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Search Results (1,587)

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Keywords = polymer additive manufacturing

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40 pages, 7182 KiB  
Review
Additively Manufactured Polymers for Electronic Components
by Filippo Iervolino, Raffaella Suriano, Marco Cavallaro, Laura Castoldi and Marinella Levi
Appl. Sci. 2025, 15(15), 8689; https://doi.org/10.3390/app15158689 (registering DOI) - 6 Aug 2025
Abstract
Over the last decade, polymers have attracted increasing attention for the fabrication of electronic devices due to the innovative results that can be achieved using additive manufacturing (AM) processes. Intrinsically conductive polymers are commonly used to obtain flexible and stretchable devices. They also [...] Read more.
Over the last decade, polymers have attracted increasing attention for the fabrication of electronic devices due to the innovative results that can be achieved using additive manufacturing (AM) processes. Intrinsically conductive polymers are commonly used to obtain flexible and stretchable devices. They also enable the customisation of electronic devices when processed through AM. However, their main limitation is the reduction in electrical conductivity under mechanical deformation, such as bending. Extrinsically conductive nanocomposites, incorporating conductive fillers into polymer matrices, demonstrate the ability to retain electrical conductivity even following repeated bending, presenting a promising solution to the limitations of intrinsically conductive polymers. However, a gap remains in optimising their processing conditions for diverse 3D printing technologies. Moreover, fillers should be carefully selected according to the application’s specific needs. Dielectric polymers are also very promising for various electronic applications, but they are less investigated and have lower visibility than their conductive counterparts. This review presents three classes of polymer materials, i.e., intrinsically and extrinsically conductive polymers and insulators, discussing their advantages, drawbacks, and applications for 3D printing in electronics. This overview concludes with assessing future investigation areas needed to unlock the possibilities of 3D-printed polymers in electronics. Full article
(This article belongs to the Special Issue Feature Review Papers in Additive Manufacturing Technologies)
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16 pages, 2029 KiB  
Article
Multi-Objective Optimization of Biodegradable and Recyclable Composite PLA/PHA Parts
by Burak Kisin, Mehmet Kivanc Turan and Fatih Karpat
Polymers 2025, 17(15), 2147; https://doi.org/10.3390/polym17152147 - 6 Aug 2025
Abstract
Additive manufacturing (AM) techniques, especially fused deposition modeling (FDM), offer significant advantages in terms of cost, material efficiency, and design flexibility. In this study, the mechanical performance of biodegradable PLA/PHA composite samples produced via FDM was optimized by evaluating the influence of key [...] Read more.
Additive manufacturing (AM) techniques, especially fused deposition modeling (FDM), offer significant advantages in terms of cost, material efficiency, and design flexibility. In this study, the mechanical performance of biodegradable PLA/PHA composite samples produced via FDM was optimized by evaluating the influence of key printing parameters—layer height, printing orientation, and printing speed—on both the tensile and compressive strength. A full factorial design (3 × 3 × 3) was employed, and all of the samples were triplicated to ensure the consistency of the results. Grey relational analysis (GRA) was used as a multi-objective optimization method to determine the optimal parameter combinations. An analysis of variance (ANOVA) was also conducted to assess the statistical significance of each parameter. The ANOVA results revealed that printing orientation is the most significant parameter for both tensile and compression strength. The optimal parameter combination for maximizing mechanical properties was a layer height of 0.1 mm, an X printing orientation, and a printing speed of 50 mm/s. This study demonstrates the effectiveness of GRA in optimizing the mechanical properties of biodegradable composites and provides practical guidelines to produce environmentally sustainable polymer parts. Full article
(This article belongs to the Special Issue Sustainable Bio-Based and Circular Polymers and Composites)
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20 pages, 4467 KiB  
Review
Structuring the Future of Cultured Meat: Hybrid Gel-Based Scaffolds for Edibility and Functionality
by Sun Mi Zo, Ankur Sood, So Yeon Won, Soon Mo Choi and Sung Soo Han
Gels 2025, 11(8), 610; https://doi.org/10.3390/gels11080610 - 3 Aug 2025
Viewed by 90
Abstract
Cultured meat is emerging as a sustainable alternative to conventional animal agriculture, with scaffolds playing a central role in supporting cellular attachment, growth, and tissue maturation. This review focuses on the development of gel-based hybrid biomaterials that meet the dual requirements of biocompatibility [...] Read more.
Cultured meat is emerging as a sustainable alternative to conventional animal agriculture, with scaffolds playing a central role in supporting cellular attachment, growth, and tissue maturation. This review focuses on the development of gel-based hybrid biomaterials that meet the dual requirements of biocompatibility and food safety. We explore recent advances in the use of naturally derived gel-forming polymers such as gelatin, chitosan, cellulose, alginate, and plant-based proteins as the structural backbone for edible scaffolds. Particular attention is given to the integration of food-grade functional additives into hydrogel-based scaffolds. These include nanocellulose, dietary fibers, modified starches, polyphenols, and enzymatic crosslinkers such as transglutaminase, which enhance mechanical stability, rheological properties, and cell-guidance capabilities. Rather than focusing on fabrication methods or individual case studies, this review emphasizes the material-centric design strategies for building scalable, printable, and digestible gel scaffolds suitable for cultured meat production. By systemically evaluating the role of each component in structural reinforcement and biological interaction, this work provides a comprehensive frame work for designing next-generation edible scaffold systems. Nonetheless, the field continues to face challenges, including structural optimization, regulatory validation, and scale-up, which are critical for future implementation. Ultimately, hybrid gel-based scaffolds are positioned as a foundational technology for advancing the functionality, manufacturability, and consumer readiness of cultured meat products, distinguishing this work from previous reviews. Unlike previous reviews that have focused primarily on fabrication techniques or tissue engineering applications, this review provides a uniquely food-centric perspective by systematically evaluating the compositional design of hybrid hydrogel-based scaffolds with edibility, scalability, and consumer acceptance in mind. Through a comparative analysis of food-safe additives and naturally derived biopolymers, this review establishes a framework that bridges biomaterials science and food engineering to advance the practical realization of cultured meat products. Full article
(This article belongs to the Special Issue Food Hydrocolloids and Hydrogels: Rheology and Texture Analysis)
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33 pages, 3776 KiB  
Review
The Role of Additive Manufacturing in Dental Implant Production—A Narrative Literature Review
by Ján Duplák, Darina Dupláková, Maryna Yeromina, Samuel Mikuláško and Jozef Török
Sci 2025, 7(3), 109; https://doi.org/10.3390/sci7030109 - 3 Aug 2025
Viewed by 191
Abstract
This narrative review explores the role of additive manufacturing (AM) technologies in the production of dental implants, focusing on materials and key AM methods. The study discusses several materials used in implant fabrication, including porous titanium, trabecular tantalum, zirconium dioxide, polymers, and composite [...] Read more.
This narrative review explores the role of additive manufacturing (AM) technologies in the production of dental implants, focusing on materials and key AM methods. The study discusses several materials used in implant fabrication, including porous titanium, trabecular tantalum, zirconium dioxide, polymers, and composite materials. These materials are evaluated for their mechanical properties, biocompatibility, and suitability for AM processes. Additionally, the review examines the main AM technologies used in dental implant production, such as selective laser melting (SLM), electron beam melting (EBM), stereolithography (SLA), selective laser sintering (SLS), and direct metal laser sintering (DMLS). These technologies are compared based on their accuracy, material limitations, customization potential, and applicability in dental practice. The final section presents a data source analysis of the Web of Science and Scopus databases, based on keyword searches. The analysis evaluates the research trends using three criteria: publication category, document type, and year of publication. This provides an insight into the evolution and current trends in the field of additive manufacturing for dental implants. The findings highlight the growing importance of AM technologies in producing customized and efficient dental implants. Full article
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25 pages, 17212 KiB  
Article
Three-Dimensional Printing of Personalized Carbamazepine Tablets Using Hydrophilic Polymers: An Investigation of Correlation Between Dissolution Kinetics and Printing Parameters
by Lianghao Huang, Xingyue Zhang, Qichen Huang, Minqing Zhu, Tiantian Yang and Jiaxiang Zhang
Polymers 2025, 17(15), 2126; https://doi.org/10.3390/polym17152126 - 1 Aug 2025
Viewed by 304
Abstract
Background: Precision medicine refers to the formulation of personalized drug regimens according to the individual characteristics of patients to achieve optimal efficacy and minimize adverse reactions. Additive manufacturing (AM), also known as three-dimensional (3D) printing, has emerged as an optimal solution for precision [...] Read more.
Background: Precision medicine refers to the formulation of personalized drug regimens according to the individual characteristics of patients to achieve optimal efficacy and minimize adverse reactions. Additive manufacturing (AM), also known as three-dimensional (3D) printing, has emerged as an optimal solution for precision drug delivery, enabling customizable and the fabrication of multifunctional structures with precise control over morphology and release behavior in pharmaceutics. However, the influence of 3D printing parameters on the printed tablets, especially regarding in vitro and in vivo performance, remains poorly understood, limiting the optimization of manufacturing processes for controlled-release profiles. Objective: To establish the fabrication process of 3D-printed controlled-release tablets via comprehensively understanding the printing parameters using fused deposition modeling (FDM) combined with hot-melt extrusion (HME) technologies. HPMC-AS/HPC-EF was used as the drug delivery matrix and carbamazepine (CBZ) was used as a model drug to investigate the in vitro drug delivery performance of the printed tablets. Methodology: Thermogravimetric analysis (TGA) was employed to assess the thermal compatibility of CBZ with HPMC-AS/HPC-EF excipients up to 230 °C, surpassing typical processing temperatures (160–200 °C). The formation of stable amorphous solid dispersions (ASDs) was validated using differential scanning calorimetry (DSC), hot-stage polarized light microscopy (PLM), and powder X-ray diffraction (PXRD). A 15-group full factorial design was then used to evaluate the effects of the fan speed (20–100%), platform temperature (40–80 °C), and printing speed (20–100 mm/s) on the tablet properties. Response surface modeling (RSM) with inverse square-root transformation was applied to analyze the dissolution kinetics, specifically t50% (time for 50% drug release) and Q4h (drug released at 4 h). Results: TGA confirmed the thermal compatibility of CBZ with HPMC-AS/HPC-EF, enabling stable ASD formation validated by DSC, PLM, and PXRD. The full factorial design revealed that printing speed was the dominant parameter governing dissolution behavior, with high speeds accelerating release and low speeds prolonging release through porosity-modulated diffusion control. RSM quadratic models showed optimal fits for t50% (R2 = 0.9936) and Q4h (R2 = 0.9019), highlighting the predictability of release kinetics via process parameter tuning. This work demonstrates the adaptability of polymer composite AM for tailoring drug release profiles, balancing mechanical integrity, release kinetics, and manufacturing scalability to advance multifunctional 3D-printed drug delivery devices in pharmaceutics. Full article
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33 pages, 3709 KiB  
Review
A Review of Methods and Data on the Recycling of Plastics from the European Waste Stream of Electric and Electronic Equipment
by Nicolas Nève, Xavier Mackré-Delannoy, Bruno Fayolle, Matthieu Gervais, Stéphane Pompidou, Carole Charbuillet, Cyrille Sollogoub and Nicolas Perry
Recycling 2025, 10(4), 148; https://doi.org/10.3390/recycling10040148 - 28 Jul 2025
Viewed by 303
Abstract
Plastics make up a significant proportion of the stream of the European Waste of Electric and Electronic Equipment (WEEE), yet the use of recycled plastic materials is very low in new manufactured products. A description of the WEEE waste stream in Europe is [...] Read more.
Plastics make up a significant proportion of the stream of the European Waste of Electric and Electronic Equipment (WEEE), yet the use of recycled plastic materials is very low in new manufactured products. A description of the WEEE waste stream in Europe is given, with a focus on the plastic materials commonly found in WEEE that include four principal polymers: polypropylene (PP), polycarbonate (PC), acrylonitrile-butadiene-styrene (ABS) and polystyrene (PS). Furthermore, the legislative aspects related to WEEE and plastics recycling in Europe are complex, and numerous norms have been dictated by the European Commission. These norms are crucial to the sector of polymer recycling and production in Europe. Moreover, an overview of the entire treatment chain is presented. More specifically, each step of a typical recycling chain is introduced, with a focus on the sorting of plastics and the separation of polymers. Lastly, the influence of contaminants in the plastic fraction is discussed, both in terms of polymer particles and unwanted additives. By showing the impact of the purity rate on the mechanical properties of recycled plastics, the consequences of inadequate end-of-life treatment for WEEE-plastics is highlighted, hence linking the quality of recycled plastics to the separation step and the re-compounding of recycled granulates. Full article
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18 pages, 4344 KiB  
Review
Additive Manufacturing Technologies and Their Applications in Dentistry: A Systematic Literature Review
by Dragana Oros, Marko Penčić, Marko Orošnjak and Slawomir Kedziora
Appl. Sci. 2025, 15(15), 8346; https://doi.org/10.3390/app15158346 - 26 Jul 2025
Viewed by 375
Abstract
Additive manufacturing (AM) has emerged as a transformative technology in dentistry, enabling the production of patient-specific dental applications with reduced costs and fabrication times. Despite the growth of applications, a consolidated understanding of current 3D printing technologies, materials, and performance in dental settings [...] Read more.
Additive manufacturing (AM) has emerged as a transformative technology in dentistry, enabling the production of patient-specific dental applications with reduced costs and fabrication times. Despite the growth of applications, a consolidated understanding of current 3D printing technologies, materials, and performance in dental settings remains fragmented. Here, we perform a Systematic Literature Review (SLR) using the PRISMA protocol, retrieving 19 closely related primary studies. The evidence is synthesized across three axes: application domain, AM technology, and critical quality parameters. Dental restorations, prosthetics, crowns, and implants are the most common applications, while fused deposition modeling, stereolithography, digital light processing, selective laser sintering, and laser-directed energy deposition are the most used technologies. AM materials include polymers, metals, and emerging biomaterials. Key quality determinants include dimensional accuracy, wear and corrosion resistance, and photosensitivity. Notably, biocompatibility and cytotoxicity remain underexplored yet critical factors for ensuring long-term clinical safety. The evidence also suggests a lack of in vivo studies, insufficient tribological and microbiological testing, including limited data degradation pathways of AM materials under oral conditions. Understanding that there are disconnects between the realization of the clinical and the economic benefits of 3D printing in dentistry, future research requires standardized testing frameworks and long-term biocompatibility validation. Full article
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31 pages, 5261 KiB  
Review
Wear- and Corrosion-Resistant Coatings for Extreme Environments: Advances, Challenges, and Future Perspectives
by Subin Antony Jose, Zachary Lapierre, Tyler Williams, Colton Hope, Tryon Jardin, Roberto Rodriguez and Pradeep L. Menezes
Coatings 2025, 15(8), 878; https://doi.org/10.3390/coatings15080878 - 26 Jul 2025
Viewed by 735
Abstract
Tribological processes in extreme environments pose serious material challenges, requiring coatings that resist both wear and corrosion. This review summarizes recent advances in protective coatings engineered for extreme environments such as high temperatures, chemically aggressive media, and high-pressure and abrasive domains, as well [...] Read more.
Tribological processes in extreme environments pose serious material challenges, requiring coatings that resist both wear and corrosion. This review summarizes recent advances in protective coatings engineered for extreme environments such as high temperatures, chemically aggressive media, and high-pressure and abrasive domains, as well as cryogenic and space applications. A comprehensive overview of promising coating materials is provided, including ceramic-based coatings, metallic and alloy coatings, and polymer and composite systems, as well as nanostructured and multilayered architectures. These materials are deployed using advanced coating technologies such as thermal spraying (plasma spray, high-velocity oxygen fuel (HVOF), and cold spray), chemical and physical vapor deposition (CVD and PVD), electrochemical methods (electrodeposition), additive manufacturing, and in situ coating approaches. Key degradation mechanisms such as adhesive and abrasive wear, oxidation, hot corrosion, stress corrosion cracking, and tribocorrosion are examined with coating performance. The review also explores application-specific needs in aerospace, marine, energy, biomedical, and mining sectors operating in aggressive physiological environments. Emerging trends in the field are highlighted, including self-healing and smart coatings, environmentally friendly coating technologies, functionally graded and nanostructured coatings, and the integration of machine learning in coating design and optimization. Finally, the review addresses broader considerations such as scalability, cost-effectiveness, long-term durability, maintenance requirements, and environmental regulations. This comprehensive analysis aims to synthesize current knowledge while identifying future directions for innovation in protective coatings for extreme environments. Full article
(This article belongs to the Special Issue Advanced Tribological Coatings: Fabrication and Application)
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18 pages, 7614 KiB  
Article
The Influence of Print Orientation and Discontinuous Carbon Fiber Content on the Tensile Properties of Selective Laser-Sintered Polyamide 12
by Jonathan J. Slager, Joshua T. Green, Samuel D. Levine and Roger V. Gonzalez
Polymers 2025, 17(15), 2028; https://doi.org/10.3390/polym17152028 - 25 Jul 2025
Viewed by 340
Abstract
Discontinuous fibers are commonly added to matrix materials in additive manufacturing to enhance properties, but such benefits may be constrained by print and fiber orientation. The additive processes of forming rasters and layers in powder bed fusion inherently cause anisotropy in printed parts. [...] Read more.
Discontinuous fibers are commonly added to matrix materials in additive manufacturing to enhance properties, but such benefits may be constrained by print and fiber orientation. The additive processes of forming rasters and layers in powder bed fusion inherently cause anisotropy in printed parts. Many print parameters, such as laser, temperature, and hatch pattern, influence the anisotropy of tensile properties. This study characterizes fiber orientation attributed to recoating non-encapsulated fibers and the resulting anisotropic tensile properties. Tensile and fracture properties of polyamide 12 reinforced with 0%, 2.5%, 5%, and 10% discontinuous carbon fibers by volume were characterized in two primary print/tensile loading orientations: tensile loading parallel to the recoater (“horizontal specimens”) and tensile load along the build axis (“vertical specimens”). Density and fractographic analysis indicate a homogeneous mixture with low porosity and primary fiber orientation along the recoating direction for both print orientations. Neat specimens (zero fiber) loaded in either direction have similar tensile properties. However, fiber-reinforced vertical specimens have significantly reduced consistency and tensile strength as fiber content increased, while the opposite is true for horizontal specimens. These datasets and results provide a mechanism to tune material properties and improve the functionality of selectively laser-sintered fiber-reinforced parts through print orientation selection. These datasets could be used to customize functionally graded parts with multi-material selective laser-sintering manufacturing. Full article
(This article belongs to the Special Issue Polymeric Composites: Manufacturing, Processing and Applications)
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17 pages, 7181 KiB  
Article
Piezoelectric Effect of k-Carrageenan as a Tool for Force Sensor
by Vytautas Bučinskas, Uldis Žaimis, Dainius Udris, Jūratė Jolanta Petronienė and Andrius Dzedzickis
Sensors 2025, 25(15), 4594; https://doi.org/10.3390/s25154594 - 24 Jul 2025
Viewed by 211
Abstract
Natural polymers, polysaccharides, demonstrate piezoelectric behavior suitable for force sensor manufacturing. Carrageenan hydrogel film with α-iron oxide particles can act as a piezoelectric polysaccharide-based force sensor. The mechanical impact on the hydrogel caused by a falling ball shows the impact response time, which [...] Read more.
Natural polymers, polysaccharides, demonstrate piezoelectric behavior suitable for force sensor manufacturing. Carrageenan hydrogel film with α-iron oxide particles can act as a piezoelectric polysaccharide-based force sensor. The mechanical impact on the hydrogel caused by a falling ball shows the impact response time, which is measured in milliseconds. Repeating several experiments in a row shows the dynamics of fatigue, which does not reduce the speed of response to impact. Through the practical experiments, we sought to demonstrate how theoretical knowledge describes the hydrogel we elaborated, which works as a piezoelectric material. In addition to the theoretical basis, which includes the operation of the metal and metal oxide contact junction, the interaction between the metal oxide and the hydrogel surfaces, the paper presents the practical application of this knowledge to the complex hydrogel film. The simple calculations presented in this paper are intended to predict the hydrogel film’s characteristics and explain the results obtained during practical experiments. Carrageenan, as a low-cost and already widely used polysaccharide in various industries, is suitable for the production of low-cost force sensors in combination with iron oxide. Full article
(This article belongs to the Section Electronic Sensors)
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23 pages, 1998 KiB  
Article
Hybrid Experimental–Machine Learning Study on the Mechanical Behavior of Polymer Composite Structures Fabricated via FDM
by Osman Ulkir and Sezgin Ersoy
Polymers 2025, 17(15), 2012; https://doi.org/10.3390/polym17152012 - 23 Jul 2025
Viewed by 295
Abstract
This study explores the mechanical behavior of polymer and composite specimens fabricated using fused deposition modeling (FDM), focusing on three material configurations: acrylonitrile butadiene styrene (ABS), carbon fiber-reinforced polyphthalamide (PPA/Cf), and a sandwich-structured composite. A systematic experimental plan was developed using the Box–Behnken [...] Read more.
This study explores the mechanical behavior of polymer and composite specimens fabricated using fused deposition modeling (FDM), focusing on three material configurations: acrylonitrile butadiene styrene (ABS), carbon fiber-reinforced polyphthalamide (PPA/Cf), and a sandwich-structured composite. A systematic experimental plan was developed using the Box–Behnken design (BBD) to investigate the effects of material type (MT), infill pattern (IP), and printing direction (PD) on tensile and flexural strength. Experimental results showed that the PPA/Cf material with a “Cross” IP printed “Flat” yielded the highest mechanical performance, achieving a tensile strength of 75.8 MPa and a flexural strength of 102.3 MPa. In contrast, the lowest values were observed in ABS parts with a “Grid” pattern and “Upright” orientation, recording 37.8 MPa tensile and 49.5 MPa flexural strength. Analysis of variance (ANOVA) results confirmed that all three factors significantly influenced both outputs (p < 0.001), with MT being the most dominant factor. Machine learning (ML) algorithms, Bayesian linear regression (BLR), and Gaussian process regression (GPR) were employed to predict mechanical performance. GPR achieved the best overall accuracy with R2 = 0.9935 and MAPE = 11.14% for tensile strength and R2 = 0.9925 and MAPE = 12.96% for flexural strength. Comparatively, the traditional BBD yielded slightly lower performance with MAPE = 13.02% and R2 = 0.9895 for tensile strength. Validation tests conducted on three unseen configurations clearly demonstrated the generalization capability of the models. Based on actual vs. predicted values, the GPR yielded the lowest average prediction errors, with MAPE values of 0.54% for tensile and 0.45% for flexural strength. In comparison, BLR achieved 0.79% and 0.60%, while BBD showed significantly higher errors at 1.76% and 1.32%, respectively. Full article
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18 pages, 4169 KiB  
Article
Sustainable Thermoelectric Composites: A Study of Bi2Te3-Filled Biobased Resin
by Luca Ferretti, Pietro Russo, Jessica Passaro, Francesca Nanni, Saverio D’Ascoli, Francesco Fabbrocino and Mario Bragaglia
Materials 2025, 18(15), 3453; https://doi.org/10.3390/ma18153453 - 23 Jul 2025
Viewed by 302
Abstract
In this work, bio-based thermoelectric composites were developed using acrylated epoxidized soybean oil (AESO) as the polymer matrix and bismuth telluride (Bi2Te3) as the thermoelectric filler. The materials were formulated for both UV-curing and thermal-curing processes, with a focus [...] Read more.
In this work, bio-based thermoelectric composites were developed using acrylated epoxidized soybean oil (AESO) as the polymer matrix and bismuth telluride (Bi2Te3) as the thermoelectric filler. The materials were formulated for both UV-curing and thermal-curing processes, with a focus on Digital Light Processing (DLP) 3D printing. Although UV curing proved ineffective at high filler concentrations due to the light opacity of Bi2Te3, thermal curing enabled the fabrication of stable, homogeneously dispersed composites. The samples were thoroughly characterized through rheology, FTIR, TGA, XRD, SEM, and density measurements. Thermoelectric performance was assessed under a 70 °C temperature gradient, with Seebeck coefficients reaching up to 51 µV/K. Accelerated chemical degradation studies in basic media confirmed the degradability of the matrix. The results demonstrate the feasibility of combining additive manufacturing with sustainable materials for low-power thermoelectric energy harvesting applications. Full article
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27 pages, 36926 KiB  
Article
Comparison of Additive Manufacturing and Injection Molding of Biocomposites Reinforced with Alkali-Treated Wood Flour Derived from Recycled Wooden Pallets
by Mehmet Demir, Nilgül Çetin and Nasır Narlıoğlu
Polymers 2025, 17(15), 2004; https://doi.org/10.3390/polym17152004 - 22 Jul 2025
Viewed by 386
Abstract
Biodegradable polymer composites offer promising alternatives to petroleum-based plastics, supporting the principles of a zero waste and circular economy. This study investigates the reinforcing potential of alkali-treated wood flour derived from recycled pine (Pinus brutia Ten.) and poplar (Populus alba L.) [...] Read more.
Biodegradable polymer composites offer promising alternatives to petroleum-based plastics, supporting the principles of a zero waste and circular economy. This study investigates the reinforcing potential of alkali-treated wood flour derived from recycled pine (Pinus brutia Ten.) and poplar (Populus alba L.) waste wooden pallets in poly(lactic acid) (PLA) biocomposites. Wood flour was initially recovered through grinding and screening during recycling, followed by alkali treatment via a green chemistry approach to enhance interfacial bonding with the PLA matrix. The impact of alkali concentration and two fabrication methods—additive manufacturing (AM) and injection molding (IM)—on the properties of developed biocomposite materials was assessed through mechanical, physical, morphological, and thermal analyses. IM samples outperformed AM counterparts, with the IM PLA containing 30 wt% wood flour (alkali-treated with 10% solution) showing the highest mechanical gains: tensile (+71.35%), flexural (+64.74%), and hardness (+2.62%) compared to untreated samples. Moreover, the AM sample with 10 wt% wood flour and 10% alkali treatment showed a 49.37% decrease in water absorption compared to the untreated sample, indicating improved hydrophobicity. Scanning electron microscopy confirmed that alkali treatment reduced void content and enhanced morphological uniformity, while thermal properties remained consistent across fabrication methods. This work introduces a green composite using non-toxic materials and treatments, facilitating eco-friendly production aligned with zero waste and circular economy principles throughout the manufacturing lifecycle. Full article
(This article belongs to the Special Issue Polymer Composites: Structure, Properties and Processing, 2nd Edition)
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16 pages, 5658 KiB  
Article
Pressure Effect on the Rheological Behavior of Highly Filled Solid Propellant During Extrusion Flow
by Jun Zhang, Wei Zheng, Zhifeng Yuan, Junbo Chen, Jiangfeng Pei and Ping Xue
Polymers 2025, 17(15), 2003; https://doi.org/10.3390/polym17152003 - 22 Jul 2025
Viewed by 284
Abstract
Currently, the shear-extrusion behavior of solid propellants (SPs), which comprise a significant volume fraction of micro-/nanoscale solid particles (e.g., octogen/HMX), nitroglycerin as a plasticizer/solvent, nitrocellulose as a binder, and other functional additives, is still insufficiently understood. While the rheology of highly filled polymers [...] Read more.
Currently, the shear-extrusion behavior of solid propellants (SPs), which comprise a significant volume fraction of micro-/nanoscale solid particles (e.g., octogen/HMX), nitroglycerin as a plasticizer/solvent, nitrocellulose as a binder, and other functional additives, is still insufficiently understood. While the rheology of highly filled polymers has been extensively documented, the rheological behavior of SPs within the practical processing temperature range of 80–95 °C remains poorly understood. This study investigated, in particular, the pressure dependence of the viscosity of SPs melts during steady-state shear flow. Steady-state shear measurements were conducted using a twin-bore capillary rheometer with capillary dies of varying diameters and lengths to explore the viscosity dependence of SPs. The results reveal that interface defects between octogen particles and the polymer matrix generate a melt pressure range of 3–30 MPa in the long capillary die, underscoring the non-negligible impact of pressure on the measured viscosity (η). At constant temperature and shear rate, the measured viscosity of SPs exhibits strong pressure dependence, showing notable deviations in pressure sensitivity (β), which was found to be greatly relevant to the contents of solvent and solid particles. Such discrepancies are attributed to the compressibility of particle–particle and particle–polymer networks during capillary flow. The findings emphasize the critical role of pressure effect on the rheological properties of SPs, which is essential for optimizing manufacturing processes and ensuring consistent propellant performance. Full article
(This article belongs to the Section Polymer Processing and Engineering)
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26 pages, 4285 KiB  
Article
Machinability and Geometric Evaluation of FFF-Printed PLA-Carbon Fiber Composites in CNC Turning Operations
by Sergio Martín-Béjar, Fermín Bañón-García, Carolina Bermudo Gamboa and Lorenzo Sevilla Hurtado
Appl. Sci. 2025, 15(15), 8141; https://doi.org/10.3390/app15158141 - 22 Jul 2025
Viewed by 214
Abstract
Fused Filament Fabrication (FFF) enables the manufacturing of complex polymer components. However, surface finish and dimensional accuracy remain key limitations for their integration into functional assemblies. This study explores the potential of conventional turning as a post-processing strategy to improve the geometric and [...] Read more.
Fused Filament Fabrication (FFF) enables the manufacturing of complex polymer components. However, surface finish and dimensional accuracy remain key limitations for their integration into functional assemblies. This study explores the potential of conventional turning as a post-processing strategy to improve the geometric and surface quality of PLA reinforced with carbon fiber (CF) parts produced by FFF. Machinability was evaluated through the analysis of cutting forces, thermal behavior, energy consumption, and surface integrity under varying cutting speeds, feed rates, and specimen slenderness. The results indicate that feed is the most influential parameter across all performance metrics, with lower values leading to improved dimensional accuracy and surface finish, achieving the most significant reductions of 63% in surface roughness (Sa) and 62% in cylindricity deviation. Nevertheless, the surface roughness is higher than that of metals, and deviations in geometry along the length of the specimen have been observed. A critical shear stress of 0.237 MPa has been identified as the limit for interlayer failure, defining the boundary conditions for viable cutting operation. The incorporation of CNC turning as a post-processing step reduced the total fabrication time by approximately 83% compared with high-resolution FFF, while maintaining dimensional accuracy and enhancing surface quality. These findings support the use of machining operations as a viable and efficient post-processing method for improving the functionality of polymer-based components produced by additive manufacturing. Full article
(This article belongs to the Special Issue Advances in Carbon Fiber Reinforced Polymers (CFRPs))
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