Search Results (1,442)

Given the urgent need to decarbonize the global energy system, green hydrogen has emerged as a key alternative in the transition to renewables. However, its production via electrolysis demands high water quality and raises environmental concerns, particularly regarding reject water discharge. This study employs an experimental and analytical approach to define optimal water characteristics for electrolysis, focusing on conductivity as a key parameter. A pilot water treatment plant with reverse osmosis and electrodeionization (EDI) was designed to simulate industrial-scale pretreatment. Twenty water samples from diverse natural sources (surface and groundwater) were tested, selected for geographical and geological variability. A predictive algorithm was developed and validated to estimate useful versus reject water based on input quality. Three conductivity-based categories were defined: optimal (0–410 µS/cm), moderate (411–900 µS/cm), and restricted (>900 µS/cm). Results show that water quality significantly affects process efficiency, energy use, waste generation, and operating costs. This work offers a technical and regulatory framework for assessing potential sites for green hydrogen plants, recommending avoidance of high-conductivity sources. It also underscores the current regulatory gap regarding reject water treatment, stressing the need for clear environmental guidelines to ensure project sustainability. Full article

African hydrological systems are incredibly complex and highly sensitive to climate variability. This review synthesizes observational data, remote sensing, and climate modeling to understand the interactions between fluvial processes, water cycle dynamics, and anthropogenic pressures. Currently, these systems are experiencing accelerating warming (+0.3 °C/decade), leading to more intense hydrological extremes and regionally varied responses. For example, East Africa has shown reversed temperature–moisture correlations since the Holocene onset, while West African rivers demonstrate nonlinear runoff sensitivity (a threefold reduction per unit decline in rainfall). Land-use and land-cover changes (LULCC) are as impactful as climate change, with analysis from 1959–2014 revealing extensive conversion of primary non-forest land and a more than sixfold increase in the intensity of pastureland expansion by the early 21st century. Future projections, exemplified by studies in basins like Ethiopia’s Gilgel Gibe and Ghana’s Vea, indicate escalating aridity with significant reductions in surface runoff and groundwater recharge, increasing aquifer stress. These findings underscore the need for integrated adaptation strategies that leverage remote sensing, nature-based solutions, and transboundary governance to build resilient water futures across Africa’s diverse basins. Full article

In mining areas with high groundwater levels, intensive coal mining has led to the accumulation of substantial surface water and significant alterations in regional landscape patterns. Reconstructing the ecological security pattern (ESP) has emerged as a critical focus for ecological restoration in coal mining subsidence areas with high groundwater levels. This study employed the patch-generating land use simulation (PLUS) model to predict the landscape evolution trend of the study area in 2032 under three scenarios, combining environmental characteristics and disturbance features of coal mining subsidence areas with high groundwater levels. In order to determine the differences in ecological network changes within the study area under various development scenarios, morphological spatial pattern analysis (MSPA) and landscape connectivity analysis were employed to identify ecological source areas and establish ecological corridors using circuit theory. Based on the simulation results of the optimal development scenario, potential ecological pinch points and ecological barrier points were further identified. The findings indicate that: (1) land use changes predominantly occur in urban fringe areas and coal mining subsidence areas. In the land reclamation (LR) scenario, the reduction in cultivated land area is minimal, whereas in the economic development (ED) scenario, construction land exhibits a marked increasing trend. Under the natural development (ND) scenario, forest land and water expand most significantly, thereby maximizing ecological space. (2) Under the ND scenario, the number and distribution of ecological source areas and ecological corridors reach their peak, leading to an enhanced ecological network structure that positively contributes to corridor improvement. (3) By comparing the ESP in the ND scenario in 2032 with that in 2022, the number and area of ecological barrier points increase substantially while the number and area of ecological pinch points decrease. These areas should be prioritized for ecological protection and restoration. Based on the scenario simulation results, this study proposes a planning objective for a “one axis, four belts, and four zones” ESP, along with corresponding strategies for ecological protection and restoration. This research provides a crucial foundation for decision-making in enhancing territorial space planning in coal mining subsidence areas with high groundwater levels. Full article

Strategic petroleum reserves are critical for energy security. In Japan, 0.5 million kiloliters of crude oil (12% of the state-owned reserves) is stored using underground rock-cavern tanks, which comprise unlined horizontal tunnels bored into bedrock. Crude oil is held within the tank by water inside the tank, the pressure of which is kept higher than that of the crude oil by natural groundwater and irrigation water. This study applied microbial DNA-based monitoring to assess the water environments in and around national petroleum-stockpiling bases (the Kuji, Kikuma, and Kushikino bases) using the rock-cavern tanks. Forty-five water samples were collected from the rock-cavern tanks, water-supply tunnels, and observation wells. Principal-component analysis and hierarchical clustering indicated that microbial profiles of the water samples reflect the local environments of their origins. Particularly, the microbial profiles of water inside the rock-cavern tanks were distinct from other samples, revealing biological conditions and hence environmental characteristics within the tanks. Moreover, the clustering analysis indicated distinct features of water samples that have not been detected by other monitoring methods. Thus, microbial DNA-based monitoring provides valuable information on the in situ environments of rock-cavern tanks and can serve as an extremely sensitive measurement to monitor the underground oil storage. Full article

Retired chemically polluted sites in southern Jiangsu Province, China, are characterized by dense nonaqueous phase liquids (DNAPLs) and extremely thick aquifers (>30 m), which pose substantial challenges for determining investigation and remediation depths during redevelopment and exploitation. This study constructed a 2D groundwater transport model using TMVOC to systematically investigate the migration, diffusion, and natural attenuation processes of two typical DNAPLs—1,2-dichloroethane (DCE) and carbon tetrachloride (CTC)—under three scenarios: individual transport, mixed transport, and heterogeneous aquifer conditions, with a simulation period of 35 years. In individual transport scenarios, DCE and CTC showed distinct migration behaviors. DCE achieved a maximum vertical transport distance of 14.01 m and a downstream migration distance of 459.58 m, while CTC reached 13.57 m vertically and 453.51 m downstream. When transported as a mixture, their migration was inhibited: DCE’s vertical and downstream distances decreased to 13.76 m and 440.46 m, respectively; and CTC’s to 13.23 m and 420.32 m, likely due to mutual solvent effects that altered their physicochemical properties such as viscosity and solubility. Under natural attenuation conditions, both DNAPLs ceased downstream transport by the end of the 6th year. DCE concentrations dropped below its risk control value (0.81 mg/L) by the 14th year, and CTC (with a risk control value of 0.23 mg/L) by the 11th year. By the 10th year, DCE’s downstream plume had retreated to 48.65 m, and CTC’s to 0.95 m. In heterogeneous aquifers, vertical upward transport of DCE and CTC increased to 14.82 m and 14.22 m, respectively, due to the partial absence of low-conductivity silt layers, while their downstream distances decreased to 397.99 m and 354.11 m, constrained by low-permeability lenses in the migration path. These quantitative results clarify the dynamic differences in DNAPL transport under varying conditions, highlighting the impacts of multicomponent interactions, natural attenuation, and aquifer heterogeneity. They provide critical references for risk management, scientific determination of remediation depths, and safe exploitation of retired chemically polluted sites with similar hydrogeological characteristics. Full article

As a critical link connecting groundwater and vegetation, the vadose zone’s lithological structural heterogeneity directly influences soil water distribution and vegetation growth. A comprehensive understanding of the ecological effects of the vadose zone can provide scientific evidence for groundwater ecological protection and natural vegetation conservation in arid regions. This study, taking the Minqin Basin in the lower reaches of China’s Shiyang River as a case, reveals the constraining effects of vadose zone lithological structures on vegetation water supply, root development, and water use strategies through integrated analysis, field investigations, and numerical simulations. The findings highlight the critical ecological role of the vadose zone. This role primarily manifests through two mechanisms: regulating capillary water rise and controlling water-holding capacity. They directly impact soil water supply efficiency, alter the spatiotemporal distribution of water deficit in the root zone, and drive vegetation to develop adaptive root growth patterns and stratified water use strategies, ultimately leading to different growth statuses of natural vegetation. During groundwater level fluctuations, fine-grained lithologies in the vadose zone exhibit stronger capillary water response rates, while multi-layered lithological structures (e.g., “fine-over-coarse” configurations) demonstrate pronounced delayed water release effects. Their effective water-holding capacities continue to exert ecological effects, significantly enhancing vegetation drought resilience. Full article

The formation of acidic goaf water in abandoned coal mines poses significant environmental threats, especially in karst regions where the risk of groundwater contamination is heightened. This study investigates the geochemical processes responsible for the generation of acidic water through batch and column leaching experiments using coal mine surrounding rocks (CMSR) from Yangquan, China. The coal-bearing strata, primarily composed of sandstone, mudstone, shale, and limestone, contain high concentrations of pyrite (up to 12.26 wt%), which oxidizes to produce sulfuric acid, leading to a drastic reduction in pH (approximately 2.5) and the mobilization of toxic elements. The CMSR samples exhibit elevated levels of arsenic (11.0 mg/kg to 18.1 mg/kg), lead (69.5 mg/kg to 113.5 mg/kg), and cadmium (0.6 mg/kg to 2.6 mg/kg), all of which exceed natural crustal averages and present significant contamination risks. The fluorine content varies widely (106.1 mg/kg to 1885 mg/kg), with the highest concentrations found in sandstone. Sequential extraction analyses indicate that over 80% of fluorine is bound in residual phases, which limits its immediate release but poses long-term leaching hazards. The leaching experiments reveal a three-stage release mechanism: first, the initial oxidation of sulfides rapidly lowers the pH (to between 2.35 and 2.80), dissolving heavy metals and fluorides; second, slower weathering of aluminosilicates and adsorption by iron and aluminum hydroxides reduce the concentrations of dissolved elements; and third, concentrations stabilize as adsorption and slow silicate weathering regulate the long-term release of contaminants. The resulting acidic goaf water contains extremely high levels of metals (with aluminum at 191.4 mg/L and iron at 412.0 mg/L), which severely threaten groundwater, particularly in karst areas where rapid cross-layer contamination can occur. These findings provide crucial insights into the processes that drive the acidity of goaf water and the release of contaminants, which can aid in the development of effective mitigation strategies for abandoned mines. Targeted management is essential to safeguard water resources and ecological health in regions affected by mining activities. Full article

Groundwater at petroleum-contaminated sites typically exhibits elevated dissolved inorganic carbon (DIC) levels due to hydrocarbon biodegradation; however, our prior field investigations revealed an enigmatic DIC depletion anomaly that starkly contradicts this global pattern and points to an unrecognized carbon sink. In a breakthrough demonstration, this study provides the first experimental confirmation that sulfur-oxidizing bacteria (SOB) drive substantial carbon sequestration via a coupled sulfur oxidation autotrophic assimilation process. Through integrated hydrochemical monitoring and 16S rRNA sequencing in an enrichment culture system, we captured the complete DIC transformation trajectory: heterotrophic acetate degradation initially increased DIC to 370 mg/L, but subsequent autotrophic assimilation by SOB dramatically reduced DIC to 270 mg/L, yielding a net consumption of 85 mg/L. The distinctive pH dynamics (initial alkalization followed by acidification) further corroborated microbial regulation of carbon cycling. Critically, Pseudomonas stutzeri and P. alcaliphila were identified as the dominant carbon-fixing agents. These findings definitively establish that chemolithoautotrophic SOB convert DIC into organic carbon through a “sulfur oxidation-carbon fixation” coupling mechanism, overturning the conventional paradigm of petroleum-contaminated sites as perpetual carbon sources. The study fundamentally redefines natural attenuation frameworks by introducing microbial carbon sink potential as an essential assessment metric for environmental sustainability. Full article

Groundwater contamination by nitrates (NO₃⁻) and nitrites (NO₂⁻) is an urgent problem in rural areas of Eastern Europe, with profound public health and sustainability implications. This paper presents an integrated assessment of groundwater vulnerability and water quality in rural wells in the Ceanu Mare commune, Cluj County, Romania—a representative area of the Northern Transylvania Basin, characterized by diverse geological structures, intensive agricultural activities, and incomplete public water infrastructure. This study combines detailed hydrochemical analyses, household-level studies, and geological context to identify and quantify key factors influencing nitrate and microbial contamination in rural wells, providing a comprehensive perspective on water quality challenges in the central part of Romania. This study adopts a multidisciplinary approach, integrating detailed geotechnical investigations conducted through four strategically located boreholes. These are complemented by extensive hydrogeological and lithological characterization, as well as rigorous chemical and microbiological analyses of nearby wells. The results reveal persistently elevated concentrations of NO₃⁻ and NO₂⁻, commonly associated with inadequate livestock waste management and the proximity of manure storage areas. Microbiological contamination was also frequent. In this study, the NO₃⁻ levels in well water ranged from 39.7 to 48 mg/L, reaching up to 96% of the EU/WHO threshold (50 mg/L), while the NO₂⁻ concentrations varied from 0.50 to 0.69 mg/L, exceeding the legal limit (0.5 mg/L) in 87% of the sampled wells. Ammonium (NH₄⁺) was detected (0.25–0.34 mg/L) in all the wells, below the maximum allowed limit (0.5 mg/L) but indicative of ongoing organic pollution. All the well water samples were non-compliant for microbiological parameters, with E. coli detected in 100% of cases (5–13 CFU/100 mL). The regional clay–marl substrate offers only limited natural protection against pollutant infiltration, primarily due to lithological heterogeneity and discontinuities observed within the clay–marl layers in the study area. This research delivers a replicable model for rural groundwater assessment and addresses a critical gap in regional and European water safety studies. It also provides actionable recommendations for sustainable groundwater management, infrastructure development, and community risk reduction in line with EU water directives. Full article

Sulfate as a potential pollution source in the water environment of the basin, identifying sulfate sources and migration mechanisms is essential for protecting the water environment and ensuring sustainable water management. Liuyang River is a primary tributary of the Xiangjiang River. It has experienced progressively intensifying anthropogenic influences in recent decades, manifested by sustained sulfate concentration increases. However, the sulfate sources and their contributions were not clear. This study used hydrochemistry and multi-isotopes methods combined with Simmr model to study the hydrochemical characteristics, sulfate sources, and migration–transformation processes of surface water and groundwater. The results showed that the hydrochemical types of surface water were HCO₃-Ca and HCO₃·SO₄-Ca·Mg, and groundwater were HCO₃-Ca, HCO₃-Ca·Mg, and HCO₃·SO₄-Ca. Ions in the water primarily originated from carbonate and silicate rocks dissolution and sulfide oxidation, augmented by mining operations, sewage discharge, and chemical production. The analyses of hydrochemistry, isotopes, and Simmr model revealed that surface water sulfate originated from soil sulfate (35.70%), sulfide oxidation (26.56%), sewage (16.58%), and atmospheric precipitation (12.45%). Groundwater sulfate was derived predominantly from sewage (34.96%), followed by soil sulfate (28.09%), atmospheric precipitation (17.35%), and sulfide oxidation (12.25%). Sulfate migration and transformation were controlled by the natural environment and anthropogenic impacts. When unaffected by human activities, sulfate mainly originated from soil and atmospheric precipitation, relating to topography, geological conditions, agricultural activities, and precipitation intensity. However, in regions with intense human activities, contributions from sewage and sulfide oxidation significantly increased due to the influences of mining and industrial activities. Full article

As China’s primary grain-producing area, the Luxi Plain is rich in groundwater resources, which serves as the main water supply source in this region. Investigating the evolution of hydrochemical characteristics and influencing factors of groundwater in this region is crucial for maintaining the safety of groundwater quality and ensuring the high-quality development of the water supply. This study took Liaocheng City in the hinterland of the Luxi Plain as the study area. To clarify the hydrochemical characteristics evolution trend of groundwater in the area, the hydrochemical characteristics of shallow groundwater in recent years were systematically analyzed. The methods of ion ratio, correlation analysis, Gibbs and Gaillardet endmember diagrams, as well as the application of the absolute principal component scores–multiple linear regression (APCS-MLR) receptor model were used to determine the contribution rates of different ion sources to groundwater and to elucidate the driving factors behind the evolution of groundwater chemistry. Results showed significant spatiotemporal variations in the concentrations of major ions such as Na⁺, SO₄²⁻, and Cl⁻ in groundwater in the study area, and these variations demonstrated an overall increasing trend. Notably, the increases in total hardness (THRD), SO₄⁻, and Cl⁻ concentrations were particularly pronounced, while the variations in Na⁺, Mg²⁺, Ca²⁺ and other ions were relatively gradual. APCS-MLR receptor model analysis revealed that the ions such as Na⁺, Ca²⁺, Mg²⁺, SO₄²⁻, Cl⁻, HCO₃⁻ and NO₃⁻ all have a significant influence on the hydrochemical composition of groundwater due to the high absolute principal component scores of them. The hydrochemical characteristics of groundwater in the study area were controlled by multiple processes, including evaporites, silicates and carbonates weathering, evaporation-concentration, cation alternating adsorption and human activities. Among the natural driving factors, rock weathering had a greater influence on the evolution of groundwater hydrochemical characteristics. Moreover, mining activities were the most important anthropogenic factor, followed by agricultural activities and living activities. Full article

Reusing and recycling treated wastewater is a sustainable approach to meet the growing demand for clean water, ensuring its availability for both current and future generations. Wastewater can be treated in such advanced ways that it can be used for industrial operations, recharging groundwater, irrigation of fields, or even manufacturing drinkable water. This strategy meets growing water demand in water-scarce areas while protecting natural ecosystems. Treated wastewater is both a resource and a challenge. Though it may be nutrient-rich and can increase agricultural output while showing resource reuse and environmental conservation, high treatment costs, public acceptance, and contamination hazards limit its use. Proper treatment can reduce these hazards, safeguarding human health and the environment while enhancing its benefits, including a stable water supply, nutrient-rich irrigation, higher crop yields, economic development, and community resilience. On the one hand, inadequate treatment may lead to soil salinization, environmental degradation, and hazardous foods. Examining the dual benefits and risks of using treated wastewater for agricultural irrigation, this paper investigates the complexities of its use as a valuable resource and as a potential hazard. Modern treatment technologies are needed to address these difficulties and to ensure safe and sustainable use. If properly handled, treated wastewater reuse has enormous potential for reducing water scarcity and expanding sustainable agriculture as well as global food security. Full article

It is vital to stabilize pillar dams in underground reservoirs in coal mine goafs to protect groundwater resources and quarry safety, practice green mining, and protect the ecological environment. Considering the actual occurrence of coal pillar dams in underground reservoirs, acoustic emission (AE) mechanical tests were performed on dry, naturally absorbed, and soaked coal samples. According to the mechanical analysis, Quantitative analysis revealed that dry samples exhibited the highest mechanical parameters (peak strength: 12.3 ± 0.8 MPa; elastic modulus: 1.45 ± 0.12 GPa), followed by natural absorption (peak strength: 9.7 ± 0.6 MPa; elastic modulus: 1.02 ± 0.09 GPa), and soaked absorption showed the lowest values (peak strength: 7.2 ± 0.5 MPa; elastic modulus: 0.78 ± 0.07 GPa). The rate of mechanical deterioration increased by ~25% per 1% increase in moisture content. It was identified that the internal crack development presented a macrofracture surface initiating at the sample center and expanding radially outward, and gradually expanding to the edges by adopting AE seismic source localization and the K-means clustering algorithm. Soaked absorption was easier to produce shear cracks than natural absorption, and a higher water content increased the likelihood. The b-value of the AE damage evaluation index based on crack development was negatively correlated with the rock damage state, and the S-value was positively correlated, and both effectively characterized it. The research results can offer reference and guidance for the support design, monitoring, and warning of coal pillar dams in underground reservoirs. (The samples were tested under two moisture conditions: (1) ‘Soaked absorption’—samples fully saturated by immersion in water for 24 h, and (2) ‘Natural absorption’—samples equilibrated at 50% relative humidity and 25 °C for 7 days). Full article

The main goal of our work was to evaluate approaches for modeling lateral outflow from shallow unconfined aquifers in a one-dimensional model of vertical variably-saturated flow. The HYDRUS-1D model was modified by implementing formulas representing lateral flow in an aquifer, with linear or quadratic drainage functions describing the relationship between groundwater head and flux. The results obtained by the modified HYDRUS-1D model were compared to the reference simulations with HydroGeoSphere (HGS), with explicit representation of 2D flow in unsaturated and saturated zones in a vertical cross-section of a strip aquifer, including evapotranspiration and plant water uptake. Four series of simulations were conducted for sand and loamy sand soil profiles with deep (6 m) and shallow (2 m) water tables. The results indicate that both linear and quadratic drainage functions can effectively capture groundwater table fluctuations and soil water dynamics. HYDRUS-1D demonstrates notable accuracy in simulating transient fluctuations but shows higher variability near the surface. The study concludes that both quadratic and linear drainage boundary conditions can effectively represent horizontal aquifer flow in 1D models, enhancing the ability of such models to simulate groundwater table fluctuations. Full article

A VOC-contaminated shallow aquifer in an industrial site was investigated to evaluate its potential for natural attenuation. The shallow groundwater aquifer beneath the industrial site has been contaminated by dissolved volatile organic compounds (VOCs) such as trichloroethylene (TCE), cis-1,2-dichloroethylene (cis-DCE), and vinyl chloride (VC) for more than three decades. Monitoring and investigation were implemented during 2011–2024, aiming to propose future groundwater aquifer management strategies. This study included groundwater borehole investigation, well installation monitoring, hydraulic head measurements, slug tests, groundwater samplings, and microbial analyses. Microbial investigations identified the predominant group of microorganisms of Proteobacteria, indicating biodegradation potential, as demonstrated by the presence of cis-DCE and VC. BIOSCREEN was used to evaluate the process of natural attenuation, incorporating site-specific parameters. A two-layer groundwater flow model was developed using MODFLOW with hydraulic conductivities obtained from slug tests. The site has an average hydraulic head of 259.6 m amsl with a hydraulic gradient of 0.026, resulting in an average groundwater flow velocity of 11 m/y. Hydraulic conductivities were estimated during model calibration using the PEST pilot point technique. A reactive transport model, RT3D, was used to simulate dissolved TCE transport over 30 years, which can undergo sorption as well as biodegradation. Model calibration demonstrated a satisfactory fit between observed and simulated groundwater heads with a root mean square error of 0.08 m and a correlation coefficient (r) between measured and simulated heads of 0.81, confirming the validity of the hydraulic conductivity distribution. The TCE plume continuously degraded and gradually migrated southward, generating a cis-DCE plume. The concentrations in both plumes decreased toward the end of the simulation period at Source 1 (located upstream), while BIOSCREEN results confirmed ongoing natural attenuation primarily by biodegradation. The integrated MODFLOW-RT3D-BIOSCREEN approach effectively evaluated VOC attenuation and plume migration. However, future remediation strategies should consider enhanced bioremediation to accelerate contaminant degradation at Source 2 and ensure long-term groundwater quality. Full article