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18 pages, 3937 KB  
Article
A Novel SPH-Based Approach to Predicting Explosion-Induced Failure and Containment in 18650 Battery Systems
by Murat Demiral, Erol Gültekin and Murat Otkur
Appl. Sci. 2026, 16(1), 153; https://doi.org/10.3390/app16010153 - 23 Dec 2025
Abstract
This study presents a comprehensive smoothed particle hydrodynamics (SPH) framework developed to investigate the thermomechanical response and failure behavior of cylindrical 18650-type lithium-ion battery cans under explosion conditions. The model captures the coupled evolution of gas pressure, temperature, and particle dynamics, as well [...] Read more.
This study presents a comprehensive smoothed particle hydrodynamics (SPH) framework developed to investigate the thermomechanical response and failure behavior of cylindrical 18650-type lithium-ion battery cans under explosion conditions. The model captures the coupled evolution of gas pressure, temperature, and particle dynamics, as well as the resulting deformation and fracture of the metallic enclosure. Parametric analyses were conducted to evaluate the influence of the internal gas domain geometry, can wall thickness, and initial pressure on the structural response, along with the subsequent post-explosion interaction between the escaping gas and external protective coverage. The results demonstrate the strong dependence of failure initiation on gas confinement geometry and highlight the existence of transient thermodynamic asymmetries within the gas domain that govern the impulse transferred to the can wall. The proposed modeling approach provides a physically consistent means of reproducing the key stages of battery explosion—from internal pressurization to external gas impact—and offers valuable insights for designing safer and more resilient energy storage enclosures. Full article
(This article belongs to the Special Issue Advances in Structural Integrity and Failure Analysis)
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22 pages, 5756 KB  
Review
Hyperhydricity Syndrome in In Vitro Plants: Mechanisms, Physiology, and Control
by Rajesh Barua, Abir U. Igamberdiev and Samir C. Debnath
Plants 2025, 14(24), 3721; https://doi.org/10.3390/plants14243721 - 5 Dec 2025
Viewed by 499
Abstract
Understanding the physiological characteristics of hyperhydric plantlets is ultimately necessary since hyperhydricity results in financial loss for in vitro plants from a commercial perspective. Although many studies report the possible causes and symptoms of hyperhydricity, knowledge of it remains limited. This review aims [...] Read more.
Understanding the physiological characteristics of hyperhydric plantlets is ultimately necessary since hyperhydricity results in financial loss for in vitro plants from a commercial perspective. Although many studies report the possible causes and symptoms of hyperhydricity, knowledge of it remains limited. This review aims to provide an integrated overview of this phenomenon and outline the perspectives for its prevention. First, we summarize the factors of in vitro hyperhydricity, including gelling agents, growth regulators, vessel ventilation and gas exchange, light, and osmotic conditions. Second, we describe physiological and internal changes commonly observed in hyperhydric plants, such as ROS/ethylene imbalance, altered antioxidant capacity, defects in the cell wall, and lignification. Third, we outline ultrastructural characteristics and accumulate HPLC findings to recognize the metabolite profiles of hyperhydric plantlets. Fourth, we introduce emerging AI-assisted MLM (machine learning model) approaches to detect and optimize the culture parameters to prevent hyperhydricity. Finally, we evaluate the strategies for the protection of the culture from hyperhydric conditions. This structured overview intends to reduce hyperhydricity in commercial and research settings. Full article
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32 pages, 2523 KB  
Article
Hybrid Nanofluid Flow and Heat Transfer in Inclined Porous Cylinders: A Coupled ANN and Numerical Investigation of MHD and Radiation Effects
by Muhammad Fawad Malik, Reem Abdullah Aljethi, Syed Asif Ali Shah and Sidra Yasmeen
Symmetry 2025, 17(11), 1998; https://doi.org/10.3390/sym17111998 - 18 Nov 2025
Viewed by 480
Abstract
This study investigates the thermal characteristics of two hybrid nanofluids, single-walled carbon nanotubes with titanium dioxide (SWCNTTiO2) and multi-walled carbon nanotubes with copper (MWCNTCu [...] Read more.
This study investigates the thermal characteristics of two hybrid nanofluids, single-walled carbon nanotubes with titanium dioxide (SWCNTTiO2) and multi-walled carbon nanotubes with copper (MWCNTCu), as they flow over an inclined, porous, and longitudinally stretched cylindrical surface with kerosene as the base fluid. The model takes into consideration all of the consequences of magnetohydrodynamic (MHD) effects, thermal radiation, and Arrhenius-like energy of activation. The outcomes of this investigation hold practical significance for energy storage systems, nuclear reactor heat exchangers, electronic cooling devices, biomedical hyperthermia treatments, oil and gas transport processes, and aerospace thermal protection technologies. The proposed hybrid ANN–numerical framework provides an effective strategy for optimizing the thermal performance of hybrid nanofluids in advanced thermal management and energy systems. A set of coupled ordinary differential equations is created by applying similarity transformations to the governing nonlinear partial differential equations that reflect conservation of mass, momentum, energy, and species concentration. The boundary value problem solver bvp4c, which is based in MATLAB (R2020b), is used to solve these equations numerically. The findings demonstrate that, in comparison to the MWCNTCu/kerosene nanofluid, the SWCNTTiO2/kerosene hybrid nanofluid improves the heat transfer rate (Nusselt number) by up to 23.6%. When a magnetic field is applied, velocity magnitudes are reduced by almost 15%, and the temperature field is enhanced by around 12% when thermal radiation is applied. The impact of important dimensionless variables, such as the cylindrical surface’s inclination angle, the medium’s porosity, the magnetic field’s strength, the thermal radiation parameter, the curvature ratio, the activation energy, and the volume fraction of nanoparticles, is investigated in detail using a parametric study. According to the comparison findings, at the same flow and thermal boundary conditions, the SWCNTTiO2/kerosene hybrid nanofluid performs better thermally than its MWCNTCu/kerosene counterpart. These results offer important new information for maximizing heat transfer in engineering systems with hybrid nanofluids and inclined porous geometries under intricate physical conditions. With its high degree of agreement with numerical results, the ANN model provides a computationally effective stand-in for real-time thermal system optimization. Full article
(This article belongs to the Special Issue Integral/Differential Equations and Symmetry)
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14 pages, 4953 KB  
Article
Micro- and Nano-Integration in the Production of GaAs and Ga2O3 Nanowire Arrays by Top-Down Design
by Elena I. Monaico, Eduard V. Monaico, Veaceslav V. Ursaki and Ion M. Tiginyanu
J. Manuf. Mater. Process. 2025, 9(11), 376; https://doi.org/10.3390/jmmp9110376 - 16 Nov 2025
Viewed by 580
Abstract
In this paper, a strategy is proposed based on the microstructuring of GaAs substrates by photolithography combined with nanostructuring by electrochemical etching for the purposes of obtaining GaAs nanowire domains in selected regions of the substrate. The micropatterning is based on previously obtained [...] Read more.
In this paper, a strategy is proposed based on the microstructuring of GaAs substrates by photolithography combined with nanostructuring by electrochemical etching for the purposes of obtaining GaAs nanowire domains in selected regions of the substrate. The micropatterning is based on previously obtained knowledge about the mechanisms of pore growth in GaAs substrates during anodization. According to previous findings, crystallographically oriented pores, or “crysto pores,” grow along specific crystallographic directions within the GaAs substrates, with preferential propagation along the <111>B direction. Taking advantage of this feature, it is proposed to pattern the (111)B surface by photolithography and to, subsequently, apply anodization in an HNO3 electrolyte. It is shown that the areas of the GaAs substrate under the photoresist mask are protected against porosification due to the growth of pores perpendicular to the surface of the substrates in such a configuration. Pores overlapping under adjusted electrochemical etching conditions results in the formation of GaAs nanowire arrays in the substrate regions not covered by photoresist. Thermal annealing conditions in an argon atmosphere with a low oxygen concentration were developed for the selective oxidation of GaAs nanowires, thus producing a wide-bandgap Ga2O3 nanowire pattern on the GaAs substrate. It is shown that the morphology of nanowires can be controlled by adjusting the electrochemical parameters. Smooth-walled nanowire arrays were obtained under specific conditions, while perforated and wall-modulated nanowires were formed when crystallographic pores intersected at a higher applied anodizing potential. Full article
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14 pages, 3474 KB  
Article
Evaluation of the Fire Safety Performance of Fire-Resistant Coatings in BIPV Modules
by Yong Chan Jung, Min Ji Song, Hee Kyung Park, Min Chul Lee and Soo Yeol Lee
Fire 2025, 8(11), 428; https://doi.org/10.3390/fire8110428 - 31 Oct 2025
Viewed by 874
Abstract
Building-Integrated Photovoltaics (BIPV), which are used for building exteriors such as walls, roofs, balconies, and awnings, play a significant role in reducing greenhouse gas emissions. However, since the back sheet, sealant, junction box, and cable of BIPV modules are made of flammable plastic [...] Read more.
Building-Integrated Photovoltaics (BIPV), which are used for building exteriors such as walls, roofs, balconies, and awnings, play a significant role in reducing greenhouse gas emissions. However, since the back sheet, sealant, junction box, and cable of BIPV modules are made of flammable plastic materials, fire protection technologies are needed to ensure fire safety. The aim of this work is to evaluate the fire safety performance of BIPV modules coated with fire-resistant (FRs) and flame-retardant (FRt) materials. The test results show that the performance of the FRs coating was excellent in terms of fire blocking, physical properties, and durability, compared to the FRt coating. Surface damage, such as cracks and blisters, was observed on the FRt coating during the impact and acid resistance tests, whereas the FRs coating demonstrated superior durability without any defects. Specifically, aluminum hydroxide (ATH, 5–10 wt%) added to the FRs coating promoted an endothermic reaction that lowered the flame temperature, released H2O, and stably formed an Al2O3 heat-shielding layer. Due to this reaction, the suppression of the fire spread by the BIPV modules was the best compared to that of Mg, Ti, and Si-based additives. Full article
(This article belongs to the Special Issue Advances in Industrial Fire and Urban Fire Research: 2nd Edition)
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19 pages, 7223 KB  
Article
Analysis of Failure Cause in Steel Wire-Reinforced Thermoplastic Composite Pipes for Sour Gas Field Water Transportation
by Zhiming Yu, Shaomu Wen, Jie Wang, Jianwei Lin, Chuan Xie and Dezhi Zeng
Materials 2025, 18(21), 4865; https://doi.org/10.3390/ma18214865 - 24 Oct 2025
Viewed by 532
Abstract
Steel-reinforced thermoplastic pipe is widely used for water transportation in sour gas fields. However, under the combined effects of corrosive media, internal high pressure, and long-term environmental aging, premature failures such as leakage and bursting often occur. To clarify the failure causes and [...] Read more.
Steel-reinforced thermoplastic pipe is widely used for water transportation in sour gas fields. However, under the combined effects of corrosive media, internal high pressure, and long-term environmental aging, premature failures such as leakage and bursting often occur. To clarify the failure causes and primary contributing factors of the composite pipes, this study conducted a comprehensive analysis through microscopic morphology examination of different typical failure cases, differential scanning calorimetry, Fourier transform infrared spectroscopy, and mechanical property testing. The main failure mechanisms were investigated, and targeted protective measures are proposed. Key findings reveal that the typical failure modes are ductile cracking, aging-induced brittle cracking, and aging creep cracking. These failures follow a mechanism of degradation of the inner and outer polyethylene protective layers, penetration of the medium and corrosion of the steel wires, reduction in pressure-bearing capacity, and eventual structural damage or leakage propagation through the pipe wall. Notably, oxidation induction time values dropped as low as 1.4–17 min—far below the standard requirement of >20 min—indicating severe antioxidant depletion and material aging. The main controlling factors are poor material quality, external stress or mechanical damage, and long-term aging. The polyethylene used for the inner and outer protective layers is critical to the overall pipe performance; therefore, emphasis should be placed on evaluating its anti-aging properties and on protecting the pipe body during installation to ensure the long-term safety and stable operation of the pipeline system. Full article
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23 pages, 2723 KB  
Review
Assessment Methods for DC Stray Current Corrosion Hazards in Underground Gas Pipelines: A Review Focused on Rail Traction Systems
by Krzysztof Żakowski, Michał Szociński and Stefan Krakowiak
Energies 2025, 18(21), 5570; https://doi.org/10.3390/en18215570 - 23 Oct 2025
Cited by 1 | Viewed by 804
Abstract
Stray currents leaking from electrified DC rail systems cause the greatest corrosion risk to underground metal gas pipelines and can lead to pipeline wall perforation in a very short time. Leakage and gas explosion, and other direct and indirect effects, can even disrupt [...] Read more.
Stray currents leaking from electrified DC rail systems cause the greatest corrosion risk to underground metal gas pipelines and can lead to pipeline wall perforation in a very short time. Leakage and gas explosion, and other direct and indirect effects, can even disrupt the stability of the energy system. Maintaining the reliability of gas pipelines, therefore, requires protecting them against corrosion caused by stray currents. It is therefore necessary to conduct field studies to identify sections of gas pipelines at risk and where protective installations should be installed. The paper discusses the most important field methods for assessing the risk of stray currents to gas pipelines: the potential of rail traction relative to ground, electric field gradients in the ground associated with stray current flow, correlation of gas pipeline potential and voltage of pipeline vs. the rail, and time-frequency analysis of the pipeline and rail potentials. A typical application case for each method is indicated, and the advantages and disadvantages of each research technique are identified. The criterion for selecting methods for this review was a short measurement duration (tens of minutes), after which it is possible to determine the level of the hazard to the gas pipeline caused by stray currents in the examined location. This is why these methods have an advantage over other research techniques that require long-term monitoring or exposure of probes or sensors. The review will be useful for cathodic protection personnel involved in the operation of gas pipelines and may be helpful in developing new methods for assessing the impact of stray currents. Full article
(This article belongs to the Special Issue Petroleum and Natural Gas Engineering: 2nd Edition)
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25 pages, 1726 KB  
Article
Spray-Dried Microcapsules of Lavandin (Lavandula × intermedia) Essential Oil: Formulation and Functional Properties
by Jelena Bajac, Milena Terzić, Branislava Nikolovski, Lidija Petrović, Branimir Bajac, Gökhan Zengin and Ivana Mitrović
Molecules 2025, 30(20), 4098; https://doi.org/10.3390/molecules30204098 - 15 Oct 2025
Viewed by 734
Abstract
Lavandin essential oil (LEO) (Lavandula × intermedia) is a high-yielding aromatic product with broad bioactive potential, but its direct application is hindered by its volatility, rapid oxidation, and environmental sensitivity. In this study, the microencapsulation of LEO by spray drying using [...] Read more.
Lavandin essential oil (LEO) (Lavandula × intermedia) is a high-yielding aromatic product with broad bioactive potential, but its direct application is hindered by its volatility, rapid oxidation, and environmental sensitivity. In this study, the microencapsulation of LEO by spray drying using different wall materials was investigated: Maltodextrin (MD), Gum Arabic (GA), Whey Protein Concentrate (WPC), Inulin (IN), and Modified Starch (Hi-Cap). The resulting formulations exhibited encapsulation efficiencies (EEs) of 55.35–83.29%, oil retention (RE) of 49.07–76.65%, and yields of 41.39–71.47%. The MD/GA blend with Tween 80 performed best, as it offered high EE and RE, low residual moisture, fast reconstitution, and strong protection of the encapsulated oil against thermal and moisture stress. Gas chromatography–mass spectrometry (GC–MS) identified 38 volatile components, with linalyl acetate (30.38%) and linalool (24.65%) being the major components. Biological tests confirmed that the antimicrobial and antifungal activity of lavandin against some pathogens was maintained even when a much lower concentration of the oil (1–5%) was used in encapsulated form. Antioxidant activity decreased after encapsulation, while tyrosinase inhibition increased, indicating cosmetic potential. These results show that spray drying is an effective strategy for stabilizing LEO and expanding its applications in various industries. Full article
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16 pages, 2293 KB  
Article
Influence of Gas Explosions in Utility Tunnels on the Structural Safety of Overhead Pipelines
by Dai Wang, Jian Dong, Xuan Chen, Jianmei Du, Dawei Shu and Julita Krassowska
Buildings 2025, 15(18), 3391; https://doi.org/10.3390/buildings15183391 - 19 Sep 2025
Cited by 1 | Viewed by 830
Abstract
For the possible damage to overhead pipelines caused by gas explosions in utility tunnels, an overall three-dimensional finite-element model of utility tunnel–soil–pipeline is established, the overpressure loads are applied to the inner wall of the gas chamber in the utility tunnel, the dynamic [...] Read more.
For the possible damage to overhead pipelines caused by gas explosions in utility tunnels, an overall three-dimensional finite-element model of utility tunnel–soil–pipeline is established, the overpressure loads are applied to the inner wall of the gas chamber in the utility tunnel, the dynamic response laws of the utility tunnel and the pipeline are calculated and analyzed, and anti-explosion protection measures are proposed. The results show that the degree of damage to the pipe wall is determined by both the explosion-impacted area and the soil constraint. Under the same explosion-impacted area, the peak horizontal displacement of the monitoring point without soil constraint is 1.64 times that with soil constraint, and 1.29 times for the peak vertical displacement. The damage to the lower part of the pipeline is significantly greater than that to the upper part of the pipeline, and the damage to the pipeline decreases with an increase in the horizontal angle between the utility tunnel and the pipeline. The diameter deformation rates were 49% at α = 0° and 84% at α = 45°, with α = 90° showing the least damage. Therefore, it is suggested that the overhead pipeline is perpendicular to the utility tunnel. As the vertical distance between the utility tunnel and the pipeline increases, the diameter deformation rate and displacement of the pipeline both decrease, and when this distance is greater than 3 m, the influence on the pipeline significantly decreases. Therefore, it is recommended that the distance between the pipeline and the utility tunnel should be at least 3 m. In addition, the damage caused by gas explosions to the overhead pipeline can be reduced by reinforcing the gas chamber, using energy-absorbing materials around the utility tunnel, and setting up hollow piles between the utility tunnel and pipelines. Full article
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16 pages, 1265 KB  
Article
Enhancing Stability of Boesenbergia rotunda Bioactive Compounds: Microencapsulation via Spray-Drying and Its Physicochemical Evaluation
by Fahmi Ilman Fahrudin, Suphat Phongthai and Pilairuk Intipunya
Foods 2025, 14(15), 2699; https://doi.org/10.3390/foods14152699 - 31 Jul 2025
Cited by 2 | Viewed by 1197
Abstract
This study aimed to microencapsulate Boesenbergia rotunda (fingerroot) extract using maltodextrin (MD) and gum arabic (GA) as wall materials via spray-drying to improve powder physicochemical properties and protect bioactive compounds. MD and GA were employed as wall materials in varying ratios (MD:GA of [...] Read more.
This study aimed to microencapsulate Boesenbergia rotunda (fingerroot) extract using maltodextrin (MD) and gum arabic (GA) as wall materials via spray-drying to improve powder physicochemical properties and protect bioactive compounds. MD and GA were employed as wall materials in varying ratios (MD:GA of 1:0, 0:1, 1:1, 2:1, 1:2) to evaluate their effects on the physicochemical properties of the resulting microcapsules. Spray-dried microcapsules were evaluated for morphology, flowability, particle size distribution, moisture content, hygroscopicity, solubility, encapsulation efficiency, major bioactive compound retention, and thermal stability. The extract encapsulation using MD:GA at 1:1 ratio (MD1GA1) demonstrated a favorable balance, with high solubility (98.70%), low moisture content (8.69%), low hygroscopicity (5.08%), and uniform particle morphology, despite its moderate EE (75.06%). SEM images revealed spherical particles with fewer surface indentations in MD-rich formulations. Microencapsulation effectively retained pinostrobin and pinocembrin in all formulations with pinostrobin consistently retained at a higher value, indicating its higher stability. The balanced profile of physical and functional properties of fingerroot extract with MD1GA1 microcapsule makes it a promising candidate for food and nutraceutical applications. Full article
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20 pages, 4487 KB  
Article
Investigation on Corrosion-Induced Wall-Thinning Mechanisms in High-Pressure Steam Pipelines Based on Gas–Liquid Two-Phase Flow Characteristics
by Guangyin Li, Wei He, Pengyu Zhang, Hu Wang and Zhengxin Wei
Processes 2025, 13(7), 2096; https://doi.org/10.3390/pr13072096 - 2 Jul 2025
Viewed by 770
Abstract
In high-pressure thermal power systems, corrosion-induced wall thinning in steam pipelines poses a significant threat to operational safety and efficiency. This study investigates the effects of gas–liquid two-phase flow on corrosion-induced wall thinning in pipe bends of high-pressure heaters in power plants, with [...] Read more.
In high-pressure thermal power systems, corrosion-induced wall thinning in steam pipelines poses a significant threat to operational safety and efficiency. This study investigates the effects of gas–liquid two-phase flow on corrosion-induced wall thinning in pipe bends of high-pressure heaters in power plants, with particular emphasis on the mechanisms of void fraction and inner wall surface roughness. Research reveals that an increased void fraction significantly enhances flow turbulence and centrifugal effects, resulting in elevated pressure and Discrete Phase Model (DPM) concentration at the bend, thereby intensifying erosion phenomena. Simultaneously, the turbulence generated by bubble collapse at the bend promotes the accumulation and detachment of corrosion products, maintaining a cyclic process of erosion and corrosion that accelerates wall thinning. Furthermore, the increased surface roughness of the inner bend wall exacerbates the corrosion process. The rough surface alters local flow characteristics, leading to changes in pressure distribution and DPM concentration accumulation points, subsequently accelerating corrosion progression. Energy-Dispersive Spectroscopy (EDS) and Scanning Electron Microscopy (SEM) analyses reveal changes in the chemical composition and microstructural characteristics of corrosion products. The results indicate that the porous structure of oxide films fails to effectively protect against corrosive media, while bubble impact forces damage the oxide films, exposing fresh metal surfaces and further accelerating the corrosion process. Comprehensive analysis demonstrates that the interaction between void fraction and surface roughness significantly intensifies wall thinning, particularly under conditions of high void fraction and high roughness, where pressure and DPM concentration at the bend may reach extreme values, further increasing corrosion risk. Therefore, optimization of void fraction and surface roughness, along with the application of corrosion-resistant materials and surface treatment technologies, should be considered in pipeline design and operation to mitigate corrosion risks. Full article
(This article belongs to the Section Chemical Processes and Systems)
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18 pages, 2402 KB  
Article
Factors Influencing Step Ablation in the Expansion Section of a Composite Nozzle in a Solid Rocket Motor
by Jiming Cheng, Chunyu Zhang, Hang Yan, Xiping Feng and Guoqiang Zhu
Aerospace 2025, 12(6), 499; https://doi.org/10.3390/aerospace12060499 - 31 May 2025
Viewed by 1946
Abstract
During the operation of a solid rocket motor, the nozzle, which is a key component, is subjected to extreme conditions, including high temperatures, high-speed gas flow, and discrete-phase particles. For composite nozzles incorporating a carbon/carbon (C/C) throat liner and a carbon/phenolic expansion section, [...] Read more.
During the operation of a solid rocket motor, the nozzle, which is a key component, is subjected to extreme conditions, including high temperatures, high-speed gas flow, and discrete-phase particles. For composite nozzles incorporating a carbon/carbon (C/C) throat liner and a carbon/phenolic expansion section, thermochemical ablation and the formation of ablation steps during the ablation process significantly hinder nozzle performance and engine operational stability. In this study, the fluid and solid domains and the physicochemical interactions between them during nozzle operation were analyzed. An innovative thermochemical ablation model for composite nozzles was developed to account for wall recession. The coupled model covered multi-component gas flow, heterogeneous chemical reactions on the nozzle surface, structural heat transfer, variations in material parameters induced by carbon/phenolic pyrolysis, and the dynamic recession process of the nozzle profile due to ablation. The model achieved coupling between gas flow, heterogeneous reactions, and structural heat transfer through interfacial mass and energy balance relationships. Based on this model, the distribution of the nozzle’s thermochemical ablation rate was analyzed to investigate the mechanisms underlying ablation step formation. Furthermore, detailed calculations and analyses were performed to determine the effects of the gas pressure, temperature, H2O concentration, and aluminum concentration in the propellant on the ablation rate of the throat liner and the thickness of the ablation steps. This study provides a theoretical foundation for the thermal protection design and performance optimization of composite nozzles, improving the reliability and service life of solid rocket motor nozzles and advancing technological development. Full article
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19 pages, 18266 KB  
Article
Advancing Sustainability in Alloy Production: The Role of Recycled Materials and Barbotage in Enhancing EN AC-46000 Castings
by Patryk Korban, Anna Wąsik and Beata Leszczyńska-Madej
Sustainability 2025, 17(11), 4755; https://doi.org/10.3390/su17114755 - 22 May 2025
Viewed by 1399
Abstract
Aluminum recycling is a key pillar of sustainable metallurgy, protecting natural resources, reducing energy consumption by up to 15 times compared with primary aluminum production and significantly lowering the demand for raw materials. This article presents a comprehensive study on the impact of [...] Read more.
Aluminum recycling is a key pillar of sustainable metallurgy, protecting natural resources, reducing energy consumption by up to 15 times compared with primary aluminum production and significantly lowering the demand for raw materials. This article presents a comprehensive study on the impact of barbotage refining time and recycled scrap content on EN AC-46000 (AlSi9Cu3) alloy, covering the entire process from the initial ingot to the final casting, contributing to a circular economy. The input material consisted of varying proportions of pure ingots and scrap, with scrap content set at 80%, 70%, and 60%, respectively. Each material batch underwent different refining times: 0, 7, 9, and 15 min. Microstructural studies were conducted using light and scanning electron microscopy techniques. Additionally, pore distribution and their proportions within the material volume were analyzed using X-ray computed tomography. This study also examined hardness and gas content relative to the refining time. It was demonstrated that the refining process promoted microstructural homogenization and reduced porosity throughout the production process. Furthermore, extending the refining time positively impacted the reduction of porosity in thin-walled castings and lowered the gas emission level from the alloy, resulting in improved final product quality. Full article
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16 pages, 4254 KB  
Article
Rich Oxygen Vacancies in Bimetallic MnCo2O4.5 Spheres for Enhancing Lean Methane Catalytic Oxidation
by Ke Yang, Chenqi Li, Qinghan Zhu, Haiwang Wang and Jian Qi
Nanomaterials 2025, 15(7), 524; https://doi.org/10.3390/nano15070524 - 31 Mar 2025
Cited by 63 | Viewed by 1109
Abstract
Methane is the second most prevalent greenhouse gas after carbon dioxide in global climate change, and catalytic oxidation technology is a very effective way to eliminate methane. However, the high reaction temperature of methane catalytic oxidation is an urgent problem that needs to [...] Read more.
Methane is the second most prevalent greenhouse gas after carbon dioxide in global climate change, and catalytic oxidation technology is a very effective way to eliminate methane. However, the high reaction temperature of methane catalytic oxidation is an urgent problem that needs to be solved. In this work, a series of MnCo2O4.5 catalysts were prepared using carbon spheres as templates, combined with metal ion adsorption and calcination processes. Excitingly, the catalytic oxidation activity of MnCo2O4.5 spherical catalyst with irregular nanoparticles on the surface for lean methane (T90 = 395 °C) is higher than that of pure phase Co3O4 (T90 = 538 °C) and Mo3O4 (T90 = 581 °C) spherical catalysts and even surpasses most precious metal catalysts. The main reasons are as follows: (1) The spherical core with irregular nanoparticle morphology significantly increases the specific surface area, creating abundant active sites; (2) through the optimized distribution of oxygen vacancies, rapid oxygen migration through this structure can quickly enter the catalytic zone; (3) the hierarchical wall structure expands the interface and provides spatial accommodation for the catalytic process. Meanwhile, the structure of the ball wall further expands the reaction interface, providing sufficient space for the occurrence of reactions. Rich and highly active oxygen vacancies are evenly distributed on the surface and inside of the ball. The extraordinary performance of low-temperature methane combustion catalysts has opened a promising new path, which is expected to inject strong impetus into the global energy transition and environmental protection. Full article
(This article belongs to the Section Energy and Catalysis)
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14 pages, 3103 KB  
Article
Air-Lifting Reverse-Circulation Drilling in Deep Geothermal Wells and the Effect of Dual-Wall Drill Pipe Depth Down the Hole
by Hongyu Ye, Ziwei Lai, Longjun Tian, Renjie Zhang, Bin Liu and Xiuhua Zheng
Energies 2025, 18(5), 1224; https://doi.org/10.3390/en18051224 - 2 Mar 2025
Viewed by 1879
Abstract
Geothermal energy is a renewable energy source that is rich in reserves, widely distributed, stable and reliable. The development of geothermal energy needs to be carried out by drilling wells to exploit the underground thermal fluid, and air-lift reverse circulation drilling technology has [...] Read more.
Geothermal energy is a renewable energy source that is rich in reserves, widely distributed, stable and reliable. The development of geothermal energy needs to be carried out by drilling wells to exploit the underground thermal fluid, and air-lift reverse circulation drilling technology has the advantages of protecting the thermal reserves and reducing costs in the development of geothermal energy. In this paper, based on the working principle of air-lift reverse circulation drilling, combined with the single-phase liquid, liquid–solid, gas–liquid–solid three-phase fluid mechanics theory, the pressure model of air-lift reverse circulation in geothermal deep wells is established. The influence of the depth of dual-wall drilling rods on the lifting force and total friction loss pressure of air-lifting reverse circulation is analyzed, and it is proved that there is an optimal value of the depth of dual-wall drilling rods, which provides a theoretical basis for selecting a suitable depth of dual-wall drilling rods in the construction of air-lifting reverse circulation in geothermal deep wells. Full article
(This article belongs to the Special Issue Development and Utilization in Geothermal Energy)
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