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Keywords = green additive manufacturing

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24 pages, 613 KB  
Article
How Regional Employment Density Shapes Sustainable Manufacturing Performance: A Multidimensional Spatial Analysis
by Yuan Shentu and Rosita Hamdan
Sustainability 2026, 18(3), 1292; https://doi.org/10.3390/su18031292 - 27 Jan 2026
Viewed by 139
Abstract
This study investigates the spatial effects of employment density on the economic, technological, and carbon efficiency of China’s manufacturing sector, using panel data from 30 provinces from 2008 to 2022. A multidimensional performance framework and spatial econometric models are employed to identify both [...] Read more.
This study investigates the spatial effects of employment density on the economic, technological, and carbon efficiency of China’s manufacturing sector, using panel data from 30 provinces from 2008 to 2022. A multidimensional performance framework and spatial econometric models are employed to identify both direct impacts and spatial spillovers. The results show that employment density significantly enhances local economic performance while imposing negative spillover effects on neighboring regions. Technological performance exhibits uneven spatial returns, indicating a “technology siphoning” effect in more agglomerated provinces. Carbon efficiency presents a divergent pattern of “local improvement but neighboring deterioration,” highlighting cross-regional ecological externalities. In addition, human capital, capital investment, and regional policy intensity are found to regulate the strength and direction of spatial spillovers across the three performance dimensions. Based on these findings, this study recommends optimizing the spatial layout of manufacturing and population, strengthening interregional innovation collaboration, promoting green transformation, and improving the quality of human capital. These policy implications provide empirical support for advancing sustainable manufacturing development and enhancing regional governance capacity. Full article
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26 pages, 550 KB  
Review
Recovery of Critical Metals from Waste-Printed Circuit Boards for Sustainable Energy Transition
by Lucian-Cristian Pop, Szabolcs Szima and Szabolcs Fogarasi
Crystals 2026, 16(1), 67; https://doi.org/10.3390/cryst16010067 - 20 Jan 2026
Viewed by 377
Abstract
It is undeniable that rapid population increase coupled with growing resource constraints are making the demand for smart and sustainable solutions more urgent than ever to secure future resources for the transition to sustainable energy production. To address these issues, it is necessary [...] Read more.
It is undeniable that rapid population increase coupled with growing resource constraints are making the demand for smart and sustainable solutions more urgent than ever to secure future resources for the transition to sustainable energy production. To address these issues, it is necessary to define innovative approaches that can exploit more efficiently and extensively the resources we have at our disposal. Consequently, this paper provides an overview of the potential benefits of processing waste-printed circuit boards (WPCBs) that are generated in large quantities and, due to their high metal content, can emerge as an adequate and profitable supply of critical metals, such as copper, aluminum, and nickel, which are essential for green energy transition. The review promotes the idea of industrial symbiosis as a concept that goes beyond circular economy and can integrate WPCB treatment and manufacturing processes related to sustainable energy transition, although they are different industrial sectors that can be even regionally separated. Major metal recovery processes from WPCBs are examined and discussed, with the primary focus on the performances of copper, aluminum, and nickel production, while additional metals relevant to the energy transition are also highlighted. Finally, the review paper argues and exemplifies that the recovered metals from WPCBs have the required properties to be supplied into the manufacturing processes of wind turbines, solar panels, and lithium-ion batteries. Full article
(This article belongs to the Special Issue Exploring New Materials for the Transition to Sustainable Energy)
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0 pages, 4591 KB  
Article
Environmental Impact Assessment of New Cement Production Blending Calcareous Green Algae and Fly Ash
by Hafiz M. Irfan, Chi-Yun Wu, Muhammad Saddam Hussain and Wei Wu
Processes 2026, 14(2), 299; https://doi.org/10.3390/pr14020299 - 14 Jan 2026
Viewed by 241
Abstract
To improve traditional cement manufacturing, which generates a large amount of greenhouse gases, blending calcareous green algae and fly ash as cement replacement materials is expected to achieve nearly zero carbon emissions. As a calcareous green alga, Halimeda macroloba is a significant producer [...] Read more.
To improve traditional cement manufacturing, which generates a large amount of greenhouse gases, blending calcareous green algae and fly ash as cement replacement materials is expected to achieve nearly zero carbon emissions. As a calcareous green alga, Halimeda macroloba is a significant producer of biogenic calcium carbonate (CaCO3), sequestering approximately 440 kg of carbon dioxide (CO2) per 1000 kg of CaCO3, with CaCO3 production reported in relation to algal biomass. To assess the new low-carbon/low-waste cement production process, the proposed scenarios (2 and 3) are validated via Python-based modeling (Python 3.12) and Aspen Plus® simulation (Aspen V14). The core technology is the pre-calcination of algae-derived CaCO3 and fly ash from coal combustion, which are added to a rotary kiln to enhance the proportions of tricalcium silicate (C3S) and dicalcium silicate (C2S) for forming the desired silicate phases in clinker. Through the lifecycle assessment (LCA) of all scenarios using SimaPro® (SimaPro 10.2.0.3), the proposed Scenario 2 achieves the GWP at approximately 0.906 kg CO2-eq/kg clinker, lower than the conventional cement production process (Scenario 1) by 47%. If coal combustion is replaced by natural gas combustion, the fly ash additive is reduced by 74.5% in the cement replacement materials, but the proposed Scenario 3 achieves the GWP at approximately 0.753 kg CO2-eq/kg clinker, lower than Scenario 2 by 16.9%. Moreover, the LCA indicators show that Scenario 3 has lower environmental impacts on human health, ecosystem, and resources than Scenario 1 by 24.5%, 60.0% and 68.6%, respectively. Full article
(This article belongs to the Section Environmental and Green Processes)
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21 pages, 12758 KB  
Article
Implementation of a Digital Twin in Additive Manufacturing of Copper—Methodology, Implications, and Future Prospects
by Moritz Benedikt Schäfle, Michel Fett, Philipp Bojunga, Florian Sondermann and Eckhard Kirchner
Machines 2026, 14(1), 97; https://doi.org/10.3390/machines14010097 - 13 Jan 2026
Viewed by 251
Abstract
Digital twins are increasingly being used to visualize, analyze, or control physical processes and systems. Implementation currently poses challenges for users due to the cross-domain complexity of digital twins. In this study, the authors utilize a self-developed method to support the implementation of [...] Read more.
Digital twins are increasingly being used to visualize, analyze, or control physical processes and systems. Implementation currently poses challenges for users due to the cross-domain complexity of digital twins. In this study, the authors utilize a self-developed method to support the implementation of a digital twin (DT) for a powder bed fusion additive manufacturing system (PBF-LB/M) for copper components, utilizing a green laser. The study highlights the support offered by the developed approach and the implications of using DTs for PBF of copper. The DT focuses in particular on monitoring maintenance requirements, assisting in the selection of correct process parameters, and alerting plant operators in the event of problems. In addition, a process model focused on lack of fusion is implemented, based on earlier studies. In the human–machine system, DTs thus represent a further building block towards an improved process stability in PBF-LB/M of copper, and the method used lowers the barrier to entry for widespread use of DTs. Full article
(This article belongs to the Section Advanced Manufacturing)
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13 pages, 2799 KB  
Article
Effects of Binder Saturation and Drying Time in Binder Jetting Additive Manufacturing on Dimensional Deviation and Density of SiC Green Parts
by Mostafa Meraj Pasha, Zhijian Pei, Md Shakil Arman and Stephen Kachur
J. Manuf. Mater. Process. 2026, 10(1), 26; https://doi.org/10.3390/jmmp10010026 - 9 Jan 2026
Viewed by 300
Abstract
Binder jetting additive manufacturing (BJAM) offers an effective approach for fabricating silicon carbide (SiC) parts with complex geometries; however, part quality is strongly influenced by process variables. Binder saturation and drying time are key process variables in BJAM, yet their individual influences on [...] Read more.
Binder jetting additive manufacturing (BJAM) offers an effective approach for fabricating silicon carbide (SiC) parts with complex geometries; however, part quality is strongly influenced by process variables. Binder saturation and drying time are key process variables in BJAM, yet their individual influences on the density and dimensional deviation of SiC green parts remain underexplored. To address this gap, this study systematically investigates the effects of binder saturation and drying time on the dimensional deviation and density of SiC green parts by evaluating four binder saturation levels (60%, 80%, 100%, and 120%) and three drying times (15, 30, and 45 s). The results show that increasing binder saturation reduces green part density and increases dimensional deviation, whereas increasing drying time improves density and reduces dimensional deviation. Excessive drying, however, causes severe warpage, preventing the fabrication of dimensionally accurate parts. These findings highlight the need to optimize binder saturation and drying time to improve the density of printed parts while minimizing dimensional deviation. Full article
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22 pages, 616 KB  
Article
Green Transformational Leadership and Value–Action Barrier on Employees’ Pro-Environmental Behavior: The Moderating Role of Green Brand Image in Chinese Food Manufacturing Enterprises
by Liqing Zhong and Juhee Hahn
Behav. Sci. 2026, 16(1), 71; https://doi.org/10.3390/bs16010071 - 5 Jan 2026
Viewed by 357
Abstract
As public attention to environmental issues grows, enterprises have begun implementing environment-centered business management. Achieving environmental sustainability requires the participation of all organizational members. This study was conducted in Chinese food manufacturing small and medium-sized enterprises located in Guangdong and Jiangsu provinces, China, [...] Read more.
As public attention to environmental issues grows, enterprises have begun implementing environment-centered business management. Achieving environmental sustainability requires the participation of all organizational members. This study was conducted in Chinese food manufacturing small and medium-sized enterprises located in Guangdong and Jiangsu provinces, China, and employed a three-wave, time-lagged survey design to collect and match data from team leaders and employees. Hierarchical linear modeling was used to test the cross-level hypotheses, and the indirect effect was assessed using Bayesian multilevel mediation analysis. Using cross-level data from both team leaders and team members, this study examines how green transformational leadership impacts employees’ pro-environmental behavior. In addition, this study examines the mediating role of employee value–action barriers and the moderating role of green brand image. The results indicate that (1) green transformational leadership positively influences employee pro-environmental behavior, (2) employee value–action barriers mediate the relationship between green transformational leadership and employee pro-environmental behavior, and (3) green brand image moderates both the correlation between green transformational leadership and employee pro-environmental behavior and the relationship between employee value–action barriers and employee pro-environmental behavior. These findings provide empirical support for the application of social learning theory and offer managerial insights into how managers can more effectively enhance their employees’ pro-environmental behavior. Future research may further test the robustness and applicability of these relationships in other industries and in different regional and national contexts. Full article
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18 pages, 822 KB  
Article
Evaluating Green Finance: Investment Patterns and Environmental Outcomes
by Lala Rukh, Shakir Ullah, Ijaz Sanober, Umar Hayat and Sangeen Khan
Int. J. Financial Stud. 2025, 13(4), 245; https://doi.org/10.3390/ijfs13040245 - 18 Dec 2025
Viewed by 581
Abstract
This study aims to investigate the impact of green finance on corporate sector investments and their associated environmental outcomes. The authors collected cross-sectional survey data with a sample of four hundred firms selected from the five green-relevant industries in an emerging economy. The [...] Read more.
This study aims to investigate the impact of green finance on corporate sector investments and their associated environmental outcomes. The authors collected cross-sectional survey data with a sample of four hundred firms selected from the five green-relevant industries in an emerging economy. The results indicate that, over the last three years, seventy percent of firms have accessed at least one green instrument. Overall, the firms under study indicate that PKR 3.4 million is being allocated to green finance, and PKR 2.7 million is spent on CAPEX. However, each million PKR is associated with a ten percent capital expenditure, which exhibits the highest adoption of the renewable energy sector, while the manufacturing sector has the lowest adoption. Regression results depict that Greenhouse gas reduction is only achievable if expenditure on R&D is ensured for environmental gains. This study indicates a declining incremental impact when green finance exceeds PKR 5.00 million, suggesting that firms’ limitations in utilizing the additional amount may be a factor. Financially constrained firms achieve stronger environmental goals, confirming that strict criteria to finance projects show more responsibility and discipline in executing projects. However, small- and medium-sized firms are confronted with barriers, such as lack of information and transaction costs. The findings of this study highlight the need for a multi-layered regulatory framework, innovation-driven incentives, and fintech integration to fully realize the potential of green finance. The outcome enables financial institutions, sustainability practitioners, and regulators to connect financial markets, national climate, and development goals. Full article
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34 pages, 9360 KB  
Review
Flame-Retardant Fiber-Reinforced Composites: Advances and Prospects in Multi-Performance Synergy
by Zihan Zhang, Feng Han, Haoran Li, Tianyu Li, Boran Yang, Jinhu Hu and Ye-Tang Pan
J. Compos. Sci. 2025, 9(12), 703; https://doi.org/10.3390/jcs9120703 - 16 Dec 2025
Cited by 1 | Viewed by 974
Abstract
Fiber-reinforced polymer composites, particularly carbon fiber and glass fiber reinforced composites, are widely used in cutting-edge industries due to their excellent properties, such as light weight and high strength. This review systematically compares and summarizes recent research advances in flame retardancy for carbon [...] Read more.
Fiber-reinforced polymer composites, particularly carbon fiber and glass fiber reinforced composites, are widely used in cutting-edge industries due to their excellent properties, such as light weight and high strength. This review systematically compares and summarizes recent research advances in flame retardancy for carbon fiber-reinforced polymers and glass fiber-reinforced polymers. Focusing on various polymer matrices, including epoxy, polyamide, and polyetheretherketone, the mechanisms and synergistic effects of different flame-retardant modification strategies—such as additive flame retardants, nanocomposites, coating techniques, intrinsically flame-retardant polymers, and advanced manufacturing processes—are analyzed with emphasis on improving flame retardancy and suppressing the “wick effect.” The review critically examines the challenges in balancing flame retardancy, mechanical performance, and environmental friendliness in current approaches, highlighting the key role of interface engineering in mitigating the “wick effect.” Based on this analysis, four future research directions are proposed: implementing green design principles throughout the material life cycle; promoting the use of natural fibers, bio-based resins, and bio-derived flame retardants; developing intelligent responsive flame-retardant systems based on materials such as metal–organic frameworks; advancing interface engineering through biomimetic design and advanced characterization to fundamentally suppress the fiber “wick effect”; and incorporating materials genome and high-throughput preparation technologies to accelerate the development of high-performance flame-retardant composites. This review aims to provide systematic theoretical insights and clear technical pathways for developing the next generation of high-performance, safe, and sustainable fiber-reinforced composites. Full article
(This article belongs to the Section Polymer Composites)
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19 pages, 1037 KB  
Article
Effects of Manufacturing Agglomeration on Pollutant Emissions: The Role of Energy Intensity in China
by Yidai Feng and Huaxi Yuan
Sustainability 2025, 17(24), 11225; https://doi.org/10.3390/su172411225 - 15 Dec 2025
Viewed by 392
Abstract
Manufacturing agglomeration (MA) is an important driving force for both sustained economic expansion and structural upgrading. Understanding whether and how MA contributes to energy conservation and pollutant mitigation is essential for promoting China’s green transition and offers valuable insight for emerging economies pursuing [...] Read more.
Manufacturing agglomeration (MA) is an important driving force for both sustained economic expansion and structural upgrading. Understanding whether and how MA contributes to energy conservation and pollutant mitigation is essential for promoting China’s green transition and offers valuable insight for emerging economies pursuing sustainable growth. The paper first theoretically examines the mechanisms linking MA, energy intensity (EI), and pollutant emission (PE). To overcome the regression bias caused by the heterogeneity of pollutant types among cities, the comprehensive index of PE is constructed. The empirical analysis yields two principal findings. First, MA significantly reduces PE, and this relationship remains robust after a series of tests. Second, EI plays a significant mediating role between MA and PE, that is, MA can achieve the reduction targets of PE by reducing EI. Therefore, in addition to its established role in fostering economic growth, MA should be utilized for its environmental advantages. Policymakers should give greater weight to the capacity of MA to enhance energy conservation and emission reduction, so as to stimulate the positive interaction among MA, EI, and PE, and thereby formulate more differentiated policies. Full article
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17 pages, 333 KB  
Review
Effectiveness of Common Extraction Solvents in Obtaining Antioxidant Compounds from African Medicinal Plants
by Khayelihle Ncama, Joseph Malele, Dhiren Munsami Govender, Thagen Anumanthoo and Mack Moyo
Antioxidants 2025, 14(12), 1498; https://doi.org/10.3390/antiox14121498 - 13 Dec 2025
Viewed by 1001
Abstract
The efficacy of phytoextracts is equally affected by the extraction solvent and the extraction method. Details of the solvent type, concentration, density, and other characteristics are associated with the quality of the resultant extract. Some solvents have been found to be effective only [...] Read more.
The efficacy of phytoextracts is equally affected by the extraction solvent and the extraction method. Details of the solvent type, concentration, density, and other characteristics are associated with the quality of the resultant extract. Some solvents have been found to be effective only on specific parts of plants. Industry has shown a growing interest in eco-friendly plant extracts for the formulation of medication, food additives, cosmetics, and agricultural products. This interest is aligned with the proven necessity of sustainability, marketability, and regulation of manufactured products in value chains. In this review, the literature on antioxidant compounds and activity of extracts from African medicinal plants is reviewed. Findings indicate that the use of ethanol, methanol, water, and to a lesser extent, acetone as solvents for the extraction of antioxidant compounds is common. The use of these solvents is supported by decisive selection of procedure, ideal temperature, duration, solvent pH, and the extracted plant parts. Fermentation enhances the antioxidant activity of aqueous extracts but reduces that of alcohol extracts. This is particularly essential in continents such as Africa, where water is available but alcohol is scarce. “Green” extraction technologies are not as successful as solvent extractions for use with African medicinal plants. There is a financial hurdle that results in a mismatch between academic research innovations and societal transmission to new technologies, as most communities are dominated by small-to-medium enterprises. Further studies on the extraction of antioxidants from African medicinal plants are recommended to guide the research and link it to ordinary African societies. Full article
40 pages, 2992 KB  
Review
Advances in Mesoporous Silica and Hybrid Nanoparticles for Drug Delivery: Synthesis, Functionalization, and Biomedical Applications
by Ahmad Almatroudi
Pharmaceutics 2025, 17(12), 1602; https://doi.org/10.3390/pharmaceutics17121602 - 12 Dec 2025
Cited by 1 | Viewed by 1080
Abstract
Mesoporous silica nanoparticles (MSNs) are among the most adaptable nanocarriers in modern pharmaceutics, characterized by a high surface area, tunable pore size, controllable morphology, and excellent biocompatibility. These qualities enable effective encapsulation, protection, and the delivery of drugs in a specific area and, [...] Read more.
Mesoporous silica nanoparticles (MSNs) are among the most adaptable nanocarriers in modern pharmaceutics, characterized by a high surface area, tunable pore size, controllable morphology, and excellent biocompatibility. These qualities enable effective encapsulation, protection, and the delivery of drugs in a specific area and, therefore, MSNs are powerful platforms for the targeted and controlled delivery of drugs and theragnostic agents. Over the past ten years and within the 2021–2025 period, the advancement of MSN design has led to the creation of hybrid nanostructures into polymers, lipids, metals, and biomolecules that have yielded multifunctional carriers with enhanced stability, responsiveness, and biological activities. The current review provides a review of the synthesis methods, surface functionalization techniques, and physicochemical characterization techniques that define the next-generation MSN-based delivery systems. The particular focus is put on stimuli-responsive systems, such as redox, pH, enzyme-activated, and light-activated systems, that enable delivering drugs in a controlled and localized manner. We further provide a summary of the biomedical use of MSNs and their hybrids such as in cancer chemotherapy, gene and nucleic acid delivery, antimicrobial and vaccine delivery, and central nervous system targeting, supported by recent in vivo and in vitro studies. Important evaluations of biocompatibility, immunogenicity, degradation, and biodistribution in vivo are also provided with a focus on safety in addition to the regulatory impediments to clinical translation. The review concludes by saying that there are still limitations such as large-scale reproducibility, long-term toxicity, and standardization by the regulators, and that directions are being taken in the future in the fields of smart programmable nanocarriers, green synthesis, and sustainable manufacture. Overall, mesoporous silica and hybrid nanoparticles represent a breakthrough technology in the nanomedicine sector with potentials that are unrivaled in relation to targeted, controlled, and personalized therapeutic interventions. Full article
(This article belongs to the Section Drug Delivery and Controlled Release)
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21 pages, 4153 KB  
Article
Profit-Driven Framework for Low-Carbon Manufacturing: Integrating Green Certificates, Demand Response, Distributed Generation and CCUS
by Yi-Chang Li, Mengyao Wang, Rui Huang, Lu Chen, Xueying Wang, Xiaoqin Xiong, Min Jiang, Lijie Cui, Zhiyang Jia and Zhong Jin
Energies 2025, 18(24), 6517; https://doi.org/10.3390/en18246517 - 12 Dec 2025
Viewed by 337
Abstract
In recent years, the manufacturing industry and power sector have collectively accounted for nearly 60% of global carbon emissions, presenting a formidable obstacle to achieving net-zero targets by 2050. To address the urgent need for industrial decarbonization, this paper proposes a profit-driven framework [...] Read more.
In recent years, the manufacturing industry and power sector have collectively accounted for nearly 60% of global carbon emissions, presenting a formidable obstacle to achieving net-zero targets by 2050. To address the urgent need for industrial decarbonization, this paper proposes a profit-driven framework for low-carbon manufacturing that synergistically integrates green certificates, demand response, distributed generation, and carbon capture, utilization, and storage (CCUS) technologies. A comprehensive optimization model is formulated to enable manufacturers to maximize profits through strategic participation in electricity, carbon, green certificate, and industrial manufacturing product markets simultaneously. By solving this optimization problem, manufacturers can derive optimal production decisions. The framework’s effectiveness is demonstrated through a case study on lithium-ion battery manufacturing, which reveals promising outcomes: meaningful profit growth, substantial carbon emission reductions, and only minimal impacts on production output. Furthermore, the proposed demand response strategy achieves significant reductions in electricity consumption during peak hours, while the integration of distributed generation systems markedly decreases reliance on the main grid. The incorporation of CCUS extends the clean operation periods of thermal power units, generating additional revenue from carbon trading and CO2 utilization. In summary, the proposed model represents the first unified profit-maximizing optimization framework for low-carbon manufacturing industries, shifting from traditional cost minimization to profitability optimization, addressing gaps in fragmented low-carbon strategies, and providing a replicable blueprint for carbon-neutral operations while enhancing profitability. Full article
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17 pages, 2488 KB  
Article
Constructing a Cradle-to-Gate Carbon Emission Assessment and Analysis Framework Based on Life Cycle Thinking: A Case Study of Bicycle Brake Cable Products
by Jui-Che Tu, Pei-Chi Huang, Shi-Chen Luo and Kharisma Creativani
Sustainability 2025, 17(24), 10938; https://doi.org/10.3390/su172410938 - 7 Dec 2025
Viewed by 407
Abstract
In 2023, the bicycle industry in Taiwan reached a historic high. However, concerns about carbon emissions persist, particularly during the material acquisition and manufacturing stages of bicycle production. This study utilizes the Life Cycle Assessment (LCA) method, using SimaPro 9.5 for cradle-to-gate carbon [...] Read more.
In 2023, the bicycle industry in Taiwan reached a historic high. However, concerns about carbon emissions persist, particularly during the material acquisition and manufacturing stages of bicycle production. This study utilizes the Life Cycle Assessment (LCA) method, using SimaPro 9.5 for cradle-to-gate carbon emission data analysis. This study thoroughly examines the complete life cycle of a bicycle brake cable product through a carbon reduction evaluation tool, identifying carbon hotspots in the product’s life cycle. The data reveals that packaging accounts for the highest proportion of factory carbon emissions in the brake cable product analysis (34.42%), followed by the product’s casing (30.60%), with the leading materials being metal, plastic, and paper. Throughout the cradle-to-gate process, we collaborated with product developers to utilize the LCA carbon reduction evaluation tool to analyze the life cycle of the brake cable product. By aligning market and development needs, we supported manufacturers in identifying additional carbon reduction strategies at the material selection, mechanical design, and manufacturing process stages. These strategies include using natural raw materials, reducing packaging volume, developing lightweight products, and investing in integrated equipment. By implementing these measures, companies can reduce the product’s carbon footprint and enhance resource efficiency during production. This assessment tool serves as a communication bridge between designers and engineers, translating LCA quantitative data into references for design and management decision-making. It also functions as a simplified analytical tool for SMEs to conduct preliminary diagnosis of carbon emission hotspots and plan improvement directions, particularly suitable for manufacturers lacking consulting resources and carbon inventory capabilities. The research findings not only help companies integrate carbon reduction thinking early in product development, forming a closed-loop system of quantitative analysis and design actions, but also provide concrete references for Taiwan’s bicycle industry to promote supply chain collaboration, achieve green transformation, and meet global carbon reduction goals. Full article
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19 pages, 4311 KB  
Article
Effect of Initial Relative Density on Liquid-Phase Sintering Behaviors of Al Powder Using Al–Cu Eutectic Alloy Aid: In Situ Observations Using Tomography and Microscopy
by Ryotaro Kusunoki, Erika Matsumoto, Takeshi Higaki, Asuka Suzuki, Makoto Kobashi, Yukiko Ozaki, Masato Hoshino and Masayuki Uesugi
Materials 2025, 18(24), 5499; https://doi.org/10.3390/ma18245499 - 7 Dec 2025
Viewed by 588
Abstract
Aluminum (Al) powder with low sinterability is difficult to use in binder jetting (BJT) additive manufacturing, which involves sintering a metal powder after forming a green body. A liquid-phase sintering process for Al powder using Al–Cu eutectic alloy powder as a sintering aid [...] Read more.
Aluminum (Al) powder with low sinterability is difficult to use in binder jetting (BJT) additive manufacturing, which involves sintering a metal powder after forming a green body. A liquid-phase sintering process for Al powder using Al–Cu eutectic alloy powder as a sintering aid has recently been developed. In this study, to clarify the applicability of liquid-phase sintering to BJT additive manufacturing, the effect of the initial relative density of green bodies (ρrel,0 = 50–90%) on the final relative density was investigated. The final relative density was not significantly affected by ρrel,0 and achieved 96–97% after sintering at 630 °C for 1800 s. However, pores are likely to remain in the sintered body with a high ρrel,0 of 90%. In situ observations using synchrotron radiation X-ray computed tomography revealed that large pores were formed at the early sintering stage of the green body with ρrel,0 of 90% and partially retained after sintering. By contrast, the green body with ρrel,0 of 50% exhibited a significant rearrangement at the early sintering stage, promoting the densification. This study provides a deep understanding of liquid-phase sintering of Al powder, which is considered a suitable post-processing method for BJT additive manufacturing. Full article
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35 pages, 15734 KB  
Article
Demonstration of 3D-Printed Concrete Containing Fine Recycled Concrete Aggregates (fCAs) and Recycled Concrete Powder (RCP): Rheology, Early-Age, Shrinkage, Mechanical, and Durability Performance
by Pawel Sikora, Karol Federowicz, Szymon Skibicki, Mateusz Techman, Marcin Hoffmann, Joao Nuno Pacheco, Mehdi Chougan, Daniel Grochała, Krzysztof Cendrowski, Daniel Sibera, Jarosław Błyszko, Bartosz Budziński, Guan Lin and Aleksandra Ludwiczak-Sarzała
Buildings 2025, 15(23), 4255; https://doi.org/10.3390/buildings15234255 - 25 Nov 2025
Viewed by 797
Abstract
The paper presents a comprehensive analysis of cement-based composites incorporating both fine recycled concrete aggregates (fRAs) and recycled concrete powder (RCP), which were used for 3D concrete printing. The study evaluates properties ranging from fresh-state behaviour to hardened properties, durability, and microstructural characteristics. [...] Read more.
The paper presents a comprehensive analysis of cement-based composites incorporating both fine recycled concrete aggregates (fRAs) and recycled concrete powder (RCP), which were used for 3D concrete printing. The study evaluates properties ranging from fresh-state behaviour to hardened properties, durability, and microstructural characteristics. In the final stage, a life cycle assessment (LCA) was conducted. A study found that it is feasible to print a composite containing up to 100% fRA as a replacement for natural river sand. Notably, an increase in fRA content enhances the buildability of the mix, as confirmed by green strength tests. However, the open time of mixes containing fRA and RCP was shortened. Incorporation of RCP and fRA led to a decrease in shrinkage within the first 24 h of hydration. Mechanical studies reported a significant reduction in compressive strength (up to 55%) when RCP and fRA were introduced to the mix. Despite the reduction in mechanical properties in specific configurations, all mixes—including 100% fRA and 10% RCP—exhibited compressive strengths above 30 MPa, demonstrating their potential suitability for use in the construction industry. The durability properties of mixes modified with fRA show that there is a statistically significant reduction in flexural strength after 25 and 50 freeze–thaw cycles. In terms of compressive strength, cast specimens did not exhibit any notable reduction in mechanical performance after freezing and thawing cycles. The LCA results demonstrate the high potential for using fRA and RCP derived from concrete waste in the additive manufacturing industry. Full article
(This article belongs to the Special Issue Advanced Studies in Cement-Based Materials)
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