Search Results (427)

Difficult, extreme operating conditions of parabolic antennas under precipitation and sub-zero temperatures require the creation of effective heating systems. The purpose of the research is to develop a multilayer coating containing two metal-ceramic layers, epoxy composite layers, carbon fabric, and an outer layer of basalt fabric, which allows for effective heating of the antenna, and to study the properties of this coating. The multilayer coating was formed on an aluminum base that was subjected to abrasive jet processing. The first and second metal-ceramic layers, Al₂O₃ + 5% Al, which were applied by high-speed multi-chamber cumulative detonation spraying (CDS), respectively, provide maximum adhesion strength to the aluminum base and high adhesion strength to the third layer of the epoxy composite containing Al₂O₃. On this not-yet-polymerized layer of epoxy composite containing Al₂O₃, a layer of carbon fabric (impregnated with epoxy resin) was formed, which serves as a resistive heating element. On top of this carbon fabric, a layer of epoxy composite containing Cr₂O₃ and SiO₂ was applied. Next, basalt fabric was applied to this still-not-yet-polymerized layer. Then, the resulting layered coating was compacted and dried. To study this multilayer coating, X-ray analysis, light and raster scanning microscopy, and transmission electron microscopy were used. The thickness of the coating layers and microhardness were measured on transverse microsections. The adhesion strength of the metal-ceramic coating layers to the aluminum base was determined by both bending testing and peeling using the adhesive method. It was established that CDS provides the formation of metal-ceramic layers with a maximum fraction of lamellae and a microhardness of 7900–10,520 MPa. In these metal-ceramic layers, a dispersed subgrain structure, a uniform distribution of nanoparticles, and a gradient-free level of dislocation density are observed. Such a structure prevents the formation of local concentrators of internal stresses, thereby increasing the level of dispersion and substructural strengthening of the metal-ceramic layers’ material. The formation of materials with a nanostructure increases their strength and crack resistance. The effectiveness of using aluminum, chromium, and silicon oxides as nanofillers in epoxy composite layers was demonstrated. The presence of structures near the surface of these nanofillers, which differ from the properties of the epoxy matrix in the coating, was established. Such zones, specifically the outer surface layers (OSL), significantly affect the properties of the epoxy composite. The results of industrial tests showed the high performance of the multilayer coating during antenna heating. Full article

Cement-based building materials usually exhibit weak flexural behavior under high temperature or fire conditions. This paper develops a novel geopolymer with enhanced residual flexural strength, incorporating fly ash/metakaolin precursors and corundum aggregates based on our previous study, and further improves flexural performance using hybrid fibers. The flexural load–deflection response, strength, deformation capacity, toughness and microstructure are investigated by a thermal exposure test, bending test and microstructure observation. The results indicate that the plain geopolymer exhibits a continuously increasing flexural strength from 10 MPa at 20 °C to 25.9 MPa after 1000 °C exposure, attributed to thermally induced further geopolymerization and ceramic-like crystalline phase formation. Incorporating 5% wollastonite fibers results in slightly increased initial and residual flexural strength but comparable peak deflection, toughness and brittle failure. The binary 5% wollastonite and 1% basalt fibers in geopolymer obviously improve residual flexural strength exposed to 400–800 °C. The steel fibers show remarkable reinforcement on flexural behavior at 20–800 °C exposure; however, excessive steel fiber content such as 2% weakens flexural properties after 1000 °C exposure due to severe oxidation deterioration and thermal incompatibility. The wollastonite/basalt/steel fibers exhibit a positive synergistic effect on flexural strength and toughness of geopolymers at 20–600 °C. Full article

Asphalt pavement cracking is an important factor affecting its service life. Under certain conditions, the self-healing behavior of asphalt itself can repair pavement cracks. However, the self-healing ability of asphalt itself is limited. In order to strengthen the self-healing ability of asphalt, the microcapsule wrapped with a repair agent is pre-mixed into the asphalt mixture. When the crack occurs and spreads to the surface of the microcapsule, the microcapsule ruptures and the healing agent flows out to realize the self-healing of the crack. Current microcapsules are mostly prepared with healing agents and bio-oil as core materials, and their high-temperature resistance to rutting is poor. While the epoxy resin contains a three-membered cyclic ether, it can undergo ring-opening polymerization to bond and repair the asphalt matrix. In addition, research on microcapsules mainly focuses on the self-healing properties of microcapsule-modified asphalt. In fact, before adding microcapsules to asphalt to improve its self-healing performance, it is necessary to ensure that the asphalt has a good road performance. On this basis, the self-healing performance of asphalt is improved, thereby extending the service life of asphalt pavement. Therefore, two-component epoxy self-healing microcapsules (E-mic and G-mic) were first prepared in this paper. Then, a temperature scanning test, rheological test of bending beams, and linear amplitude scanning test were, respectively, conducted for the microcapsule/asphalt to evaluate its road performance, including the high-temperature performance, low-temperature crack resistance, and fatigue performance. Finally, the self-healing performance of microcapsules/asphalt was tested. The results showed that the self-developed epoxy self-healing microcapsules were well encapsulated and presented as spherical micron-sized particles. The average particle size of the E-mic was approximately 23.582 μm, while the average particle size of the G-mic was approximately 22.440 μm, exhibiting a good normal distribution. In addition, they can remain intact and unbroken under high-temperature conditions. The results of road performance tests indicated that the microcapsule/asphalt mixture exhibits an excellent high-temperature resistance to permanent deformation, low-temperature crack resistance, and fatigue resistance. The self-healing test demonstrated that the microcapsule/asphalt exhibited an excellent self-healing performance. When the microcapsule content was 4%, the self-healing rate reached its optimal level of 67.8%, which was 149.2% higher than that of the base asphalt. Full article

In order to solve various problems in traditional roads and extend their service life, new road materials have become a research hotspot. Polyurethane prepolymers (PUPs) and ceramic fibers (CFs), as materials with unique properties, were chosen due to their synergistic effect: PUPs provide elasticity and gel-like behavior, while CFs contribute to structural stability and high-temperature resistance, making them ideal for enhancing asphalt performance. PUPs, a thermoplastic and elastic polyurethane gel material, not only enhance the flexibility and adhesion properties of asphalt but also significantly improve the structural stability of composite materials when synergistically combined with CF. Using response surface methodology, an optimized preparation scheme for PUP/CF composite-modified asphalt was investigated. Through aging tests, dynamic shear rate (DSR) testing, bending rate (BBR) testing, microstructure scanning (MSCR), scanning electron microscopy (SEM), atomic force microscopy (AFM), and infrared spectroscopy (IR), the aging performance, rheological properties, permanent deformation resistance, microstructure, and modification mechanism of PUP/CF composite-modified asphalt were investigated. The results indicate that the optimal preparation scheme is a PUP content of 7.4%, a CF content of 2.1%, and a shear time of 40 min. The addition of the PUP and CF significantly enhances the asphalt’s aging resistance, and compared with single-CF-modified asphalt and base asphalt, the PUP/CF composite-modified asphalt exhibits superior high- and low-temperature rheological properties, demonstrating stronger strain recovery capability. The PUP forms a gel network structure in the material, effectively filling the gaps between CF and asphalt, enhancing interfacial bonding strength, and making the overall performance more stable. AFM microscopic morphology shows that PUP/CF composite-modified asphalt has more “honeycomb structures” than matrix asphalt and CF-modified asphalt, forming more structural asphalt and enhancing overall structural stability. This study indicates that the synergistic effect of PUP gel and CF significantly improves the macro and micro properties of asphalt. The PUP forms a three-dimensional elastic gel network in asphalt, improving adhesion and deformation resistance. Using response surface methodology, the optimal formulation (7.4% PUP, 2.1% CF) improves penetration (↓41.5%), softening point (↑6.7 °C), and ductility (↑9%), demonstrating the relevance of gel-based composites for asphalt modification. Full article

In actual service, asphalt pavement is subjected to freeze–thaw cycles and ultraviolet radiation (UV) over the long term, which can easily lead to mixture aging, enhanced brittleness, and structural damage, thereby reducing pavement durability. This study focuses on the influence of freeze–thaw cycles and ultraviolet aging on the performance of recycled asphalt mixtures. Systematic indoor road performance tests were carried out, and a fatigue prediction model was established to explore the comprehensive effects of recycled asphalt pavement (RAP) content, environmental action (ultraviolet radiation + freeze–thaw cycle), and other factors on the performance of recycled asphalt mixtures. The results show that the high-temperature stability of recycled asphalt mixtures decreases with the increase in environmental action days, while higher RAP content contributes to better high-temperature stability. The higher the proportion of old materials, the more significant the environmental impact on the mixture; both the flexural tensile strain and flexural tensile strength decrease with the increase in environmental action time. When the RAP content increased from 30% to 50%, the bending strain continued to decline. With the extension of environmental action days, the decrease in the immersion Marshall residual stability and the freeze–thaw splitting strength became more pronounced. Although the increase in RAP content can improve the forming stability, the residual stability decreases, and the freeze–thaw splitting strength is lower than that before the freeze–thaw. Based on the fatigue test results, a fatigue life prediction model with RAP content and freeze–thaw cycles as independent variables was constructed using the multiple nonlinear regression method. Verification shows that the established prediction model is basically consistent with the change trend of the test data. The research results provide a theoretical basis and optimization strategy for the performance improvement and engineering application of recycled asphalt materials. Full article

Nowadays, Fused Filament Fabrication (FFF) 3D printing offers promising opportunities for the customized manufacturing of ankle–foot orthoses (AFOs) targeted towards rehabilitation purposes. Polypropylene (PP) represents an ideal candidate in orthotic applications due to its light weight and superior mechanical properties, offering an excellent balance between flexibility, chemical resistance, biocompatibility, and long-term durability. However, Additive Manufacturing (AM) of AFOs based on PP remains a major challenge due to its limited bed adhesion and high shrinkage, especially for making large parts such as AFOs. The primary innovation of the present study lies in the optimization of FFF 3D printing parameters for the fabrication of functional, patient-specific orthoses using PP, a material still underutilized in the AM of medical devices. Firstly, a thorough thermomechanical characterization was conducted, allowing the implementation of a (thermo-)elastic material model for the used PP filament. Thereafter, a Taguchi design of experiments (DOE) was established to study the influence of several printing parameters (extrusion temperature, printing speed, layer thickness, infill density, infill pattern, and part orientation) on the mechanical properties of 3D-printed specimens. Three-point bending tests were conducted to evaluate the strength and stiffness of the samples, while additional tensile tests were performed on the 3D-printed orthoses using a home-made innovative device to validate the optimal configurations. The results showed that the maximum flexural modulus of 3D-printed specimens was achieved when the printing speed was around 50 mm/s. The most significant parameter for mechanical performance and reduction in printing time was shown to be infill density, contributing 73.2% to maximum stress and 75.2% to Interlaminar Shear Strength (ILSS). Finally, the applicability of the finite element method (FEM) to simulate the FFF process-induced deflections, part distortion (warpage), and residual stresses in 3D-printed orthoses was investigated using a numerical simulation tool (Digimat-AM^®). The combination of Taguchi DOE with Digimat-AM for polypropylene AFOs highlighted that the 90° orientation appeared to be the most suitable configuration, as it minimizes deformation and von Mises stress, ensuring improved quality and robustness of the printed orthoses. The findings from this study contribute by providing a reliable method for printing PP parts with improved mechanical performance, thereby opening new opportunities for its use in medical-grade additive manufacturing. Full article

This research evaluates the rheological and mechanical properties of polymer- and nanomaterials-modified bitumen by incorporating nanosilica (NSA), nanoclay (NCY), and Acrylonitrile Styrene Acrylate (ASA) at 5% by weight of the bitumen. The samples were prepared at 165 °C for one hour to obtain homogeneous blends. All samples were subjected to short- and long-term aging to simulate the effects of different operating conditions. The research conducted a series of tests, including consistency, frequency sweep, and multiple creep stress and recovery (MSCR) using the dynamic shear rheometer (DSR) and bending beam rheometer (BBR). The results showed that all modified bitumen outperformed the neat bitumen. The frequency sweep showed a higher complex modulus (G*) and lower phase angle (δ), indicating enhanced viscoelastic properties and, thus, higher resistance to permanent deformation. The BBR test revealed that the bitumen modified with NCY5% has a creep stiffness of 47.13 MPa, a 51.5% improvement compared to the neat bitumen, while the NSA5% has the highest m-value, a 28.5% enhancement compared with the neat bitumen. The MSCR showed that the modified blends have better recovery properties and, therefore, better resistance to permanent deformation under repeated loadings. The aging index demonstrated that the modified bitumen is less vulnerable to aging and maintains their good flexibility and resistance to permanent deformations. Finally, these results showed that adding 5% polymer and nanomaterials improved the bitumen’s’ performance before and after aging by reducing permanent deformation and enhancing crack resistance at low temperatures, thus extending the pavement service life and making them an effective alternative for improving pavement performance in various climatic conditions and under high traffic loads. Full article

Hydrogen embrittlement (HE) can significantly degrade the mechanical properties of steels. This phenomenon is particularly relevant for high-strength steels where large elastic stresses lead to detrimental localized concentrations of hydrogen at defects. In this study, unnotched rotating bending specimens of the bearing steel SAE 52100 (100Cr6) quenched and tempered at 180 °C and 400 °C were electrochemically charged with hydrogen. Charged and non-charged specimens then underwent rotating bending fatigue testing, either immediately after charging or after aging at room temperature up to 72 h. The hydrogen-charged specimens annealed at 180 °C showed a sizeable drop in fatigue limit and fatigue lifetime compared to the non-charged specimens with cracks mainly originating from near-surface non-metallic inclusions. In comparison, the specimens annealed at 400 °C exhibited a moderate drop in fatigue limit and lifetime due to hydrogen charging with cracks originating mostly from the surface. Aging had only insignificant effects on the fatigue lifetime. Notably, annealing of charged samples for 2 h at 180 °C restored their lifetime to that of non-charged specimens. Full article

This work presents the development of two vanillin-based vitrimer epoxy flax fibre-reinforced composites, with both the VER1-1-FFRC (a vitrimer-to-epoxy ratio of 1:1) and VER1-2-FFRC (a vitrimer-to-epoxy ratio of 1:2), via a vacuum-assisted resin infusion. The thermal and mechanical properties of the resulting vitrimer epoxy flax composites were characterised using thermal gravimetric analysis (TGA), differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), and mechanical four-point bending tests, alongside studies of solvent resistance and chemical recyclability. Both the VER1-1-FFRC (degradation temperature T_deg of 377.0 °C) and VER1-2-FFRC (T_deg of 395.9 °C) exhibited relatively high thermal stability, which is comparable to the reference ER-FFRC (T_deg of 396.7 °C). The VER1-1-FFRC, VER1-2-FFRC, and ER-FFRC demonstrated glass transition temperatures T_g of 54.1 °C, 68.8 °C, and 83.4 °C, respectively. The low T_g of the vitrimer composite is due to the low crosslink density in the vitrimer epoxy resin. Particularly, the crosslinked density of the VER1-1-FFRC was measured to be 319.5 mol·m⁻³, which is lower than that obtained from the VER1-2-FFRC (434.7 mol·m⁻³) and ER-FFRC (442.9 mol·m⁻³). Furthermore, the mechanical properties of these composites are also affected by the low crosslink density. Indeed, the flexural strength of the VER1-1-FFRC was found to be 76.7 MPa, which was significantly lower than the VER1-2-FFRC (116.2 MPa) and the ER-FFRC (138.3 MPa). Despite their lower thermal and mechanical performance, these vitrimer composites offer promising recyclability and contribute to advancing sustainable composite materials. Full article

To broaden clean asphalt modification methods, this study employs a composite polymer of maleic anhydride-grafted styrene-butadiene-styrene (MA-g-SBS) and styrene-butadiene-styrene (SBS) as a modifier. The composite is formulated into polymer latex and used to modify emulsified asphalt. Routine performance tests were conducted on MA-g-SBS/SBS composite latex-modified emulsified asphalt (MSMEA) with varying ratios to determine the optimal composition. The ideal ratio was found to be MA-g-SBS:SBS = 1:4. Subsequently, conventional property tests, rheological analyses, microphase structure observations, and bending beam creep tests were conducted on MSMEA with the optimal ratio to assess the impact of the composite latex on asphalt performance. Findings indicated that increasing the latex content significantly enhanced the softening point and ductility while reducing penetration. These macroscopic improvements were notably superior to those achieved with single SBS latex modification. Fluorescence microscopy revealed that at low dosages, the MA-g-SBS/SBS composite dispersed uniformly as point-like structures within the asphalt. At higher dosages (above 5%), a distinct network structure emerged. The addition of the composite latex raised the complex shear modulus and rutting factor while reducing the phase angle, with pronounced fluctuations observed between 4% and 5% dosages. This suggests a substantial enhancement in the high-temperature performance of the emulsified asphalt, attributed to the formation of the network structure. FT-IR results confirmed that a chemical reaction occurred during the modification process. Additionally, the bending beam creep test demonstrated that the composite latex reduced asphalt brittleness and improved its low-temperature performance. Full article

USP (usual temperature pitch)-modified asphalt optimizes its rheological properties through reactions between the modifier and the asphalt. This significantly enhances the high- and low-temperature adaptability and environmental friendliness of asphalt. It has now become an important research direction in the field of highway engineering. This article systematically investigates the impact of different dosages of USP warm mix modifier on asphalt binders through rheological and microstructural analysis. Base asphalt and SBS-modified asphalt were blended with USP at varying ratios. Conventional tests (penetration, softening point, ductility) were combined with dynamic shear rheometry (DSR, AASHTO T315) and bending beam rheometry (BBR, AASHTO T313) to characterize temperature/frequency-dependent viscoelasticity. High-temperature performance was quantified via multiple stress creep recovery (MSCR, ASTM D7405), while fluorescence microscopy and FTIR spectroscopy elucidated modification mechanisms. Key findings reveal that (1) optimal USP thresholds exist at 4.0% for base asphalt and 4.5% for SBS modified asphalt, beyond which the rutting resistance factor (G*/sin δ) decreases by 20–31% due to plasticization effects; (2) USP significantly improves low-temperature flexibility, reducing creep stiffness at −12 °C by 38% (USP-modified) and 35% (USP/SBS composite) versus controls; (3) infrared spectroscopy displays that no new characteristic peaks appeared in the functional group region of 4000–1300 cm⁻¹ for the two types of modified asphalt after the incorporation of USP, indicating that no chemical changes occurred in the asphalt; and (4) fluorescence imaging confirmed that the incorporation of USP led to disintegration of the spatial network structure of the control asphalt, explaining the reason for the deterioration of high-temperature performance. Full article

Aiming at the problems of serious pavement temperature diseases, low efficiency and high loss of ice-breaking methods, high occupancy rate of waste tires and the low utilization rate and insufficient durability of rubber particles, this paper aims to improve the service level of roads and ensure the safety of winter pavements. A pavement material with high efficiency, low carbon and environmental friendliness for active snow melting and ice breaking is developed. Firstly, NaOH, NaClO and KH550 were used to optimize the treatment of rubber particles. The hydrophilic properties, surface morphology and phase composition of rubber particles before and after optimization were studied, and the optimal treatment method of rubber particles was determined. Then, the optimized rubber particles were used to replace the natural aggregate in the polyurethane gel mixture by the volume substitution method, and the optimum polyurethane gel dosages and molding and curing processes were determined. Finally, the influence law of the road performance of RPGM was compared and analyzed by means of an indoor test, and the ice-breaking effect of RPGM was explored. The results showed that the contact angles of rubber particles treated with three solutions were reduced by 22.5%, 30.2% and 36.7%, respectively. The surface energy was improved, the element types on the surface of rubber particles were reduced and the surface impurities were effectively removed. Among them, the improvement effect of the KH550 solution was the most significant. With the increase in rubber particle content from 0% to 15%, the dynamic stability of the mixture gradually increases, with a maximum increase of 23.5%. The maximum bending strain increases with the increase in its content. The residual stability increases first and then decreases with the increase in rubber particle content, and the increase ranges are 1.4%, 3.3% and 0.5%, respectively. The anti-scattering performance increases with the increase in rubber content, and an excessive amount will lead to an increase in the scattering loss rate, but it can still be maintained below 5%. The fatigue life of polyurethane gel mixtures with 0%, 5%, 10% and 15% rubber particles is 2.9 times, 3.8 times, 4.3 times and 4.0 times higher than that of the AC-13 asphalt mixture, respectively, showing excellent anti-fatigue performance. The friction coefficient of the mixture increases with an increase in the rubber particle content, which can be increased by 22.3% compared with the ordinary asphalt mixture. RPGM shows better de-icing performance than traditional asphalt mixtures, and with an increase in rubber particle content, the ice-breaking ability is effectively improved. When the thickness of the ice layer exceeds 9 mm, the ice-breaking ability of the mixture is significantly weakened. Mainly through the synergistic effect of stress coupling, thermal effect and interface failure, the bonding performance of the ice–pavement interface is weakened under the action of driving load cycle, and the ice layer is loosened, broken and peeled off, achieving efficient de-icing. Full article

The present work introduces a sustainable, low-carbon method to fabricate durable, non-toxic superhydrophobic surfaces using bamboo-derived cellulose. Uniform TEMPO-carboxylated cellulose particles (TOC-Ps), approximately 2 μm in diameter, were synthesized through thermal polymerization and spray drying. These particles, featuring a nano-scale convex structure formed by intertwined TOC nanofibers, were applied to substrates and modified with low-surface-energy materials to achieve superhydrophobicity. At an optimal TOC-P mass ratio of 6%, the surface displayed a water contact angle of 156.2° and a sliding angle of 7°. The coating maintained superhydrophobicity after extensive mechanical testing—120 cm of abrasion, 100 bending cycles, and continuous trampling—and exhibited robust chemical stability across harsh conditions, including subjection to high temperatures, UV irradiation, and corrosive solutions (pH 2–12). The hierarchical micro–nano structure was found to enhance both hydrophobicity and durability, offering an environmentally friendly alternative for self-cleaning surfaces, textiles, and building applications. Full article

Composite materials have the advantages of high strength and low weight, and are therefore used in many areas. However, in humid and marine environments, mechanical properties may deteriorate due to moisture diffusion, especially in glass fiber reinforced polymers (GFRP) and carbon fiber reinforced polymers (CFRP). This study investigated the damage formation and changes in mechanical properties of single-layer adhesive-bonded GFRP and CFRP connections under the effect of sea water. In the experiment, 0/90 orientation, twill-woven GFRP (7 ply) and CFRP (8 ply) plates were produced as prepreg using the hand lay-up method in accordance with ASTM D5868-01 standard. CNC Router was used to cut 36 samples were cut from the plates produced for the experiments. The samples were kept in sea water taken from the Aegean Sea, at 3.3–3.7% salinity and 23.5 °C temperature, for 1, 2, 3, 6, and 15 months. Moisture absorption was monitored by periodic weighings; then, the connections were subjected to three-point bending tests according to the ASTM D790 standard. The damages were analyzed microscopically with SEM (ZEISS GEMINI SEM 560). As a result of 15 months of seawater storage, moisture absorption reached 4.83% in GFRP and 0.96% in CFRP. According to the three-point bending tests, the Young modulus of GFRP connections decreased by 25.23% compared to dry samples; this decrease was 11.13% in CFRP. Moisture diffusion and retention behavior were analyzed according to Fick’s laws, and the moisture transfer mechanism of single-lap adhesively bonded composites under the effect of seawater was evaluated. Full article

The research on nano titanium dioxide (nano-TiO₂)-modified asphalt has received increasing attention. However, further studies are required in order to ascertain the influence of the phenomenon under discussion on the rheological characteristics and ability to resist deformation of bitumen. In the present study, modified bitumen was formulated by adding nano titanium dioxide. Physical property tests, temperature scanning tests, frequency scanning tests, repeated creep recovery tests, bending creep stiffness tests, and long-term aging performance experiments were carried out on the specimen of asphalt that had undergone the process of modification in order to assess the rheological characteristics and ability to resist unrecoverable deformation of the modified bitumen at different temperatures, both high and low. The outcomes of the repeated creep recovery experiment were analyzed using Burgers and fractional derivative models. The microstructure of nano-TiO₂ high-viscosity modified asphalt was observed by Scanning Electron Microscope(SEM). In order to ascertain the manner in which base bitumen and nano-TiO₂ interact, Fourier transform infrared spectroscopy (FTIR) was utilized in the study. The results show that the thermal stability and prolonged aging resistant properties of the modified bitumen binder improved, but nano-TiO₂ made the asphalt binder weaker and more likely to crack at lower temperatures. Taking into account the variation in the road performance of the bitumen binder, 6% is recommended as the optimal amount of nano-TiO₂. Nano-TiO₂ was mainly uniformly distributed in asphalt and nano-TiO₂ was physically mixed with asphalt. In comparison with the Burgers model, the present fractional derivative empirical creep model can fit the creep test data of the asphalt binder well with the advantages of high accuracy and few parameters. The research results provide a reference for promoting the implementation of modified bitumen incorporating nano-TiO₂. Full article