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19 pages, 4156 KiB  
Article
Experimental and Numerical Analyses of Diameter Reduction via Laser Turning with Respect to Laser Parameters
by Emin O. Bastekeli, Haci A. Tasdemir, Adil Yucel and Buse Ortac Bastekeli
J. Manuf. Mater. Process. 2025, 9(8), 258; https://doi.org/10.3390/jmmp9080258 - 1 Aug 2025
Viewed by 103
Abstract
In this study, a novel direct laser beam turning (DLBT) approach is proposed for the precision machining of AISI 308L austenitic stainless steel, which eliminates the need for cutting tools and thereby eradicates tool wear and vibration-induced surface irregularities. A nanosecond-pulsed Nd:YAG fiber [...] Read more.
In this study, a novel direct laser beam turning (DLBT) approach is proposed for the precision machining of AISI 308L austenitic stainless steel, which eliminates the need for cutting tools and thereby eradicates tool wear and vibration-induced surface irregularities. A nanosecond-pulsed Nd:YAG fiber laser (λ = 1064 nm, spot size = 0.05 mm) was used, and Ø1.6 mm × 20 mm cylindrical rods were processed under ambient conditions without auxiliary cooling. The experimental framework systematically evaluated the influence of scanning speed, pulse frequency, and the number of laser passes on dimensional accuracy and material removal efficiency. The results indicate that a maximum diameter reduction of 0.271 mm was achieved at a scanning speed of 3200 mm/s and 50 kHz, whereas 0.195 mm was attained at 6400 mm/s and 200 kHz. A robust second-order polynomial correlation (R2 = 0.99) was established between diameter reduction and the number of passes, revealing the high predictability of the process. Crucially, when the scanning speed was doubled, the effective fluence was halved, considerably influencing the ablation characteristics. Despite the low fluence, evidence of material evaporation at elevated frequencies due to the incubation effect underscores the complex photothermal dynamics governing the process. This work constitutes the first comprehensive quantification of pass-dependent diameter modulation in DLBT and introduces a transformative, noncontact micromachining strategy for hard-to-machine alloys. The demonstrated precision, repeatability, and thermal control position DLBT as a promising candidate for next-generation manufacturing of high-performance miniaturized components. Full article
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37 pages, 5856 KiB  
Article
Machine Learning-Based Recommender System for Pulsed Laser Ablation in Liquid: Recommendation of Optimal Processing Parameters for Targeted Nanoparticle Size and Concentration Using Cosine Similarity and KNN Models
by Anesu Nyabadza and Dermot Brabazon
Crystals 2025, 15(7), 662; https://doi.org/10.3390/cryst15070662 - 20 Jul 2025
Viewed by 317
Abstract
Achieving targeted nanoparticle (NP) size and concentration combinations in Pulsed Laser Ablation in Liquid (PLAL) remains a challenge due to the highly nonlinear relationships between laser processing parameters and NP properties. Despite the promise of PLAL as a surfactant-free, scalable synthesis method, its [...] Read more.
Achieving targeted nanoparticle (NP) size and concentration combinations in Pulsed Laser Ablation in Liquid (PLAL) remains a challenge due to the highly nonlinear relationships between laser processing parameters and NP properties. Despite the promise of PLAL as a surfactant-free, scalable synthesis method, its industrial adoption is hindered by empirical trial-and-error approaches and the lack of predictive tools. The current literature offers limited application of machine learning (ML), particularly recommender systems, in PLAL optimization and automation. This study addresses this gap by introducing a ML-based recommender system trained on a 3 × 3 design of experiments with three replicates covering variables, such as fluence (1.83–1.91 J/cm2), ablation time (5–25 min), and laser scan speed (3000–3500 mm/s), in producing magnesium nanoparticles from powders. Multiple ML models were evaluated, including K-Nearest Neighbors (KNN), Extreme Gradient Boosting (XGBoost), Random Forest, and Decision trees. The DT model achieved the best performance for predicting the NP size with a mean percentage error (MPE) of 10%. The XGBoost model was optimal for predicting the NP concentration attaining a competitive MPE of 2%. KNN and Cosine similarity recommender systems were developed based on a database generated by the ML predictions. This intelligent, data-driven framework demonstrates the potential of ML-guided PLAL for scalable, precise NP fabrication in industrial applications. Full article
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16 pages, 10306 KiB  
Article
Fabrication and Characterization of Flexible pH Sensors Based on Pulsed Laser-Ablated Graphene/MoS2 Interdigitated Electrodes
by Zhaochi Chen, Chengche Liu and Minh-Quang Tran
Nanomaterials 2025, 15(14), 1115; https://doi.org/10.3390/nano15141115 - 18 Jul 2025
Viewed by 407
Abstract
Point-of-care (POC) diagnostic technologies have become essential for the real-time monitoring and management of chronic wounds, where maintaining a moist environment and controlling pH levels are critical for effective healing. In this study, a flexible pH sensor based on a graphene/molybdenum disulfide (graphene/MoS [...] Read more.
Point-of-care (POC) diagnostic technologies have become essential for the real-time monitoring and management of chronic wounds, where maintaining a moist environment and controlling pH levels are critical for effective healing. In this study, a flexible pH sensor based on a graphene/molybdenum disulfide (graphene/MoS2) composite interdigitated electrode (IDE) structure was fabricated using pulsed laser ablation. The pH sensor, with an active area of 30 mm × 30 mm, exhibited good adhesion to the polyethylene terephthalate (PET) substrate and maintained structural integrity under repeated bending cycles. Precise ablation was achieved under optimized conditions of 4.35 J/cm2 laser fluence, a repetition rate of 300 kHz, and a scanning speed of 500 mm/s, enabling the formation of defect-free IDE arrays without substrate damage. The influence of laser processing parameters on the surface morphology, electrical conductivity, and wettability of the composite thin films was systematically characterized. The fabricated pH sensor exhibited high sensitivity (~4.7% change in current per pH unit) across the pH 2–10 range, rapid response within ~5.2 s, and excellent mechanical stability under 100 bending cycles with negligible performance degradation. Moreover, the sensor retained > 95% of its stable sensitivity after 7 days of ambient storage. Furthermore, the pH response behavior was evaluated for electrode structures with different pitches, demonstrating that structural design parameters critically impact sensing performance. These results offer valuable insights into the scalable fabrication of flexible, wearable pH sensors, with promising applications in wound monitoring and personalized healthcare systems. Full article
(This article belongs to the Special Issue Laser-Based Nano Fabrication and Nano Lithography: Second Edition)
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33 pages, 5307 KiB  
Article
SiPM Developments for the Time-Of-Propagation Detector of the Belle II Experiment
by Flavio Dal Corso, Jakub Kandra, Roberto Stroili and Ezio Torassa
Sensors 2025, 25(13), 4018; https://doi.org/10.3390/s25134018 - 27 Jun 2025
Viewed by 275
Abstract
Belle II is a particle physics experiment working at an high luminosity collider within a hard irradiation environment. The Time-Of-Propagation detector, aimed at the charged particle identification, surrounds the Belle II tracking detector on the barrel part. This detector is composed by 16 [...] Read more.
Belle II is a particle physics experiment working at an high luminosity collider within a hard irradiation environment. The Time-Of-Propagation detector, aimed at the charged particle identification, surrounds the Belle II tracking detector on the barrel part. This detector is composed by 16 modules, each module contains a finely fused silica bar, coupled to microchannel plate photomultiplier tube (MCP-PMT) photo-detectors and readout by high-speed electronics. The MCP-PMT lifetime at the nominal collider luminosity is about one year, this is due to the high photon background degrading the quantum efficiency of the photocathode. An alternative to these MCP-PMTs is multi-pixel photon counters (MPPC), known as silicon photomultipliers (SiPM). The SiPMs, in comparison to MCP-PMTs, have a lower cost, higher photon detection efficiency and are unaffected by the presence of a magnetic field, but also have a higher dark count rate that rapidly increases with the integrated neutron flux. The dark count rate can be mitigated by annealing the damaged devices and/or operating them at low temperatures. We tested SiPMs, with different dimensions and pixel sizes from different producers, to study their time resolution (the main constraint that has to satisfy the photon detector) and to understand their behavior and tolerance to radiation. For these studies we irradiated the devices to radiation up to 5×10111 MeV neutrons equivalent (neq) per cm2 fluences; we also started studying the effect of annealing on dark count rates. We performed several measurements on these devices, on top of the dark count rate, at different conditions in terms of overvoltage and temperatures. These measurements are: IV-curves, amplitude spectra, time resolution. For the last two measurements we illuminated the devices with a picosecond pulsed laser at very low intensities (with a number of detected photons up to about twenty). We present results mainly on two types of SiPMs. A new SiPM prototype developed in collaboration with FBK with the aim of improving radiation hardness, is expected to be delivered in September 2025. Full article
(This article belongs to the Section Physical Sensors)
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14 pages, 4632 KiB  
Article
Resistive Heater Element Based on a Conductive Line in AlN Ceramic Fabricated by Laser Processing
by Nikolay Nedyalkov, Nadya Stankova, Fatme Padikova, Stefan Valkov, Genoveva Atanasova, Tina Dilova and Lyubomir Aleksandrov
Materials 2025, 18(12), 2861; https://doi.org/10.3390/ma18122861 - 17 Jun 2025
Viewed by 372
Abstract
The purpose of this work is to demonstrate that laser-induced conductive tracts in AlN ceramic can be applied for fabrication of an integrated resistive heating element. Nanosecond laser processing at a wavelength of 1064 nm of ceramic in vacuum is used for a [...] Read more.
The purpose of this work is to demonstrate that laser-induced conductive tracts in AlN ceramic can be applied for fabrication of an integrated resistive heating element. Nanosecond laser processing at a wavelength of 1064 nm of ceramic in vacuum is used for a formation of conductive areas. It is demonstrated that the applied laser fluence and the number of pulses influence strongly the electrical properties of the material in the irradiated zone. The resistance value of the produced tracks with a length of about 4 mm and width of about 1 mm may vary from 17 to about 2000 Ohms, depending on the processing conditions. The material in the processed zone is characterized by means of surface composition, morphology, and electric properties. It is found that the electrical conductivity of the formed structure is based on the ceramic decomposition and formation of aluminum layer. The analysis of the influence of the temperature on the electrical resistance value shows that the material’s conductivity could be preserved after annealing, as in the present study it is confirmed up to 300 °C. The ability of the formed tracks to serve as a basis element of ceramic integrated resistive heater is studied by applying DC voltage. It is found that the fabricated element can be used with a high reliability to about 90 °C without special requirements for contact design and encapsulation. Operation at higher temperatures is also demonstrated as the maximal one achieved is about 150 °C at 10V. The performance of the heater is investigated and discussed as the operation range is defined. The proposed element can be a basis for a design of an integrated heater in ceramic with high stability and applications in everyday life and research. Full article
(This article belongs to the Special Issue Advances in Laser Processing Technology of Materials—Second Edition)
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23 pages, 9331 KiB  
Article
Non-Ideal Hall MHD Rayleigh–Taylor Instability in Plasma Induced by Nanosecond and Intense Femtosecond Laser Pulses
by Roman S. Zemskov, Maxim V. Barkov, Evgeniy S. Blinov, Konstantin F. Burdonov, Vladislav N. Ginzburg, Anton A. Kochetkov, Aleksandr V. Kotov, Alexey A. Kuzmin, Sergey E. Perevalov, Il’ya A. Shaikin, Sergey E. Stukachev, Ivan V. Yakovlev, Alexander A. Soloviev, Andrey A. Shaykin, Efim A. Khazanov, Julien Fuchs and Mikhail V. Starodubtsev
Plasma 2025, 8(2), 23; https://doi.org/10.3390/plasma8020023 - 10 Jun 2025
Viewed by 1364
Abstract
A pioneering detailed comparative study of the dynamics of plasma flows generated by high-power nanosecond and high-intensity femtosecond laser pulses with similar fluences of up to 3×104 J/cm2 is presented. The experiments were conducted on the petawatt laser facility [...] Read more.
A pioneering detailed comparative study of the dynamics of plasma flows generated by high-power nanosecond and high-intensity femtosecond laser pulses with similar fluences of up to 3×104 J/cm2 is presented. The experiments were conducted on the petawatt laser facility PEARL using two types of high-power laser radiation: femtosecond pulses with energy exceeding 10 J and a duration less than 60 fs, and nanosecond pulses with energy exceeding 10 J and a duration on the order of 1 ns. In the experiments, high-velocity (>100 km/s) flows of «femtosecond» (created by femtosecond laser pulses) and «nanosecond» plasmas propagated in a vacuum across a uniform magnetic field with a strength over 14 T. A significant difference in the dynamics of «femtosecond» and «nanosecond» plasma flows was observed: (i) The «femtosecond» plasma initially propagated in a vacuum (no B-field) as a collimated flow, while the «nanosecond» flow diverged. (ii) The «nanosecond» plasma interacting with external magnetic field formed a quasi-spherical cavity with Rayleigh–Taylor instability flutes. In the case of «femtosecond» plasma, such flutes were not observed, and the flow was immediately redirected into a narrow plasma sheet (or «tongue») propagating across the magnetic field at an approximately constant velocity. (iii) Elongated «nanosecond» and «femtosecond» plasma slabs interacting with a transverse magnetic field broke up into Rayleigh–Taylor «tongues». (iv) The ends of these «tongues» in the femtosecond case twisted into vortex structures aligned with the ion motion in the external magnetic field, whereas the «tongues» in the nanosecond case were randomly oriented. It was suggested that the twisting of femtosecond «tongues» is related to Hall effects. The experimental results are complemented by and consistent with numerical 3D magnetohydrodynamic simulations. The potential applications of these findings for astrophysical objects, such as short bursts in active galactic nuclei, are discussed. Full article
(This article belongs to the Special Issue New Insights into Plasma Theory, Modeling and Predictive Simulations)
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53 pages, 7134 KiB  
Review
Effects of Process Parameters on Pulsed Laser Micromachining for Glass-Based Microfluidic Devices
by Mrwan Alayed, Nojoud Al Fayez, Salman Alfihed, Naif Alshamrani and Fahad Alghannam
Materials 2025, 18(11), 2657; https://doi.org/10.3390/ma18112657 - 5 Jun 2025
Viewed by 816
Abstract
Glass-based microfluidic devices are essential for applications such as diagnostics and drug discovery, which utilize their optical clarity and chemical stability. This review systematically analyzes pulsed laser micromachining as a transformative technique for fabricating glass-based microfluidic devices, addressing the limitations of conventional methods. [...] Read more.
Glass-based microfluidic devices are essential for applications such as diagnostics and drug discovery, which utilize their optical clarity and chemical stability. This review systematically analyzes pulsed laser micromachining as a transformative technique for fabricating glass-based microfluidic devices, addressing the limitations of conventional methods. By examining three pulse regimes—long (≥nanosecond), short (picosecond), and ultrashort (femtosecond)—this study evaluates how laser parameters (fluence, scanning speed, pulse duration, repetition rate, wavelength) and glass properties influence ablation efficiency and quality. A higher fluence improves the material ablation efficiency across all the regimes but poses risks of thermal damage or plasma shielding in ultrashort pulses. Optimizing the scanning speed balances the depth and the surface quality, with slower speeds enhancing the channel depth but requiring heat accumulation mitigation. Shorter pulses (femtosecond regime) achieve greater precision (feature resolution) and minimal heat-affected zones through nonlinear absorption, while long pulses enable rapid deep-channel fabrication but with increased thermal stress. Elevating the repetition rate improves the material ablation rates but reduces the surface quality. The influence of wavelength on efficiency and quality varies across the three pulse regimes. Material selection is critical to outcomes and potential applications: fused silica demonstrates a superior surface quality due to low thermal expansion, while soda–lime glass provides cost-effective prototyping. The review emphasizes the advantages of laser micromachining and the benefits of a wide range of applications. Future directions should focus on optimizing the process parameters to improve the efficiency and quality of the produced devices at a lower cost to expand their uses in biomedical, environmental, and quantum applications. Full article
(This article belongs to the Section Manufacturing Processes and Systems)
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50 pages, 6501 KiB  
Review
A State-of-the-Art Review on Micro-Machining of Nitinol Shape Memory Alloys and Optimization of Process Variables Considering the Future Trends of Research
by Souradeep Dutta, Deba Kumar Sarma, Jay Vora, Rakesh Chaudhari, Abhijit Bhowmik, Priyaranjan Samal and Sakshum Khanna
J. Manuf. Mater. Process. 2025, 9(6), 183; https://doi.org/10.3390/jmmp9060183 - 30 May 2025
Cited by 2 | Viewed by 3611
Abstract
The miniaturization of smart materials has become a new trend in the modern manufacturing industry due to its enormous application in the aerospace, biomedical, and automobile sectors. Nickel–titanium (NiTi)-based binary shape memory alloys (SMAs) are one of the smart materials with certain supreme [...] Read more.
The miniaturization of smart materials has become a new trend in the modern manufacturing industry due to its enormous application in the aerospace, biomedical, and automobile sectors. Nickel–titanium (NiTi)-based binary shape memory alloys (SMAs) are one of the smart materials with certain supreme features like shape memory effect, pseudo-elasticity, high ductility, strong corrosion-resistance, and elevated wear resistance. For this, several micro-machining processes have been developed to machine NiTi SMAs. This paper summarizes all of the conventional and non-conventional micro-machining processes employed to machine NiTi SMAs. In this review process, the surface integrity, dimensional accuracy of the machined surface, cutting force and tool wear analysis during conventional and non-conventional micro-machining of NiTi SMA are evaluated mostly with the aid of input process variables like cutting speed, depth of cut, width of cut, types of coolants, tool coating, discharge voltage, capacitance, laser fluence, pulse duration, scan speed, electrolysis concentration and gap voltage. The optimization of process parameters using different methods during conventional and non-conventional micro-machining of NiTi SMAs is also analyzed. The problems faced during conventional micro-machining of NiTi SMAs are overcome by non-conventional micro-machining processes as discussed. The present study aims to recognize potential developments in the improvement of the micro-machinability of NiTi SMAs. Full article
(This article belongs to the Special Issue Advances in High-Performance Machining Operations)
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11 pages, 2615 KiB  
Article
Electronic Excitation-Induced Modification in Electronic Structure and Magnetism for Pulsed Laser Deposited Barium Strontium Titanate Thin Films with Changing Fe Impurity
by Arkaprava Das and Carla Bittencourt
Materials 2025, 18(11), 2534; https://doi.org/10.3390/ma18112534 - 28 May 2025
Viewed by 337
Abstract
This study presents a comprehensive analysis of the modifications in electronic structure and magnetism resulting from electronic excitation in pulsed laser-deposited Ba0.7Sr0.3FexTi(1−x)O3 thin films, specifically for compositions with x = 0, 0.1, and 0.2. [...] Read more.
This study presents a comprehensive analysis of the modifications in electronic structure and magnetism resulting from electronic excitation in pulsed laser-deposited Ba0.7Sr0.3FexTi(1−x)O3 thin films, specifically for compositions with x = 0, 0.1, and 0.2. To investigate the effects of electronic energy loss (Se) within the lattice, we performed 120 MeV Ag ion irradiation at varying fluences (1 × 1012 ions/cm2 and 5 × 1012 ions/cm2) and compared the results with those of the pristine sample. The Se induces lattice damage by generating ion tracks along its trajectory, which subsequently leads to a reduction in peak intensity observed in X-ray diffraction patterns. Atomic force microscopy micrographs indicate that irradiation resulted in a decrease in average grain height, accompanied by a more homogeneous grain distribution. X-ray photoelectron spectroscopy reveals a significant increase in oxygen vacancy (VO) concentration as ion fluence increases. Ferromagnetism exhibits progressive deterioration with rising irradiation fluence. Due to the high Se and multiple ion impact processes, cation interstitial defects are highly likely, which may overshadow the influence of VO in inducing ferromagnetism, thereby contributing to an overall decline in magnetic properties. Furthermore, the elevated Se potentially disrupts bound magnetic polarons, leading to a degradation of long-range ferromagnetism. Collectively, this investigation elucidates the electronic excitation-induced modulation of ferromagnetism, employing Fe impurity incorporation and irradiation techniques for precise defect engineering. Full article
(This article belongs to the Special Issue Advanced Nanomaterials and Nanocomposites for Energy Conversion)
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23 pages, 5205 KiB  
Article
Femtosecond Laser-Engineered β-TCP Scaffolds: A Comparative Study of Green-Synthesized AgNPs vs. Ion Doping Against S. aureus for Bone Regeneration
by Marco Oliveira, Liliya Angelova, Georgi Avdeev, Liliana Grenho, Maria Helena Fernandes and Albena Daskalova
Int. J. Mol. Sci. 2025, 26(10), 4888; https://doi.org/10.3390/ijms26104888 - 20 May 2025
Viewed by 570
Abstract
Implant-associated infections, particularly those linked to Staphylococcus aureus (S. aureus), continue to compromise the clinical success of β-tricalcium phosphate (β-TCP) implants despite their excellent biocompatibility and osteoconductivity. This investigation aims to tackle these challenges by integrating femtosecond (fs)-laser surface processing with [...] Read more.
Implant-associated infections, particularly those linked to Staphylococcus aureus (S. aureus), continue to compromise the clinical success of β-tricalcium phosphate (β-TCP) implants despite their excellent biocompatibility and osteoconductivity. This investigation aims to tackle these challenges by integrating femtosecond (fs)-laser surface processing with two complementary strategies: ion doping and functionalization with green-synthesized silver nanoparticles (AgNPs). AgNPs were produced via fs-laser photoreduction using green tea leaf extract (GTLE), noted for its anti-inflammatory and antioxidant properties. Fs-laser processing was applied to modify β-TCP scaffolds by systematically varying scanning velocities, fluences, and patterns. Lower scanning velocities generated organized nanostructures with enhanced roughness and wettability, as confirmed by scanning electron microscopy (SEM), optical profilometry, and contact angle measurements, whereas higher laser energies induced significant phase transitions between hydroxyapatite (HA) and α-tricalcium phosphate (α-TCP), as revealed by X-ray diffraction (XRD). AgNP-functionalized scaffolds demonstrated markedly superior antibacterial activity against S. aureus compared to the ion-doped variants, attributed to the synergistic interplay of nanostructure-mediated surface disruption and AgNP-induced bactericidal mechanisms. Although ion-doped scaffolds exhibited limited direct antibacterial effects, they showed concentration-dependent activity in indirect assays, likely due to controlled ion release. Both strategies promoted osteogenic differentiation of human bone marrow mesenchymal stem cells (hBM-MSCs) under defined conditions, albeit with transient cytotoxicity at higher fluences and excessive ion doping. Overall, this approach holds promise for markedly improving antibacterial efficacy and osteogenic compatibility, potentially transforming bone regeneration therapies. Full article
(This article belongs to the Special Issue Recent Research of Nanomaterials in Molecular Science: 2nd Edition)
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13 pages, 2316 KiB  
Article
Laser Nanostructuring of Titanium Surfaces for Enhanced Bioactive Applications
by Angela De Bonis, Mariangela Curcio, Agostino Galasso, Nicola Caggiano, Antonio Lettino, Patrizia Dolce, Donato Mollica, Maria Lucia Pace and Antonio Santagata
Materials 2025, 18(10), 2362; https://doi.org/10.3390/ma18102362 - 19 May 2025
Viewed by 714
Abstract
Laser nanostructuring via Laser-Induced Periodic Surface Structures (LIPSS), generated using femtosecond laser pulses, has been investigated as a method for precisely modifying titanium surfaces. By adjusting parameters such as the fluence and pulse number of the laser beam, it is feasible to tailor [...] Read more.
Laser nanostructuring via Laser-Induced Periodic Surface Structures (LIPSS), generated using femtosecond laser pulses, has been investigated as a method for precisely modifying titanium surfaces. By adjusting parameters such as the fluence and pulse number of the laser beam, it is feasible to tailor the surface morphology, roughness, and oxidation states of species that can significantly influence the properties and surface bioactivity of the material. In this study, the LIPSS was applied to commercially pure titanium and evaluated for its ability to support calcium phosphate nucleation and growth in Simulated Body Fluid (SBF). Scanning Electron Microscopy (SEM) and Fast Fourier Transform (FFT) analysis confirmed the formation of well-defined periodic structures. Additional characterizations performed by Atomic Force Microscopy (AFM) and X-ray Photoelectron Spectroscopy (XPS) revealed, after laser treatment of titanium, its increased surface roughness and oxidation levels, respectively. These features, when assessed after immersion in SBF, were associated with an improved potential biological performance of the nanostructured surface of the investigated material. The results demonstrated that LIPSS-treated titanium effectively promoted calcium phosphate growth, indicating its enhanced potential bioactivity. Overall, LIPSS nanostructuring presents a scalable and cost-effective strategy for engineering titanium surfaces with potential bioactive properties, supporting their promising application in advanced biomedical implants. Full article
(This article belongs to the Special Issue Emerging Trends and Innovations in Engineered Nanomaterials)
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20 pages, 2107 KiB  
Article
Exact Solutions to Cancer Laser Ablation Modeling
by Luisa Consiglieri
Photonics 2025, 12(4), 400; https://doi.org/10.3390/photonics12040400 - 21 Apr 2025
Viewed by 595
Abstract
The present paper deals with the study of the fluence rate over both healthy and tumor tissues in the presence of focal laser ablation (FLA). We propose new analytical solutions for a coupled partial differential equation (PDE) system, which includes the transport equation [...] Read more.
The present paper deals with the study of the fluence rate over both healthy and tumor tissues in the presence of focal laser ablation (FLA). We propose new analytical solutions for a coupled partial differential equation (PDE) system, which includes the transport equation modeling of light penetration into biological tissue, the bioheat equation modeling the heat transfer, and its respective damage. The present work could be the first step toward knowledge of the mathematical framework for biothermophysical problems, as well as the main key to simplify the numerical calculations due to its zero cost. We derive exact solutions and simulate results from them. We discuss the potential physical contributions and present respective conclusions about the following: (1) the validity of the diffusion approximation of the radiative transfer equation; (2) the local behavior of the source of scattered photons; (3) the unsteady state of the fluence rate; and (4) the boundedness of the critical time of the thermal damage to the cancerous tissue. We also discuss some controversial and diverging hypotheses. Full article
(This article belongs to the Section Lasers, Light Sources and Sensors)
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13 pages, 3123 KiB  
Article
Loss Analysis of P3 Laser Patterning of Perovskite Solar Cells via Hyperspectral Photoluminescence Imaging
by Christof Schultz, Markus Fenske, Nicolas Otto, Laura-Isabelle Dion-Bertrand, Guillaume Gélinas, Stéphane Marcet, Janardan Dagar, Rutger Schlatmann, Eva Unger and Bert Stegemann
Solar 2025, 5(2), 13; https://doi.org/10.3390/solar5020013 - 11 Apr 2025
Viewed by 753
Abstract
Upscaling perovskite solar cells and modules requires precise laser patterning for series interconnection and spatial characterization of cell parameters to understand laser–material interactions and their impact on performance. This study investigates the use of nanosecond (ns) and picosecond (ps) laser pulses at varying [...] Read more.
Upscaling perovskite solar cells and modules requires precise laser patterning for series interconnection and spatial characterization of cell parameters to understand laser–material interactions and their impact on performance. This study investigates the use of nanosecond (ns) and picosecond (ps) laser pulses at varying fluences for the P3 patterning step of perovskite solar cells. Hyperspectral photoluminescence (PL) imaging was employed to map key parameters such as optical bandgap energy, Urbach energy, and shunt resistance. The mappings were correlated with electrical measurements, revealing that both ns and ps lasers can be utilized for effective series interconnections with minimal performance losses at optimized fluences. Our findings provide a deeper understanding of fluence-dependent effects in P3 patterning. Moreover, the results demonstrate that the process window is robust, allowing for reasonable cell performance even with deviations from optimal parameters. This robustness, coupled with the scalability of the laser patterning process, emphasize its suitability for industrial module production. Full article
(This article belongs to the Special Issue Developments in Perovskite Solar Cells)
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23 pages, 7257 KiB  
Article
Effect of Nanosecond Laser Ablation and Oxidation on the Surface Wettability and Microstructure of Cu-ETP Copper Sheets
by Monika Walkowicz, Piotr Osuch, Małgorzata Zasadzińska, Paweł Strzępek and Klaudia Kludacz
Coatings 2025, 15(4), 383; https://doi.org/10.3390/coatings15040383 - 25 Mar 2025
Viewed by 726
Abstract
Nanosecond laser ablation effectively modifies Cu-ETP copper surfaces by controlling wettability and microstructure. This study examines the effects of nanosecond fiber laser processing and subsequent oxidation on surface evolution. The analyzed parameters include fluence (25.46–1018.59 J/cm2), wavelength (1064 nm), repetition rate [...] Read more.
Nanosecond laser ablation effectively modifies Cu-ETP copper surfaces by controlling wettability and microstructure. This study examines the effects of nanosecond fiber laser processing and subsequent oxidation on surface evolution. The analyzed parameters include fluence (25.46–1018.59 J/cm2), wavelength (1064 nm), repetition rate (25–1000 kHz), and pulse duration (2–500 ns). To investigate high energy densities, fluence values were set above typical ablation thresholds, inducing hierarchical surface structures affecting wettability. Post-ablation oxidation was examined under two conditions: natural oxidation in ambient air and accelerated oxidation via low-temperature annealing (200 °C) in air. Contact angle measurements revealed that over time, the initially hydrophilic (θ < 90°) laser-textured surfaces exhibited a transition toward hydrophobicity (θ > 90°), which can be attributed to the adsorption of airborne organic compounds rather than oxidation alone. In contrast, annealing significantly accelerated hydrophobicity, attributed to controlled copper oxide growth. SEM and EDS analyses confirmed that higher fluences enhanced roughness and oxidation, forming multi-scale textures and oxide layers, which influenced water repellency. These findings demonstrate that high-fluence laser ablation, combined with controlled oxidation, enables precise wettability engineering. This method provides an efficient strategy for tuning surface properties, offering potential applications in anti-corrosion coatings, self-cleaning surfaces, and heat exchangers, where hydrophobicity and durability are essential. Full article
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16 pages, 9709 KiB  
Article
Al Doping Effect on Enhancement of Nonlinear Optical Absorption in Amorphous Bi2Te3 Thin Films
by Tengfei Zhang, Shenjin Wei, Shubo Zhang, Menghan Li, Jiawei Wang, Jingze Liu, Junhua Wang, Ertao Hu and Jing Li
Materials 2025, 18(6), 1372; https://doi.org/10.3390/ma18061372 - 20 Mar 2025
Viewed by 472
Abstract
Bismuth telluride (Bi2Te3) has attracted significant attention due to its broadband ultrafast optical response and strong nonlinearity at high laser fluence in the field of optoelectronic materials. The objective of this work is to study the effect of Al [...] Read more.
Bismuth telluride (Bi2Te3) has attracted significant attention due to its broadband ultrafast optical response and strong nonlinearity at high laser fluence in the field of optoelectronic materials. The objective of this work is to study the effect of Al doping on the structure, linear optical properties, and nonlinear optical absorption behavior of Bi2Te3 thin films. The amorphous Al-doped Bi2Te3 thin films with varying Al doping concentrations were prepared using magnetron co-sputtering. The structure and linear optical properties were characterized using X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, spectroscopic ellipsometry, and UV/Vis/NIR spectrophotometry. The third-order nonlinear optical absorption properties of Al: Bi2Te3 thin films were investigated using the open-aperture Z-scan system with a 100 fs laser pulse width at a wavelength of 800 nm and a repetition rate of 1 kHz. The results indicate that Al dopant reduces both the refractive index and extinction coefficient and induces a redshift in the optical bandgap. The optical properties of the films can be effectively modulated by varying the Al doping concentration. Compared with undoped Bi2Te3 thin films, Al-doped Bi2Te3 thin films exhibit larger nonlinear optical absorption coefficients and higher damage thresholds and maintaining high transmittance. These findings provide experimental evidence and a reliable approach for the further optimization and design of ultrafast nonlinear optical devices. Full article
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