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26 pages, 9507 KB  
Article
Damage Evolution of Initial Tunnel Support and Structural Safety of Lining Under Complex Oil–Gas Corrosive Environment
by Baijun Yue, Yu Wang, Xingping Wang, Quanwei Zhu, Junqian He and Yukai Wu
Buildings 2026, 16(9), 1694; https://doi.org/10.3390/buildings16091694 (registering DOI) - 25 Apr 2026
Abstract
Tunnels excavated in non-coal oil- and gas-bearing strata may experience the seepage and intermittent ingress of an oil–gas–water mixture during construction, creating aggressive corrosive conditions that can compromise the integrity of primary support and the safety margin of the final lining. However, the [...] Read more.
Tunnels excavated in non-coal oil- and gas-bearing strata may experience the seepage and intermittent ingress of an oil–gas–water mixture during construction, creating aggressive corrosive conditions that can compromise the integrity of primary support and the safety margin of the final lining. However, the coupled degradation mechanism of primary support and its cascading effect on lining safety under such conditions remain poorly understood. Based on the Huaying Mountain Tunnel project, this study investigates the corrosion-driven damage evolution of primary support and its implications for the structural safety of the secondary lining under wet–dry cycling exposure. Accelerated wet–dry cycling tests were performed on concrete specimens using an on-site crude-oil–formation-water mixture collected during tunnelling, with exposure levels ranging from 0 to 120 cycles. Laboratory observations were then combined with inverse identification of degradation-dependent material parameters to establish a corrosion-informed mechanical description, which was implemented in numerical simulations for structural response assessment. Results show a staged evolution of mechanical properties, with an initial increase followed by progressive deterioration. After 120 cycles, compressive strength, tensile strength, and elastic modulus decreased by approximately 18.9%, 23.1%, and 17.4%, respectively. Degradation is more pronounced in the corroded zone, with tensile capacity and stiffness deteriorating earlier than compressive resistance. Numerical results indicate that corrosion leads to significant stress redistribution and damage development. The sidewall tensile stress reaches 2.80 MPa after 120 cycles, exceeding the post-corrosion capacity, while the safety factor drops below the code threshold at 90 cycles. The overall safety probability decreases from 1.0 to 0.4, accompanied by a degradation in safety grade from Level I to Level IV. These findings provide a quantitative basis for deterioration assessment, safety verification, and maintenance planning for tunnels subjected to oil–gas corrosive environments. Full article
(This article belongs to the Special Issue Advances in Structural Systems and Construction Methods)
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31 pages, 169044 KB  
Article
Uranium Sources and Depositional Environments in Southeastern Mongolia: Case Studies from the Han Bogd Granite Massif, Ail Bayan Coal Deposit, Suujin Tal Structural System, Zuunbayan Depression, and Naarst Structural Complex
by Boris Vakanjac, Marko Simić, Siniša Drobnjak, Rastko Petrović, Radoje Banković, Saša Bakrač and Miodrag Kostić
Minerals 2026, 16(5), 447; https://doi.org/10.3390/min16050447 (registering DOI) - 25 Apr 2026
Abstract
Uranium exploration in southeastern Mongolia remains constrained by fragmented Soviet-era datasets and limited modern synthesis. This study addresses the problem of integrating historical geological records with contemporary exploration methods to evaluate uranium mineralization potential. A comprehensive GIS-based database was compiled from Soviet reports [...] Read more.
Uranium exploration in southeastern Mongolia remains constrained by fragmented Soviet-era datasets and limited modern synthesis. This study addresses the problem of integrating historical geological records with contemporary exploration methods to evaluate uranium mineralization potential. A comprehensive GIS-based database was compiled from Soviet reports legally acquired from the Mineral Resources Authority of Mongolia and expanded with geological, geophysical, and drilling data collected between 2006 and 2011. Methodological advances included remote sensing detection of anomalous radioactivity in arid environments, stratigraphic modeling, and hydrogeochemical surveys. The dataset encompasses more than 1100 radioactive anomalies and approximately 300 mineralized zones, with emphasis on the Han Bogd granite massif, Ail Bayan coal deposit, Suujin Tal structural system, Zuunbayan depression, and Naarst structural complex. Results indicate that most anomalous zones are sub-economic, commonly associated with organic-rich facies such as coal seams, while the continuity of mineralized bodies remains uncertain. Nevertheless, the dual consideration of granitic source terrains and coal-bearing sedimentary traps provides new insights into uranium mobility and deposition. The significance of this work lies in its systematic integration of historical and modern data, offering a refined geological framework and highlighting key areas for future investigation, thereby contributing to ongoing discussions on sedimentary uranium resources in Mongolia. Results indicate that most anomalous zones are sub-economic, commonly associated with organic-rich facies such as coal seams, while the continuity of mineralized bodies remains uncertain. Importantly, the study highlights granitic intrusions and volcanic complexes as the primary uranium sources, with coal-bearing and sedimentary basins acting as secondary depositional environments. The dual consideration of source terrains and depositional traps provides new insights into uranium mobility and deposition. Full article
(This article belongs to the Special Issue Genesis of Uranium Deposit: Geology, Geochemistry, and Geochronology)
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34 pages, 1823 KB  
Article
The Agglomeration Scale Within Urban Agglomerations and Energy Intensity: Empirical Evidence from China
by Min Wu, Qirui Chen, Zihan Hu and Huimin Wang
Land 2026, 15(5), 727; https://doi.org/10.3390/land15050727 (registering DOI) - 25 Apr 2026
Abstract
Urban agglomerations have become the dominant spatial platform of urbanization, regional coordination, and economic transformation in China. Yet whether the expansion of agglomeration scale at the urban-agglomeration level alleviates or intensifies energy use remains insufficiently understood. Extending the scale of analysis from individual [...] Read more.
Urban agglomerations have become the dominant spatial platform of urbanization, regional coordination, and economic transformation in China. Yet whether the expansion of agglomeration scale at the urban-agglomeration level alleviates or intensifies energy use remains insufficiently understood. Extending the scale of analysis from individual cities to integrated urban agglomerations, this study investigates 64 cities in four major Chinese urban agglomerations, including Beijing–Tianjin–Hebei, the Yangtze River Delta, the Pearl River Delta, and Chengdu–Chongqing, over the period 2006–2023. Using panel data models, this study examines the impact of the scale agglomeration within urban agglomeration on urban energy intensity. The results show that the overall agglomeration scale generated by urban agglomeration formation significantly suppresses energy intensity while indicating a robust energy-saving effect: every 10% increase in agglomeration scale is associated with a decline of approximately 0.0893 million tons of standard coal per CNY 100 million of GDP. This finding remains stable after addressing endogeneity concerns and performing a series of robustness checks. Mechanism analyses further suggest that this effect operates primarily through talent agglomeration, technological progress, and public transportation expansion. In addition, the energy-saving effect is more pronounced in smaller cities, cities with lower administrative rank, cities with weaker factor mobility, and cities characterized by poorer air quality but stronger public environmental attention. These findings contribute to the literature on urban agglomeration and green development by showing that the agglomeration scale within urban agglomerations can generate inclusive energy-efficiency gains, especially for relatively disadvantaged cities, thereby offering important implications for spatial governance and low-carbon transition in rapidly urbanizing economies. Full article
32 pages, 14398 KB  
Article
An Intelligent Airflow Regulation Method for Mine Ventilation Networks Based on MIST Topological Dimensionality Reduction and the IDBO Algorithm
by Zhenguo Yan, Longcheng Zhang, Yanping Wang, Lipeng Dang and Tianhe Fu
Mathematics 2026, 14(9), 1446; https://doi.org/10.3390/math14091446 (registering DOI) - 25 Apr 2026
Abstract
Mine ventilation network (MVN) regulation faces severe challenges: strong variable coupling, high search dimensionality, and the inherent conflict between energy conservation and safety constraints. To address these issues, we propose a novel airflow optimization framework integrating a Minimum Influence Spanning Tree (MIST), sensitivity [...] Read more.
Mine ventilation network (MVN) regulation faces severe challenges: strong variable coupling, high search dimensionality, and the inherent conflict between energy conservation and safety constraints. To address these issues, we propose a novel airflow optimization framework integrating a Minimum Influence Spanning Tree (MIST), sensitivity attenuation boundaries, and an Improved Dung Beetle Optimizer (IDBO). Initially, high-influence co-tree chords are strategically extracted via MIST to compress the mathematical optimization dimensionality. Subsequently, effective ventilation resistance search intervals are bounded using sensitivity attenuation, preventing the algorithm from performing invalid searches in high-resistance regions. Furthermore, the standard DBO is enhanced via Fuchs chaotic initialization, Golden Sine and Lens Imaging collaborative learning, and differential mutation to minimize system power consumption. A 46-branch MVN case study validates the approach, identifying an 8-dimensional control combination as the absolute minimum requirement for full compliance. Compared to state-of-the-art baselines (DBO, SSA, WOA, DE), IDBO achieved the lowest power consumption. Post-optimization, the airflow constraint satisfaction rate improved from 89.13% to 100%, and total system power decreased by 11.87% (from 185.03 kW to 163.08 kW). Ultimately, this method robustly achieves Ventilation on Demand (VoD), providing a reliable computational tool for intelligent underground mining. Full article
17 pages, 6524 KB  
Article
Mechanism and Engineering Practice of Pressure Relief by Hydraulic Fracturing with Directional Long Boreholes in Hard Roof Strata
by Zhuangzhuang Yao, Tianxin Feng, Linchao Dai, Zhigang Zhang and Wenbin Wu
Appl. Sci. 2026, 16(9), 4209; https://doi.org/10.3390/app16094209 (registering DOI) - 25 Apr 2026
Abstract
To address the technical challenge of large-area roof hanging and induced strong strata behaviors in deep mines with hard roof strata, a study on pressure relief using hydraulic fracturing technology was conducted, taking the 1012006 working face in the Yuanzigou Coal Mine as [...] Read more.
To address the technical challenge of large-area roof hanging and induced strong strata behaviors in deep mines with hard roof strata, a study on pressure relief using hydraulic fracturing technology was conducted, taking the 1012006 working face in the Yuanzigou Coal Mine as the engineering background. Through geological survey and key stratum theory analysis, a low-position key stratum located 23 m above the roadway roof was identified as the target layer for fracturing. True triaxial hydraulic fracturing experiments coupled with acoustic emission (AE) monitoring revealed a synchronous response characterized by a sudden drop in injection pressure and a rapid increase in AE counts. This established a quantitative correlation between rock mass fracturing and AE characteristics, providing a theoretical basis for field microseismic monitoring. Based on the “dual-borehole synergy” borehole layout principle, a fracturing network comprising 6 drilling fields and 12 directional long boreholes was designed, with a total drilling length of 5727 m and 120 planned fracturing stages. Specialized equipment was selected for implementation. Field monitoring results demonstrated: a maximum fracturing influence radius of 27.8 m; that the average daily frequency and total energy of microseismic events decreased by 50.65% and 27.73%, respectively; and that the stress in the deep part of the roadway decreased by 17.69%. These results confirm the effective improvement of the roof stress environment and the successful achievement of the expected pressure relief and rockburst prevention effect. Full article
(This article belongs to the Special Issue Advanced Technologies in Rock Mechanics and Mining Science)
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26 pages, 1853 KB  
Article
Reaction Sequence Coordination in Ternary Solid-Waste Systems for Low-Carbon Cementitious Materials
by Youlin Ye, Guangyu Zhou, Yannian Zhang, Xin Wei and Ben Niu
Appl. Sci. 2026, 16(9), 4205; https://doi.org/10.3390/app16094205 (registering DOI) - 24 Apr 2026
Abstract
Using solid waste as supplementary cementitious materials (SCMs) is an effective strategy for promoting low-carbon construction development. However, single or binary systems often exhibit mismatched reaction kinetics, thereby limiting their performance at high cement replacement rates. This study focuses on a novel low-carbon [...] Read more.
Using solid waste as supplementary cementitious materials (SCMs) is an effective strategy for promoting low-carbon construction development. However, single or binary systems often exhibit mismatched reaction kinetics, thereby limiting their performance at high cement replacement rates. This study focuses on a novel low-carbon concrete designed based on reaction sequence coordination, containing recycled brick powder (RBP), ground granulated blast-furnace slag (GGBS), and self-combusting coal gangue (SCCG). The effects of RBP, GGBS, and SCCG on the hydration process and microstructure of the novel low-carbon concrete with different replacement levels have been studied by testing compressive strength, workability, and durability and observing microstructural changes. The results showed that an optimized ternary composition with an RBP:GGBS:SCCG ratio of 4:3:1 achieves a cement replacement level of 30% while exhibiting a 28-day compressive strength of 38.26 MPa, representing a 14.2% increase compared with plain cement mortar. Microstructural analyses indicate that this enhanced performance results from a time-dependent reaction sequence, in which GGBS contributes predominantly at early ages by supplying calcium, whereas RBP and SCCG mainly participate through delayed pozzolanic reactions and pore refinement at later ages. Consequently, the optimized ternary mortar exhibits a water absorption of 11.12% and a 27.2% reduction in electrical flux. This study aims to provide practical strategies for enhancing the performance of low-carbon cementitious materials through a reaction sequence coordination design approach, thereby improving the utilization efficiency of solid waste in the production of low-carbon building materials. Full article
(This article belongs to the Section Civil Engineering)
17 pages, 6779 KB  
Article
Polarization Fading Noise Suppression in Phase-Sensitive OTDR Using Variational Mode Decomposition
by Ruotong Mei, Weidong Bai, Xinming Zhang, Junhong Wang, Yu Wang and Baoquan Jin
Photonics 2026, 13(5), 421; https://doi.org/10.3390/photonics13050421 - 24 Apr 2026
Abstract
To address the polarization fading noise in coherent detection phase-sensitive optical time-domain reflectometry (Φ-OTDR) for distributed low-frequency vibration sensing, a Φ-OTDR sensing scheme integrating polarization diversity reception and the variational mode decomposition (VMD) algorithm is proposed. The mechanism of polarization fading induced by [...] Read more.
To address the polarization fading noise in coherent detection phase-sensitive optical time-domain reflectometry (Φ-OTDR) for distributed low-frequency vibration sensing, a Φ-OTDR sensing scheme integrating polarization diversity reception and the variational mode decomposition (VMD) algorithm is proposed. The mechanism of polarization fading induced by fiber birefringence and external perturbations is systematically analyzed. A signal–noise mathematical model for polarization diversity reception is established, and the adaptive decomposition capability of the VMD algorithm for non-stationary phase signals is elaborated. This scheme can accurately separate the additional noise introduced by polarization diversity reception from the target low-frequency vibration signals. Experimental results demonstrate that, compared with the single-path detection scheme, the proposed method eliminates the amplitude attenuation of beat frequency signals caused by polarization mismatch at the optical path level. Meanwhile, it effectively suppresses both the additional noise introduced by polarization diversity and the low-frequency phase drift resulting from unstable laser frequency. It achieves precise phase restoration of vibration signals excited at 50 Hz under three typical sensing distances of 5 km, 10 km, and 30 km. Additionally, it successfully restores low-frequency vibration signals as low as 0.6 Hz at the sensing distance of 30 km. Full article
(This article belongs to the Section Lasers, Light Sources and Sensors)
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25 pages, 8485 KB  
Article
Evolution Mechanism and Bearing Capacity of End-Area Hanging Roofs in Thick Hard Roofs with Liquid Nitrogen Fracturing Control
by Pengfei Shan, Ke Yang, Huicong Xu, Gen Li, Zheng Meng and Bojia Xi
Appl. Sci. 2026, 16(9), 4195; https://doi.org/10.3390/app16094195 - 24 Apr 2026
Abstract
To address severe strata pressure induced by large end-area hanging spans and poor caving of thick, hard roofs in western coal mines, this study takes the 1302 working face of Zhujiamao Coal Mine as a case study. A multiscale mechanical model is developed [...] Read more.
To address severe strata pressure induced by large end-area hanging spans and poor caving of thick, hard roofs in western coal mines, this study takes the 1302 working face of Zhujiamao Coal Mine as a case study. A multiscale mechanical model is developed to describe the progressive evolution of a stratified hard roof from a continuous beam to a cantilever beam and finally to an arched triangular hanging roof. Limit criteria for the maximum hanging length under bending and shear failure are derived, indicating that bending governs end-area roof instability. The theoretical results show good agreement with field observations and numerical simulations, providing guidance for liquid nitrogen fracturing target selection. Coupled FLAC3D-3DEC simulations reveal the staged deformation of overlying strata and clarify the spatial correspondence between the “O-X” fracture pattern and the arched triangular hanging roof. Based on these findings, a collaborative weakening strategy integrating directional drilling, hydraulic pre-cracking, and deep liquid nitrogen fracturing is proposed. Field observations and comparative tests confirm that this method effectively forms a three-dimensional fracture network, reduces roof stiffness and strength, shortens the caving interval, lowers peak shield resistance, and promotes stable caving of the end-area hanging roof. Full article
18 pages, 6208 KB  
Article
Enhanced Gas Drainage via Gas Injection Displacement Based on Hydraulic Flushing: Numerical Simulation and Field Test
by Xin Yang, Feiyan Tan and Qingcheng Zhang
Energies 2026, 19(9), 2061; https://doi.org/10.3390/en19092061 - 24 Apr 2026
Abstract
Hydraulic flushing is an effective permeability enhancement technology for coal seams in underground coal mines and has been widely applied in several mining areas in China. However, in low-permeability coal seams, gas drainage from hydraulic flushing boreholes often enters a rapid depletion phase, [...] Read more.
Hydraulic flushing is an effective permeability enhancement technology for coal seams in underground coal mines and has been widely applied in several mining areas in China. However, in low-permeability coal seams, gas drainage from hydraulic flushing boreholes often enters a rapid depletion phase, and achieving secondary enhanced drainage remains a critical challenge. To address this issue, this study investigates a synergistic gas drainage technology that combines gas injection displacement with hydraulic flushing. Taking the No. 3 coal seam in the Lu’an mining area of China as the research object, the optimal process parameters of this synergistic technology are systematically determined through numerical simulation and validated by underground field tests. A fully coupled numerical model incorporating the adsorption–desorption–seepage processes of the CH4/N2/O2 ternary gas system is established. The influences of injection spacing and injection pressure on drainage performance are systematically analyzed. Simulation results identify the optimal process parameters as an injection spacing of 3.5 m and an injection pressure of 1.4 MPa. Under these conditions, the relative coal permeability reaches a maximum of 1.06, the permeability enhancement zone fully covers the region between the injection and drainage boreholes, and the coal seam gas content decreases to the critical threshold of 8 m3/t in approximately 235 days. The model is quantitatively validated using 82-day field monitoring data from the synergistic module, with a relative error of approximately 1.1% between the simulated and field-derived recovery ratios. Subsequently, four sets of underground engineering trials—conventional drainage, gas injection displacement alone, hydraulic flushing alone, and the synergistic technology—are conducted in the target coal seam based on the optimized parameters. Statistical analysis of the 82-day field data shows that the synergistic technology achieves a cumulative pure methane volume of 4.83 m3, outperforming conventional drainage by 85.8% (4.83 m3 compared with 2.60 m3), gas injection alone by 23.5% (4.83 m3 compared with 3.91 m3), and hydraulic flushing alone by 52.4% (4.83 m3 compared with 3.17 m3). The mean flow rate of the synergistic module during the injection phase reaches 0.070 ± 0.012 L/min, significantly higher than that of gas injection alone (0.044 ± 0.011 L/min). This study provides economically feasible theoretical and technical support for efficient gas drainage in low-permeability coal seams in underground mines. Full article
(This article belongs to the Special Issue Petroleum and Natural Gas Engineering: 2nd Edition)
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31 pages, 9627 KB  
Article
AI-Enhanced Numerical Modeling for Structural Optimization of a Conceptual Large-Scale Coal MILD-oxy Combustion Boiler
by Weizhen Yu, Cong Yu, Feng Wang, Yongyi Xu, Peng Zou and Wei Wu
Energies 2026, 19(9), 2067; https://doi.org/10.3390/en19092067 - 24 Apr 2026
Abstract
To advance the design of novel clean coal-fired boilers, this study integrates artificial intelligence with numerical simulations to optimize a 130 MW conceptual boiler based on Moderate or Intense Low-oxygen Dilution (MILD) and oxy-coal combustion technologies. First, mathematical models for pulverized-coal MILD-oxy combustion [...] Read more.
To advance the design of novel clean coal-fired boilers, this study integrates artificial intelligence with numerical simulations to optimize a 130 MW conceptual boiler based on Moderate or Intense Low-oxygen Dilution (MILD) and oxy-coal combustion technologies. First, mathematical models for pulverized-coal MILD-oxy combustion are validated using experimental data from a 0.58 MW pilot-scale boiler and then applied to the full-scale 130 MW boiler. An orthogonal experimental design with four factors and five levels is employed to generate 25 simulation cases, evaluating the effects of burner nozzle configuration and furnace geometry on boiler performance. Based on the simulation dataset, mutual information analysis is conducted to identify key influencing features, guiding nine additional simulations to refine samples in critical design areas. Finally, using the complete 34 simulation data, an optimal boiler structure is identified using support vector machine and multi-objective optimization algorithms. The results indicate that both the burner circumferential diameter and the O2/CO2 inlet diameter are positively correlated with nitrogen oxide (NOx) emissions, whereas the former is negatively correlated with the wall thermal non-uniformity. After optimization, the average char burnout rate increased by 1.4%, NOx emissions decreased by 4%, and wall heat non-uniformity coefficient reduced by 1.1%, demonstrating the effectiveness of the proposed approach. Full article
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24 pages, 1653 KB  
Article
Early Detection of Spatiotemporal Stabilization in Open-Pit Mine Waste Dumps via Time-Series InSAR Coherence
by Yueming Sun, Yanjie Tang, Zhibin Li and Yanling Zhao
Remote Sens. 2026, 18(9), 1310; https://doi.org/10.3390/rs18091310 - 24 Apr 2026
Abstract
Accurately monitoring the surface stabilization of waste dumps in open-pit coal mines is critical for hazard prevention and ecological reclamation. In arid and semi-arid regions, traditional optical remote sensing vegetation indices suffer from a systematic “response lag” in assessing physical stability due to [...] Read more.
Accurately monitoring the surface stabilization of waste dumps in open-pit coal mines is critical for hazard prevention and ecological reclamation. In arid and semi-arid regions, traditional optical remote sensing vegetation indices suffer from a systematic “response lag” in assessing physical stability due to the slow establishment of pioneer vegetation. To overcome this biological limitation, this study proposes a quantitative spatiotemporal monitoring framework based on time-series Interferometric Synthetic Aperture Radar (InSAR) coherence to detect early-stage geotechnical stabilization. Using Sentinel-1 imagery of the Balongtu coal mine, a sliding-window detection algorithm was developed to capture the physical transition of surface electromagnetic scattering mechanisms from active disturbance to stable consolidation. The main findings are as follows: (1) Statistical analysis identified a critical geophysical coherence threshold of 0.15, which effectively and objectively distinguishes active dumping disturbance zones from structurally stable areas. (2) The spatiotemporal evolution dynamics of the completed dump areas from 2017 to 2023 were successfully characterized, revealing that 87.6% of the open-pit areas achieved physical stabilization within three years post-mining, with a spatial distribution highly consistent with the objective operational rule of “mining first, dumping later”. (3) Accuracy assessment using 700 spatiotemporally balanced validation points—derived through strict visual interpretation of high-resolution optical imagery—demonstrated high algorithm reliability, achieving overall accuracies (OA) of 87.57% and 90.43% at half-yearly and annual monitoring intervals, respectively. By decoupling physical surface stabilization from optical greenness, this study provides a timely abiotic precursor indicator, offering scientific, quantitative decision support for precision ecological zoning and accelerated land turnover approval in mining areas. Full article
17 pages, 2282 KB  
Article
Deactivation Mechanism and Thermal Decomposition Kinetics of Mechanically Activated Pyrite in Air
by Yajing Chen, Hongying Yang, Linlin Tong, Guomin Chen and Jianing Xu
Minerals 2026, 16(5), 443; https://doi.org/10.3390/min16050443 (registering DOI) - 24 Apr 2026
Abstract
Mechanically activated pyrite plays an important role in gold extraction and coal utilization, but its reactivity may change markedly during storage. This study investigates how air deactivation during storage affects the crystal structure and subsequent thermal decomposition behavior of mechanically activated pyrite. Pyrite [...] Read more.
Mechanically activated pyrite plays an important role in gold extraction and coal utilization, but its reactivity may change markedly during storage. This study investigates how air deactivation during storage affects the crystal structure and subsequent thermal decomposition behavior of mechanically activated pyrite. Pyrite was mechanically activated and then stored in air for 0, 7 and 180 days. X-ray diffraction (XRD) combined with Rietveld refinement was used to characterize variations in lattice parameters and unit-cell-related structural features, while non-isothermal thermogravimetric–differential scanning calorimetry (TG-DSC) under an argon atmosphere, together with the Flynn–Wall–Ozawa (FWO) method, was applied to evaluate the decomposition kinetics. Air deactivation induced a non-monotonic evolution of lattice parameters and unit-cell volume, which is attributed to combined effects of residual stress relaxation and air-induced surface-related modification during storage. All samples exhibited two mass-loss stages during heating, reflecting stepwise thermal decomposition, and their decomposition behavior varied systematically with deactivation time. The apparent activation energy depended on both conversion fraction and deactivation degree, and nucleation-and-growth-type mechanisms were found to dominate the decomposition process, with their relative contributions evolving with storage time. These results clarify how prior air-deactivation history influences the structural evolution and subsequent thermal decomposition behavior of mechanically activated pyrite and provide useful insight for its storage and utilization in related processes. Full article
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29 pages, 1673 KB  
Article
Product Structure Optimization of Coal Preparation Plants Based on GPSOM–WOA
by Gan Luo, Ranfeng Wang, Xiang Fu, Mingzhang Yang, Longkang Li, Xinlei Li, Shunqiang Wang and Hanchi Ren
Processes 2026, 14(9), 1366; https://doi.org/10.3390/pr14091366 - 24 Apr 2026
Abstract
Coal preparation plants pursue maximum economic benefit, yet product structure optimization under fluctuating coal quality and changing market demand is a coupled decision-making problem involving the organization of primary products such as lump clean coal, clean coal, raw fine coal, coal slime, and [...] Read more.
Coal preparation plants pursue maximum economic benefit, yet product structure optimization under fluctuating coal quality and changing market demand is a coupled decision-making problem involving the organization of primary products such as lump clean coal, clean coal, raw fine coal, coal slime, and gangue, together with commercial coal blending and process-scheme selection. Conventional optimization methods that focus on a single stage are often insufficient to address such complex coordinated decisions. To this end, a GPSOM–WOA nested optimization model was developed to achieve the coordinated optimization of primary product separation, commercial coal blending, and process-scheme selection under the objective of economic benefit maximization. In the outer layer, where process-scheme selection and primary product structure adjustment involve both discrete decisions and continuous variables, a simplified Group-based Particle Swarm Optimization with Multiple Strategies (GPSOM) was employed to search the primary product structure parameters and generate engineering-feasible primary product balance tables. In the inner layer, where the commercial coal blending problem is subject to multiple constraints, including ash content, moisture, calorific value, and supply demand, the Whale Optimization Algorithm (WOA) was adopted to optimize blending ratios within a restricted feasible region. A piecewise penalty function was introduced for quality-limit violations to support profit-oriented constrained optimization. Subject to commercial coal quality constraints on ash content, moisture, and calorific value, a case study of a coal preparation plant in Inner Mongolia was conducted to compare product structures and economic benefits under different process conditions. The results show that the proposed model can realize the joint optimization of primary product structure and commercial coal blending, and can provide a quantitative basis for product structure optimization and process selection in coal preparation plants. Full article
(This article belongs to the Section Petroleum and Low-Carbon Energy Process Engineering)
22 pages, 14681 KB  
Article
Pore Permeability Cycling Characteristics of Coal-Bearing Strata in the Agong Syncline, Western Guizhou, South China: Implications for Superposed Gas Systems
by Lingling Lu, Chen Guo, Chao Deng and Yan Ji
Appl. Sci. 2026, 16(9), 4178; https://doi.org/10.3390/app16094178 - 24 Apr 2026
Abstract
The Late Permian coal-bearing strata in western Guizhou Province, South China, are developed with multiple coal seams and rich in coalbed methane (CBM) resources. Controlled by the sealing layers within the coal-bearing strata, multiple vertically superposed independent CBM systems were formed, which complicates [...] Read more.
The Late Permian coal-bearing strata in western Guizhou Province, South China, are developed with multiple coal seams and rich in coalbed methane (CBM) resources. Controlled by the sealing layers within the coal-bearing strata, multiple vertically superposed independent CBM systems were formed, which complicates the CBM accumulation characteristics and limits CBM development. Through systematic sampling of the main coal seams and different lithologic strata in Borehole 101 on the southeastern limb of the Agong Syncline in western Guizhou, mercury intrusion porosimetry (MIP) and Klinkenberg permeability experiments were conducted on coal and rock samples. The results show that the coal samples have an average pore volume of 0.0417 mL/g, an average porosity of 5.37%, an average mercury withdrawal efficiency of 69.79%, and an average well test permeability of 0.3743 mD; the rock samples have an average pore volume of 0.0064 mL/g, an average porosity of 1.43%, an average mercury withdrawal efficiency of 7.88%, and an average Klinkenberg permeability of 0.0128 mD. The pore and permeability conditions of rock layers are significantly poorer than those of coal seams, which favorably contributes to the formation of effective sealing layers between coal seams and facilitates the CBM preservation. Mudstone and argillaceous siltstone in the coal-bearing strata, characterized by their low porosity and permeability, are suitable as effective gas and water barriers between coal seams. Based on a comprehensive analysis of the vertical variations in permeability, porosity, and gas-bearing characteristics of Borehole 101, the Upper Permian coal-bearing strata are preliminarily divided into four independent CBM-bearing systems. These systems are separated by tight rock layers with extremely low permeability and porosity, and their division aligns closely with the third-order sequence stratigraphic framework. The findings can provide a theoretical basis for deepening the understanding of CBM accumulation mechanisms in multi-seam regions and optimizing the orderly CBM development models. Full article
12 pages, 5606 KB  
Article
Relationship Between Moisture Transfer and Pore Structure Evolution and Its Induced Damage Mechanism During Lignite Drying
by Mingqiang Gao, Cheng Cheng, Zhenyong Miao, Pengchao Ji, Keji Wan and Qiongqiong He
Processes 2026, 14(9), 1362; https://doi.org/10.3390/pr14091362 - 24 Apr 2026
Abstract
Lignite particles generate considerable dust during drying due to structural damage, which increases the dust removal costs of the drying system, pollutes the environment, and raises the risk of combustion and explosion, thereby posing a threat to the safety of the drying system. [...] Read more.
Lignite particles generate considerable dust during drying due to structural damage, which increases the dust removal costs of the drying system, pollutes the environment, and raises the risk of combustion and explosion, thereby posing a threat to the safety of the drying system. Moisture plays a crucial role in the structural damage of lignite particles during drying. In this study, lignite samples with moisture contents of 60%, 36%, and 18% were prepared and dried in hot air at 200 °C. The transfer behavior of moisture in the pore structure was investigated, and the evolution of the pore structure was observed. The relationship between pore structure evolution and moisture transfer behavior was correlated, and the mechanism of structural damage under the action of moisture during the drying process was proposed. The results demonstrated that the moisture in large pores was transported rapidly in the form of a gas–liquid mixture; the liquid moisture in the pores boiled into water vapor, and the water vapor pressure was the main reason for the destruction of the pore structure. For raw lignite, the total pore volume decreased sharply from 0.92 to 0.37 mL/g within the first 360 s of drying, and the fractal dimension dropped from 2.701 to 2.545, indicating severe pore collapse. However, the moisture in small pores migrated by molecular diffusion, which is nondestructive to the lignite structure. Full article
(This article belongs to the Section Chemical Processes and Systems)
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