Search Results (287)

Ice accumulation on power transmission lines poses serious threats to operational safety and can lead to substantial social and economic impacts. While various anti-icing coatings have been investigated, their performance is often limited by the effectiveness and durability of anti-icing. Slippery lubricant-infused porous surfaces (SLIPSs) have shown remarkable anti-icing properties and durability, aided by their lubricant-infused and self-healing capability. In this study, SLIPSs were successfully fabricated on aluminum substrates using a two-step anodization process. The effects of the anodizing parameter of the current density on pore diameter and depth at each stage were systematically investigated. Compared to untreated aluminum and superhydrophobic coatings (SHCs), SLIPSs presented good anti-icing properties. First, at −6 °C, droplets slid off the surface completely within 4340.5 ms without pinning, indicating sustained droplet-shedding capability. It also significantly delayed ice formation, extending the freezing time to 80 min—eight times longer than that of the untreated surface. Moreover, the SLIPSs also exhibited ultra-low ice adhesion, with an initial strength of only 6.93 kPa. Meanwhile, after 100 frosting–defrosting cycles, SLIPSs could still maintain low ice adhesion strength (<20 kPa). The prepared SLIPS with a Y-shaped pore structure demonstrates good potential for anti-icing. Full article

Meteorological data from automatic weather stations (AWS) in tea plantations is critical for agricultural management, but is often compromised by sensor errors and physical implausibilities that traditional quality control (QC) methods fail to detect. This study proposes a novel, meteorologically informed QC framework that mines association rules from long-term ERA5 reanalysis data (2012–2023) using the Apriori algorithm to establish a knowledge base of normal multivariate atmospheric patterns. A comprehensive feature engineering process generated temporal, physical, and statistical features, which were discretized using meteorological thresholds. The mined rules were filtered, prioritized, and integrated with hard physical constraints. The system employs a fuzzy logic mechanism for violation assessment and a weighted anomaly scoring system for classification. When validated on a synthetic dataset with injected anomalies, the method significantly outperformed traditional QC techniques, achieving an F1-score of 0.878 and demonstrating a superior ability to identify complex physical inconsistencies. Application to an independent historical dataset from a Zhenjiang tea plantation (2008–2016) successfully identified 14.6% anomalous records, confirming the temporal transferability and robustness of the approach. This framework provides an accurate, interpretable, and scalable solution for enhancing the quality of meteorological data, with direct implications for improving the reliability of frost prediction and pest management in precision agriculture. Full article

The rates of CO₂ mass deposition onto cryogenically cooled surfaces are crucial for CO₂ removal processes that rely on cryogenics. A dedicated experimental setup was constructed to measure CO₂ mass deposition rates under controlled conditions. Experiments were carried out with both pure CO₂ and CO₂/N₂ mixtures, growing frost layers up to 8 mm thick. Results demonstrated that heat transfer through the frost layer significantly slows down the mass deposition process. Furthermore, it was found that the addition of N₂ to the gas phase has a considerable influence on mass deposition rates, because it introduces an additional mass transfer resistance toward the frost surface. To describe the experimentally observed behavior, a frost growth model based on mass and energy balances was developed. Expressions for the frost density as a function of the frost temperature and for the effective frost conductivity as a function of the frost density were derived and implemented in the model. When accounting for drift fluxes, the model accurately captures the behavior observed in experiments. The findings of this work highlight the significant impact of heat transfer limitations on processes that accumulate a thick solid CO₂ layer, such as continuously cooled heat exchangers. Conversely, technologies like cryogenically refrigerated packed beds do not develop a thick solid CO₂ layer; calculations showed that a frost layer of 3.24·10⁻⁵ m is formed, resulting in a Biot number well below 0.01, indicating that heat transfer in the frost layer is not limiting. Full article

To address the energy and environmental challenges, this study targets the need for ultra-low energy buildings in China’s hot summer-cold winter region (HSCW) by developing high-performance alkali-activated foam concrete (AAFC) insulation material. Initially, a target performance indicator system was established. Subsequently, a mix proportion design method based on the volume method was proposed, and preliminary mix proportions were designed and tested to achieve the target performance. Accordingly, eight factors, including alkali equivalent and SiO₂ aerogel content, were selected for further optimization. A systematic optimization of performance was then conducted using an L₃₂(4⁸) orthogonal experimental design. Range analysis and analysis of variance indicated that foam content significantly affected all target properties. The water-to-binder ratio notably influenced mechanical performance and dry density. Alkali equivalent and activator modulus directly regulated the reaction process. Notably, the incorporation of 2.5 wt% SiO₂ aerogel reduced the thermal conductivity to 0.1107 W/(m·K), highlighting its significant role in improving thermal insulation and effectively resolving the common trade-off between insulation and mechanical properties in FC. Furthermore, the waterproofing agent played a critical role in reducing water absorption and enhancing frost resistance. Finally, the optimal mix proportion was determined through matrix analysis, with all material properties meeting the expected targets. Test results confirmed that the optimized FC achieved a dry density of 576.34 kg/m³, compressive and flexural strengths of 5.83 MPa and 1.41 MPa, respectively, a drying shrinkage rate of only 0.614 mm/m, a mass water absorption of 3.87%, and strength and mass loss rates below 10.5% and 1.8% after freeze–thaw cycles. Therefore, this material presents a novel solution for the envelope structures of low-energy buildings. Full article

Exocarpium Citri Grandis (ECG) is a distinctive medicinal and edible product originating from southern China and is often covered with a layer of characteristic “white frost” (WF). This study investigated the composition, formation mechanism, microbial safety, and anti-inflammatory activity of the WF. Multi-technique analyses revealed that WF mainly consisted of crystalline naringin (~80% of total mass). Drying-induced shrinkage and rupture of oil glands on ECG suggested metabolite migration and surface crystallization as the key mechanisms for WF formation. Microbial profiling revealed no significant differences in fungal and bacterial communities between WF and non-frost (NF) samples, and none of eight common mycotoxins was detected, confirming its microbial safety. Brewing tests demonstrated that water boiling for 30 min achieved efficient extraction of naringin, with higher yields in WF samples than in NF samples. In RAW264.7 cells, both WF and NF extract significantly inhibited lipopolysaccharide-induced NO production as well as the secretion and transcription of TNF-α, IL-6, IL-1β, iNOS, and NF-κB, with WF extract showing a stronger effect. Overall, these findings indicate that WF originates from endogenous flavonoid crystallization rather than microbial contamination and enhances the anti-inflammatory activity. This study provides a scientific basis for quality evaluation, processing optimization, and standardization of ECG products. Full article

The development of the ceramic industry requires the creation of new innovative products with improved properties. Given the growing demand for high-quality finishing materials and the limited availability of traditional raw materials, the search for more efficient technologies for porcelain stoneware production is a relevant challenge. The aim of this study was to develop porcelain stoneware with enhanced performance characteristics. The research presents the results of a study aimed at improving the production technology of porcelain stoneware in Kazakhstan using local raw materials and microsilica. The raw materials from the Turkestan region were examined for their suitability for porcelain stoneware production. The influence of technological parameters (firing temperature, particle size) on the properties of porcelain stoneware was studied. New ceramic compositions with various microsilica contents, a by-product of silicon production, were investigated. Different compositions with varying raw material mixtures and microsilica content were prepared and fired at temperatures of 1100, 1150, and 1200 °C. The optimization of process parameters for producing porcelain stoneware in different compositions showed the degree of yield dependence on firing temperature and time as well as the effect of microsilica content. The temperature, time, and visually determined parameters at which different yield values were achieved were highlighted in different colors. The results showed that changes in the mixture composition and sintering temperature affect the quality of ceramic tiles. The final experimental conclusions demonstrated that the production of ceramic tiles containing up to 3% microsilica at a firing temperature of 1200 °C. The addition of microsilica increases the flexural strength of porcelain stoneware to 41 MPa (exceeding the standard), reduces water absorption to 0.023%, increases frost resistance to 107 cycles, and also enhances shrinkage. These findings open new prospects for the development of the domestic ceramic industry, the expansion of the product range, and the resolution of environmental issues. Full article

Plants such as winter crops are able to acclimate to low temperatures through complex physiological and biochemical modifications that enhance their frost tolerance. Cold acclimation involves changes in, e.g., photosynthetic efficiency, carbohydrate metabolism, the accumulation of osmoprotectants, the remodelling of membrane lipid composition, and the activation of the antioxidant system. Now, due to ongoing global climate change, temperature fluctuations have become more frequent, particularly during the autumn–winter period. Episodes of warm breaks (mainly above 9 °C) during winter disrupt the cold acclimation process and induce deacclimation, leading to a decrease in frost tolerance and a partial reversal of cold-induced metabolic adjustments. However, deacclimation is not just the reversal of acclimation, as evidenced by distinct responses in metabolites and hormones. Moreover, plants are able to regain lost freezing tolerance through reacclimation upon re-exposure to low temperatures. The article aimed to summarize the current knowledge on the basics underlying cold acclimation, deacclimation, and reacclimation. An explanation of these processes is crucial for protecting winter crop plants under the increasing frequency of variable temperatures during their growth. Full article

Generalized frosts have a significant impact on the Pampa Húmeda of Argentina, particularly those without persistence (0DP), defined as events that do not last more than one day, and are the most frequent generalized frosts. This study investigates the dynamical and physical mechanisms that sustain these events, emphasizing the nonlinear interactions represented by the Rossby Wave Source (RWS) equation. Composite analysis of pressure, temperature, wind and geopotential height fields were performed, showing that 0DP events are related to abrupt cold air intrusion linked to the enhancement of upper levels troughs over the eastern Pacific Ocean and transient surface anticyclones over South America. This linear analysis only showed a lack of persistent upper-level maintenance and did not explain the dynamics of the rapid weakening of the circulation. For this reason, a nonlinear analysis based on the decomposition of the RWS equation into its advective and divergent terms is performed. The advective term only acts as an initial trigger, deepening troughs and favoring meridional cold air advection, while the divergent term dominates the events, representing 63–67% of the affected area. This term reinforces ridges, promotes subsidence and favors clear sky conditions that enhance nocturnal radiative cooling and frost formation. Positive anomalies of the divergent RWS term strengthen the ridge and advect cold air over the Pampa Húmeda, whereas subsequent negative anomalies over the southwestern Atlantic act as sinks of wave activity, leading to the rapid dissipation of the synoptic configuration. Consequently, the same mechanism that generates favorable conditions for frost development also determines their lack of persistence. These findings demonstrate that the short-lived nature of 0DP frosts is not due to the absence of dynamical forcing, but rather to nonlinear processes that both enable and constrain frost occurrence. This highlights the importance of incorporating nonlinear diagnostics, such as the RWS, to improve the understanding of short-lived atmospheric extremes. Full article

This study presents a systematic evaluation of frost resistance in concrete modified with nano-alumina (NA, 1 wt%), nano-silica (NS, 2 wt%), and polypropylene fiber (PP, 0.2 wt%) through accelerated freeze–thaw testing. The investigation employed a comparative experimental approach, subjecting specimens with optimal mechanical dosages to 300 freeze–thaw cycles. The degradation was quantitatively assessed by monitoring the evolution of mass loss, dynamic elastic modulus, and compressive strength. Results reveal that PP-modified concrete demonstrates optimal performance, retaining 70% of its dynamic elastic modulus (vs. 68% for NA and 64% for control, and failing at 58% for NS after 200 cycles) and exhibiting only 9.3% compressive strength loss (vs. 13.9% for NA and 27.3% for control, and 43.6% for NS). These findings establish PP as the most effective modifier, offering both superior frost resistance (300+ cycle durability) and practical advantages (simpler processing, lower cost). The results provide a scientific basis for designing high-performance concrete in cold regions, with particular relevance to infrastructure requiring long-term durability under cyclic freezing conditions. Full article

Climate change is expected to negatively impact agricultural production, leading to phenological and metabolic changes, increased water demands, diminished yields, and changed organoleptic characteristics, restricting the positive geographic productivity potential. As an adaptive strategy, agriculture in mountainous regions has gained prominence despite the fact that it entails new challenges. Indeed, mountain-specific conditions and limitations need to be considered, compared to the traditional productive regions. Consequently, there is a lack of information about the most suitable locations because the new conditions and limitations need to be accounted for. This study provides a crop suitability assessment approach to be used in mountainous regions where data about crop yield or development is scarce or nonexistent. Specifically, we evaluated the suitability of vineyards and apple orchards in the southern Pyrenees and Pre-Pyrenees. Using Geographical Information System (GIS) techniques, integrated with fuzzy logic and the Analytic Hierarchy Process (AHP), we combined traditional climatic, soil, and topographic indicators with factors relevant to mountainous regions. Our results indicated that the most suitable areas were primarily in lower basins and sunny hillsides, with smaller water needs. Vineyards would benefit from a very low risk of late spring frosts and elevated solar radiation, whereas apple orchards from a reduced risk of hailstorms, a very low risk of late spring frosts, and mild slopes. The fuzzy membership functions combined with the AHP facilitated the integration of indicators, effectively identifying areas with high potential for crop development. This approach contributes to landscape management and planning by offering a modifiable tool for assessing crop suitability in mountainous regions. Full article

Asphalt mixtures designed with an elevated air void content are intended to lower traffic noise as well as to improve traffic safety and quality by improving rainwater evacuation through the layer of the surface mixture, not just on top of it. While undoubtedly mixtures with high air voids have significant advantages, the durability of such mixes could be an issue. In the research presented in this paper, a performance evaluation case study of asphalt mixes with medium and high air void content was investigated, in both the laboratory and the trial section. The study assessed asphalt mixtures intended for so-called quiet pavements in terms of selected properties (such as water and frost resistance, low temperature cracking, fatigue life, and water permeability) that significantly impact the durability of the pavement surface course under traffic loads and climatic conditions. Five different mixtures were designed, which differed in the proportion of individual components, grain size, asphalt content, and void content. The conducted research indicates that mixtures with increased void content may exhibit lower durability parameters. In addition, the surface drainage performance can be effectively managed by selecting the appropriate mixture type, maximum aggregate size, and target air void content, depending on the functional requirements for macrotexture and pavement type. This should be considered both in the mix design process, by using the best possible materials and conducting additional testing, and also when selecting the mixture type to find an optimum between durability and acoustic parameters of the pavement layer. Full article

Icing on aircraft surfaces during operation poses a threat to flight safety. As a passive anti-icing technology, hydrophobic microstructure can achieve long-term anti-icing. In this work, a composite process combining hot-embossing of PVD-coated punches with a low surface energy fluoride-modification scheme is proposed to generate nanoscale cluster structures on hundreds of microns array channels to construct a superhydrophobic micro-nano composite structure. The droplet freezing and frosting behavior of the hydrophobic microstructures was analyzed, and it was found that the anti-icing and anti-frost properties of the microstructure surface improved with an increase in the microstructure period size (T). Compared with the original surface, the freezing time of the microstructure at T = 500 μm was delayed by 214.3% (7 s → 22 s), and the frost layer coverage time was delayed by 75.7% (70 s → 123 s). The maximum water contact angle of the superhydrophobic micro-nano composite structure was 153.3°, and the droplet freezing time was delayed to 95 s, which is a 1166.67% difference, indicating that the multi-stage micro-nano composite structure can significantly improve surface anti-icing performance. The main reason for this result is that the bottom of the microstructure can store air pockets, preventing droplet wetting and heat exchange. Full article

The freezing method is widely employed in the construction of a vertical shaft in soft soil and water-rich strata. As the construction depth increases, investigating the water–heat–force coupling effects induced by the hydration heat (internal heat source) of concrete is crucial for the safety of the lining structure and its resistance to cracking and seepage. A three-dimensional coupled thermal–hydraulic–mechanical analysis model was developed, incorporating temperature and soil relative saturation as unknown variables based on heat transfer in porous media, unsaturated soil seepage, and frost heave theory. The coefficient type PDE module in COMSOL was used for secondary development to solve the coupling equation, and the on-site temperature and pressure monitoring data of the frozen construction process were compared. This study obtained the model-related parameters and elucidated the evolution mechanism of freeze–thaw and freeze–swelling pressures of a frozen wall under the influence of hydration heat. The resulting model shows that the maximum thaw depth of the frozen wall reaches 0.3576 m after 160 h of pouring, with an error rate of 4.64% compared to actual measurements. The peak temperature of the shaft wall is 73.62 °C, with an error rate of 3.76%. The maximum influence range of hydration heat on the frozen temperature field is 1.763 m. The peak freezing pressure is 4.72 MPa, which exhibits a 5.03% deviation from the actual measurements, thereby confirming the reliability of the resulting model. According to the strength growth pattern of concrete and the freezing pressure bearing requirements, it can provide a theoretical basis for quality control of the lining structure and a safety assessment of the freezing wall. Full article

To investigate differences in water and salt transport during irrigation, freezing, and thawing periods in typical saline-affected paddy fields and saline-affected upland fields, field-based automated in situ monitoring was conducted in both types of saline-affected farmland (May 2023 to May 2024). Correlation analysis identified seasonal drivers of water–salt migration, while the HYDRUS-3D model simulated transport and equilibrium processes. The HYDRUS-3D model, equipped with a freeze–thaw module, accurately simulated complex water–salt transport in cold arid regions. Key findings include: (1) During freeze–thaw periods, soil moisture content and electrical conductivity (Ec) increased with the retreating frost front in both upland and paddy soils. During the irrigation period, maximum soil moisture content and Ec values occurred at 80 cm depth in dryland soils and 60 cm depth in paddy soils, primarily influenced by irrigation and capillary rise. (2) Groundwater salt ions significantly affected soil salinization in both farmland types. During the freeze–thaw period, Ec positively correlated with soil temperature. During the irrigation period, Ec positively correlated with evapotranspiration and negatively correlated with precipitation. (3) Salt changes during the irrigation, freezing, and thawing periods were −565.4, 326.85, and 376.55 kg/ha for upland fields, respectively; corresponding changes for paddy fields were −1217.0, 280.07, and 299.35 kg/ha. (4) Both land types exhibited reduced salinity during the irrigation period, with paddy fields showing a reduction 3.36 times greater than dryland fields. During the freezing and thawing periods, both land types experienced salinity accumulation, with dryland fields accumulating higher salinity levels than paddy fields. These results indicate that paddy field irrigation and drainage systems help mitigate salinization, while dryland fields are more prone to springtime salt accumulation. These findings provide a basis for developing targeted management strategies for saline–alkali soils. Full article

Against the backdrop of global climate change intensifying seasonal freeze–thaw cycles, deteriorating soil conditions in farmland within seasonal frost zones constrain agricultural sustainability. This study employed an in situ field experiment during seasonal freeze–thaw periods in the black soil zone of Northeast China to investigate the joint regulatory effects of seasonal freeze–thaw processes and tillage practices on multidimensional features of soil bacterial communities. Key results demonstrate that soil bacterial communities possess self-reorganization capacity. α-diversity exhibited cyclical fluctuations: an initial decline followed by a rebound, ultimately approaching pre-freeze–thaw levels. Significant compositional shifts occurred throughout this process, with the frozen period (FP) representing the phase of maximal differentiation. Actinomycetota and Acidobacteriota consistently dominated as the predominant phyla, collectively accounting for 33.4–49% of relative abundance. Bacterial co-occurrence networks underwent dynamic topological restructuring in response to freeze–thaw stress. Period-specific response patterns supported sustained soil ecological functionality. Furthermore, NCM and NST analyses revealed that stochastic processes dominated community assembly during freeze–thaw (NCM R² > 0.75). Tillage practices modulated this stochastic–deterministic balance: no-tillage with straw mulching (NTS) shifted toward determinism (NST = 0.608 ± 0.224) during the thawed period (TP). Across the seasonal freeze–thaw process, soil temperature emerged as the primary driver of temporal community variations, while soil water content governed treatment-specific differences. This work provides a theoretical framework for exploring agricultural soil ecological evolution in seasonal frost zones. Full article