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13 pages, 2012 KB  
Article
Sub-Diffraction Photoacoustic Microscopy Enabled by a Novel Phase-Shifted Excitation Strategy: A Numerical Study
by George J. Tserevelakis
Sensors 2026, 26(2), 498; https://doi.org/10.3390/s26020498 - 12 Jan 2026
Viewed by 192
Abstract
This numerical simulation study introduces a novel phase-shifted Gaussian and donut beam excitation strategy for frequency-domain photoacoustic microscopy, capable of achieving optical sub-diffraction-limited lateral resolution. We demonstrate that the spatial overlapping of Gaussian and donut beams with π-radian phase-shifted intensity modulation may confine [...] Read more.
This numerical simulation study introduces a novel phase-shifted Gaussian and donut beam excitation strategy for frequency-domain photoacoustic microscopy, capable of achieving optical sub-diffraction-limited lateral resolution. We demonstrate that the spatial overlapping of Gaussian and donut beams with π-radian phase-shifted intensity modulation may confine the effective photoacoustic excitation region, substantially reducing the beam-waist-normalized full width at half maximum value from 1.177 to 0.828 units. This effect corresponds to a ~1.42-fold lateral resolution enhancement compared with conventional focused Gaussian beam excitation. Furthermore, the influence of the optical power ratio between the beams was systematically analyzed, revealing an optimal value of 1.16, balancing excitation confinement and side-lobe suppression. Within this framework, the presented simulation results establish a basis for the experimental realization of phase-shifted dual-beam excitation photoacoustic microscopy systems, with a potential impact on high-resolution biomedical imaging of subcellular and microvascular structures using low-cost continuous-wave optical sources such as laser diodes. Full article
(This article belongs to the Special Issue Recent Trends and Advances in Biomedical Optics and Imaging)
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34 pages, 4003 KB  
Review
Rydberg Atom-Based Sensors: Principles, Recent Advances, and Applications
by Dinelka Somaweera, Amer Abdulghani, Ambali Alade Odebowale, Andergachew Mekonnen Berhe, Muthugalage I. U. Weerasinghe, Khalil As’ham, Ibrahim A. M. Al Ani, Morphy C. Dumlao, Andrey E. Miroshnichenko and Haroldo T. Hattori
Photonics 2025, 12(12), 1228; https://doi.org/10.3390/photonics12121228 - 12 Dec 2025
Viewed by 1637
Abstract
Rydberg atoms are neutral atoms excited to high principal quantum number states, which endows them with exaggerated properties such as large electric dipole moments, long lifetimes, and extreme sensitivity to external electromagnetic fields. These characteristics form the foundation of Rydberg atom-based sensors, an [...] Read more.
Rydberg atoms are neutral atoms excited to high principal quantum number states, which endows them with exaggerated properties such as large electric dipole moments, long lifetimes, and extreme sensitivity to external electromagnetic fields. These characteristics form the foundation of Rydberg atom-based sensors, an emerging class of quantum devices capable of optically detecting electric fields across frequencies from DC to the terahertz regime. Rydberg-based electrometry operates through both Autler–Townes (AT) splitting of resonant Rydberg transitions and Stark-shift measurements for high-frequency or far-detuned fields, enabling broadband field sensing from DC to the THz regime. Using ladder-type electromagnetically induced transparency (EIT) and AT splitting, these sensors enable non-invasive, SI-traceable measurements of field amplitude, frequency, phase, and polarization. Recent developments have demonstrated broadband electric field probes, voltage calibration standards, and compact RF receivers based on thermal vapor cells and integrated photonic architectures. Furthermore, innovations in multi-photon EIT, superheterodyne readout, and multi wave mixing have expanded the dynamic range and bandwidth of Rydberg-based electrometry. Despite challenges related to environmental perturbations, linewidth broadening, and laser stabilization, ongoing advances in atomic control, hybrid photonic integration, and EIT-based readout promise scalable, chip-compatible sensors. This review summarizes the physical principles, experimental progress, and emerging applications of Rydberg atom-based sensing, emphasizing their potential for next generation quantum metrology, wireless communication, and precision field mapping. Full article
(This article belongs to the Section Lasers, Light Sources and Sensors)
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20 pages, 1873 KB  
Article
Nonlinear Subharmonic Resonance Instability of an Arch-Type Structure Under a Vertical Base-Excitation
by Zilin Zhong, Xiaobin Xu, Fulin Shen, Zhiyong Yao and Weiguo Xiao
Buildings 2025, 15(23), 4356; https://doi.org/10.3390/buildings15234356 - 1 Dec 2025
Viewed by 1306
Abstract
This study develops an analytical framework for investigating in-plane nonlinear subharmonic resonance in fixed–fixed circular arches under a vertical base-excitation, a phenomenon not adequately addressed in previous research. Based on Hamilton’s principle, the governing partial differential equation for in-plane nonlinear motion is first [...] Read more.
This study develops an analytical framework for investigating in-plane nonlinear subharmonic resonance in fixed–fixed circular arches under a vertical base-excitation, a phenomenon not adequately addressed in previous research. Based on Hamilton’s principle, the governing partial differential equation for in-plane nonlinear motion is first derived. The tangential displacement is then expressed as a modal superposition, and the system is reduced to a set of second-order ordinary differential equations via the Galerkin method. Using the method of multiple scales, the nonlinear 1/2-subharmonic resonance is solved, yielding closed-form, steady-state amplitude–phase relations and corresponding stability conditions. Validation against finite element simulations and Runge–Kutta analyses confirms the accuracy of the proposed approach. Dimensionless fundamental frequencies match finite element results exactly, with discrepancies in critical base-excitation below 2.5%. A close agreement is observed in both the amplitude–frequency and force–response curves with numerical predictions and Bolotin’s method, accurately capturing the characteristic hardening nonlinearity and three distinct dynamic regions spanning negligible vibration, stable resonance, and instability. Parametric studies further reveal key trends. Larger included angles intensify the vibration amplitude and promote saddle-node bifurcation, while narrowing stable operating regions. Higher slenderness ratios enhance structural flexibility and nonlinearity, shifting resonant peaks toward higher frequencies. Increased damping suppresses the response amplitude and raises the thresholds for vibration initiation and bifurcation. Full article
(This article belongs to the Section Building Structures)
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26 pages, 1137 KB  
Article
“One Face, Many Roles”: The Role of Cognitive Load and Authenticity in Driving Short-Form Video Ads
by Yadi Feng, Bin Li, Yixuan Niu and Baolong Ma
J. Theor. Appl. Electron. Commer. Res. 2025, 20(4), 272; https://doi.org/10.3390/jtaer20040272 - 3 Oct 2025
Viewed by 2960
Abstract
Short-form video platforms have shifted advertising from standalone, time-bounded spots to feed-embedded, swipeable stimuli, creating a high-velocity processing context that can penalize casting complexity. We ask whether a “one face, many roles” casting strategy (a single actor playing multiple characters) outperforms multi-actor executions, [...] Read more.
Short-form video platforms have shifted advertising from standalone, time-bounded spots to feed-embedded, swipeable stimuli, creating a high-velocity processing context that can penalize casting complexity. We ask whether a “one face, many roles” casting strategy (a single actor playing multiple characters) outperforms multi-actor executions, and why. A two-phase pretest (N = 3500) calibrated a realistic ceiling for “multi-actor” casts, then four experiments (total N = 4513) tested mechanisms, boundary conditions, and alternatives. Study 1 (online and offline replications) shows that single-actor ads lower cognitive load and boost account evaluations and purchase intention. Study 2, a field experiment, demonstrates that Need for Closure amplifies these gains via reduced cognitive load. Study 3 documents brand-type congruence: one actor performs better for entertaining/exciting brands, whereas multi-actor suits professional/competence-oriented brands. Study 4 rules out cost-frugality and sympathy using a budget cue and a sequential alternative path (perceived cost constraint → sympathy). Across studies, a chain mediation holds: single-actor casting reduces cognitive load, which elevates brand authenticity and increases purchase intention; a simple mediation links cognitive load to account evaluations. Effects are robust across settings and participant gender. We theorize short-form advertising as a context-embedded persuasion episode that connects information-processing efficiency to authenticity inferences, and we derive practical guidance for talent selection and script design in short-form campaigns. Full article
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31 pages, 9665 KB  
Article
Motor Airgap Torque Harmonics Due to Cascaded H-Bridge Inverter Operating with Failed Cells
by Hamid Hamza, Ideal Oscar Libouga, Pascal M. Lingom, Joseph Song-Manguelle and Mamadou Lamine Doumbia
Energies 2025, 18(16), 4286; https://doi.org/10.3390/en18164286 - 12 Aug 2025
Viewed by 736
Abstract
This paper proposes the expressions for the motor airgap torque harmonics induced by a cascaded H-bridge inverter operating with failed cells. These variable frequency drive systems (VFDs), are widely used in oil and gas applications, where a torsional vibration evaluation is a critical [...] Read more.
This paper proposes the expressions for the motor airgap torque harmonics induced by a cascaded H-bridge inverter operating with failed cells. These variable frequency drive systems (VFDs), are widely used in oil and gas applications, where a torsional vibration evaluation is a critical challenge for field engineers. This paper proposes mathematical expressions that are crucial for an accurate torsional analysis during the design stage of VFDs, as required by international standards such as API 617, API 672, etc. By accurately reconstructing the electromagnetic torque from the stator voltages and currents in the (αβ0) reference frame, the obtained expressions enable the precise prediction of the exact locations of torque harmonics induced by the inverter under various real-world operating conditions, without the need for installed torque sensors. The neutral-shifted and peak-reduction fault-tolerant control techniques are commonly adopted under faulty operation of these VFDs. However, their effects on the pulsating torques harmonics in machine air-gap remain uncovered. This paper fulfils this gap by conducting a detailed evaluation of spectral characteristics of these fault-tolerant methods. The theoretical analyses are supported by MATLAB/Simulink 2024 based offline simulation and Typhoon based virtual real-time simulation results performed on a (4.16 kV and 7 MW) vector-controlled induction motor fed by a 7-level cascaded H-bridge inverter. According to the theoretical analyses- and simulation results, the Neutral-shifted and Peak-reduction approaches rebalance the motor input line-to-line voltages in the event of an inverter’s failed cells but, in contrast to the normal mode the carrier, all the triplen harmonics are no longer suppressed in the differential voltage and current spectra due to inequal magnitudes in the phase voltages. These additional current harmonics induce extra airgap torque components that can excite the lowly damped eigenmodes of the mechanical shaft found in the oil and gas applications and shut down the power conversion system due torsional vibrations. Full article
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20 pages, 3689 KB  
Article
Active Colitis-Induced Atrial Electrophysiological Remodeling
by Hiroki Kittaka, Edward J. Ouille V, Carlos H. Pereira, Andrès F. Pélaez, Ali Keshavarzian and Kathrin Banach
Biomolecules 2025, 15(7), 982; https://doi.org/10.3390/biom15070982 - 10 Jul 2025
Viewed by 1000
Abstract
Patients with ulcerative colitis exhibit an increased risk for supraventricular arrhythmia during the active disease phase of the disease and show signs of atrial electrophysiological remodeling in remission. The goal of this study was to determine the basis for colitis-induced changes in atrial [...] Read more.
Patients with ulcerative colitis exhibit an increased risk for supraventricular arrhythmia during the active disease phase of the disease and show signs of atrial electrophysiological remodeling in remission. The goal of this study was to determine the basis for colitis-induced changes in atrial excitability. In a mouse model (C57BL/6; 3 months) of dextran sulfate sodium (DSS)-induced active colitis (3.5% weight/volume, 7 days), electrocardiograms (ECG) revealed altered atrial electrophysiological properties with a prolonged P-wave duration and PR interval. ECG changes coincided with a decreased atrial conduction velocity in Langendorff perfused hearts. Action potentials (AP) recorded from isolated atrial myocytes displayed an attenuated maximal upstroke velocity and amplitude during active colitis, as well as a prolonged AP duration (APD). Voltage clamp analysis revealed a colitis-induced shift in the voltage-dependent activation of the Na-current (INa) to more depolarizing voltages. In addition, protein levels of Nav1.5 protein and connexin isoform Cx43 were reduced. APD prolongation depended on a reduction in the transient outward K-current (Ito) mostly generated by Kv4.2 channels. The changes in ECG, atrial conductance, and APD were reversible upon remission. The change in conduction velocity predominantly depended on the reversibility of the reduced Cx43 and Nav1.5 expression. Treatment of mice with inhibitors of Angiotensin-converting enzyme (ACE) or Angiotensin II (AngII) receptor type 1 (AT1R) prevented the colitis-induced atrial electrophysiological remodeling. Our data support a colitis-induced increase in AngII signaling that promotes atrial electrophysiological remodeling and puts colitis patients at an increased risk for atrial arrhythmia. Full article
(This article belongs to the Special Issue Molecular Advances in Inflammatory Bowel Disease)
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16 pages, 5587 KB  
Article
Rotational vs. Vibrational Excitations in a Chemical Laser
by José Daniel Sierra Murillo
Physchem 2025, 5(3), 26; https://doi.org/10.3390/physchem5030026 - 4 Jul 2025
Viewed by 866
Abstract
The research reviews and contrasts two studies based on the gas-phase reaction OH + D2(v, j). In these studies, Quasi-Classical Trajectory (QCT) calculations and the Gaussian Binning (GB) technique were used on the Wu–Schatz–Lendvay–Fang–Harding (WSLFH) potential energy surface. Large sample sizes [...] Read more.
The research reviews and contrasts two studies based on the gas-phase reaction OH + D2(v, j). In these studies, Quasi-Classical Trajectory (QCT) calculations and the Gaussian Binning (GB) technique were used on the Wu–Schatz–Lendvay–Fang–Harding (WSLFH) potential energy surface. Large sample sizes allow for precise energy state distribution analysis across translational, vibrational, and rotational components in the products. A key observation is the influence of the vibrational and rotational excitation of D2 on the total angular momentum (J′) of the HOD* product. This study reveals that increasing the vibrational level, vD2, significantly shifts P(J′) distributions toward higher values, broadening them due to increased isotropy. In contrast, increasing the rotational level, jD2, results in a smaller shift but introduces greater anisotropy, leading to a more selective distribution of J′ values. The dual Gaussian Binning selection—Vibrational-GB followed by Rotational-GB—further highlights a preference for either odd or even J′ values, depending on the specific excitation conditions. These findings have implications for the development of chemical lasers, as the excitation and emission properties of HOD* can be leveraged in the laser design. Future research aims to extend this study to a broader range of initial conditions, refining the understanding of reaction dynamics in controlled gas-phase environments. Full article
(This article belongs to the Section Application of Lasers to Physical Chemistry)
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16 pages, 34384 KB  
Article
A Low-Profile Dual-Polarized High-Gain Low Cross-Polarization Phased Array for Ku-Band Satellite Communications
by Yuhan Huang, Jie Zhang, Xiuping Li, Zihang Qi, Fan Lu, Hua Jiang, Xin Xue, Hua Zhu and Xiaobin Guo
Sensors 2025, 25(13), 3986; https://doi.org/10.3390/s25133986 - 26 Jun 2025
Viewed by 1400
Abstract
A low-profile dual-polarized shared-aperture phased array antenna is proposed for Ku-band satellite communications in this paper. The stacked octagonal patches loaded with Via-rings are proposed as dual-polarized shared-aperture radiation elements, with the characteristics of wide impedance bandwidth, high gain, and weak coupling. Furthermore, [...] Read more.
A low-profile dual-polarized shared-aperture phased array antenna is proposed for Ku-band satellite communications in this paper. The stacked octagonal patches loaded with Via-rings are proposed as dual-polarized shared-aperture radiation elements, with the characteristics of wide impedance bandwidth, high gain, and weak coupling. Furthermore, innovative minimized three-port ring couplers are utilized for the differential-fed antenna array, further suppressing the cross-polarization component. Substrate integrated coaxial line (SICL) and microstrip line (MS) feed networks are employed for the excitation of transmitting band (Tx) horizontal polarization and receiving band (Rx) vertical polarization, respectively. The non-uniform subarray architecture is optimized to minimize the sidelobe levels with the reduced number of transmitter and receiver (T/R) radio frequency phase-shifting modules. As proof-of-concept examples, 16 × 24 and 32 × 24 array antennas are demonstrated and fabricated. The measured impedance bandwidths of the proposed phased array antennas are around 21.1%, while the in-band isolations are above 36.7 dB. Gains up to 29 dBi and 32.4 dBi are performed by two prototypes separately. In addition, the T/R phase-shifting modules are utilized to validate the beam-scanning characteristic, which is of value for dynamic satellite communications. Full article
(This article belongs to the Special Issue Design and Measurement of Millimeter-Wave Antennas)
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19 pages, 3801 KB  
Article
Effect of BaO Content on the Photoluminescence Properties of Mn2+ and Eu2+-Codoped Sr3−xBaxMgSi2O8 Phosphors
by Shu-Han Liao, Fang-Tzu Hsu, Cheng-Fu Yang and Kao-Wei Min
Inorganics 2025, 13(6), 187; https://doi.org/10.3390/inorganics13060187 - 6 Jun 2025
Cited by 1 | Viewed by 886
Abstract
In this study, Mn2+ and Eu2+-codoped Sr3−xBaxMgSi2O8 (x = 0–1.5) phosphors were synthesized at 1400 °C under a reducing atmosphere composed of 5% H2 and 95% N2 to produce [...] Read more.
In this study, Mn2+ and Eu2+-codoped Sr3−xBaxMgSi2O8 (x = 0–1.5) phosphors were synthesized at 1400 °C under a reducing atmosphere composed of 5% H2 and 95% N2 to produce materials with blue light emission. The resulting powders were characterized using several analytical techniques: X-ray diffraction (XRD) was employed to identify the crystalline phases, scanning electron microscopy (SEM) was used to observe the microstructure, and photoluminescence excitation (PLE) and emission (PL) spectra were measured using a fluorescence spectrophotometer. The results revealed several key findings. XRD analysis showed that the Sr3MgSi2O8 (Sr3−xBaxMgSi2O8) phase coexisted with secondary phases of Sr2SiO4 and Sr2MgSi2O7. SEM observations indicated that the synthesized powders exhibited a distinctive needle-like structure anchored on the surfaces of the particles. The PL and PLE intensities increased sharply as the BaO content increased from x = 0 to x = 0.6, followed by a more gradual increase, reaching a peak at x = 1.2. Additionally, as the value of x increased, the wavelengths corresponding to maximum PL and PLE intensities exhibited a blue shift, moving to shorter wavelengths. Further investigation focused on the excitation behavior by replotting the PLE spectra using energy (eV) as the x-axis. A Gaussian fitting function was applied to deconvolute the excitation bands, enabling an in-depth analysis of how compositional variations influenced the Stokes shift. Full article
(This article belongs to the Section Inorganic Solid-State Chemistry)
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15 pages, 6231 KB  
Article
Alternative Sensing for State-of-Charge Estimation of Latent Heat Thermal Energy Storage
by James Wilson, Robert J. Barthorpe and Furkan Terzioglu
Energies 2025, 18(11), 2853; https://doi.org/10.3390/en18112853 - 29 May 2025
Cited by 1 | Viewed by 930
Abstract
Thermal energy storage (TES) is likely to play a significant role in the decarbonisation of domestic heat, allowing consumers to shift their energy consumption away from peak demand periods and reducing overall strain on the grid. Phase change materials (PCMs) are a promising [...] Read more.
Thermal energy storage (TES) is likely to play a significant role in the decarbonisation of domestic heat, allowing consumers to shift their energy consumption away from peak demand periods and reducing overall strain on the grid. Phase change materials (PCMs) are a promising option for TES, in which energy can be stored in the latent heat of the melting of the PCM; these offer greater storage densities than sensible heat TES and have the benefit of releasing stored heat at a consistent temperature (the crystallisation temperature of the PCM). One of the key difficulties for PCM-based TES is state of charge (SoC) estimation (the estimation of the proportion of energy stored in the TES unit up to its maximum capacity), particularly during idle periods while the unit is storing heat. SoC estimation is key to the implementation of TES, as it enables the effective control of the units. The use of a resonator within the PCM for SoC estimation could potentially provide a global estimate of the SoC, since the resonator passes through the full depth of the PCM in the unit. The SoC could be inferred by measuring the vibrational response of the resonator under excitation, which varies depending on the melt state of the PCM. This paper presents findings from a test rig investigating this proposal, including discussions on the features required from the resonator response for SoC inference. Full article
(This article belongs to the Special Issue Advanced Energy Storage Technologies)
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12 pages, 9743 KB  
Article
Similarities in the Low-Energy Elastic and Ps Formation Differential Cross-Sections for e+-H and e+-He Scattering
by Peter Van Reeth and John W. Humberston
Atoms 2025, 13(6), 46; https://doi.org/10.3390/atoms13060046 - 28 May 2025
Viewed by 1010
Abstract
Scattering differential cross-sections (DCSs) are important tools, both experimentally and theoretically, in the investigation of scattering processes in lepton–atom collisions. In the present work, the elastic scattering differential cross-sections (EDCSs) for e+-H and e+-He below the first excitation threshold [...] Read more.
Scattering differential cross-sections (DCSs) are important tools, both experimentally and theoretically, in the investigation of scattering processes in lepton–atom collisions. In the present work, the elastic scattering differential cross-sections (EDCSs) for e+-H and e+-He below the first excitation threshold of the target were evaluated using the Kohn variational method and found to be very similar. In both cases, the EDCS below the positronium formation threshold, i.e., for pure elastic scattering, had minimum valley features in which significant minima close to 90 degrees were found at ≈2.8 eV for H and ≈2 eV for He. These minima were shown to be linked to the zero in the s-wave phase shift, which gives rise to the Ramsauer minimum in the elastic integrated cross-sections. They were not vortices, but the overall EDCS structure was found to be related to the structures and vortices found in the Ps formation differential cross-sections just above the Ps formation threshold. The valley-type structure in the EDCS went smoothly through the Ps formation threshold, where it linked up with a similar valley structure in both the EDCS above the threshold and the Ps formation DCS. A comparison with the EDCS for e-H and e-He scattering over the same energy range revealed similarities with the positron EDCS, however, with less pronounced structures that had different angular and momentum dependences. Full article
(This article belongs to the Section Atomic, Molecular and Nuclear Spectroscopy and Collisions)
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16 pages, 4820 KB  
Article
Triple-Band Warm White-Light Emission from Type II Band-Aligned Aggregation-Induced Enhanced Emission Organic Cation-Incorporated Two-Dimensional Lead Iodide Perovskite
by Almaz R. Beisenbayev, Igor Ivanov-Prianichnikov, Anatoly Peshkov, Tangsulu Adil, Davit Hayrapetyan and Chang-Keun Lim
Int. J. Mol. Sci. 2025, 26(11), 5054; https://doi.org/10.3390/ijms26115054 - 24 May 2025
Viewed by 923
Abstract
Single-phase white-light-emitting materials, particularly 2D hybrid organic–inorganic halide perovskites, have garnered significant attention due to their strong electron–phonon interactions, which lead to broad luminescence and a notable Stokes shift resulting from self-trapped exciton recombination. However, 2D lead iodide perovskites typically display these characteristics [...] Read more.
Single-phase white-light-emitting materials, particularly 2D hybrid organic–inorganic halide perovskites, have garnered significant attention due to their strong electron–phonon interactions, which lead to broad luminescence and a notable Stokes shift resulting from self-trapped exciton recombination. However, 2D lead iodide perovskites typically display these characteristics poorly, restricting their efficiency as white-light emitters. This study presents a 2D lead iodide perovskite that incorporates a fluorinated π-conjugated aggregation-induced enhanced emission luminophore, FPCSA, as a bulky organic cation to create a quasi-2D perovskite. The FPCSA cation establishes a Type II energy level alignment with the lead iodide layer in the 2D perovskite, and a significant energy offset effectively suppresses charge transfer, enabling independent emission from both the organic and inorganic layers while facilitating self-trapped exciton formation. Under 315 nm UV excitation, this material demonstrates warm white-light emission with RGB triple-band photoluminescence stemming from the electronically decoupled FPCSA and perovskite layers. These findings provide a promising new method for designing efficient single-phase white-light-emitting materials for optoelectronic applications. Full article
(This article belongs to the Section Physical Chemistry and Chemical Physics)
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13 pages, 7718 KB  
Article
Recoverable and Sensitive Pressure-Induced Mechanochromic Photoluminescence of a Au-P Complex
by Ningwen Yang, Yijia Chang, Jiangyue Wang, David James Young, Hong-Xi Li, Yuxin Lu and Zhi-Gang Ren
Molecules 2025, 30(9), 2011; https://doi.org/10.3390/molecules30092011 - 30 Apr 2025
Viewed by 956
Abstract
A binuclear Au-P complex [Au2(2-bdppmapy)2](PF6)2 (1) was synthesised by the reaction of 2-bdppmapy (N,N′-bis-(diphenylphosphanylmethyl-2-aminopyridine) with AuCN and [Cu(MeCN)4]PF6. The solid phase of 1 emitted bright yellow phosphorescence at λmax [...] Read more.
A binuclear Au-P complex [Au2(2-bdppmapy)2](PF6)2 (1) was synthesised by the reaction of 2-bdppmapy (N,N′-bis-(diphenylphosphanylmethyl-2-aminopyridine) with AuCN and [Cu(MeCN)4]PF6. The solid phase of 1 emitted bright yellow phosphorescence at λmax = 580 nm under UV excitation (QY = 4.41%, τ = 1.88 μs), which shifted to green (λmax = 551 nm, QY = 5.73%) after being pressurised under 5 MPa. This colour change was recoverable upon exposure to CH2Cl2 vapor. Similar mechanochromic photoluminescence behaviour was observed after grinding the crystals of 1. A filter paper impregnated with 1 demonstrated recyclable write/erase functionality for encrypted information transfer. Full article
(This article belongs to the Special Issue Inorganic Chemistry in Asia)
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12 pages, 6581 KB  
Article
Hydrated Electrons in Phase-Matching Generation of Second-Order Stokes X-Waves in Water
by Xinxin Chen, Qing Zhou and Zhongyang Wang
Molecules 2025, 30(9), 1969; https://doi.org/10.3390/molecules30091969 - 29 Apr 2025
Viewed by 604
Abstract
Two components of X-waves, near-axis and off-axis, were observed in the generation of second-order Stokes around 550 nm, excited by intense 400 nm, 100 fs pump pulses in a 50 cm water cuvette. The emission angles of these two X-waves exhibited different evolutions; [...] Read more.
Two components of X-waves, near-axis and off-axis, were observed in the generation of second-order Stokes around 550 nm, excited by intense 400 nm, 100 fs pump pulses in a 50 cm water cuvette. The emission angles of these two X-waves exhibited different evolutions; when the pump energy increased, the emission angle of the near-axis X-wave increased, while that of the off-axis X-wave decreased. These abnormal features of second-order X-waves came from the four-wave mixing process, accompanied by induced intense hydrated electrons via cascade ionization. The induced wave vector from high-density hydrated electrons led to angle-dependent phase-matching for the generation of the off-axis X-wave. However, for the generation of the near-axis X-wave, the induced wave vector from hydrated electrons initially compensated for the phase mismatch at a low pump energy, but as the energy increased, the phase mismatch also increased. Moreover, anomalous Raman shifts at second-order Stokes wavelengths (3262 cm−1 and 3350 cm−1) exhibited a similar evolutionary process to the anomalous Raman peaks at the Stokes wavelengths. The shifts arose from excess electrons being injected into the hydrogen bond network of water clusters. Full article
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35 pages, 5473 KB  
Review
Assessing the Effect of Organic, Inorganic, and Hybrid Phase Change Materials on Thermal Regulation and Energy Efficiency in Asphalt Pavements—A Review
by Farhan Lafta Rashid, Mudhar A. Al-Obaidi, Wadhah Amer Hatem, Raid R. A. Almuhanna, Zeina Ali Abdul Redha, Najah M. L. Al Maimuri and Anmar Dulaimi
Processes 2025, 13(3), 597; https://doi.org/10.3390/pr13030597 - 20 Feb 2025
Cited by 8 | Viewed by 1813
Abstract
Harnessing the power of phase change materials (PCMs) in asphalt pavements proposes a sustainable solution for addressing temperature-related issues, affording more robust and energy-efficient infrastructure. PCMs hold enormous potential for reforming various industries due to their ability to store and release large amounts [...] Read more.
Harnessing the power of phase change materials (PCMs) in asphalt pavements proposes a sustainable solution for addressing temperature-related issues, affording more robust and energy-efficient infrastructure. PCMs hold enormous potential for reforming various industries due to their ability to store and release large amounts of thermal energy, offering noteworthy benefits in energy efficiency, thermal management, and sustainability. The integration of PCMs within pavements presents an increasingly exciting field of research. PCMs have the ability to efficiently manage the changes in and distribution of temperature in asphalt pavements via the release and absorption of latent heat that occurs during the phase shifts of PCMs. Asphalt pavements experience less severe temperatures and a slower rate of temperature fluctuation as a result of this, which in turn reduces the amount of stress caused by temperature. In addition, the function of temperature adjustment that PCMs provide is natural, intelligent, and in line with the direction in which the development of smart pavements is heading in the future. This study aims to explore the impact of organic, inorganic, and mixed organic–inorganic PCMs on diverse surface characteristics of asphalt. In addition, this review addresses current challenges associated with using PCMs in asphalt and explores potential advantages that could facilitate future research in addition to broadening the implementation of PCMs in construction. Full article
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