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Search Results (1,694)

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Keywords = magnetic field characteristic

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14 pages, 2177 KiB  
Article
Study on the Regulation Mechanism of Silane Coupling Agents’ Molecular Structure on the Rheological Properties of Fe3O4/CNT Silicone Oil-Based Magnetic Liquids
by Wenyi Li, Xiaotong Zeng, Shiyu Yang, Bingxue Wang, Xiangju Tian and Weihao Shen
J. Compos. Sci. 2025, 9(8), 423; https://doi.org/10.3390/jcs9080423 - 7 Aug 2025
Abstract
Silicone oil-based magnetic liquids containing carbon nanotubes (CNTs) were prepared using an in situ chemical coprecipitation method. The surface modification of Fe3O4/CNT composite particles was carried out by using three silane coupling agents: γ-aminopropyltriethoxysilane (550), γ-methacryloxypropyltrimethoxysilane (570), and phenyltrimethoxysilane [...] Read more.
Silicone oil-based magnetic liquids containing carbon nanotubes (CNTs) were prepared using an in situ chemical coprecipitation method. The surface modification of Fe3O4/CNT composite particles was carried out by using three silane coupling agents: γ-aminopropyltriethoxysilane (550), γ-methacryloxypropyltrimethoxysilane (570), and phenyltrimethoxysilane (7030). Infrared Spectroscopy (IR), Transmission Electron Microscopy (TEM), and X-ray Diffraction (XRD) were used to confirm the successful doping of CNTs and the effective coating of the coupling agents. The rheological behavior of the magnetic liquids was systematically studied using an Anton Paar Rheometer. The results show that viscosity decreases exponentially with increasing temperature (fitting the Arrhenius equation), increases and tends to saturate with rising magnetic field intensity, and exhibits shear-thinning characteristics with increasing shear rate. Among the samples, Fe3O4@7030 has the best visco-thermal performance due to the benzene ring structure, which reduces the symmetry of the molecular chains. In contrast, Fe3O4@570 shows the most significant magneto-viscous effect (viscosity variation of 161.4%) as a result of the long-chain structure enhancing the steric hindrance of the magnetic dipoles. Full article
(This article belongs to the Section Composites Modelling and Characterization)
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13 pages, 3474 KiB  
Article
Energy Dispersion Relationship and Hofstadter Butterfly of Triangle and Rectangular Moiré Patterns in Tight Binding States
by Ziheng Li, Jiangwei Liu, Xiaoxiao Zheng, Yu Sun, Nan Han, Liang Wang, Muyang Li, Lei Han, Safia Khan, S. Hassan M. Jafri, Klaus Leifer, Yafei Ning and Hu Li
Physics 2025, 7(3), 34; https://doi.org/10.3390/physics7030034 - 5 Aug 2025
Abstract
Herein, the energy dispersion relationship and the density of states of triangular and rectangular moiré patterns are investigated using a tight binding model. Their characteristics of Hofstadter butterflies under different magnetic fields are also examined. The results indicate that, by analyzing different moiré [...] Read more.
Herein, the energy dispersion relationship and the density of states of triangular and rectangular moiré patterns are investigated using a tight binding model. Their characteristics of Hofstadter butterflies under different magnetic fields are also examined. The results indicate that, by analyzing different moiré superlattices, Hofstadter butterflies arising from different moiré pattern structures are obtained, exhibiting considerable fractal characteristics and self-similarities. Moreover, it is also observed that under an alternating magnetic field, the redistribution of electronic states leads to a significant change in the density of states curve, and the Van Hove peak changes with the increase in magnetic field intensity. This study enriches the understanding of the electronic behavior of moiré systems, but it also provides multiple potential application directions for future technological development. Full article
(This article belongs to the Section Statistical Physics and Nonlinear Phenomena)
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27 pages, 30231 KiB  
Article
Modelling and Simulation of a 3MW, Seventeen-Phase Permanent Magnet AC Motor with AI-Based Drive Control for Submarines Under Deep-Sea Conditions
by Arun Singh and Anita Khosla
Energies 2025, 18(15), 4137; https://doi.org/10.3390/en18154137 - 4 Aug 2025
Viewed by 207
Abstract
The growing need for high-efficiency and reliable propulsion systems in naval applications, particularly within the evolving landscape of submarine warfare, has led to an increased interest in multiphase Permanent Magnet AC motors. This study presents a modelling and simulation approach for a 3MW, [...] Read more.
The growing need for high-efficiency and reliable propulsion systems in naval applications, particularly within the evolving landscape of submarine warfare, has led to an increased interest in multiphase Permanent Magnet AC motors. This study presents a modelling and simulation approach for a 3MW, seventeen-phase Permanent Magnet AC motor designed for submarine propulsion, integrating an AI-based drive control system. Despite the advantages of multiphase motors, such as higher power density and enhanced fault tolerance, significant challenges remain in achieving precise torque and variable speed, especially for externally mounted motors operating under deep-sea conditions. Existing control strategies often struggle with the inherent nonlinearities, unmodelled dynamics, and extreme environmental variations (e.g., pressure, temperature affecting oil viscosity and motor parameters) characteristic of such demanding deep-sea applications, leading to suboptimal performance and compromised reliability. Addressing this gap, this research investigates advanced control methodologies to enhance the performance of such motors. A MATLAB/Simulink framework was developed to model the motor, whose drive system leverages an AI-optimised dual fuzzy-PID controller refined using the Harmony Search Algorithm. Additionally, a combination of Indirect Field-Oriented Control (IFOC) and Space Vector PWM strategies are implemented to optimise inverter switching sequences for precise output modulation. Simulation results demonstrate significant improvements in torque response and control accuracy, validating the efficacy of the proposed system. The results highlight the role of AI-based propulsion systems in revolutionising submarine manoeuvrability and energy efficiency. In particular, during a test case involving a speed transition from 75 RPM to 900 RPM, the proposed AI-based controller achieves a near-zero overshoot compared to an initial control scheme that exhibits 75.89% overshoot. Full article
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33 pages, 4142 KiB  
Review
Advances in Wettability-Engineered Open Planar-Surface Droplet Manipulation
by Ge Chen, Jin Yan, Junjie Liang, Jiajia Zheng, Jinpeng Wang, Hongchen Pang, Xianzhang Wang, Zihao Weng and Wei Wang
Micromachines 2025, 16(8), 893; https://doi.org/10.3390/mi16080893 (registering DOI) - 31 Jul 2025
Viewed by 324
Abstract
Firstly, this paper reviews the fundamental theories of solid surface wettability and contact angle hysteresis. Subsequently, it further introduces four typical wettability-engineered surfaces with low hysteresis (superhydrophobic, superamphiphobic, super-slippery, and liquid-like smooth surfaces). Finally, it focuses on the latest research progress in the [...] Read more.
Firstly, this paper reviews the fundamental theories of solid surface wettability and contact angle hysteresis. Subsequently, it further introduces four typical wettability-engineered surfaces with low hysteresis (superhydrophobic, superamphiphobic, super-slippery, and liquid-like smooth surfaces). Finally, it focuses on the latest research progress in the field of droplet manipulation on open planar surfaces with engineered wettability. To achieve droplet manipulation, the core driving forces primarily stem from natural forces guided by bioinspired gradient surfaces or the regulatory effects of external fields. In terms of bioinspired self-propelled droplet movement, this paper summarizes research inspired by natural organisms such as desert beetles, cacti, self-aligning floating seeds of emergent plants, or water-walking insects, which construct bioinspired special gradient surfaces to induce Laplace pressure differences or wettability gradients on both sides of droplets for droplet manipulation. Moreover, this paper further analyzes the mechanisms, advantages, and limitations of these self-propelled approaches, while summarizing the corresponding driving force sources and their theoretical formulas. For droplet manipulation under external fields, this paper elaborates on various external stimuli including electric fields, thermal fields, optical fields, acoustic fields, and magnetic fields. Among them, electric fields involve actuation mechanisms such as directly applied electrostatic forces and indirectly applied electrocapillary forces; thermal fields influence droplet motion through thermoresponsive wettability gradients and thermocapillary effects; optical fields cover multiple wavelengths including near-infrared, ultraviolet, and visible light; acoustic fields utilize horizontal and vertical acoustic radiation pressure or acoustic wave-induced acoustic streaming for droplet manipulation; the magnetic force acting on droplets may originate from their interior, surface, or external substrates. Based on these different transport principles, this paper comparatively analyzes the unique characteristics of droplet manipulation under the five external fields. Finally, this paper summarizes the current challenges and issues in the research of droplet manipulation on the open planar surfaces and provides an outlook on future development directions in this field. Full article
(This article belongs to the Special Issue Advanced Microfluidic Chips: Optical Sensing and Detection)
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14 pages, 5364 KiB  
Article
Study on the Microbial Inactivation and Quality Assurance of Ultrasonic-Assisted Slightly Acidic Electrolyzed Water for Mirror Carp (Cyprinus carpio L.) Fillets During Refrigerated Storage
by Qiang Zhong, Xiufang Xia and Fangfei Li
Foods 2025, 14(15), 2652; https://doi.org/10.3390/foods14152652 - 29 Jul 2025
Viewed by 238
Abstract
The advancement of non-thermal disinfection technologies represents a critical pathway for ensuring food safety, meeting environmental sustainability requirements, and meeting consumer preferences for clean-label products. This study systematically evaluated the combined preservation effect of ultrasonic-assisted slightly acidic electrolyzed water (US+SAEW) on mirror carp [...] Read more.
The advancement of non-thermal disinfection technologies represents a critical pathway for ensuring food safety, meeting environmental sustainability requirements, and meeting consumer preferences for clean-label products. This study systematically evaluated the combined preservation effect of ultrasonic-assisted slightly acidic electrolyzed water (US+SAEW) on mirror carp fillets during refrigeration. Results demonstrated that US+SAEW exhibited superior antimicrobial efficacy compared to individual US or SAEW, achieving reductions of 0.73, 0.74, and 0.79 log CFU/g in total viable counts (TVC), Aeromonas bacteria, and lactic acid bacteria counts compared to the control, respectively. Furthermore, the combined intervention significantly suppressed microbial proliferation throughout the refrigeration period while simultaneously delaying protein and lipid degradation/oxidation induced by spoilage bacteria, thereby inhibiting the formation of alkaline nitrogenous compounds. Consequently, lower levels of pH, total volatile basic nitrogen (TVB-N), protein carbonyl, and thiobarbituric acid reactive substances (TBARS) were observed in US+SAEW compared to the other treatments. Multimodal characterization through low-field nuclear magnetic resonance (LF-NMR), texture, and color analysis confirmed that US+SAEW effectively preserved quality characteristics, extending the shelf life of mirror carp fillets by four days. This study provides a novel non-thermal preservation strategy that combines microbial safety maintenance with quality retention, offering particular advantages for thermolabile food. Full article
(This article belongs to the Special Issue Innovative Muscle Foods Preservation and Packaging Technologies)
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32 pages, 5809 KiB  
Review
Superconducting Quantum Magnetometers for Brain Investigations
by Carmela Bonavolontà, Antonio Vettoliere, Pierpaolo Sorrentino and Carmine Granata
Sensors 2025, 25(15), 4625; https://doi.org/10.3390/s25154625 - 25 Jul 2025
Viewed by 424
Abstract
This review article aims to provide an overview of superconducting magnetic quantum sensors and their applications in the biomedical field, particularly in the neurological field. These quantum sensors are based on superconducting quantum interference devices (SQUIDs), the operating principles of which will be [...] Read more.
This review article aims to provide an overview of superconducting magnetic quantum sensors and their applications in the biomedical field, particularly in the neurological field. These quantum sensors are based on superconducting quantum interference devices (SQUIDs), the operating principles of which will be presented along with the most relevant characteristics. Emphasis will be placed on the magnetic flux and magnetic field noise, which are essential for applications, especially brain investigations requiring ultra-high magnetic field sensitivity. The main configurations of SQUID magnetometers used for highly sensitive applications will be shown, stressing their design aspects. In particular, the configurations based on the superconducting flux transformer and the multiloop will be explained. We will discuss the most critical application of SQUID magnetometers, magnetoencephalography, which measures the weak magnetic signals produced by neuronal currents. Starting from the realization of a multichannel system for magnetoencephalography, we will present an accurate comparison with recent systems using optically pumped magnetometers. Finally, we will discuss the main clinical applications of magnetoencephalography. Full article
(This article belongs to the Special Issue Advances and Applications of Magnetic Sensors: 2nd Edition)
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26 pages, 8292 KiB  
Review
Progress in the Circular Arc Source Structure and Magnetic Field Arc Control Technology for Arc Ion Plating
by Hao Du, Ke Zhang, Debin Liu and Wenchang Lang
Materials 2025, 18(15), 3498; https://doi.org/10.3390/ma18153498 - 25 Jul 2025
Viewed by 179
Abstract
Aiming at the goal of preparing high-quality coatings, this paper reviews the progress on circular arc source structure and magnetic field arc controlling technology in arc ion plating (AIP), with a focus on design characteristics of the different structures and configuration optimization of [...] Read more.
Aiming at the goal of preparing high-quality coatings, this paper reviews the progress on circular arc source structure and magnetic field arc controlling technology in arc ion plating (AIP), with a focus on design characteristics of the different structures and configuration optimization of the corresponding magnetic fields. The circular arc source, due to its simple structure, convenient installation, flexible target combination, high cooling efficiency, and high ionization rate and deposition rate, has shown significant application potential in AIP technology. In terms of magnetic field arc controlling technology, this paper delves into the design progress of various magnetic field configurations, including fixed magnetic fields generated by permanent magnets, dynamic rotating magnetic fields, axially symmetric magnetic fields, rotating transverse magnetic fields, and multi-mode alternating electromagnetic coupling fields. By designing the magnetic field distribution reasonably, the trajectory and velocity of the arc spot can be controlled precisely, thus reducing the generation of macroparticles, improving target utilization, and enhancing coating uniformity. In particular, the introduction of multi-mode magnetic field coupling technology has broken through the limitations of traditional single magnetic field structures, achieving comprehensive optimization of arc spot motion and plasma transport. Hopefully, these research advances provide an important theoretical basis and technical support for the application of AIP technology in the preparation for high-quality decorative and functional coatings. Full article
(This article belongs to the Section Materials Physics)
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80 pages, 962 KiB  
Review
Advancements in Hydrogels: A Comprehensive Review of Natural and Synthetic Innovations for Biomedical Applications
by Adina-Elena Segneanu, Ludovic Everard Bejenaru, Cornelia Bejenaru, Antonia Blendea, George Dan Mogoşanu, Andrei Biţă and Eugen Radu Boia
Polymers 2025, 17(15), 2026; https://doi.org/10.3390/polym17152026 - 24 Jul 2025
Viewed by 988
Abstract
In the rapidly evolving field of biomedical engineering, hydrogels have emerged as highly versatile biomaterials that bridge biology and technology through their high water content, exceptional biocompatibility, and tunable mechanical properties. This review provides an integrated overview of both natural and synthetic hydrogels, [...] Read more.
In the rapidly evolving field of biomedical engineering, hydrogels have emerged as highly versatile biomaterials that bridge biology and technology through their high water content, exceptional biocompatibility, and tunable mechanical properties. This review provides an integrated overview of both natural and synthetic hydrogels, examining their structural properties, fabrication methods, and broad biomedical applications, including drug delivery systems, tissue engineering, wound healing, and regenerative medicine. Natural hydrogels derived from sources such as alginate, gelatin, and chitosan are highlighted for their biodegradability and biocompatibility, though often limited by poor mechanical strength and batch variability. Conversely, synthetic hydrogels offer precise control over physical and chemical characteristics via advanced polymer chemistry, enabling customization for specific biomedical functions, yet may present challenges related to bioactivity and degradability. The review also explores intelligent hydrogel systems with stimuli-responsive and bioactive functionalities, emphasizing their role in next-generation healthcare solutions. In modern medicine, temperature-, pH-, enzyme-, light-, electric field-, magnetic field-, and glucose-responsive hydrogels are among the most promising “smart materials”. Their ability to respond to biological signals makes them uniquely suited for next-generation therapeutics, from responsive drug systems to adaptive tissue scaffolds. Key challenges such as scalability, clinical translation, and regulatory approval are discussed, underscoring the need for interdisciplinary collaboration and continued innovation. Overall, this review fosters a comprehensive understanding of hydrogel technologies and their transformative potential in enhancing patient care through advanced, adaptable, and responsive biomaterial systems. Full article
37 pages, 3791 KiB  
Review
The Advancing Understanding of Magnetorheological Fluids and Elastomers: A Comparative Review Analyzing Mechanical and Viscoelastic Properties
by Salah Rouabah, Fadila-Yasmina Didouche, Abdelmalek Khebli, Salah Aguib and Noureddine Chikh
Magnetochemistry 2025, 11(8), 62; https://doi.org/10.3390/magnetochemistry11080062 - 24 Jul 2025
Viewed by 291
Abstract
Magnetorheological fluids (MRFs) and elastomers (MREs) are two types of smart materials that exhibit modifiable rheological properties in response to an applied magnetic field. Although they share a similarity in their magnetorheological response, these two materials differ in their nature, structure, and mechanical [...] Read more.
Magnetorheological fluids (MRFs) and elastomers (MREs) are two types of smart materials that exhibit modifiable rheological properties in response to an applied magnetic field. Although they share a similarity in their magnetorheological response, these two materials differ in their nature, structure, and mechanical behavior when exposed to a magnetic field. They also have distinct application differences due to their specific rheological properties. These fundamental differences therefore influence their properties and applications in various industrial fields. This review provides a synthesis of the distinct characteristics of MRFs and MREs. The differences in their composition, rheological behavior, mechanical properties, and respective applications are summarized and highlighted. This analysis will enable a comprehensive understanding of these differences, thereby allowing for the appropriate selection of the material based on the specific requirements of a given application and fostering the development of new applications utilizing these MR materials. Full article
(This article belongs to the Section Applications of Magnetism and Magnetic Materials)
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10 pages, 3121 KiB  
Article
Influence of Niobium Substitution on the Properties of Pb2Fe2O5 Thin Films Synthesized via Reactive Magnetron Sputtering
by Benas Beklešovas, Vytautas Stankus and Aleksandras Iljinas
Coatings 2025, 15(8), 863; https://doi.org/10.3390/coatings15080863 - 23 Jul 2025
Viewed by 240
Abstract
Lead ferrite (Pb2Fe2O5) is a promising multiferroic material that exhibits both ferroelectric and magnetic properties at room temperature. This study investigates how substituting niobium and adjusting the synthesis temperature affect the structural, morphological, and ferroelectric properties of [...] Read more.
Lead ferrite (Pb2Fe2O5) is a promising multiferroic material that exhibits both ferroelectric and magnetic properties at room temperature. This study investigates how substituting niobium and adjusting the synthesis temperature affect the structural, morphological, and ferroelectric properties of lead ferrite thin films deposited via reactive magnetron sputtering. Niobium-substituted PFO films (Pb2Fe2(1−x)Nb2xO5), where x corresponds to Nb2O5 contents of 3 wt.%, 5 wt.% and 10 wt.%, were prepared for this study, and denoted as PFONb3, PFONb5 and PFONb10, respectively. X-ray diffraction analysis confirmed the formation of Nb-substituted PFO phases, while polarization–electric field measurements demonstrated an increase in remnant polarization (Pr), with higher Nb content reaching a maximum Pr of 65 µC/cm2 at 10 wt.% Nb and a substrate temperature of 500 °C. Scanning electron microscopy and energy-dispersive spectroscopy revealed a uniform distribution of elements and a well-defined surface structure. These results highlight the need to fine tune synthesis parameters, such as temperature and substitution concentrations, to achieve optimal ferroelectric characteristics. Full article
(This article belongs to the Special Issue Advances in Novel Coatings)
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18 pages, 1169 KiB  
Article
Multi-Dimensional Analysis of Quality-Related Traits Affecting the Taste of Main Cultivated Japonica Rice Varieties in Northern China
by Hongwei Yang, Liying Zhang, Xiangquan Gao, Shi Han, Zuobin Ma and Lili Wang
Agronomy 2025, 15(8), 1757; https://doi.org/10.3390/agronomy15081757 - 22 Jul 2025
Viewed by 325
Abstract
The quality of rice, one of the most important food crops in the world, is directly related to people’s dietary experience and nutritional health. With the improvement in living standards, consumer requirements for the taste quality of rice are becoming increasingly strict. Japonica [...] Read more.
The quality of rice, one of the most important food crops in the world, is directly related to people’s dietary experience and nutritional health. With the improvement in living standards, consumer requirements for the taste quality of rice are becoming increasingly strict. Japonica rice occupies an important position in rice production due to its rich genetic diversity and excellent agronomic characteristics. In this study, LJ433, JY653, LJ218, LJ177, LY66, and LX21, which are mainly popularized in northern China and have different taste values, were selected as the experimental subjects, and YJ219, which won the gold award in the third China high-quality rice variety taste quality evaluation, was taken as the control (CK). Low-field nuclear magnetic resonance and spectral analysis were adopted as the main detection techniques. The effects of free water (peak area increased by 13.24–86.68% when p < 0.05), bound water, appearance characteristics (such as chalkiness, which decreased by 18.48–86.48%), and chemical composition (amylose content decreased by 3.76–26.47%) on the taste value of rice were systematically analyzed, and a multi-dimensional “appearance–palatability–nutrition” evaluation system was constructed. The experimental results indicated that increasing the free water content, reducing the chalkiness and chemical component content could significantly improve the taste value of rice (p < 0.05). The results of this research provide a theoretical basis for breeding new high-yield and high-quality rice varieties and have guiding significance for the practice of rice planting and processing. Full article
(This article belongs to the Section Plant-Crop Biology and Biochemistry)
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23 pages, 6480 KiB  
Article
Mechanism Analysis and Evaluation of Formation Physical Property Damage in CO2 Flooding in Tight Sandstone Reservoirs of Ordos Basin, China
by Qinghua Shang, Yuxia Wang, Dengfeng Wei and Longlong Chen
Processes 2025, 13(7), 2320; https://doi.org/10.3390/pr13072320 - 21 Jul 2025
Viewed by 434
Abstract
Capturing CO2 emitted by coal chemical enterprises and injecting it into oil reservoirs not only effectively improves the recovery rate and development efficiency of tight oil reservoirs in the Ordos Basin but also addresses the carbon emission problem constraining the development of [...] Read more.
Capturing CO2 emitted by coal chemical enterprises and injecting it into oil reservoirs not only effectively improves the recovery rate and development efficiency of tight oil reservoirs in the Ordos Basin but also addresses the carbon emission problem constraining the development of the region. Since initiating field experiments in 2012, the Ordos Basin has become a significant base for CCUS (Carbon capture, Utilization, and Storage) technology application and demonstration in China. However, over the years, projects have primarily focused on enhancing the recovery rate of CO2 flooding, while issues such as potential reservoir damage and its extent have received insufficient attention. This oversight hinder the long-term development and promotion of CO2 flooding technology in the region. Experimental results were comprehensively analyzed using techniques including nuclear magnetic resonance (NMR), X-ray diffraction (XRD), scanning electron microscopy (SEM), inductively coupled plasma (ICP), and ion chromography (IG). The findings indicate that under current reservoir temperature and pressure conditions, significant asphaltene deposition and calcium carbonate precipitation do not occur during CO2 flooding. The reservoir’s characteristics-high feldspar content, low carbon mineral content, and low clay mineral content determine that the primary mechanism affecting physical properties under CO2 flooding in the Chang 4 + 5 tight sandstone reservoir is not, as traditional understand, carbon mineral dissolution or primary clay mineral expansion and migration. Instead, feldspar corrosion and secondary particles migration are the fundamental reasons for the changes in reservoir properties. As permeability increases, micro pore blockage decreases, and the damaging effect of CO2 flooding on reservoir permeability diminishes. Permeability and micro pore structure are therefore significant factors determining the damage degree of CO2 flooding inflicts on tight reservoirs. In addition, temperature and pressure have a significant impact on the extent of reservoir damage caused by CO2 flooding in the study region. At a given reservoir temperature, increasing CO2 injection pressure can mitigate reservoir damage. It is recommended to avoid conducting CO2 flooding projects in reservoirs with severe pressure attenuation, low permeability, and narrow pore throats as much as possible to prevent serious damage to the reservoir. At the same time, the production pressure difference should be reasonably controlled during the production process to reduce the risk and degree of calcium carbonate precipitation near oil production wells. Full article
(This article belongs to the Section Energy Systems)
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13 pages, 9148 KiB  
Article
Investigation of Thermoelectric Properties in Altermagnet RuO2
by Jun Liu, Chunmin Ning, Xiao Liu, Sicong Zhu and Shuling Wang
Nanomaterials 2025, 15(14), 1129; https://doi.org/10.3390/nano15141129 - 21 Jul 2025
Viewed by 306
Abstract
An altermagnet, characterized by its distinctive magnetic properties, may hold potential applications in diverse fields such as magnetic materials, spintronics, data storage, and quantum computing. As a prototypical altermagnet, RuO2 exhibits spin polarization and demonstrates the advantageous characteristics of high electrical conductivity [...] Read more.
An altermagnet, characterized by its distinctive magnetic properties, may hold potential applications in diverse fields such as magnetic materials, spintronics, data storage, and quantum computing. As a prototypical altermagnet, RuO2 exhibits spin polarization and demonstrates the advantageous characteristics of high electrical conductivity and low thermal conductivity. These exceptional properties endow it with considerable promise in the emerging field of thermal spintronics. We studied the electronic structure and thermoelectric properties of RuO2; the constructed RuO2/TiO2/RuO2 all-antiferromagnetic tunnel junction (AFMTJ) exhibited thermally induced magnetoresistance (TIMR), reaching a maximum TIMR of 1756% at a temperature gradient of 5 K. Compared with prior studies on RuO2-based antiferromagnetic tunnel junctions, the novelty of this work lies in the thermally induced magnetoresistance based on its superior thermoelectric properties. In parallel structures, the spin-down current dominates the transmission spectrum, whereas in antiparallel structures, the spin-up current governs the transmission spectrum, underscoring the spin-polarized thermal transport. In addition, thermoelectric efficiency emphasizes the potential of RuO2 to link antiferromagnetic robustness with ferromagnetic spin functionality. These findings promote the development of efficient spintronic devices and spin-based storage technology for waste heat recovery and emphasize the role of spin splitting in zero-magnetization systems. Full article
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18 pages, 6380 KiB  
Article
Synthesis and Application of Fe3O4–ZrO2 Magnetic Nanoparticles for Fluoride Adsorption from Water
by Israel Águila-Martínez, José Antonio Pérez-Tavares, Efrén González-Aguiñaga, Pablo Eduardo Cardoso-Avila, Héctor Pérez Ladrón de Guevara and Rita Patakfalvi
Inorganics 2025, 13(7), 248; https://doi.org/10.3390/inorganics13070248 - 19 Jul 2025
Viewed by 616
Abstract
This study presents the synthesis, characterization, and application of magnetic magnetite–zirconium dioxide (Fe3O4–ZrO2) nanoparticles as an efficient nanoadsorbent for fluoride removal from water. The nanoparticles were synthesized using a wet chemical co-precipitation method with Fe/Zr molar ratios [...] Read more.
This study presents the synthesis, characterization, and application of magnetic magnetite–zirconium dioxide (Fe3O4–ZrO2) nanoparticles as an efficient nanoadsorbent for fluoride removal from water. The nanoparticles were synthesized using a wet chemical co-precipitation method with Fe/Zr molar ratios of 1:1, 1:2, and 1:4, and characterized using Fourier-transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), X-ray diffraction (XRD), and energy-dispersive X-ray spectroscopy (EDS). FTIR analysis confirmed the presence of Fe3O4 and ZrO2 functional groups, while XRD showed that increased Zr content led to a dominant amorphous phase. SEM and EDS analyses revealed quasi-spherical and elongated morphologies with uniform elemental distribution, maintaining the designed Fe/Zr ratios. Preliminary adsorption tests identified the Fe/Zr = 1:1 (M1) nanoadsorbent as the most effective due to its high surface homogeneity and optimal fluoride-binding characteristics. Adsorption experiments demonstrated that the material achieved a maximum fluoride adsorption capacity of 70.4 mg/g at pH 3, with the adsorption process best fitting the Temkin isotherm model (R2 = 0.987), suggesting strong adsorbate–adsorbent interactions. pH-dependent studies confirmed that adsorption efficiency decreased at higher pH values due to electrostatic repulsion and competition with hydroxyl ions. Competitive ion experiments revealed that common anions such as nitrate, chloride, and sulfate had negligible effects on fluoride adsorption, whereas bicarbonate, carbonate, and phosphate reduced removal efficiency due to their strong interactions with active adsorption sites. The Fe3O4–ZrO2 nanoadsorbent exhibited excellent magnetic properties, facilitating rapid and efficient separation using an external magnetic field, making it a promising candidate for practical water treatment applications. Full article
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18 pages, 2708 KiB  
Article
Mathematical Model of a Semiconductor Structure Based on Vanadium Dioxide for the Mode of a Conductive Phase
by Oleksii Kachura, Valeriy Kuznetsov, Mykola Tryputen, Vitalii Kuznetsov, Sergei Kolychev, Artur Rojek and Petro Hubskyi
Electronics 2025, 14(14), 2884; https://doi.org/10.3390/electronics14142884 - 18 Jul 2025
Viewed by 237
Abstract
This study presents a comprehensive mathematical model of a semiconductor structure based on vanadium dioxide (VO2), specifically in its conductive phase. The model was developed using the finite element method (FEM), enabling detailed simulation of the formation of a conductive [...] Read more.
This study presents a comprehensive mathematical model of a semiconductor structure based on vanadium dioxide (VO2), specifically in its conductive phase. The model was developed using the finite element method (FEM), enabling detailed simulation of the formation of a conductive channel under the influence of low-frequency alternating voltage (50 Hz). The VO2 structure under investigation exhibits pronounced electric field concentration at the surface, where the field strength reaches approximately 5 × 104 V/m, while maintaining a more uniform distribution of around 2 × 104 V/m within the bulk of the material. The simulation results were validated experimentally using a test circuit. Minor deviations—no greater than 8%—were observed between the simulated and measured current values, attributed to magnetic core saturation and modeling assumptions. A distinctive feature of the model is its ability to incorporate the nonlinear dependencies of VO2’s electrical properties on frequency. Analytical expressions were derived for the magnetic permeability and resistivity of VO2, demonstrating excellent agreement with experimental data. The coefficients of determination (R2) for the frequency dependence of magnetic permeability and resistance were found to be 0.9976 and 0.9999, respectively. The current version of the model focuses exclusively on the conductive phase and does not include the thermally induced metal–insulator phase transition characteristic of VO2. The study confirms that VO2-based structures exhibit high responsiveness and nonlinear switching behavior, making them suitable for applications in electronic surge protection, current limiting, and switching elements. The developed model provides a reliable and physically grounded tool for the design and optimization components based on VO2 in power electronics and protective circuitry. Full article
(This article belongs to the Section Electronic Materials, Devices and Applications)
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