Search Results (145)

Balancing high fluidity and stability is a critical challenge in deep-shaft cemented paste backfill (CPB) with high-concentration tailings. This study investigates the synergistic regulation mechanism of a combined admixture system comprising hydroxypropyl methylcellulose (HPMC) thickener and polycarboxylate (PCE) or Melamine-Formaldehyde Resin (MFR) superplasticizers on CPB rheology, mechanical strength, and microstructure. Results indicate that HPMC significantly enhanced anti-segregation performance via intermolecular bridging, substantially increasing yield stress and plastic viscosity. Upon PCE introduction, the steric hindrance provided by its side chains effectively disrupted HPMC-induced flocs and released entrapped water. Consequently, yield stress and plastic viscosity were reduced by up to 22.1% and 64.3%, respectively, with PCE exhibiting markedly superior viscosity-reducing efficiency compared to MFR. Mechanical testing revealed that PCE co-addition did not compromise early-age strength but enhanced 3, 7, and 28-day unconfined compressive strength (UCS) by refining pore structures and promoting the uniform distribution of hydration products. Microstructural analysis unveiled a competitive adsorption mechanism: preferential PCE adsorption dispersed particle agglomerates, while non-adsorbed HPMC formed a viscoelastic network within the pore solution, constructing a stable “dispersion-suspension” microstructure. This work provides a theoretical basis for optimizing high-performance backfill formulations. Full article

The overlying rock in the weathering and oxidation zone has well-developed micro-fissures, making roadway roof control highly challenging. Ordinary cement slurry is hard to inject, failing to achieve effective reinforcement. By introducing admixtures like ultrafine fly ash and polyvinyl alcohol (PVA) to modify ultrafine cement, this paper developed a PVA-modified ultrafine cement-based grouting material (PVAM-UFCG). It systematically investigated the influences of various factors on the slurry’s setting time, fluidity, water separation rate, viscosity, and 28-day uniaxial compressive strength, determining the optimal mix ratio through comprehensive analysis. The results show that the water–cement ratio is the dominant factor affecting slurry viscosity, strength, and setting time; the polycarboxylate superplasticizer concentration has the most significant influence on fluidity and water separation rate; a 20% ultrafine fly ash replacement rate can optimize particle gradation and enhance long-term strength; and a 1.0% polyvinyl alcohol concentration can effectively control the water separation rate (≤5%) and improve slurry cohesiveness. Through range analysis and multi-indicator comprehensive evaluation based on the entropy weight method, the performance-balanced optimal mix ratio meeting the grouting requirements for the Weathering and Oxidation Zone was determined: a water–cement ratio of 0.6, an ultrafine fly ash replacement rate of 20%, a polyvinyl alcohol concentration of 1.0%, and a polycarboxylate superplasticizer concentration of 0.4%. This mix ratio material exhibits good permeability, stability, and appropriate reinforcement strength. The research results can provide a new material choice and theoretical basis for controlling the surrounding rock of roadways under similar geological conditions. Full article

The growing demand for concrete in tropical regions faces two unresolved challenges: the high carbon footprint of ordinary Portland cement (OPC) and limited understanding of how supplementary cementitious materials affect the mechanical performance of laterite rock aggregates concrete. Although metakaolin (MK) is a highly reactive pozzolan, its combined use with laterite rock aggregates concrete and its influence on strength development and microstructure have not been sufficiently clarified. This study investigates the mechanical behavior and sustainability potential of laterite rock aggregate concrete in which OPC is partially replaced by MK at 0%, 5%, 10%, 15%, and 20% by weight. All mixes were prepared at a constant water–binder ratio of 0.50 and tested for workability, compressive strength, split-tensile strength, and flexural strength at 7, 14, and 28 days, with and without a polycarboxylate-based superplasticizer. The results show that MK significantly enhances the mechanical performance of laterite rock concrete, with an optimum at 10% replacement: the 28-day compressive strength increased from 35.6 MPa (control) to 53.9 MPa in the superplasticized mix, accompanied by corresponding gains in tensile and flexural strengths. SEM–EDS analyses revealed microstructural densification, reduced portlandite, and a refined interfacial transition zone, explaining the improved strength and cracking resistance. From an environmental perspective, a 10% MK replacement corresponds to an approximate 10% reduction in clinker-related CO₂ emissions, while the use of locally available laterite rock reduces the dependence on quarried granite and transportation impacts. The findings demonstrate that MK-modified laterite rock concrete is a viable and eco-efficient option for structural applications in tropical regions. The study concludes that MK-enhanced laterite rock aggregate concrete can deliver higher structural performance and improved sustainability without altering conventional mix design and curing practices. Full article

Conventional synthesis of polycarboxylate superplasticizers (PCEs) typically relies on high-temperature processes, posing challenges for sustainable production. Ethylene glycol monovinyl polyethylene glycol ether (EPEG), characterized by the high reactivity of its vinyloxy double bond, offers a promising sustainable alternative for low-temperature synthesis. This study systematically investigates the aqueous free radical copolymerization of EPEG and acrylic acid, identifying a reaction temperature of 20 °C as the kinetic optimum that achieves a macromonomer conversion rate exceeding 95% under ambient conditions. Through the variation in five key process parameters, a clear “synthesis–structure–property” relationship was established, revealing that the weight-average molecular weight (M_w) acts as the pivotal regulator of performance. High-M_w PCEs exhibited superior initial dispersion driven by strong electrostatic repulsion and high adsorption but suffered from poor slump retention due to the rapid depletion of free polymers. Conversely, low-M_w variants, regulated by chain transfer agent dosage, significantly reduced the pore solution surface tension, thereby enhancing wetting ability and workability retention. The optimal synthesis conditions (20 °C, 4:1 acid-to-ether ratio, 2.5% initiator, 1.5% chain transfer agent) yielded PCEs with an ideal balance between initial dispersion and retention. Furthermore, the synthesis demonstrated excellent process robustness with a broad dosing window (>60 min). These findings provide a vital theoretical basis for the robust and low-temperature industrial production of EPEG-based PCEs for sustainable infrastructure materials. Full article

In this work, a complex and eco-friendly biomass raffinose monomer-modified polycarboxylate superplasticizer (RAF-PCE) was designed and synthesized via the free radical polymerization technique to simultaneously improve paste fluidity and delay fluidity loss in concrete applications. The adsorption, fluidity, and early hydration behaviors of cementitious systems after the introduction of RAF-PCE have been systematically investigated. Experimental results demonstrate that the hydroxy group in raffinose promotes the adsorption of RAF-PCE on the cement particles, thereby elevating the dispersion characteristic of cement paste through electrostatic repulsion, enabling excellent initial fluidity (310 mm). Additionally, its steric hindrance effect has also been identified to play a role in improving paste fluidity and reducing the slump loss of cement slurry. Detailed analyses unveil that RAF-PCE can reduce the concentration of free Ca²⁺ in the pore solution through complexation with Ca²⁺, which prevents the early precipitation of hydration products and realizes a delayed effect on cement hydration, ultimately evolving into a homogeneous and compact microstructure for superior compressive tensile strength of the cement mortar. The 28-day compressive strength of cement incorporating RAF-PCE reached 79.2 MPa, representing a 5.5% enhancement over conventional PCE systems. Our work provides novel insights into the promotion of innovative and green development in the concrete industry by utilizing renewable biomass resources for high-performance materials. Full article

This study systematically explored the influence of Polycarboxylate Ether (PCE) content on the fluidity, setting time, and compressive and flexural strength of Ultra-fine Portland Cement (SPC) cement-based grout through the external admixture method. The microstructure and evolution of hydration products were analyzed using XRD and SEM to reveal the modification mechanism. The results showed that the optimal PCE content was 0.25% (calculated based on the mass of SPC), at which the fluidity of the grout reached 273 mm, and the initial and final setting times were extended from 130 min and 235 min to 268 min and 310 min, respectively, reflecting significant plasticizing and retarding effects. The mechanical properties were particularly improved, with the compressive strength of the hardened paste at 7 d and 28 d increasing by 28.78% and 37.09%, respectively, and the flexural strength increasing by 11.20% and 14.52%, respectively. Microscopic analysis indicated that PCE optimized particle packing through adsorption–dispersion effects and moderately delayed the early hydration process, promoting the more thorough and uniform growth of hydration products (such as C-S-H gel), thereby generating a denser microstructure. This is the fundamental reason for the improvement in macroscopic properties. This study provides important theoretical and experimental basis for the performance optimization and engineering application of SPC-based grouting materials under low water–cement ratios. Full article

Three-dimensional concrete printing (3DCP) requires mixtures that develop sufficient early buildability while preserving open time for reliable interlayer bonding. This study investigates the time-dependent evolution of static yield stress for printable concretes incorporating three supplementary cementitious materials—metakaolin (MK), silica fume (SF), and biochar (BC)—used with either a polycarboxylate ether- (PCE) or naphthalene-based superplasticizer. Static yield stress was measured at 15, 30, and 45 min of concrete age using the stress-growth method with a shear vane apparatus. Performance targets were τ_s (15 min) ≤ 2.8 kPa, reflecting extrudability/pumpability; τ_s (30 min) ≤ 3.1 kPa, representing printability/open time; and τ_s (45 min) ≥ 3.4 kPa, representing buildability. Pooled Type-II ANOVA showed a highly significant SP effect (p < 0.001), a significant SCM × SP interaction (p = 0.031), and a significant time effect (p = 0.005), whereas SCM (p = 0.709) and SCM% (p = 0.914) were non-significant once interaction and time were included. Across SCMs, SNF–PCE gaps are ~0.2–0.8 kPa at 30 min (+7–30%) and ~0.4–1.3 kPa at 45 min (+12–45%), with the largest gaps in SF, intermediate in MK, and smallest in BC. Full article

The growing demand for sustainable construction materials has intensified efforts to reduce the environmental impact of Portland cement. This study investigates the effect of partial substitution of cement with metakaolin (MK, 5–15 wt.%) and biosilica (BS, 5 wt.%) on the physical, mechanical, and microstructural properties of cementitious mortars. The influence of a polycarboxylate ether-based superplasticizer (Mf) and ultrasonic treatment (ULT) was also evaluated. The mortars were characterized through setting time, density, water absorption, flexural and compressive strength tests, as well as FTIR and SEM analyses. Water absorption decreased from 12.21% to 9.8%, indicating improved pore refinement and densification. Flexural strength of all modified mortars exceeded that of the control mix: from 10.0% to 89.9% at 7 days, and from 4.7% to 50.4% at 28 days. The compressive strength improved markedly with MK and BS incorporation, from 20.8% to 51.3% at 7 days and from 9.7% to 35.2% at 28 days compared to the control sample. FTIR and SEM results confirmed enhanced pozzolanic activity and formation of C–S–H gel. The synergistic use of MK, BS, and Mf—especially with ultrasonic dispersion—yielded denser, stronger, and more sustainable cementitious composites. Full article

Cement-based materials are essential construction components, yet their complex microstructures critically govern mechanical performance and durability. This study investigates the micro-textural characteristics and mechanical properties of cement paste modified with grinding aids (triethanolamine, TEA; maleic acid triethanolamine ester, MGA) and polycarboxylate-based superplasticizer (PCA). Moving beyond qualitative SEM limitations, we employ advanced image-based quantitative techniques: grayscale-based texture analysis for statistical evaluation and fractal dimension analysis for geometric quantification of microstructural irregularity. Results demonstrate that grinding aids enhance particle dispersion and reduce agglomeration, resulting in a more uniform micro-texture characterized by lower grayscale variability and reduced fractal dimensions. PCA superplasticizers further significantly enhance fluidity and compressive strength. The optimal formulation (MGA + PCA) achieved a 20% increase in 28-day compressive strength compared to control samples. The fractal dimension D_B exhibits a positive correlation with compressive strength, while energy and correlation values show a negative correlation; in contrast, entropy and contrast values demonstrate a positive correlation. This research advances quantitative microstructure characterization in cementitious materials, offering insights for tailored additive formulations to enhance sustainability and efficiency in concrete production. Full article

Practical use of calcium sulfoaluminate cements (CSAs) is dependent on their compatibility with admixtures. The following paper presents research into the effects of three different superplasticizers (SPs) (polycarboxylate ethers, modified polycarboxylates, and polynaphthalene sulfonate), and the effect of a w/c ratio in a range of 0.45–0.35 in mortars containing superplasticizer on the chosen mortar properties. The conducted tests related to consistency, initial setting time, hydration heat, flexural and compressive strength, early shrinkage (first 20 h), and drying shrinkage. The results indicate that the superplasticizer type has significant effect on the properties of CSA mortars. All superplasticizers prolonged the initial setting and induction phase of hydration in relation to CSA mortar which did not contain superplasticizer by up to 109%; however, their effect on compressive and flexural strength, drying shrinkage, and early shrinkage was dependent on the type of superplasticizer involved. Polycarboxylate ether SP provided the best results for mortar properties, as it did not affect compressive strength significantly, but reduced plastic shrinkage. Polynapthalene-based SP decreased strength and increased shrinkage more than other superplasticizers, making it the least compatible. Decreasing the w/c ratio for mortar containing superplasticizer allowed us to mitigate some of the issues, as mortars with SP1 in a low w/c ratio exhibited higher compressive and flexural strength by, respectively, 41% and 80% in the case of a w/c ratio of 0.35, and lower shrinkage. Full article

Recycled coarse aggregates (RCA) offer an alternative to natural coarse aggregates in concrete production, reducing natural aggregate extraction and landfill burdens and potentially lowering embodied energy and CO₂ emissions. This study leverages machine learning algorithms to predict the dynamic yield stress (DYS) and plastic viscosity (PV) of RCA concrete (RCAC). A database of 380 RCAC mixtures, incorporating 11 input features, was analyzed using six machine learning models: Artificial Neural Network (ANN), Decision Tree (DT), Random Forest (RF), Extreme Gradient Boosting (XGBoost), Light Gradient Boosting Machine (LightGBM), and Support Vector Machine (SVM). The model performance was compared, followed by sensitivity analyses to identify critical factors influencing DYS and PV. For DYS, the DT model demonstrated the highest predictive performance (testing R²/RMSE/MAE = 0.95/18.25/13.99; others: 0.90–0.93/12.14–26.10/15.40–19.50) due to its robustness on smaller datasets. The XGBoost model led for PV (testing R²/RMSE/MAE = 0.93/7.06/4.58; others: 0.82–0.89/8.69–11.20/6.06–7.51) owing to its sequential residual minimization that captures nonlinear interactions. Sensitivity analyses revealed that polycarboxylate superplasticizer content and water-to-binder ratio significantly influence DYS, while cement content and saturated-surface-dried water absorption of RCA (i.e., measured with open pores filled and the aggregate surface dry) dominate PV. The time-dependent role in affecting PV was also highlighted. By optimizing and comparing different machine learning algorithms, this study advances predictive methodologies for the rheological properties of RCAC, addressing the underexplored use of machine learning for RCAC rheology (DYS and PV) and the limitations of traditional empirical rheology methods, thereby promoting the efficient use of recycled materials in sustainable concrete design. Full article

Water-reducing admixtures are of enormous importance to adjust the workability of alkali-activated materials. Especially in geopolymers activated by highly concentrated alkaline solutions, the polycarboxylate ether (PCE) superplasticizers are less effective than in conventional cementitious systems. The aim of this study was to clarify the reasons for the lower dispersing performance of PCE and the synthesis of alternative dispersing agents based on the biopolymer starch to improve the workability of highly alkaline geopolymers. Furthermore, the focus of investigations was on the role of activator type and concentration as key parameters for geopolymer reaction and interaction of water-reducing agents. Therefore, in this study the conformation of three different types of PCE (MPEG: methacrylate ester, IPEG: isoprenol ether, and HPEG: methallyl ether) and synthesized starch admixtures in sodium and potassium hydroxide solutions (1 mol/L up to 8 mol/L) were studied. Furthermore, the dispersing performance, adsorption behavior, and influence on reaction kinetics in metakaolin-based geopolymer pastes were investigated in dependence on activator type and concentration. While the PCE superplasticizers show coiling and formation of insoluble aggregates at activator concentrations of 3 mol/L and 4 mol/L, the synthesized starch admixtures show no significant change in conformation. The cationic starch admixtures showed a higher dispersing performance in geopolymer pastes at all activator concentrations and types. The obtained adsorption isotherms depend strongly on the activator type and the charge density of the starch admixtures. The reaction kinetics of geopolymer pastes were not significantly influenced using the synthesized starch admixtures. Especially the cationic starch admixtures allow the reduction of liquid/solid ratios, which leads to higher flexural and compressive strengths. Full article

Rheological properties are essential to ultra-high performance concrete (UHPC), and it is necessary to guarantee a relatively lower viscosity to avoid fiber segregation and mechanical degradation. In this study, an innovative physical-chemical integrated approach, namely the simultaneous use of fly ash microbeads and a modified low-viscosity polycarboxylic acid superplasticizer (JN-PCE), was proposed to regulate the rheological performance of UHPC containing industrial by-products. The effect of varying microbead dosage, different superplasticizers, and their combined influence on the rheological parameters, mechanical characteristics, and microstructure evolution were systematically explored in this study. The results demonstrated that the addition of 1.5% JN-PCE led to significant improvements in the UHPC properties including a flow expansion of 775 mm, a static yield stress of 376.9 Pa, a dynamic yield stress of 188.01 Pa, a plastic viscosity of 160.87 Pa·s, and a 28-day compressive strength of 136.6 MPa. Moreover, when a combination of 10% microbeads and 1.5% JN-PCE was used, the UHPC exhibited a flow expansion of 730 mm, a static yield stress of 693.5 Pa, a dynamic yield stress of 542.90 Pa, a plastic viscosity of 202.40 Pa·s, and a 28-day compressive strength of 142.1 MPa. This study thus offers valuable insights into optimizing low-viscosity UHPC formulations using eco-friendly additives for construction applications. Full article

The environmental impact of cement production is strongly associated with the high clinker content and its corresponding CO₂ emissions. This study examines the performance of low-emission cement mortars incorporating supplementary cementitious materials (SCMs), such as ground granulated blast-furnace slag (GGBFS) and fly ash, which partially replace clinker and contribute to CO₂ reduction. Six cement types (CEM I, CEM II/B-V, CEM II/B-S, CEM III/A, CEM V/A (S-V), and CEM V/B (S-V)) were assessed in 104 mortar formulations using a polycarboxylate-based superplasticizer, under varied curing temperatures (10 °C, 20 °C, 29 °C, and 33 °C). The present study is an experimental analysis of the impact of different plasticising and superplasticising admixtures on the demand for admixtures to achieve high flowability and low air content in cement-standardised mortar for admixture testing. PN-EN 480-1. The results indicate that mortars containing CEM III/A and CEM V/B (S-V) exhibited compressive strengths comparable to or superior to CEM I at 28 days, with strength gains exceeding 60 MPa at 20 °C. Workability retention at elevated temperatures was most effective in slag-rich cements. The plasticizing efficiency of the admixture decreased at temperatures above 29 °C, especially in fly ash-rich systems. The incorporation of SCMs resulted in an estimated reduction of up to 60% in clinker, with a corresponding potential decrease in CO₂ emissions of 35–45%. These findings demonstrate the technical feasibility of using low-clinker, superplasticized mortars in varying thermal environments, supporting the advancement of sustainable cementitious systems. Full article

This study employed response surface methodology (RSM) to optimize admixture proportions in 3D-printed cementitious materials, with the aim of enhancing printability. Based on preliminary tests, three additives, namely, an accelerator, hydroxypropyl methylcellulose (HPMC), and polycarboxylate superplasticizer (PCE), were incorporated to evaluate their effects on flowability and dynamic yield stress. A Box–Behnken central composite design was used to establish a mathematical model, followed by the RSM-driven optimization of mix proportions. The optimized formulation (0.32% accelerator, 0.24% HPMC, and 0.23% PCE) achieved a flowability of 147.5 mm and a dynamic yield stress of 711 Pa, which closely matched the predicted values and fulfilled the printability requirements, thus establishing RSM as an effective approach for designing printable cementitious composites. This approach established an RSM-based optimization framework for mix proportion design. These findings offer a mechanistic framework for rational 3DPC mixture design, combining theoretical insights and practical implementation in additive construction. Full article