Shannon E. Foley and Hong Zhou
Electronics 2025, 14(15), 3061; https://doi.org/10.3390/electronics14153061 - 31 Jul 2025
Viewed by 187
Abstract
We investigate the temperature evolution in the three-dimensional skin tissue exposed to a millimeter-wave electromagnetic beam that is not necessarily perpendicular to the skin surface. This study examines the effect of the beam’s incident angle. The incident angle influences the thermal heating in [...] Read more.
We investigate the temperature evolution in the three-dimensional skin tissue exposed to a millimeter-wave electromagnetic beam that is not necessarily perpendicular to the skin surface. This study examines the effect of the beam’s incident angle. The incident angle influences the thermal heating in two aspects: (i) the beam spot projected onto the skin is elongated compared to the intrinsic beam spot in a perpendicular cross-section, resulting in a lower power per skin area; and (ii) inside the tissue, the beam propagates at the refracted angle relative to the depth direction. At millimeter-wavelength frequencies, the characteristic penetration depth is sub-millimeter, whereas the lateral extent of the beam spans at least several centimeters in applications. We explore the small ratio of the penetration depth to the lateral length scale in a nondimensional formulation and derive a leading-term asymptotic solution for the temperature distribution. This analysis does not rely on a small incident angle and is therefore applicable to arbitrary angles of incidence. Based on the asymptotic solution, we establish scaling laws for the three-dimensional skin temperature, the skin surface temperature, and the skin volume in which thermal nociceptors are activated. Full article
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20 pages, 834 KiB  
Article
Time-Fractional Evolution of Quantum Dense Coding Under Amplitude Damping Noise
by Chuanjin Zu, Baoxiong Xu, Hao He, Xiaolong Li and Xiangyang Yu
Fractal Fract. 2025, 9(8), 501; https://doi.org/10.3390/fractalfract9080501 - 30 Jul 2025
Viewed by 146
Abstract
In this paper, we investigate the memory effects introduced by the time-fractional Schrödinger equation proposed by Naber on quantum entanglement and quantum dense coding under amplitude damping noise. Two formulations are analyzed: one with fractional operations applied to the imaginary unit and one [...] Read more.
In this paper, we investigate the memory effects introduced by the time-fractional Schrödinger equation proposed by Naber on quantum entanglement and quantum dense coding under amplitude damping noise. Two formulations are analyzed: one with fractional operations applied to the imaginary unit and one without. Numerical results show that the formulation without fractional operations on the imaginary unit may be more suitable for describing non-Markovian (power-law) behavior in dissipative environments. This finding provides a more physically meaningful interpretation of the memory effects in time-fractional quantum dynamics and indirectly addresses fundamental concerns regarding the violation of unitarity and probability conservation in such frameworks. Our work offers a new perspective for the application of fractional quantum mechanics to realistic open quantum systems and shows promise in supporting the theoretical modeling of decoherence and information degradation. Full article
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19 pages, 1297 KiB  
Article
The Genghis Khan Effect
by Sergio Da Silva, Raul Matsushita and Sergio Bonini
Humans 2025, 5(3), 19; https://doi.org/10.3390/humans5030019 - 30 Jul 2025
Viewed by 228
Abstract
This study examines the impact of reproductive inequality on the long-term survival of Homo sapiens by comparing two reproductive models: the Pareto (power-law) distribution of unequal reproduction and the Gaussian (normal) distribution of equal reproduction. We conducted simulations to explore how genetic diversity, [...] Read more.
This study examines the impact of reproductive inequality on the long-term survival of Homo sapiens by comparing two reproductive models: the Pareto (power-law) distribution of unequal reproduction and the Gaussian (normal) distribution of equal reproduction. We conducted simulations to explore how genetic diversity, measured by heterozygosity, evolves over time. The results predict population crashes due to genetic bottlenecks under both models, but with large differences in timing. We refer to Pareto reproductive inequality as the Genghis Khan effect. This effect accelerates the loss of genetic diversity, increasing the species’ vulnerability to environmental stressors, resource depletion, and genetic drift, and thereby raising the risk of an earlier population collapse. Our findings showcase the importance of reproductive balance for the prolonged presence of Homo sapiens on this planet. Full article
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31 pages, 11019 KiB  
Review
A Review of Tunnel Field-Effect Transistors: Materials, Structures, and Applications
by Shupeng Chen, Yourui An, Shulong Wang and Hongxia Liu
Micromachines 2025, 16(8), 881; https://doi.org/10.3390/mi16080881 - 29 Jul 2025
Viewed by 373
Abstract
The development of an integrated circuit faces the challenge of the physical limit of Moore’s Law. One of the most important “Beyond Moore” challenges is the scaling down of Metal-Oxide-Semiconductor Field-Effect Transistors (MOSFETs) versus their increasing static power consumption. This is because, at [...] Read more.
The development of an integrated circuit faces the challenge of the physical limit of Moore’s Law. One of the most important “Beyond Moore” challenges is the scaling down of Metal-Oxide-Semiconductor Field-Effect Transistors (MOSFETs) versus their increasing static power consumption. This is because, at room temperature, the thermal emission transportation mechanism will cause a physical limitation on subthreshold swing (SS), which is fundamentally limited to a minimum value of 60 mV/decade for MOSFETs, and accompanied by an increase in off-state leakage current with the process of scaling down. Moreover, the impacts of short-channel effects on device performance also become an increasingly severe problem with channel length scaling down. Due to the band-to-band tunneling mechanism, Tunnel Field-Effect Transistors (TFETs) can reach a far lower SS than MOSFETs. Recent research works indicated that TFETs are already becoming some of the promising candidates of conventional MOSFETs for ultra-low-power applications. This paper provides a review of some advances in materials and structures along the evolutionary process of TFETs. An in-depth discussion of both experimental works and simulation works is conducted. Furthermore, the performance of TFETs with different structures and materials is explored in detail as well, covering Si, Ge, III-V compounds and 2D materials, alongside different innovative device structures. Additionally, this work provides an outlook on the prospects of TFETs in future ultra-low-power electronics and biosensor applications. Full article
(This article belongs to the Special Issue MEMS/NEMS Devices and Applications, 3rd Edition)
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18 pages, 9954 KiB  
Article
Adaptive Continuous Non-Singular Terminal Sliding Mode Control for High-Pressure Common Rail Systems: Design and Experimental Validation
by Jie Zhang, Yinhui Yu, Sumin Wu, Wenjiang Zhu and Wenqian Liu
Processes 2025, 13(8), 2410; https://doi.org/10.3390/pr13082410 - 29 Jul 2025
Viewed by 235
Abstract
The High-Pressure Common Rail System (HPCRS) is designed based on fundamental hydrodynamic principles, after which this paper formally defines the key control challenges. The proposed continuous sliding mode control strategy is developed based on a non-singular terminal sliding mode framework, integrated with an [...] Read more.
The High-Pressure Common Rail System (HPCRS) is designed based on fundamental hydrodynamic principles, after which this paper formally defines the key control challenges. The proposed continuous sliding mode control strategy is developed based on a non-singular terminal sliding mode framework, integrated with an improved power reaching law. This design effectively eliminates chattering and achieves fast dynamic response with enhanced tracking precision. Subsequently, a bidirectional adaptive mechanism is integrated into the proposed control scheme to eliminate the necessity for a priori knowledge of unknown disturbances within the HPCRS. This mechanism enables real-time evaluation of the system’s state relative to a predefined detection region. To validate the effectiveness of the proposed strategy, experimental studies are conducted under three distinct operating conditions. The experimental results indicate that, compared with conventional rail pressure controllers, the proposed method achieves superior tracking accuracy, faster dynamic response, and improved disturbance rejection. Full article
(This article belongs to the Special Issue Design and Analysis of Adaptive Identification and Control)
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16 pages, 4613 KiB  
Article
Passive Layer Evolution of Anodized B206 Aluminum in Seawater for Tidal Energy Applications: An Electrochemical Approach
by Ibrahim M. Gadala, Shabnam Pournazari, Davood Nakhaie, Akram Alfantazi, Daan M. Maijer and Edouard Asselin
Metals 2025, 15(8), 846; https://doi.org/10.3390/met15080846 - 29 Jul 2025
Viewed by 257
Abstract
Aluminum–copper casting alloys are potential candidate materials for use in marine applications where high mechanical strength and superior fatigue resistance are desired. The corrosion and protection of aluminum alloy B206 in seawater through surface passivation continues to pose challenges, hampering its widespread use [...] Read more.
Aluminum–copper casting alloys are potential candidate materials for use in marine applications where high mechanical strength and superior fatigue resistance are desired. The corrosion and protection of aluminum alloy B206 in seawater through surface passivation continues to pose challenges, hampering its widespread use in marine structures. In this study, the electrochemical behavior of B206 is investigated in artificial seawater at temperatures and dissolved oxygen (DO) concentrations anticipated during service in marine environments. In particular, the influence of anodizing B206 in deaerated seawater on the subsequent corrosion behavior of the alloy is studied using potentiodynamic and potentiostatic polarization, electrochemical impedance spectroscopy (EIS), and Mott–Schottky analysis. The results showed that the effect of DO on the corrosion of B206 is more significant than the effect of temperature. In the absence of DO, results of potentiostatic polarization, EIS, and Mott–Schottky analysis at anodic potentials all indicated the development of a thicker, more protective passive layer in colder seawater. Moreover, passive layer thickness modeled using Power-Law was found to range between 3 and 9 nm, whilst decreasing in thickness with temperature. Donor densities of the n-type passive layer are on the order of 1021 cm−3 and increase with temperature. The findings presented in this study support the feasibility of implementing anodizing for B206 in marine service environments. Full article
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