Search Results (483)

To improve the rutting resistance and low-temperature cracking performance of polymer-modified asphalt under extreme conditions, hierarchically structured ZnO-loaded porous activated carbon (ZnO/PAC) nanosheets were introduced as a synergistic reinforcing agent for SBS-modified asphalt. The ZnO/PAC hybrids were synthesized via template-assisted carbonization followed by hydrothermal growth, and their effects were evaluated by microscopic characterization and rheological tests, including temperature sweeps, multiple stress creep and recovery (MSCR), and bending beam rheometer (BBR) analyses. ZnO was successfully anchored onto the PAC, forming a three-dimensional flower-like nanostructure. Among the investigated samples, ZPS3 with 3 wt.% ZnO/PAC showed the best overall performance. At 64 °C, the rutting factor increased from 4.2 kPa for the SBS-modified asphalt to 6.8 kPa for ZPS3, representing a ~62% enhancement and indicating markedly improved high-temperature deformation resistance. MSCR results further confirmed the superior rutting resistance of ZPS3, which exhibited the highest recovery and the lowest non-recoverable creep compliance. In addition, BBR results showed that the low-temperature performance grade improved from −12 °C for conventional the SBS-modified asphalt to −18 °C for the ZnO/PAC-modified system. These results demonstrate that ZnO/PAC nanosheets can effectively enhance both the high-temperature rutting resistance and low-temperature cracking resistance of SBS-modified asphalt. Full article

Warm-mix asphalt (WMA) technology and basalt fiber modification have been increasingly applied in road engineering. However, conventional basalt fibers often disperse unevenly and tend to agglomerate. In this study, basalt fiber powder (BFP) was incorporated into a Sasobit-based WMA system and systematically compared with matrix asphalt, Sasobit-modified WMA, conventional basalt fiber-modified WMA, and styrene butadiene styrene (SBS)-modified asphalt. Multiscale characterization—including dynamic shear rheometry (DSR), bending beam rheometry (BBR), scanning electron microscopy (SEM), and nanoindentation—was conducted to elucidate rheological behavior and interfacial micromechanical responses. The corresponding Asphalt Concrete-13 (AC-13) mixtures were further evaluated through rutting tests, low-temperature bending tests, and moisture susceptibility tests. Results demonstrate that micronized BFP achieves more homogeneous dispersion within the asphalt matrix and may promote a more effective reinforcing morphology, significantly enhancing high-temperature deformation resistance while partially mitigating the low-temperature stiffness increase induced by Sasobit. Compared with conventional basalt fiber systems, BFP shows better stress relaxation capacity and interfacial mechanical response under the tested conditions. At the mixture level, the BFP–Sasobit system showed the best overall performance, with the dynamic stability increasing by 242.2% relative to the base asphalt mixture and the residual Marshall stability reaching 92.3%, while the low-temperature flexural strain increased by 33.3%. Overall, the findings suggest that morphology-controlled micronization provides a morphology-guided enhancement strategy for Sasobit-based warm-mix asphalt by promoting coordinated improvements across the rheological, micromechanical, and mixture scales. Full article

To address the growing demand for sustainable road infrastructure development and resolve technical bottlenecks in reclaimed asphalt pavement (RAP) recycling, this study optimized the performance of recycled asphalt mixtures (RAMs) and validated their engineering applicability for field construction. RAM specimens were prepared using 5-year and 10-year aged RAP from Ningxia, with a constant RAP content of 30%. Laboratory tests including high-temperature rutting, moisture susceptibility, low-temperature cracking, dynamic modulus, and four-point bending fatigue were performed to determine the optimal mix proportion. Fourier Transform Infrared Spectroscopy (FTIR) and Thin-Layer Chromatography-Flame Ionization Detection (TLC-FID) were employed to reveal the regeneration mechanism of waste engine oil (WEO). Results showed that WEO modified the functional groups and four fractions of asphalt, optimizing its colloidal structure, while excessive WEO compromised high-temperature stability. The optimal WEO contents were 4% for RAP (5Y) and 8% for RAP (10Y), which significantly enhanced the overall performance of RAM to adapt to Ningxia’s climate. This study provides technical support for sustainable road infrastructure in arid and semi-arid regions. Full article

High-sensitivity rapid detection of ammonia (NH₃) in environmental monitoring, industrial safety, early diagnosis, and other fields is of great significance. Covalent organic frameworks (COFs) have shown great potential in the field of gas sensing due to their designable porous structure and active sites. However, the traditional solvothermal synthesis method of COFs has problems such as cumbersome steps, high energy consumption and serious environmental pollution. Therefore, it is of great significance to invent a new method for COF synthesis that is green and efficient and makes it easy to conduct flexible ammonia gas sensing. This study first reported a solvent-free synthesis of imine connection 1,3,5-Triformylbenzene (TFB) and p-Phenylenediamine (PDA)—a new strategy for COF. This method innovatively employs zinc trifluoromethyl sulfonate (Zn(OTf)₂) as a bifunctional catalyst. This catalyst not only efficiently catalyzes para-phenylenediamine, but its zinc ions also play a unique structural guiding role, guiding the reactants to be arranged in a directional manner, thereby constructing a highly ordered porous crystal structure. A series of characterizations confirmed that the obtained TFB-PDA-COF had good crystallinity and a high proportion of imine bonds (C=N). The powder material was coated onto a flexible polyimide (PI) substrate, successfully constructing a resistive ammonia gas sensor that operates at room temperature. The test results show that this sensor has a high response value, rapid response/recovery capability, and good selectivity for ammonia gas. More importantly, based on a flexible PI substrate, the device can maintain stable sensing performance even under repeated bending conditions, demonstrating its great potential in practical flexible electronic applications. This work not only provides a brand-new “zinc ion-guided” paradigm for the green and controllable synthesis of COF but also lays a material foundation for their application in the next-generation flexible sensing field. Full article

While the utilization of waste polymers in asphalt mixtures is widely studied, the specific influence of additive geometry on performance mechanisms remains underexplored. This study presents a multi-scale performance assessment of asphalt mixtures modified with waste Polyvinyl Chloride (PVC) foils. Waste PVC foils were processed into two distinct geometries, “Wiry” and “Random”, and incorporated into mixture at dosages ranging from 5% to 12.5% by weight of bitumen via the dry process. At the macro-scale, Semi-Circular Bending, Hamburg Wheel Tracking, Repeated Creep, and Modified Lottman tests were conducted. At the micro-scale, Scanning Electron Microscopy and EDS analyses were employed to investigate interfacial adhesion. The results demonstrated that the “Wiry” geometry significantly outperformed the “Random” by establishing a three-dimensional reinforcement network. Specifically, the mixture modified with 7.5% “Wiry” PVC yielded the highest Flexibility Index of 24.17, representing a 3.7-fold improvement. Furthermore, this optimum dosage enhanced high-temperature stability and maintained moisture resistance (TSR > 85%), whereas dosages exceeding 10% caused agglomeration and performance loss. Microstructural imaging indicated that the fibrous morphology and calcite-rich surface of the “Wiry” additive facilitate superior mechanical interlocking. Consequently, this study suggests that optimizing waste PVC geometry is as critical as dosage for maximizing the durability and sustainability of flexible pavements. Full article

This study investigates the synergistic effects of combining polyphosphoric acid (PPA) and styrene–butadiene–styrene (SBS) as modifiers in asphalt binders to enhance their performance. The research focuses on optimizing the concentrations of PPA and SBS to improve the resistance to permanent deformation, cracking at intermediate and low temperatures, and resistance to aging. A series of empirical and rheological tests, including penetration, softening point, elastic recovery, dynamic shear rheometer (DSR), multiple stress creep recovery (MSCR), and bending beam rheometer (BBR), were conducted to evaluate the rheological and engineering properties of the modified binders. The results indicate that PPA can partially replace SBS, offering comparable improvements in high-temperature performance and creep resistance. The MSCR test revealed a statistically significant synergistic effect between PPA and SBS, resulting in improved recovery and reduced non-recoverable compliance. However, PPA alone shows limited effectiveness at low temperatures and in properties that are governed by elastic response. This study highlights the potential for optimizing asphalt modifiers by leveraging the complementary properties of PPA and SBS in hybrid systems, particularly regarding high-temperature properties and dynamic loading. Full article

During fires, the temperature difference between indoor and outdoor environments induces out-of-plane deformation in steel studs. Due to the differential coefficients of thermal expansion between panels and steel, the panels exert a restraining effect on the studs. However, there remains a lack of systematic experimental and theoretical models addressing the failure modes, restraining mechanisms, and synergistic effects of various panels on steel studs. This study conducted high-temperature bending tests to compare the failure modes, load–displacement curves, and key mechanical parameters (peak load, elastic stiffness) of connections combining steel studs with three types of panels: autoclaved lightweight concrete (ALC) panels, fire-resistant gypsum boards, and medium-density calcium silicate board. The research clarifies the constraining effect and temperature sensitivity of different panels. Based on experimental data, a bending constitutive model was developed to quantify the attenuation of the out-of-plane constraining effect at elevated temperatures. The results indicate that the load–displacement curves exhibit three distinct stages: Elastic Ascending Stage, Elastoplastic Ascending Stage, and Post-Peak Stage. A two-stage bending constitutive model was proposed and formulated. Comparison between numerical simulations and experimental specimens in terms of failure modes and characteristic parameters demonstrated that simplifying the panels as spring elements, with stiffness defined by the proposed bending constitutive model, yields errors within 15%, confirming the accuracy of the model. This study systematically investigates the influence of sheathing panels on the high-temperature out-of-plane mechanical behavior of cold-formed steel studs, innovatively proposes a two-stage bending constitutive model, provides theoretical and data support for cold-formed steel structural fire-resistant design, and offers new perspectives and methodologies for future research. Full article

In this study, 1.5Y-2.2Ca-TZP materials were obtained by hot pressing of a mixed and milled blend of 3Y-TZP and 4.4Ca-TZP powders. The materials were sintered at temperatures between 1250 °C and 1400 °C and characterized with respect to mechanical properties, microstructure, phase composition and stability against low-temperature degradation. In the tested range, the bending strength of the TZP decreases with increasing sintering temperature from 1300 MPa to 1050 MPa while the toughness shows a rising trend from 5 MPa√m to 8 MPa√m. The grain size distribution in the microstructure is broad with average grain sizes increasing from 150 nm to 250 nm with rising sintering temperature. LTD tests revealed high aging resistance for TZP sintered at 1300 °C. The Y-Ca-co-stabilized TZP equilibrates the properties of Ca-TZP and Y-TZP. Full article

Foaming technology can effectively reduce the viscosity of polymer-modified asphalt and significantly decrease energy consumption during pavement construction, making it an effective approach for achieving low-carbon pavement construction and maintenance. However, mechanically foamed asphalt relies on specialized equipment and requires strict parameter control. Although water-based foaming methods using zeolites or ethanol can alleviate these issues to some extent, they still present disadvantages such as significant variability in foaming performance and potential risks during transportation and construction. Therefore, this study investigates the feasibility of using crystalline hydrates with high water of crystallization for micro-foamed asphalt. Three types of micro-foamed SBS-modified asphalt (MFPA) were prepared using hydrates with different contents of water of crystallization. Physical property tests, foaming characteristic parameters, viscosity–temperature analysis, Fourier transform infrared spectroscopy (FTIR), adhesion tensile tests, scanning electron microscopy (SEM), and fluorescence microscopy were conducted to evaluate their effects on the physical and chemical properties, viscosity reduction performance, adhesion, and compatibility of SBS-modified asphalt. Furthermore, dynamic shear rheometer (DSR) tests, bending beam rheometer (BBR) tests, fatigue life modeling, and morphological analysis were employed to investigate the rheological properties, fatigue life, and bubble evolution behavior of the MFPA system. The results indicate that utilizing the thermal decomposition characteristics of crystalline hydrates with high water of crystallization (Na₂SO₄·10H₂O, Na₂HPO₄·12H₂O, and Na₂CO₃·10H₂O) to release H₂O and CO₂ in SBS-modified asphalt for micro-foaming is a short-term reversible physical viscosity reduction process. The maximum expansion ratio (ERmax) of MFPA reaches 8–10, the half-life (HL) remains stable at approximately 180 s, and the foaming index (FI) peak is about 1160. The construction temperature can be reduced by 10–15%, and the viscosity reduction effect remains stable within 60 min. Compared with unfoamed SBS-modified asphalt, the compatibility, rutting resistance, and fatigue life of MFPA increase by approximately 65%, 32%, and 30%, respectively, while the low-temperature performance decreases by 18%. Under the same short-term and long-term aging conditions, MFPA exhibits better aging resistance. Specifically, its rutting resistance increases by 37%, and fatigue resistance improves by 30% compared with aged SBS-modified asphalt, while the low-temperature performance remains essentially unchanged. Full article

This study presents an experimental investigation into the direct use of date kernel powder (DKP) as a biomass-based modifier for bituminous binders, with the aim of evaluating its feasibility as a sustainable binder modifier. DKP was incorporated into a conventional bituminous binder at different contents (5, 10, 15, and 20 wt.% by weight of binder), and its physicochemical properties were characterized using SEM, XRD, and FTIR. The rheological and performance properties of the modified binders were evaluated through conventional tests, aging procedures, rotational viscosity (RV), dynamic shear rheometer (DSR), bending beam rheometer (BBR), and linear amplitude sweep (LAS) testing, and the performance grades (PG) of all binders were determined. The results indicate that DKP addition increases binder stiffness and reduces temperature susceptibility while maintaining acceptable fatigue and low-temperature performance. Performance grading results showed that the high-temperature grade increased from PG 64 to PG 70 and the low-temperature grade improved from PG-22 to PG-34 at a DKP content of 15%. LAS test results indicated that fatigue life was maintained or improved at intermediate temperatures. Among the tested contents, 15% DKP provided the most balanced performance considering performance grade improvement, fatigue behavior, and workability characteristics, while higher contents resulted in increased stiffness. Overall, the findings suggest that DKP is a promising modifier for bituminous binders at the binder level. However, further studies at the mixture and field scale are recommended to confirm the long-term engineering applicability of DKP-modified binders. Full article

Steel slag is a major solid waste generated by the steelmaking industry. Its characteristics, including high hardness and large specific surface area, offer the potential to replace traditional mineral fillers in asphalt mixtures. However, the high alkalinity of unmodified steel slag often leads to unbalanced rheological properties and insufficient moisture stability in asphalt mastic. In this study, a modified steel slag filler was prepared using a process involving crushing and screening, water washing for dealkalization, and surface modification with a silane coupling agent. Using limestone powder and hydrated lime as control groups, the modification effects on base asphalt mastic were systematically investigated. Rheological properties were characterized using a dynamic shear rheometer (DSR) and bending beam rheometer (BBR). Interfacial performance was evaluated through pull-off tests and water immersion dispersion tests. Furthermore, mechanisms were elucidated using X-ray Fluorescence (XRF), BET specific surface area analysis, and surface free energy (SFE) tests. The results indicate that the modified steel slag significantly enhances the high-temperature deformation resistance of the asphalt mastic. At 58 °C, the complex modulus reached 7.3 MPa, representing increases of 43.3% compared to limestone powder mastic. At −18 °C, the creep stiffness increased by only 3.0%, suggesting that low-temperature cracking resistance remained fundamentally stable. The water immersion dispersion loss rate was 2.12%, and the attenuation rate of pull-off strength after water immersion was 12.5%, indicating that its resistance to moisture damage is superior to that of limestone powder and comparable to that of hydrated lime. Mechanism analysis reveals that the large specific surface area of the modified steel slag strengthens physical adsorption, while the basic oxides undergo a weak acid–base reaction with the acidic components of the asphalt. Additionally, surface modification improves compatibility. The preparation process for modified steel slag is simple; it can be used as a standalone substitute for traditional mineral fillers, balancing both performance and environmental benefits. Full article

This study aims to investigate the restorative effects and rejuvenation mechanisms of two rejuvenators on ultraviolet (UV)-aged SBS modified asphalt binder. Two types of rejuvenators were developed. The rheological properties of aged and rejuvenated asphalt were systematically evaluated using a dynamic shear rheometer (DSR), bending beam rheometer (BBR), and multiple stress creep and recovery (MSCR) tests. Fourier transform infrared spectroscopy (FTIR) and gel permeation chromatography (GPC) were employed to analyze the rejuvenation mechanisms. The results demonstrate that UV aging significantly deteriorates both the high- and low-temperature performance of SBS modified asphalt binder. Oil-rich rejuvenator A effectively restores UV-aged asphalt’s high-temperature performance and low-temperature stiffness. Polymer-based rejuvenator B better repairs PAV-aged cross-linked networks with superior chemical dilution, but over-dilutes large molecules. Both comparably restore aged low-temperature performance, with rejuvenator A favoring stiffness recovery and rejuvenator B favoring m-value recovery. FTIR analysis reveals that aging significantly increases the carbonyl and sulfoxide indices of SBS modified asphalt binder, especially after PAV and UV aging. Rejuvenator B exhibits superior chemical dilution, reducing these indices nearly to their original levels. GPC analysis demonstrates an aging-induced molecular weight increase and large molecular size (LMS) formation. The recovery effect of rejuvenator A is quite limited (reducing LMS by 2%). Conversely, rejuvenator B aggressively reduces LMS but causes over-dilution. Overall, rejuvenator B is recommended to be used for aged SBS modified asphalt binder, especially after UV aging. Full article

To investigate the dynamic behavior of smart composite structures with embedded heat sources over a wide temperature range, this study employed thermoplastic polypropylene as the matrix, combined with glass/carbon fiber prepregs and Ni80Cr20 alloy heating wires, and fabricated functional laminated specimens with integrated heating elements via a prepreg molding process. Using a self-developed variable-temperature cantilever beam vibration testing system, the evolution of natural frequencies and damping ratios from room temperature to 140 °C was systematically examined. Results indicate that temperature-induced thermal softening of the polypropylene matrix reduces the effective bending stiffness of the composites, leading to a decline in natural frequencies across all modes. For example, the first-order natural frequency of the sample decreased from approximately 30.8 Hz at room temperature to about 28.3 Hz at 140 °C, representing a reduction of approximately 8.12%. The second-order reduction reached about 8.99%, and the third-order reduction was approximately 9.65%. Carbon fiber-reinforced specimens exhibited relatively smaller frequency reductions due to the high modulus of the fibers. Concurrently, elevated temperatures enhance molecular chain mobility and interfacial viscoelastic dissipation at the fiber–matrix interface, causing a sharp increase in damping ratios at high temperatures (>100 °C). For instance, the damping ratio of the first-order mode increased significantly from approximately 1.02% at room temperature to about 2.9% at 140 °C. By comparatively analyzing carbon fiber and glass fiber systems, the study elucidated the distinct mechanisms underlying the “fiber-dominated” stiffness retention effect and the “resin/interface-dominated” damping dissipation effect under thermal influence. These findings provide critical experimental data and theoretical references for the active thermal regulation of structural performance in thermoplastic composite structures with integrated heat sources, thereby mitigating damage caused by external disturbances. Full article

The Yellow River Great Bend Urban Agglomeration is a key area in the ecological protection and high-quality development strategy of the Yellow River Basin. In the process of coordinated regional development, the contradiction between economic development and environmental protection has become increasingly prominent, and the pollution problems of PM_2.5 and O₃ have become prominent. Based on the observation data of air pollutants and meteorological data of 15 cities from 2020 to 2023, this study explored the spatio-temporal variation characteristics of PM_2.5 and O₃ concentrations in this region and the influence of meteorological factors (temperature, relative humidity, wind speed, and precipitation). The results showed that the proportion of days with good air quality in the Yellow River Great Bend Urban Agglomeration metropolitan area increased first and then decreased from 2020 to 2023. PM_2.5 concentrations were highest in winter and lowest in summer, with moderate levels in spring and autumn. In contrast, O₃ concentrations peaked in summer and reached their lowest levels in winter. In terms of spatial variation, the spatial distribution of the number of PM_2.5 polluted days roughly decreases from northwest to southeast, with Taiyuan City having the largest number of polluted days. The number of days with O₃ pollution roughly shows a pattern of more in the middle and less around the periphery. Spatial autocorrelation analysis indicates that the PM_2.5 concentration and O₃ concentration in the Yellow River Great Bend Urban Agglomeration have obvious high-value and low-value spatial agglomeration characteristics. Meteorological elements have a significant influence on the concentrations of PM_2.5 and O₃. The occurrence frequencies of PM_2.5 pollution and O₃ pollution were significantly higher respectively within the temperature ranges of −10 to 15 °C and 20 to 30 °C, as well as under the condition of RH > 50% and in the range of 30% to 70% of the relative humidity. Statistical analysis revealed a universally significant negative correlation between wind speed and PM_2.5 concentrations across all cities (mean R = −0.09, binomial test p < 0.001), confirming the critical role of stagnant conditions in local pollutant accumulation. The results of this study can provide important references for regional precise pollution control and environmental quality improvement and are of great significance for promoting regional sustainable development. Full article

This paper aims to investigate the effects of the co-pyrolytic product produced from the co-pyrolysis of waste cooking oil (WCO) and polypropylene (PP) on pure bitumen by using some physical and rheological tests. To reach this goal, the product was obtained by producing from the co-pyrolysis of WCO and PP at distinct conditions. Different pyrolytic products with different structural properties can be obtained from the co-pyrolysis of various materials at different pyrolysis conditions. It was not found any study in which bitumen was modified with the co-pyrolytic product produced from the co-pyrolysis of WCO and PP materials at specified blending ratios and conditions, as described in this paper. For this reason, this paper investigates the effects of this co-pyrolytic product as an additive on bitumen in order to improve some of the rheological and physical properties of bitumen and to overcome some problems for the first time. The mixture ratio was determined as 1:2 (WCO:PP). PG 64-22 neat bitumen was modified with this co-pyrolytic product, and some features of the bituminous binders were detected by using differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FTIR), penetration, softening point, dynamic shear rheometer (DSR), rotational viscometer (RV), a rolling thin film oven test (RTFOT), a pressurized aging vessel (PAV), a bending beam rheometer (BBR), storage stability, and scanning electron microscopy (SEM) tests. From the FTIR results of the modified binders, it was found that the intensity of the peak around 2357.69 cm⁻¹ increased with the addition of this pyrolytic product. This pyrolytic additive hardened the pure bitumen’s consistency, increased its viscosity, improved its resistance against rutting deformations, and enhanced its high-temperature performance. It can be said that PG 64-22 pure bitumen can easily be modified with this pyrolytic product at the conditions described in this study. Additionally, this co-pyrolytic product improved the high-temperature performance grade (PG) of pure bitumen from PG 64 to PG 76 when it was used at 5% of the weight of neat bitumen. The findings demonstrated that the modified bituminous binders containing 3% and 5% co-pyrolytic product had suitable storage stabilities. Full article