Search Results (15,430)

To improve coating adhesion and tribological stability on aircraft-grade aluminum, this work utilizes periodic fiber-laser microtexts as a surface-engineering pre-treatment before applying an epoxy primer. AA2024-T3 panels were imprinted with rhombus, hexagon, and circular lattices (scale factors 100–250 µm; scan speeds 250–750 mm s⁻¹), then primed with an aerospace epoxy primer and evaluated within reciprocating sliding wear tests. Areal profilometry and sessile-drop goniometry measured topography and wettability, whereas friction–distance traces and scratch-track metrology resolved interfacial integrity. The textures expanded surface area and modified energy states in a geometry- and scale-dependent fashion, producing stable friction plateaus and smaller, less-lateral scratch scars compared to the untextured reference. Circular dimples reliably provided the best damage-tolerant behavior, a function of improved mechanical interlocking and debris/film management (reservoir and micro-trap effects), whereas polygonal lattices evidenced greater sensitivity to both scale and speed. Factorial analyses disclosed prevalent interaction effects amongst geometry, scale, and scan speed, reinforcing the notion that performance arises from co-optimized texture architecture rather than a single parameter. In systemic terms, laser-defined microtexts complemented with aerospace-standard primers represent a controllable pathway to vary friction, dampen wear, and improve coating–substrate adhesion. These results provide practical selection guides; and a broad selection prefers larger, well-spaced circular dimples for best-in-class performance and a transferable framework for designing texture-coating systems across aerospace and allied manufacturing contexts. Full article

Bacterial infections can delay wound healing and represent serious medical problems both in the hospital and community settings, especially skin wound infections caused by Staphylococcus aureus. In this work, a gelatin hydrogel modified with photo-cross-linkable methacrylamide groups at 10% concentration (GelMA10%), enriched with titanium dioxide nanoparticles (TiO₂NPs), and loaded with Neomycin sulphate was developed with the aim to realize a tissue for wound care with improved mechanical and antimicrobial properties. TiO₂ nanocomposite GelMA films with two concentrations of TiO₂NPs were characterized to assess physicochemical, structural and mechanical properties by scanning electron microscopy equipped with an energy-dispersive X-ray spectrometer (SEM/EDX), micro-computed tomography (micro-CT) and X-ray photoelectron spectroscopy (XPS). TiO₂ nanocomposite GelMA films showed a more compact structure, reduced pore sizes and a higher compressive modulus at the increasing concentration of TiO₂NPs. They were able to absorb and retain water for a prolonged time; however, no significant differences in the swelling degree at the increasing concentration of TiO₂NPs were observed. In vitro drug release and antibacterial activity against Staphylococcus aureus of TiO₂ nanocomposite GelMA film enriched with higher concentrations of TiO₂NPs, identified as a suitable candidate for wound healing, were investigated. Both GelMA10% and TiO₂ nanocomposite GelMA films loaded with drug exhibited a strong antibacterial action, whereas GelMA10% containing only TiO₂NPs did not show any antimicrobial properties. Full article

Materials derived from renewable and recycled resources offer a promising route toward more sustainable thermoset composites. In this study, waste poly(ethylene terephthalate) (PET) was depolymerized by glycolysis with propylene glycol to obtain a glycolysate, and subsequently polycondensed with biobased propylene glycol, maleic anhydride, and trimethylolpropane diallyl ether to synthesize biobased UV-curable unsaturated polyester resin (UV-bUPR). The composites were prepared with acryloyl-modified Kraft lignin (K_rL-A) as a reactive bio-filler using a dual-curing approach, in which rapid UV curing was followed by thermal/redox post-curing to improve conversion and network homogeneity. The structure of the synthesized resin and composites was confirmed by FTIR and NMR spectroscopy. Mechanical properties were evaluated by tensile testing and hardness measurements, while morphology and fracture behavior were analyzed by scanning electron microscopy. The unmodified lignin decreased tensile performance due to limited compatibility with the polyester matrix and the formation of interfacial defects and agglomerates. In contrast, K_rL-A exhibited improved dispersion and stronger filler–matrix interactions, resulting in superior mechanical performance. The most pronounced effect of lignin modification was observed at 15 wt.% filler loading, where the tensile strength reached 27.83 MPa, compared with 13.91 MPa for the corresponding unmodified system. The developed composites also showed improved sustainability, assessed through the E-factor, due to the combined use of recycled PET and renewable lignin. Full article

Certain clayey soils are susceptible to swelling and shrinkage due to moisture variations, which can lead to ground deformation and structural damage. Although traditional stabilization methods using lime and cement are effective, they involve high energy consumption and significant CO₂ emissions. In response to sustainability concerns, this study investigates the potential of in situ geopolymer stabilization of clay soils using industrial by-products as eco-friendly binders. Experimental studies were conducted on clay specimens stabilized with geopolymer binders produced from fly ash and waste brick powder activated by alkaline solutions. The selected clay exhibited stiff to very stiff behavior and was used as a reference material to ensure reliable evaluation without the influence of severe initial degradation. Reference samples with identical water content but without alkaline activation were also prepared. The primary objective was to assess geopolymers as a sustainable alternative to conventional binders, focusing on moisture sensitivity and long-term mechanical performance. Laboratory strength tests demonstrated that geopolymer-treated specimens exhibited significantly higher strength compared to untreated samples, indicating substantial improvement in engineering properties. Furthermore, Scanning Electron Microscopy (SEM) analyses revealed that the combination of dual activators (NS+NH) and thermal curing at 85 °C transformed the weak clay matrix into a dense, fibrous geopolymer network. However, the high curing temperature was primarily used to study the reaction mechanisms; the practical applicability of the method should be evaluated based on results obtained at ambient temperature. This structure enhanced particle bonding and mechanical interlocking by filling voids within the matrix. Overall, the findings confirm that geopolymer stabilization using industrial waste materials is an effective and environmentally sustainable alternative to conventional soil stabilization techniques, contributing to reduced carbon emissions in geotechnical engineering. Full article

This study investigates the valorization of dredged sludge as a sustainable subgrade fill material through stabilization with a nano-calcium carbonate–cement composite. Unconfined compressive strength (UCS) tests were systematically conducted to determine the optimal dosage of nano-CaCO₃ as a supplementary additive at a fixed cement content of 8% by dry soil mass. Scanning electron microscopy (SEM), X-ray diffraction (XRD), and quantitative pore structure analysis were employed to elucidate the underlying solidification mechanisms. The results demonstrate that the addition of 2% nano-CaCO₃ yields the highest 28-day UCS of 721 kPa, representing a statistically significant 21% improvement over the cement-only reference (596 kPa) and a more than threefold increase relative to untreated sludge (213 kPa). Conversely, increasing the nano-CaCO₃ dosage to 2.5% leads to a significant strength reduction, attributed to nanoparticle agglomeration and hindered cement hydration. Microstructural characterization reveals that the optimal nano-CaCO₃ dosage accelerates early-age hydration through a nucleation effect, promotes the consumption of portlandite, and enhances the formation of calcium silicate hydrate (C–S–H) gel. Semi-quantitative XRD analysis further confirms the conversion of less stable monosulfate (AFm-SO₄) into stable monocarboaluminate (AFm-CO₃) phases. These synergistic mechanisms—nucleation, physical pore filling, and chemical reaction—result in a densified matrix with a refined pore structure, reduced total porosity, and a more homogeneous pore-size distribution. The findings provide a robust theoretical basis for the resource-oriented utilization of dredged sludge and the design of low-carbon composite stabilizers for soft soil treatment. Full article

Background: Total knee arthroplasty (TKA) is a common procedure aimed at alleviating knee pain and restoring function in patients with degenerative joint diseases. Traditional implants are typically designed to restore mechanical knee alignment, but personalized implants have shown promise in improving clinical outcomes. The Origin^® individualized TKA system provides a tailored approach to knee reconstruction by utilizing preoperative 3D planning to create individualized implants and cutting guides based on each patient’s unique anatomy. Surgical Technique: The Origin^® system employs a preoperative computed tomography (CT) scan and Knee-Plan^® software to design individualized implants that optimize alignment and joint anatomy. The surgical technique involves the use of patient-specific cutting guides for precise bone resections and the insertion of either cruciate-retaining (CR) or posterior-stabilized (PS) implants, depending on individual patient needs. This process aims to replicate the pre-arthritic alignment and kinematics of the pre-arthritic knee. Postoperative Protocol: The postoperative protocol allows for immediate weight-bearing, and patients are guided through a structured rehabilitation program to ensure optimal recovery. Full range-of-motion exercises begin early to promote knee mobility and strength. Discussion: The individualized TKA system offers several advantages, including precise restoration of pre-arthritic anatomy, reduced bone resection, and improved implant fit. These benefits are particularly valuable in patients with unique anatomical challenges, such as deformities or previous surgeries. Despite the potential advantages, challenges remain, including the costs and time associated with individualized manufacturing, as well as increased radiation exposure from the required CT scans. Conclusions: The Origin^® individualized TKA system represents a significant advancement in knee arthroplasty by providing a tailored approach to patient care. Future studies are needed to further evaluate the long-term outcomes and cost-effectiveness of this personalized system compared to conventional TKA approaches. Full article

To elucidate the role of environmentally friendly oxide additives in a molybdenum disulfide (MoS₂)-based solid lubricant, this study investigates the tribological behavior of a MoS₂–TiO₂ coating deposited via a spray-bonding process and compares it with a commercial Sb₂O₃-containing formulation (Everlube 620C). Interfacial characteristics and wear-related mechanisms were systematically analyzed using scanning electron microscopy (SEM), focused ion beam (FIB), Raman spectroscopy, and X-ray diffraction (XRD). The MoS₂–TiO₂ coating exhibited a higher steady-state coefficient of friction (0.35–0.45) and wear compared to the baseline. Its wear behavior was governed by fracture-induced three-body abrasion, driven by the hard and brittle nature of TiO₂, which promotes stress concentration at particle–matrix interfaces, crack initiation, particle pull-out, and debris generation. These processes suppress the formation of a desirable MoS₂-rich tribo/transfer film, leading to deformation-dominated friction. Overall, the findings indicate that the intrinsic mechanical properties and interfacial behavior of TiO₂ limit its effectiveness as an additive in MoS₂-based coatings, highlighting the importance of additive selection and compatibility in achieving optimal tribological performance. Notably, this study was performed at an additive volume fraction equivalent to that of Sb₂O₃ in Everlube 620C, serving as a foundation and indicating that further optimization of TiO₂ particle size and concentration is required to achieve comparable performance. Full article

Aim: Fixed dental prostheses (FDPs) are increasingly fabricated from high-strength ceramic materials; however, their fracture behavior under flexurally dominated loading remains incompletely understood. This in vitro study aimed to compare the mechanical performance and fracture mechanisms of four FDP material systems under standardized bending conditions. Materials and Methods: Three-unit CAD/CAM-fabricated FDPs were produced from metal-ceramic (P1), zirconia-ceramic (P2), monolithic zirconia (P3), and monolithic lithium disilicate (P4) materials (n = 9 per group). Specimens were subjected to three-point bending until failure. Crack initiation load, maximum load, displacement, and stiffness were recorded, and fracture behavior was analyzed using stereomicroscopy, micro-computed tomography (μCT), and scanning electron microscopy (SEM). Results: Metal-ceramic FDPs (P1) exhibited the highest crack initiation load (0.89 kN) and maximum load (1.91 kN), with failure predominantly occurring through ceramic veneer delamination without complete framework fracture. Monolithic zirconia FDPs (P3) demonstrated the most brittle failure behavior, characterized by abrupt fracture and unstable crack propagation immediately after crack initiation. Zirconia-ceramic (P2) and lithium disilicate (P4) FDPs showed intermediate mechanical performance, with lithium disilicate exhibiting greater resistance to catastrophic failure (F_max = 0.94 kN) compared with zirconia–ceramic FDPs. Conclusions: These findings refine current assumptions regarding the mechanical reliability of monolithic zirconia FDPs under flexural loading and highlight the importance of fracture behavior, rather than peak strength alone, in material selection. Lithium disilicate and metal-ceramic systems exhibited more favorable damage-tolerant responses under static flexural loading. These findings should be interpreted within the limitations of this in vitro model and should not be directly extrapolated to long-term clinical performance. Full article

Background: Pubic symphysis plating is a common method for stabilizing traumatic pubic symphysis disruptions, yet reported rates of implant failure vary widely in the literature. This variability may reflect inconsistent definitions and failure to distinguish clinically significant early construct failure from later asymptomatic postoperative radiographic changes. Methods: We performed a retrospective observational study of 30 patients with traumatic pubic symphysis disruption without associated fractures of the pubic body or pubic rami treated with open reduction and plate fixation. Pubic symphysis distance (PSD) was measured on admission CT, immediate postoperative anteroposterior pelvic radiographs, and follow-up CT scans obtained at 3, 6, and ≥12 months. Early mechanical failure, qualitative radiographic signs of implant loosening, and radiographic loss of reduction were predefined. Non-parametric tests were used to compare patients with and without early mechanical failure and to evaluate longitudinal PSD changes; analyses of potential associated factors were exploratory. Results: Early mechanical failure occurred in 4 patients (13.3%) within 30 days and presented as an acute symptomatic event with imaging-confirmed construct compromise requiring revision. In exploratory univariable analysis, early failure was more frequent in female patients and in those with obesity or osteoporosis, although these findings should be interpreted cautiously given the very small number of events. PSD changed significantly over time (p < 0.001), with minimal increase during the first 3 months, greater widening between 3 and 6 months, and little additional change thereafter. Qualitative radiographic signs of implant loosening and widening were observed in 8 patients (26.7%) during follow-up without clinically documented pain, instability, or need for revision. No clear association was demonstrated between PSD widening and final functional outcome measured by the Majeed score, although these analyses were limited by sample size and wide confidence intervals. Conclusions: In this retrospective cohort, postoperative radiographic widening and qualitative signs of implant loosening were not by themselves associated with clinically evident failure requiring revision during the available follow-up. Early failure was identified by acute clinical symptoms with imaging-confirmed construct compromise, whereas delayed widening was often observed without clinically documented pain, instability, or reoperation. These findings suggest that postoperative imaging should be interpreted together with symptoms and overall pelvic stability, while recognizing the methodological limitations of the study. Full article

To enhance the engineering performance of fine-grained composite soils with unbalanced particle gradation, high plasticity, and poor water stability, a synergistic stabilization strategy combining particle structure regulation and microbially induced calcium carbonate precipitation (MICP) was proposed. The particle size distribution and fundamental engineering properties of a titanium gypsum–clay (TSC) composite soil were first optimized through systematic single-factor blending tests. The results indicate that a TS:C ratio of 60:40 significantly improved gradation characteristics, reduced plasticity, and enhanced both compaction behavior and load-bearing capacity. Based on the optimized gradation framework, MICP treatment was subsequently introduced to further enhance water stability. The effects of key parameters, particularly the type of calcium source, on the evolution of water stability were systematically investigated. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were employed to elucidate the underlying reinforcement mechanisms. The results demonstrate that the water stability coefficient increased markedly from 0.35 to 0.83 following MICP treatment, while strength degradation under water immersion was effectively mitigated. Microscopic observations reveal that microbially precipitated calcite fills pore spaces and forms a continuous cementation network via particle bridging and interfacial bonding, leading to an approximately 32% reduction in porosity. Overall, the proposed synergistic strategy offers an effective and sustainable approach for improving the water stability and structural integrity of complex fine-grained composite soils. Full article

Granite residual soil slopes are highly water-sensitive and prone to rapid collapse, strength degradation, and rainfall-induced erosion. This study investigates the improvement effects and underlying mechanisms of carboxymethyl cellulose (CMC) on the water stability, mechanical properties, and rainfall erosion resistance of granite residual soil from Fuzhou, Fujian Province, China. Laboratory tests, including unconfined compressive strength (UCS) tests, direct shear tests, disintegration tests, slope rainfall scouring model experiments, X-ray diffraction test (XRD) and scanning electron microscopy (SEM) observations, were conducted to evaluate the performance and microstructural behavior of CMC-stabilized soils. The results indicate that the addition of CMC significantly enhances soil resistance to disintegration: the 24 h disintegration ratio decreased to 0.5% at 0.5% CMC content. The incorporation of CMC can significantly enhance the unconfined compressive strength (UCS) of the soil and lead to an increase in cohesion, while its effect on the internal friction angle is limited. Under simulated rainfall conditions (30° slope, 120 mm·h⁻¹ rainfall intensity, 60 min duration), slopes stabilized with 0.5% CMC exhibited suppressed rill formation and a 47.5% reduction in sediment yield, accompanied by delayed moisture increase at different depths and reduced infiltration rates. Microstructural analyses reveal that CMC hydration forms gel-like films and filamentous bridges, promoting particle aggregation and pore filling, thereby constructing a denser particle network without generating new chemical compounds. This microstructure collectively enhances soil disintegration resistance, mechanical strength, and slope erosion resistance. Full article

Objectives: To evaluate the influence of two surface finishing procedures—mechanical polishing and glaze firing—on the color stability and wear behavior of lithium aluminium disilicate (LAD) hybrid abutment crowns over a three-year clinical observation period. Methods: Twenty-four patients requiring 34 implant-supported single crowns were included in this prospective clinical study. LAD abutment crowns were fabricated using n!ce ceramic and a CAD/CAM workflow and finished either by mechanical polishing (P, n = 17) or glaze firing (G, n = 17). After insertion as well as after one and three years (P: n = 9, G: n = 9) of clinical use color measurements were performed using spectrophotometry, and color differences (ΔE00) were calculated. Wear was assessed by digital surface comparison of baseline and the two follow-up scans using three-dimensional analysis software. Reference teeth (R) were defined and evaluated comparable to the P and F groups. Biological and technical complications were recorded throughout the observation period. Results: Color deviations increased over time in all groups (P, G, R). After three years, G showed lower mean color differences (ΔE00 ≈ 2.77) compared with F (ΔE00 ≈ 5.40), although the difference was not statistically significant. No significant differences in vertical height loss were observed between P and G. One adhesive fracture occurred both in the P and G group, five crowns (P: n = 3, G: n = 2) developed periimplantitis. Conclusions: Both polishing and glazing resulted in comparable clinical outcomes regarding color stability, wear behavior, and complication rates. Clinical Significance: Both finishing protocols might be a reliable option for LAD hybrid abutment crowns. Full article

This study scientifically assessed the safety of the Ming Dynasty official-style timber structure of Taiyuan Chongshan Temple’s Great Mercy Hall, a nationally protected cultural relic. An integrated framework was adopted, including form restoration via 3D laser scanning and manual surveying, damage detection using impedance meters, stress wave tomography and one-dimensional stress wave testing, mechanical analysis with a differentiated material finite element model, and short-term on-site monitoring at risk points. Results showed that the 303.3 mm construction ruler length was restored, with the column grid tilting northwestward; the main structure was hardwood pine, and critical columns had severe localized damage (24% internal damage rate, 13% cross-sectional damage ratio) with 42% residual strength in some members; and the structure remained elastically safe, with material degradation causing 6.3–13.3% linear displacement amplification. Two weak links (eave purlin deflection: 33–37 mm; double-eave golden column axial force concentration: 86.9–88.5 kN) and dougong’s outward inclination due to eccentric compression were identified. Short-term monitoring indicated temperature-driven elastic responses and an 8 mm cumulative residual displacement in the northern single-step beam, and a three-level early warning threshold system was proposed. This study clarified the hall’s state as “overall stable with localized weaknesses”, providing a methodological reference for the preventive protection of similar ancient timber structures. Full article

Accurate, standardized dental model measurements remain labor-intensive and difficult to scale in orthodontics. This technical development study aimed to develop and preliminarily evaluate a semiautomated three-dimensional (3D) dental cast measurement system using standardized measurement templates (patent pending). The workflow integrates robotic handling of models, X-ray CT acquisition of volumetric data, optional intraoral-scan polygonal data (e.g., STL), template generation from 3D data, and orthodontist-guided landmark placement, after which dedicated software retrieves 3D coordinates and performs automated measurements and visualization. The system was demonstrated on four standard models scanned by X-ray CT. It produced automated aggregation of measurements and 3D visual outputs, and enabled calculation of conventional indices as well as template-based metrics such as palatal volume and cusp height variation. This semiautomated approach combines mechanical efficiency with expert oversight, providing a standardized alternative to manual measurement and a foundation for broader applications in orthodontic, prosthodontic, and forensic contexts. Full article

In this paper, the effects of 4 wt.% of silicon on the microstructure and mechanical properties of AM50 magnesium alloys fabricated by the casting method are presented. New AM50/Si material and the base AM50 alloy were gravity cast into a metal mould under the same conditions for comparison. Analyses of the alloys’ microstructures were carried out by light microscopy (with differential interface contrast), scanning electron microscopy (with an energy dispersive X-ray spectrometer), as well as X-ray diffraction (XRD). In as-cast conditions, both materials were composed of α-Mg solid solution, α + γ eutectic (where γ is Al₁₂Mg₁₇), Al₈Mn₅ intermetallic phases and discontinuous γ precipitates. The AM50/Si material also consisted of the Mg₂Si phase. This structural constituent appeared in the form of primary crystals with regular polygonal morphology and an α + Mg₂Si eutectic in the form of “Chinese script”. In the microstructure of the AM50/Si material, the Mn₃SiAl₉ ternary phase was also identified. The detailed analyses presented in this paper revealed that the new ternary Mn₃SiAl₉ structural compound caused a reduction in the volume fraction of the Al₈Mn₅ phase but did not completely replace it. These two phases formed competitively. The fabricated material exhibited higher tensile and compression strength as well as yield strength in comparison with the AM50 alloy. Additionally, analyses of the fracture surfaces of the AM50/Si material carried out using scanning electron microscopy (SEM) were presented. Full article