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14 pages, 2033 KB

Open AccessArticle

Influence of Catalytic Support on Hydrogen Production from Glycerol Steam Reforming

by Jorge Feijoo, Rocío Maceiras, Victor Alfonsín, Nevin Aly and Alejandro de la Fuente

Hydrogen 2025, 6(4), 88; https://doi.org/10.3390/hydrogen6040088 (registering DOI) - 14 Oct 2025

The use of hydrogen as an energy carrier represents a promising alternative for mitigating climate change. However, its practical application requires achieving a high degree of purity throughout the production process. In this study, the influence of the type of catalytic support on [...] Read more.

The use of hydrogen as an energy carrier represents a promising alternative for mitigating climate change. However, its practical application requires achieving a high degree of purity throughout the production process. In this study, the influence of the type of catalytic support on H₂ production via steam glycerol reforming was evaluated, with the objective of obtaining syngas with the highest possible H₂ concentration. Three types of support were analyzed: two natural materials (zeolite and dolomite) and one metal oxide, alumina. Alumina and dolomite were coated with Ni at different loadings, while zeolite was only evaluated without Ni. Reforming experiments were carried out at a constant temperature of 850 °C, with continuous monitoring of H₂, CO₂, CO, and CH₄ concentrations. The results showed that zeolite yielded the lowest H₂ concentration (51%), mainly due to amorphization at high temperatures and the limited effectiveness of physical adsorption processes. In contrast, alumina and dolomite achieved H₂ purities of around 70%, which increased with Ni loading. The improvement was particularly significant in dolomite, owing to its higher porosity and the recarbonation processes of CaO, enabling H₂ purities of up to 90%. Full article

(This article belongs to the Special Issue Advances in Hydrogen Production, Storage, and Utilization)

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34 pages, 6690 KB

Open AccessArticle

Assessing the Effect of Mineralogy and Reaction Pathways on Geological Hydrogen (H₂) Generation in Ultramafic and Mafic (Basaltic) Rocks

by Abubakar Isah, Hamidreza Samouei and Esuru Rita Okoroafor

Hydrogen 2025, 6(4), 76; https://doi.org/10.3390/hydrogen6040076 - 1 Oct 2025

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Abstract

This study evaluates the impact of mineralogy, elemental composition, and reaction pathways on hydrogen (H₂) generation in seven ultramafic and mafic (basaltic) rocks. Experiments were conducted under typical low-temperature hydrothermal conditions (150 °C) and captured early and evolving stages of fluid–rock [...] Read more.

This study evaluates the impact of mineralogy, elemental composition, and reaction pathways on hydrogen (H₂) generation in seven ultramafic and mafic (basaltic) rocks. Experiments were conducted under typical low-temperature hydrothermal conditions (150 °C) and captured early and evolving stages of fluid–rock interaction. Pre- and post-interactions, the solid phase was analyzed using X-ray Diffraction (XRD) and X-ray Photoelectron Spectroscopy (XPS), while Inductively Coupled Plasma Mass Spectrometry (ICP-MS) was used to determine the composition of the aqueous fluids. Results show that not all geologic H₂-generating reactions involving ultramafic and mafic rocks result in the formation of serpentine, brucite, or magnetite. Our observations suggest that while mineral transformation is significant and may be the predominant mechanism, there is also the contribution of surface-mediated electron transfer and redox cycling processes. The outcome suggests continuous H₂ production beyond mineral phase changes, indicating active reaction pathways. Particularly, in addition to transition metal sites, some ultramafic rock minerals may promote redox reactions, thereby facilitating ongoing H₂ production beyond their direct hydration. Fluid–rock interactions also regenerate reactive surfaces, such as clinochlore, zeolite, and augite, enabling sustained H₂ production, even without serpentine formation. Variation in reaction rates depends on mineralogy and reaction kinetics rather than being solely controlled by Fe oxidation states. These findings suggest that ultramafic and mafic rocks may serve as dynamic, self-sustaining systems for generating H₂. The potential involvement of transition metal sites (e.g., Ni, Mo, Mn, Cr, Cu) within the rock matrix may accelerate H₂ production, requiring further investigation. This perspective shifts the focus from serpentine formation as the primary driver of H₂ production to a more complex mechanism where mineral surfaces play a significant role. Understanding these processes will be valuable for refining experimental approaches, improving kinetic models of H₂ generation, and informing the site selection and design of engineered H₂ generation systems in ultramafic and mafic formations. Full article

(This article belongs to the Special Issue Advances in Hydrogen Production, Storage, and Utilization)

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17 pages, 2627 KB

Open AccessArticle

Investigation of Mechano-Electrochemical Effects on Hydrogen Distribution at Corrosion Defects

by Zhixiang Dai, Jiamin Tang, Sijia Zheng, Feng Wang, Qin Bie, Pengcheng Kang, Xinyi Wang, Shiwen Guo and Lin Chen

Hydrogen 2025, 6(3), 69; https://doi.org/10.3390/hydrogen6030069 - 12 Sep 2025

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Abstract

This study employed tensile test, hydrogen permeation measurements, and potentiodynamic polarization testing to investigate the mechanical properties, hydrogen diffusion coefficients, and electrochemical behavior of X80 steel. A multifield coupled finite element (FE) model was developed that incorporated the mechano-electrochemical (M-E) effect to analyze [...] Read more.

This study employed tensile test, hydrogen permeation measurements, and potentiodynamic polarization testing to investigate the mechanical properties, hydrogen diffusion coefficients, and electrochemical behavior of X80 steel. A multifield coupled finite element (FE) model was developed that incorporated the mechano-electrochemical (M-E) effect to analyze the stress–strain distribution, anodic equilibrium potential, cathodic exchange current density, and hydrogen distribution characteristics at pipeline corrosion defects under varying tensile strains. The results indicated that tensile strain significantly modulated the anodic equilibrium potential and cathodic exchange current density, leading to localized hydrogen accumulation at corrosion defects. The stress concentration and plastic deformation at the defect site intensified as the tensile strain increased, further promoting hydrogen enrichment. The study concluded that the M-E effect exacerbated hydrogen enrichment at the defect sites, increasing the risk of hydrogen-induced cracking. The simulation results showed that the hydrogen distribution state aligned with the stress–hydrogen diffusion coupling model when considering the M-E effect. However, the M-E effect slightly increased the hydrogen concentration at the defect. These findings provide critical insights for enhancing the safety and durability of hydrogen transmission pipelines. Full article

(This article belongs to the Special Issue Advances in Hydrogen Production, Storage, and Utilization)

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14 pages, 5143 KB

Open AccessArticle

An Efficient Finite Element Model to Predict the Mechanical Response of Metallic-Reinforced Pressure Vessels

by Ana Lucía León Razo, Miguel Ernesto Gutierrez Rivera, Carlos Enrique Valencia Murillo, Elias Rigoberto Ledesma Orozco and Israel Martinez Ramirez

Hydrogen 2025, 6(3), 55; https://doi.org/10.3390/hydrogen6030055 - 6 Aug 2025

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Abstract

In the design of pressure vessels for hydrogen storage, the durability and robustness of the designs are tested by using experimental methods, numerical simulations, or both. However, in the initial design phase, it is widely known that using numerical simulation tools reduces the [...] Read more.

In the design of pressure vessels for hydrogen storage, the durability and robustness of the designs are tested by using experimental methods, numerical simulations, or both. However, in the initial design phase, it is widely known that using numerical simulation tools reduces the cost of performing experiments; therefore, models that provide accurate and reliable results must be developed. This work presents an axisymmetric finite element model to predict the mechanical response of reinforced wire pressure vessels of type II. The main contribution of the present model is the use of equivalent properties and a minor number of contact elements to simulate the behavior of the wire reinforcement, which reduces the computational effort compared to a model with a solid-based mesh. The accuracy of the proposed model is tested against solid elements with very good agreement and experimental results with reasonable agreement. A parametric study was conducted to test the influence of the number of layers of reinforcement, and it was concluded that there is a limit to increasing the number of layers, which does not increase the vessel’s strength considerably, but it does with its mass. Full article

(This article belongs to the Special Issue Advances in Hydrogen Production, Storage, and Utilization)

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25 pages, 2540 KB

Open AccessArticle

Classification Framework for Hydrological Resources for Sustainable Hydrogen Production with a Predictive Algorithm for Optimization

by Mónica Álvarez-Manso, Gabriel Búrdalo-Salcedo and María Fernández-Raga

Hydrogen 2025, 6(3), 54; https://doi.org/10.3390/hydrogen6030054 - 6 Aug 2025

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Abstract

Given the urgent need to decarbonize the global energy system, green hydrogen has emerged as a key alternative in the transition to renewables. However, its production via electrolysis demands high water quality and raises environmental concerns, particularly regarding reject water discharge. This study [...] Read more.

Given the urgent need to decarbonize the global energy system, green hydrogen has emerged as a key alternative in the transition to renewables. However, its production via electrolysis demands high water quality and raises environmental concerns, particularly regarding reject water discharge. This study employs an experimental and analytical approach to define optimal water characteristics for electrolysis, focusing on conductivity as a key parameter. A pilot water treatment plant with reverse osmosis and electrodeionization (EDI) was designed to simulate industrial-scale pretreatment. Twenty water samples from diverse natural sources (surface and groundwater) were tested, selected for geographical and geological variability. A predictive algorithm was developed and validated to estimate useful versus reject water based on input quality. Three conductivity-based categories were defined: optimal (0–410 µS/cm), moderate (411–900 µS/cm), and restricted (>900 µS/cm). Results show that water quality significantly affects process efficiency, energy use, waste generation, and operating costs. This work offers a technical and regulatory framework for assessing potential sites for green hydrogen plants, recommending avoidance of high-conductivity sources. It also underscores the current regulatory gap regarding reject water treatment, stressing the need for clear environmental guidelines to ensure project sustainability. Full article

(This article belongs to the Special Issue Advances in Hydrogen Production, Storage, and Utilization)

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25 pages, 5958 KB

Open AccessArticle

Comparative Designs for Standalone Critical Loads Between PV/Battery and PV/Hydrogen Systems

by Ahmed Lotfy, Wagdy Refaat Anis, Fatma Newagy and Sameh Mostafa Mohamed

Hydrogen 2025, 6(3), 46; https://doi.org/10.3390/hydrogen6030046 - 5 Jul 2025

Cited by 1 | Viewed by 764

Abstract

This study presents the design and techno-economic comparison of two standalone photovoltaic (PV) systems, each supplying a 1 kW critical load with 100% reliability under Cairo’s climatic conditions. These systems are modeled for both the constant and the night load scenarios, accounting for [...] Read more.

This study presents the design and techno-economic comparison of two standalone photovoltaic (PV) systems, each supplying a 1 kW critical load with 100% reliability under Cairo’s climatic conditions. These systems are modeled for both the constant and the night load scenarios, accounting for the worst-case weather conditions involving 3.5 consecutive cloudy days. The primary comparison focuses on traditional lead-acid battery storage versus green hydrogen storage via electrolysis, compression, and fuel cell reconversion. Both the configurations are simulated using a Python-based tool that calculates hourly energy balance, component sizing, and economic performance over a 21-year project lifetime. The results show that the PV/H₂ system significantly outperforms the PV/lead-acid battery system in both the cost and the reliability. For the constant load, the Levelized Cost of Electricity (LCOE) drops from 0.52 USD/kWh to 0.23 USD/kWh (a 56% reduction), and the payback period is shortened from 16 to 7 years. For the night load, the LCOE improves from 0.67 to 0.36 USD/kWh (a 46% reduction). A supplementary cost analysis using lithium-ion batteries was also conducted. While Li-ion improves the economics compared to lead-acid (LCOE of 0.41 USD/kWh for the constant load and 0.49 USD/kWh for the night load), this represents a 21% and a 27% reduction, respectively. However, the green hydrogen system remains the most cost-effective and scalable storage solution for achieving 100% reliability in critical off-grid applications. These findings highlight the potential of green hydrogen as a sustainable and economically viable energy storage pathway, capable of reducing energy costs while ensuring long-term resilience. Full article

(This article belongs to the Special Issue Advances in Hydrogen Production, Storage, and Utilization)

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Review

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33 pages, 4369 KB

Open AccessReview

Fuel-Cell Thermal Management Strategies for Enhanced Performance: Review of Fuel-Cell Thermal Management in Proton-Exchange Membrane Fuel Cells (PEMFCs) and Solid-Oxide Fuel Cells (SOFCs)

by Ibham Veza

Hydrogen 2025, 6(3), 65; https://doi.org/10.3390/hydrogen6030065 - 4 Sep 2025

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Abstract

Effective thermal management is crucial for optimizing the performance, efficiency, and durability of fuel-cell technologies, including proton-exchange membrane fuel cells (PEMFCs) and solid-oxide fuel cells (SOFCs). The operation of fuel cells involves complex heat generation mechanisms, primarily driven by electrochemical reactions, which can [...] Read more.

Effective thermal management is crucial for optimizing the performance, efficiency, and durability of fuel-cell technologies, including proton-exchange membrane fuel cells (PEMFCs) and solid-oxide fuel cells (SOFCs). The operation of fuel cells involves complex heat generation mechanisms, primarily driven by electrochemical reactions, which can lead to significant energy loss as heat. This review examines the specific heat generation sources and challenges associated with different fuel-cell types, highlighting the critical importance of effective thermal management strategies. Key techniques for thermal regulation, including active and passive cooling systems, are examined in detail. Active cooling methods like liquid cooling and air cooling are effective in dissipating excess heat, while passive methods leverage advanced materials and optimized designs to enhance natural heat dissipation. Furthermore, innovative heat recovery systems are explored, demonstrating their potential to enhance overall energy efficiency by capturing and repurposing waste heat. The integration of machine learning techniques has arisen as a promising avenue for advancing temperature control in fuel cells. Reinforcement learning, deep learning algorithms, and support vector machines, along with artificial neural networks, are discussed in the context of their application in managing temperature dynamics and optimizing thermal performance. The review also emphasizes the significance of real-time monitoring, as well as adaptive control strategies to respond effectively to the dynamic operating conditions of fuel cells. Understanding and applying these thermal management strategies is essential for the successful commercialization of fuel cells across various sectors, ranging from automotive to stationary power generation. With the growing demand for clean energy solutions, progress in thermal management techniques will be crucial in improving the dependability and practicality of fuel-cell systems. Full article

(This article belongs to the Special Issue Advances in Hydrogen Production, Storage, and Utilization)

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30 pages, 3940 KB

Open AccessReview

Hydrogen-Enabled Power Systems: Technologies’ Options Overview and Effect on the Balance of Plant

by Furat Dawood, GM Shafiullah and Martin Anda

Hydrogen 2025, 6(3), 57; https://doi.org/10.3390/hydrogen6030057 - 13 Aug 2025

Cited by 1 | Viewed by 1860

Abstract

Hydrogen-based Power Systems (H2PSs) are gaining accelerating momentum globally to reduce energy costs and dependency on fossil fuels. A H2PS typically comprises three main parts: hydrogen production, storage, and power generation, called packages. A review of the literature and Original Equipment Manufacturers (OEM) [...] Read more.

Hydrogen-based Power Systems (H2PSs) are gaining accelerating momentum globally to reduce energy costs and dependency on fossil fuels. A H2PS typically comprises three main parts: hydrogen production, storage, and power generation, called packages. A review of the literature and Original Equipment Manufacturers (OEM) datasheets reveals that no single manufacturer supplies all H2PS components, posing significant challenges in system design, parts integration, and safety assurance. Additionally, both the literature and H2PS projects’ database highlight a gap in a systematic hydrogen equipment and auxiliary sub-systems technology selection process, and how this selection affects the overall H2PS Balance of Plant (BoP). This study addresses that gap by providing a guideline for available technology options and their impact on the H2PS-BoP. The analysis compares packages and auxiliary sub-system technologies to support informed engineering decisions regarding technology and equipment selection. The study finds that each package’s technology influences the selection criteria of the other packages and the associated BoP requirements. Furthermore, the choice of technologies across packages significantly affects overall system integrity and BoP. These interdependencies are illustrated using a cause-and-effect matrix. The study’s significance lies in establishing a structured guideline for engineering design and operations, enhancing the accuracy of feasibility studies, and accelerating the global implementation of H2PS. Full article

(This article belongs to the Special Issue Advances in Hydrogen Production, Storage, and Utilization)

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