Search Results (159)

Carbon fiber-reinforced polymer (CFRP) composites are widely used in aerospace due to their excellent strength-to-weight ratio and tailorable properties. However, these properties critically depend on the CFRP curing cycle. The commonly adopted manufacturer-recommended curing cycle (MRCC), designed to accommodate the most conservative conditions, involves prolonged curing times and high energy consumption. To overcome these limitations, this study proposes an efficient and adaptable method to determine the optimal curing cycle. The effects of varying heating rates on resin dynamic and isothermal–exothermic behavior were characterized via reaction kinetics analysis using differential scanning calorimetry (DSC) and rheological measurements. The activation energy of the reaction system was substituted into the modified Sun–Gang model, and the parameters were estimated using a particle swarm optimization algorithm. Based on the curing kinetic behavior of the resin, CFRP compression molding process orthogonal experiments were conducted. A weighted scoring system incorporating strength, energy consumption, and cycle time enabled multidimensional evaluation of optimized solutions. Applying this curing cycle optimization method to a commercial epoxy resin increased efficiency by 247.22% and reduced energy consumption by 35.7% while meeting general product performance requirements. These results confirm the method’s reliability and its significance for improving production efficiency. Full article

There has been a growing interest in polymer-based materials in recent years, and current research is focused on reducing fossil-derived epoxy compounds. This review examines the potential of epoxidised vegetable oils (EVOs) as sustainable alternatives to these systems. Epoxidation processes have been systematically analysed and their influence on chemical, thermal, and mechanical properties has been assessed. Results indicate that basic, low-toxicity epoxidation methods resulted in resins with comparable performance to those obtained through more complex common/commercial procedures. In total, 5–7% oxirane oxygen content (OOC) was found to be optimal to achieve a balanced crosslink density, thus enhancing tensile strength. Furthermore, mechanical properties have been insufficiently studied, as less than half of the studies were conducted at least tensile or flexural strength. Reinforcement strategies were also explored, with nano-reinforcing carbon nanotubes (CBNTs) showing the best mechanical and thermal results. Natural fibres reported better mechanical performance when mixed with EVOs than conventional systems. On the other hand, one of the main constraints observed is the lack of consistency in reporting key chemical and mechanical parameters across studies. Environmental properties and end-of-life use are significant challenges to be addressed in future studies, as there remains a significant gap in understanding the end-of-life of these materials. Future research should focus on the exploration of eco-friendly epoxidation reagents and standardise protocols to compare and measure oil properties before and after being epoxidised. Full article

Long-chain imidazolium-based ionic liquids (ILs) possess a broad-spectrum biological activity and are considered promising antifouling agents for protective coatings. A new hydrophobic IL, 1-dodecyl-3-methylimidazolium dodecylbenzenesulfonate (C₁₂C₁IM-DBS), has been synthesized, and a modified epoxy coating material containing 10, 20, and 30 wt% of this IL was prepared by dissolution of C₁₂C₁IM-DBS in commercial DER 331 epoxy resin, followed by a curing phase with diethylenetriamine. Infrared analysis revealed physicochemical interactions between the hydroxyl groups of the resin and the IL. Spectrophotometric studies showed no release of C₁₂C₁IM-DBS after 30 days of exposure of the modified coatings to water. The plasticizing effect of the IL on the epoxy resin was established by differential scanning calorimetry analysis. The introduction of 10 and 20% C₁₂C₁IM-DBS into DER 331 reduced its glass transition temperature from 122.8 °C to 109.3 and 91.5 °C, respectively. The hardness of epoxy resin decreased by approximately 26% after the introduction of the IL. Moreover, DER 331/C₁₂C₁IM-DBS coatings on steel substrates showed significantly improved impact resistance compared to neat resin. The antibiofilm efficiency of DER 331/C₁₂C₁IM-DBS coatings was evaluated by assessing the capability of two biofilm-forming model strains, Staphylococcus aureus ATCC 25923 and Pseudomonas aeruginosa PA01, to form attached biofilms on the surface. The IL effectively inhibited S. aureus surface-associated biofilm development even at the lowest content of 10%. On the contrary, an approximately 50% inhibition of biofilm metabolic activity was detected for DER 331/C₁₂C₁IM-DBS coatings containing 20% and 30% of the IL. Overall, the results of this study indicate that the hydrophobic IL C₁₂C₁IM-DBS is an efficient modifying additive for epoxy resins, which can significantly improve their operational properties for various industrial applications. Full article

In this work, the critical properties of epoxy resin reinforced with carbon-based nanoparticles were examined in order to improve its performance in protective coating applications. Epoxy resin composites with commercial multi-walled carbon nanotubes (MWCNTs) and graphene (GP) nanoplates were prepared via solution mixing. In addition, hybrid composites with 50:50 w/w MWCNTs/GP were also examined. The characterization of the EMI shielding effectiveness revealed that epoxy resin composites reinforced with MWCNTs presented the best performance. Composites with the same content of graphene exhibited much lower shielding results. As confirmed by electrical conductivity measurements, this outcome can be explained by the fact that the electrical percolation threshold in the composites reinforced with MWCNTs was met (around 5 phr), while the conductive network in the composites with graphene was not completely developed. An analysis of the mechanisms that contributed to EMI shielding for each type of specimen showed that, in the case of MWCNT composites, the main mechanism that determined the response of the material was reflection rather than absorption. It was also observed that by increasing the MWCNT content, the shielding efficiency of the composites was enhanced. In the case of graphene composites, the absorption and reflection remained at low levels, resulting in high transmission and therefore poor shielding. Regarding the examined hybrid composites (MWCNTs:GP at 50:50 w/w), it seemed that the MWCNT content determined their shielding performance. Full article

Sustainable bio-based epoxy technology is developed by using bio-based epoxy materials instead of conventional fossil-derived ones. Significant progress in new bio-based epoxy material development on bio-based epoxy resins, curing agents, and additives, as well as bio-based epoxy formulated products, has been achieved recently not only in fundamental academic studies but also in industrial product development. There are mainly two types of bio-based epoxy resins: conventional epoxy resins and novel epoxy resins, depending on the epoxy resin building-block type used. Bio-based conventional epoxy resins are prepared by using the bio-based epichlorohydrin to replace conventional fossil-based epichlorohydrin. Bio-based novel epoxy resins are usually prepared from epoxidation of renewable precursors such as unsaturated vegetable oils, saccharides, tannins, cardanols, terpenes, rosins, and lignin. Typical bio-based curing agents are bio-based polyamines, polyamides, amidoamines, and cardanol-based phenalkamine-type curing agents. Cardanol is a typical bio-based reactive additive available commercially. Certain types of partially bio-based formulated epoxy products have been developed and supplied for use in bonding, coating, casting, composite, and laminating applications. Full article

Sitagliptin, an important anti-diabetic drug, can be obtained using transaminase (TA) enzymes, which are known to be promising biocatalysts for the production of highly enantiopure amines under mild reaction conditions. In an industrial context, the use of immobilized enzymes can provide several advantages, such as the improved stability of the biocatalyst and easy product recovery. In this study, a new commercially available transaminase enzyme to produce sitagliptin was immobilized on inorganic and organic supports using two different approaches: adsorption and covalent bond formation. Among the inorganic media, non-functionalized silica gel was chosen for its stability and competitive cost. A range of commercially available resins with different functionalities have also been selected for their characteristics that can meet industrial standards. The immobilized biocatalysts were first tested in the transamination of acetophenone as a model substrate, which obtains, in most cases, higher conversions with respect to soluble enzymes. The best results in the enantioselective synthesis of sitagliptin were achieved with the sample immobilized on the epoxy- and octadecyl-functionalized methacrylic resin, which allowed the complete conversion of the corresponding ketone and high enantioselectivity (>99% ee). Moreover, the recycling of the supported enzyme could be performed in a continuous flow system without loss of activity for five consecutive runs. Full article

For a solar-powered unmanned aerial system (UAS), the performance and integration of the solar panel are of paramount importance. This paper examines the safety aspects of solar panels in electrical power systems, with a particular focus on the installation of solar cells onto an aircraft’s carbon fiber wing. Three distinct installation techniques are evaluated, and their respective advantages and disadvantages are discussed. A preliminary test is conducted to assess the viability of adhering commercial solar panels intended for boats using a bio-adhesive layer placed underneath the series of encapsulated solar panels. To ensure adhesion, the piece is placed under a vacuum. The subsequent test evaluates the lamination of the solar cells onto the carbon fiber skin with a resin as a component of the laminate. Finally, as a definitive solution, the adhesion of the solar panels onto the entire polymer layer used to seal the solar cells themselves was evaluated. This solution offers objective advantages in terms of adhesion, lightness and whiteness. Adhesion is guaranteed by the bond of the thermoplastic polymer used to seal the photovoltaic cells and the epoxy resin of the laminate. The bond is created through the autoclave process, which involves placing the laminate and solar cells in an oven at a specific temperature and pressure for a defined period of time. This solution results in a weight reduction of approximately three times compared to a solution not specifically designed for these materials and a reduction in thickness of approximately two times. Full article

Marine power systems, including generators and transformers, experience voltage stress at various frequencies. Once the stress exceeds the bearing capacity of the electrical system, it results in insulation breakdown or failure. Therefore, extensive testing is required to ensure that marine electrical insulation systems are reliable. In accordance with International Electrotechnical Commission (IEC) standards, conventional tests at commercial frequencies require over 5000 h, making them time-consuming, inefficient, and practically infeasible. This study explores frequency-based accelerated life testing to reduce the duration of testing. Insulation systems made of mica-based corona-resistant materials and epoxy resin were tested at 60, 300, 600, and 900 Hz using a variable-frequency high-voltage tester. The results show that the time to failure decreases as the frequency increases (from 381.83 h at 60 Hz to 22.33 h at 900 Hz, a 94% reduction). Power and exponential decay models effectively describe this relationship. The power model provides a better overall fit, and the exponential decay model improves the accuracy at higher frequencies. This study confirms that higher frequencies accelerate insulation degradation, shortening test times considerably. Frequency-based accelerated testing can enhance insulation system evaluation and optimize international testing standards. Full article

This study investigates the impact of an increased bio-content on the mechanical properties of bio-based epoxy resins. Cardanol-based epoxy and novolac resins (65% and 84% bio-content, respectively) were combined with two commercial cardanol-based epoxy systems to achieve higher total bio-contents. Quasi-static tensile tests showed that resin blends with up to 40% bio-content maintain tensile properties comparable to traditional formulations, with a glass transition temperature (T_g) suitable for automotive requirements. The results highlight that an increased bio-content enhances flexibility and viscoelastic behavior. Additionally, the tests showed that epoxy resins with a high bio-content represent a sustainable alternative with reduced environmental impact. This work benchmarks novel cardanol-based epoxy formulations with existing bio-based systems, supporting their industrial application. Full article

Epoxy resins are extensively employed as adhesives and matrices in fibre-reinforced composites. As polymers, they possess a viscoelastic nature and are prone to creep and stress relaxation even at room temperature. This phenomenon is also responsible for time-dependent failure or creep fracture due to cumulative strain. Several constitutive equations have been used to describe the mechanical time-dependent response of polymers. These models have been proposed over the past six decades, with minimal direct and practical confrontation. Each model is associated with a specific application or research group. This work assesses the predictive performance of four distinct time-dependent constitutive models based on experimental data. The models were deemed sufficiently straightforward to be readily integrated into practical engineering analyses. A range of loading cases, encompassing constant strain rate, creep, and relaxation tests, were conducted on a commercial epoxy resin. Model parameter calibration was conducted with a minimum data set. The extrapolative predictive capacity of the models was evaluated for creep loading by extending the tests to five decades. The selected rheological models comprise two viscoelastic models based on Volterra-type integrals, as originally proposed by Schapery and Rabotnov; one viscoplastic model, as originally proposed by Norton and Bailey; and the Burger model, in which two springs and two dashpots are combined in a serial and parallel configuration. The number of model parameters does not correlate positively to superior performance, even if it is high. Overall, the models exhibited satisfactory predictive performance, displaying similar outcomes with some relevant differences during the unloading phases. Full article

This paper deals with the design of novel epoxy adhesives by incorporating thermoplastic polymers such as polyetherimide (PEI) and poly(ε-caprolactone) (PCL) into a bio-based and recyclable epoxy resin, known as Polar Bear. The adhesives were characterized by their mechanical (quasi-static and dynamic) and rheological properties, thermal stability, and adhesion properties in single-lap joints tested at three different temperatures (i.e., −55 °C, 23 °C, 80 °C). The experimental results indicated that low PEI content substantially improved the mechanical performance and toughness of the adhesive, while preserving good processability. Nonetheless, exceeding 3% weight percentage adversely affected the adhesives’ mechanical resistance and workability. Conversely, while PCL addition enhanced the adhesives’ viscosity, it also decreased mechanical performance. However, its eco-friendliness offers potential for sustainable adhesive applications. It is worth noting that regardless of temperature, the modified adhesives consistently outperformed the commercial epoxy adhesive (DP-460), used as reference, in single-lap shear joint tests. Additionally, both PEI- and PCL-modified epoxy adhesives have demonstrated recyclability through a simple acid-based process, enabling joint disassembly and recycling of the adhesive into a thermoplastic polymer. Overall, the modified adhesives represent a promising eco-friendly, high-performance alternative for structural applications, aligning with sustainable and circular practices. Full article

Cleavable bio-based epoxy resin systems are emerging, eco-friendly, and promising alternatives to the common thermoset ones, providing quite comparable thermo-mechanical properties while enabling a circular and green end-of-life scenario of the composite materials. In addition to being designed to incorporate a bio-based resin greener than the conventional fully fossil-based epoxies, these formulations involve cleaving hardeners that enable, under mild thermo-chemical conditions, the total recycling of the composite material through the recovery of the fiber and matrix as a thermoplastic. This research addressed the characterization, processability, and recyclability of a new commercial cleavable bio-resin formulation (designed by the R-Concept company) that can be used in the fabrication of fully recyclable polymer composites. The resin was first studied to investigate the influence of the different post-curing regimes (room temperature, 100 °C, and 140 °C) on its thermal stability and glass transition temperature. According to the results obtained, the non-post-cured resin displayed the highest T_g (i.e., 76.6 °C). The same post-curing treatments were also probed on the composite laminates (glass and carbon) produced via a lab-scale vacuum-assisted resin transfer molding system, evaluating flexural behavior, microstructure, and dynamic-mechanical characteristics. The post-curing at 100 °C would enhance the crosslinking of polymer chains, improving the mechanical strength of composites. With respect to the non-post-cured laminates, the flexural strength improved by 3% and 12% in carbon and glass-based composites, respectively. The post-curing at 140 °C was instead detrimental to the mechanical performance. Finally, on the laminates produced, a chemical recycling procedure was implemented, demonstrating the feasibility of recovering both thermoplastic-based resin and fibers. Full article

The high- and low-temperature performance of asphalt-based seamless expansion joints seriously affects road performance. The purpose of this paper is to explore the application of thermosetting epoxy asphalt-based materials in bridge expansion joints. The composite modification of asphalt was performed using Styrene–Butadiene rubber (SBR) and Styrene–Butadiene–Styrene (SBS) copolymer. The study then investigates the impact of five different dosages of SBR/SBS-modified asphalt on the performance of epoxy asphalt. The results of the cone penetration test, tensile test, and stress relaxation test of SBR/SBS-modified epoxy asphalt (SSEA) and BJ200 (a commercial Seamless expansion joint material) were comparatively analyzed. The Marshall test, rutting test, three-point bending test, and freeze–thaw split test were used to evaluate the road performance of SSEA mixtures. The test results show that with the increase in asphalt content, the shear resistance and tensile strength of SSEA decrease, and the low-temperature relaxation ability and elongation at break increase. The content of SBR/SBS-modified asphalt has a positive effect on the low-temperature performance of SSEA mixtures, and the residual stability in water and freeze–thaw splitting strength ratio (TSR) are higher than that of BJ200. Based on the requirement of balancing high and low-temperature performance, SSEA-3 has the best overall performance, and the dosage of SBR and SBS modifier is 12% and 2.5%, respectively. The ratio of epoxy resin, SBR/SBS-modified asphalt, and the curing agent is 1:4:1.6, and its use is recommended in areas with slight temperature differences. Full article

Epoxy adhesives possess excellent mechanical properties, durability, and stability in harsh environments, making them suitable for producing engineering materials. This study selects four commercially available epoxy adhesives in Saudi Arabia: Epotec YD 128; Sikadur^®-52 LP; Sikadur^®-31 CF; and Sikadur^®-42 MP Slow. Firstly, a comparison of their storage, application, and service temperatures was made, detailing the hazard identification and prevention measures established in accordance with the Occupational Safety and Health Administration (OSHA) guidelines. Subsequently, test samples of the four adhesives were produced, and tensile, compressive, and shear tests were conducted to compare their fundamental mechanical properties. Finally, a gas analyzer assessed the major harmful gases emitted by these epoxy adhesives 120 min after mixing the epoxy resins and curing agents. The results show that Sika 42 exhibits the highest tensile and compressive strengths among other types of adhesives, reaching 75.7 MPa and 133.8 MPa, respectively. It also has the longest pot life of 48 min at elevated temperatures (40 °C), making it suitable for the climatic conditions in Saudi Arabia. However, as a three-component adhesive, its application is complex and associated with the most identified hazards. Sika 31 presents a tensile modulus of up to 10.4 GPa, at least 3.8 times higher than the other adhesives, making it practical for controlling tensile deformation. Additionally, its ultimate shear strain reaches 10.7%, at least 6.6 times higher than the other samples, highlighting its suitability for constructing ductile bonds. After mixing of epoxy resins with curing agents, the presence of NO₂ and SO₂ were detected. However, no harmful gases were detected after 120 min, possibly due to the complete curing of the adhesives. Full article

This paper presents the methodology developed in the repair of three oak beam ends in a protected heritage building: the Zabala Palace in Ordizia (Basque Country, Spain). It describes the structural assessment, design, calculation and execution process, as well as the experimental tests carried out in the laboratory to verify and validate the structural capacity of the repair method. The intervention consisted of cutting and removing the beam ends degraded by fungi and replacing them with wooden prostheses. These elements were connected to the beams by means of threaded steel rods and epoxy resin. Calculations based on standards and the literature were verified by laboratory tests where aspects such as the fluidity, filling and pull-out resistance of four commercial epoxy resins were tested. Once the epoxy resin was selected, three samples of the reinforcement design were also flexure tested. The results of the different tests show capacities much higher than those resulting from the application of the calculation procedures in the current bibliography and standards. The implemented solution allowed the conservation of most of the original patrimonial timber, following the criteria of minimum intervention. Full article