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Keywords = charge pump dynamics

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21 pages, 3084 KiB  
Article
CFD Analysis of a Falling Film Evaporator Using the Low-GWP Refrigerant R1336mzz(Z) in High-Temperature Heat Pump Applications
by Shehryar Ishaque, Muhammad Saeed, Qazi Shahzad Ali, Naveed Ullah, Jedd C. Junio and Man-Hoe Kim
Processes 2025, 13(8), 2398; https://doi.org/10.3390/pr13082398 - 28 Jul 2025
Viewed by 300
Abstract
High-temperature heat pump systems are essential for industrial processes that usually require high-temperature and high-pressure steam. An efficient design of these systems is critical for minimizing fossil fuel consumption, thereby contributing to a significant reduction in carbon emissions. One of the key components [...] Read more.
High-temperature heat pump systems are essential for industrial processes that usually require high-temperature and high-pressure steam. An efficient design of these systems is critical for minimizing fossil fuel consumption, thereby contributing to a significant reduction in carbon emissions. One of the key components of these systems is the horizontal falling film evaporator, which is commonly employed due to its high thermal efficiency and low refrigerant charge. This study presents a preliminary design of a falling film evaporator to meet the target of the heat duty value of 2.2 MW. The phase-change dynamics inherent to the falling film evaporation process were critically analyzed using ANSYS Fluent (2024 R2). The low-global warming potential refrigerant R1336mzz(Z) was incorporated as a refrigerant on the shell side, while hot water was used in the tubes. The study identified key regions of film flow to maximize vapor production and design optimizations. The discussed performance parameters and operational mechanisms of the evaporator are prevailing features, particularly with the adoption of environmental regulations. Overall, the simulation results offer valuable insights into heat transfer mechanisms and evaporator effectiveness for advancing heat pump technologies in industrial applications. Full article
(This article belongs to the Special Issue Application of Refrigeration and Heat Pump Technology)
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15 pages, 2537 KiB  
Article
A Comparative Experimental Analysis of a Cold Latent Thermal Storage System Coupled with a Heat Pump/Air Conditioning Unit
by Claudio Zilio, Giulia Righetti, Dario Guarda, Francesca Martelletto and Simone Mancin
Energies 2025, 18(13), 3485; https://doi.org/10.3390/en18133485 - 2 Jul 2025
Viewed by 328
Abstract
The decarbonization of residential cooling systems requires innovative solutions to overcome the mismatch between the renewable energy availability and demand. Integrating latent thermal energy storage (LTES) with heat pump/air conditioning (HP/AC) units can help balance energy use and enhance efficiency. However, the dynamic [...] Read more.
The decarbonization of residential cooling systems requires innovative solutions to overcome the mismatch between the renewable energy availability and demand. Integrating latent thermal energy storage (LTES) with heat pump/air conditioning (HP/AC) units can help balance energy use and enhance efficiency. However, the dynamic behavior of such integrated systems, particularly under low-load conditions, remains underexplored. This study investigates a 5 kW HP/AC unit coupled with an 18 kWh LTES system using a bio-based Phase Change Material (PCM) with a melting temperature of 9 °C. Two configurations were tested: charging the LTES using either a thermostatic bath or the HP/AC unit. Key parameters such as the stored energy, temperature distribution, and cooling capacity were analyzed. The results show that, under identical conditions (2 °C inlet temperature, 16 L/min flow rate), the energy stored using the HP/AC unit was only 6.3% lower than with the thermostatic bath. Nevertheless, significant cooling capacity fluctuations occurred with the HP/AC unit due to compressor modulation and anti-frost cycles. The compressor frequency varied from 75 Hz to 25 Hz, and inefficient on-off cycling appeared in the final phase, when the power demand dropped below 1 kW. These findings highlight the importance of integrated system design and control strategies. A co-optimized HP/AC–LTES setup is essential to avoid performance degradation and to fully exploit the benefits of thermal storage in residential cooling. Full article
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19 pages, 8803 KiB  
Article
An Accurate and Low-Complexity Offset Calibration Methodology for Dynamic Comparators
by Juan Cuenca, Benjamin Zambrano, Esteban Garzón, Luis Miguel Prócel and Marco Lanuzza
J. Low Power Electron. Appl. 2025, 15(2), 35; https://doi.org/10.3390/jlpea15020035 - 2 Jun 2025
Viewed by 747
Abstract
Dynamic comparators play an important role in electronic systems, requiring high accuracy, low power consumption, and minimal offset voltage. This work proposes an accurate and low-complexity offset calibration design based on a capacitive load approach. It was designed using a 65 nm CMOS [...] Read more.
Dynamic comparators play an important role in electronic systems, requiring high accuracy, low power consumption, and minimal offset voltage. This work proposes an accurate and low-complexity offset calibration design based on a capacitive load approach. It was designed using a 65 nm CMOS technology and comprehensively evaluated under Monte Carlo simulations and PVT variations. The proposed scheme was built using MIM capacitors and transistor-based capacitors, and it includes Verilog-based calibration algorithms. The proposed offset calibration is benchmarked, in terms of precision, calibration time, energy consumption, delay, and area, against prior calibration techniques: current injection via gate biasing by a charge pump circuit and current injection via parallel transistors. The evaluation of the offset calibration schemes relies on Analog/Mixed-Signal (AMS) simulations, ensuring accurate evaluation of digital and analog domains. The charge pump method achieved the best Energy-Delay Product (EDP) at the cost of lower long-term accuracy, mainly because of its capacitor leakage. The proposed scheme demonstrated superior performance in offset reduction, achieving a one-sigma offset of 0.223 mV while maintaining precise calibration. Among the calibration algorithms, the window algorithm performs better than the accelerated calibration. This is mainly because the window algorithm considers noise-induced output oscillations, ensuring consistent calibration across all designs. This work provides insights into the trade-offs between energy, precision, and area in dynamic comparator designs, offering strategies to enhance offset calibration. Full article
(This article belongs to the Special Issue Analog/Mixed-Signal Integrated Circuit Design)
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22 pages, 19106 KiB  
Article
Enhanced Charge Pump Architecture with Feedback Supply Selector for Optimized Switching Performance
by Cristian Stancu, Anca Andreea Mitu, Teodora Ionescu, Andrei Neacsu, Lidia Dobrescu and Dragos Dobrescu
Electronics 2025, 14(7), 1484; https://doi.org/10.3390/electronics14071484 - 7 Apr 2025
Viewed by 829
Abstract
Conventional operational amplifier designs often experience parameter performance issues during the transition between complementary input differential stages, which restricts the full rail-to-rail common mode voltage swing. This paper presents an innovative charge pump architecture featuring a feedback supply selector that optimizes the transition [...] Read more.
Conventional operational amplifier designs often experience parameter performance issues during the transition between complementary input differential stages, which restricts the full rail-to-rail common mode voltage swing. This paper presents an innovative charge pump architecture featuring a feedback supply selector that optimizes the transition performance. The proposed approach employs a switched-capacitor technique to boost the supply voltage by 1.5 V relative to the input voltage, thereby enabling the use of a single pMOS differential input stage. The novel supply selector dynamically chooses the maximum available voltage between the external supply and the boosted output, ensuring efficient transistor switching and improved biasing. Schematic-level and post-layout simulations in a 250 nm CMOS process validate the design under varied load currents, supply voltages, temperatures, and process corners. Results show a significant reduction in output voltage ripple, with a maximum value of 48 mV achieved post-layout, and enhanced overall efficiency, even under higher load currents. This architecture provides a robust and scalable solution for advanced operational amplifiers, particularly in fields where high performance and stability are critical. Full article
(This article belongs to the Special Issue CMOS Integrated Circuits Design)
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25 pages, 6699 KiB  
Article
Optimization of ORC-Based Micro-CHP Systems: An Experimental and Control-Oriented Study
by Márcio Santos, Jorge André, Ricardo Mendes and José B. Ribeiro
Processes 2025, 13(4), 1104; https://doi.org/10.3390/pr13041104 - 7 Apr 2025
Cited by 1 | Viewed by 910
Abstract
This study presents an experimental and numerical investigation into the performance and control optimization of an Organic Rankine Cycle (ORC)-based micro-combined heat and power (micro-CHP) system. A steady-state, off-design, charge-sensitive model is developed to design a control strategy for an ORC micro-CHP combi-boiler, [...] Read more.
This study presents an experimental and numerical investigation into the performance and control optimization of an Organic Rankine Cycle (ORC)-based micro-combined heat and power (micro-CHP) system. A steady-state, off-design, charge-sensitive model is developed to design a control strategy for an ORC micro-CHP combi-boiler, aiming to efficiently meet real-time domestic hot water demands (up to 40 °C and 35 kW) while generating up to 2 kW of electricity. The system utilizes a natural gas burner to evaporate the working fluid (R245fa), with combustion heat power, volumetric pump speed, and expander speed as control variables. Experimental and numerical evaluations generate steady-state control maps to identify optimal operating regions. A PID-based dynamic control strategy is then developed to stabilize operation during start-ups and user demand variations. The results confirm that the strategy delivers hot water within 1.5 min in simple boiler mode and 3 min in cogeneration mode while improving electricity generation stability and outperforming manual control. The findings demonstrate that integrating steady-state modeling with optimized control enhances the performance, responsiveness, and efficiency of ORC-based micro-CHP systems, making them a viable alternative for residential energy solutions. Full article
(This article belongs to the Special Issue Modeling, Simulation and Control of Industrial Processes)
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11 pages, 2574 KiB  
Article
Photo-Excited Carrier Dynamics in Ammonothermal Mn-Compensated GaN Semiconductor
by Patrik Ščajev, Paweł Prystawko, Robert Kucharski and Irmantas Kašalynas
Materials 2024, 17(23), 5995; https://doi.org/10.3390/ma17235995 - 7 Dec 2024
Viewed by 1097
Abstract
We investigated the carrier dynamics of ammonothermal Mn-compensated gallium nitride (GaN:Mn) semiconductors by using sub-bandgap and above-bandgap photo-excitation in a photoluminescence analysis and pump–probe measurements. The contactless probing methods elucidated their versatility for the complex analysis of defects in GaN:Mn crystals. The impurities [...] Read more.
We investigated the carrier dynamics of ammonothermal Mn-compensated gallium nitride (GaN:Mn) semiconductors by using sub-bandgap and above-bandgap photo-excitation in a photoluminescence analysis and pump–probe measurements. The contactless probing methods elucidated their versatility for the complex analysis of defects in GaN:Mn crystals. The impurities of Mn were found to show photoconductivity and absorption bands starting at the 700 nm wavelength threshold and a broad peak located at 800 nm. Here, we determined the impact of Mn-induced states and Mg acceptors on the relaxation rates of charge carriers in GaN:Mn based on a photoluminescence analysis and pump–probe measurements. The electrons in the conduction band tails were found to be responsible for both the photoconductivity and yellow luminescence decays. The slower red luminescence and pump–probe decays were dominated by Mg acceptors. After photo-excitation, the electrons and holes were quickly thermalized to the conduction band tails and Mg acceptors, respectively. The yellow photoluminescence decays exhibited a 1 ns decay time at low laser excitations, whereas, at the highest ones, it increased up to 7 ns due to the saturation of the nonradiative defects, resembling the photoconductivity lifetime dependence. The fast photo-carrier decay time observed in ammonothermal GaN:Mn is of critical importance in high-frequency and high-voltage device applications. Full article
(This article belongs to the Special Issue Optical Properties of Crystalline Semiconductors and Nanomaterials)
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24 pages, 9000 KiB  
Article
Energy Management System for Polygeneration Microgrids, Including Battery Degradation and Curtailment Costs
by Yassine Ennassiri, Miguel de-Simón-Martín, Stefano Bracco and Michela Robba
Sensors 2024, 24(22), 7122; https://doi.org/10.3390/s24227122 - 5 Nov 2024
Viewed by 1464
Abstract
Recent advancements in sensor technologies have significantly improved the monitoring and control of various energy parameters, enabling more precise and adaptive management strategies for smart microgrids. This work presents a novel model of an energy management system (EMS) for grid-connected polygeneration microgrids that [...] Read more.
Recent advancements in sensor technologies have significantly improved the monitoring and control of various energy parameters, enabling more precise and adaptive management strategies for smart microgrids. This work presents a novel model of an energy management system (EMS) for grid-connected polygeneration microgrids that allows optimizing the management of electrical storage systems, electric vehicles, and other deferrable loads such as heat pumps. The main novelty of this model is that it incorporates both climate comfort variables and the consideration of the degradation of the energy storage capacity in the control strategy, as well as a penalty for the dumping of surpluses. The model has been applied to a smart, sustainable building as a case study. The results show that the proposed model is highly adaptable to diverse weather conditions, minimizing renewable energy losses while satisfying the energy demand and providing comfort to the building’s users. The study shows (i) that EVs’ dynamic charging schedules play a crucial role, (ii) that it is possible to minimize a battery’s degradation by optimizing its cycling, averaging one cycle per day, and (iii) the critical impact of seasonal weather patterns on microgrid energy management and the strategic role of EVs and storage systems in maintaining energy balance and efficiency. Full article
(This article belongs to the Special Issue Sensors Technology and Data Analytics Applied in Smart Grid)
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13 pages, 7428 KiB  
Article
Novel Power-Efficient Fast-Locking Phase-Locked Loop Based on Adaptive Time-to-Digital Converter-Aided Acceleration Compensation Technology
by Ligong Sun, Yixin Luo, Zhiyao Deng, Jinchan Wang and Bo Liu
Electronics 2024, 13(18), 3586; https://doi.org/10.3390/electronics13183586 - 10 Sep 2024
Cited by 1 | Viewed by 1586
Abstract
This paper proposes an adaptive acceleration lock compensation technology for phase-locked loops (PLLs) based on a novel dual-mode programmable ring voltage-controlled oscillator (ring-VCO). In addition, a time-to-digital converter (TDC) is designed to accurately quantify the phase difference from the phase frequency detector (PFD) [...] Read more.
This paper proposes an adaptive acceleration lock compensation technology for phase-locked loops (PLLs) based on a novel dual-mode programmable ring voltage-controlled oscillator (ring-VCO). In addition, a time-to-digital converter (TDC) is designed to accurately quantify the phase difference from the phase frequency detector (PFD) in order to optimize the dead-zone effect while dynamically switching an auxiliary charge pump (CP) module to realize fast phase locking. Furthermore, a TDC-controlled three/five-stage dual-mode adaptively continuously switched VCO is proposed to optimize the phase noise (PN) and power efficiency, leading to an optimal performance tradeoff of the PLL. Based on the 180 nm/1.8 V standard CMOS technology, the complete PLL design and a corresponding simulation analysis are implemented. The results show that, with a 1 GHz reference signal as the input, the output frequency is 50–324 MHz, with a wide tuning range of 260 MHz and a low phase noise of −98.07 dBc/Hz@1 MHz. The key phase-locking time is reduced to 1.11 μs, and the power dissipation is lowered to 1.86 mW with a layout area of 66 μm × 128 μm. A significantly remarkable multiobjective performance tradeoff with topology optimization is realized, which is in contrast to several similar design cases of PLLs. Full article
(This article belongs to the Section Circuit and Signal Processing)
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21 pages, 9694 KiB  
Article
Properties Analysis of Hydraulic PTO Output Fluctuation Regulating Based on Accumulator
by Han Jia, Zhongcai Pei, Zhiyong Tang and Meng Li
Actuators 2024, 13(7), 261; https://doi.org/10.3390/act13070261 - 11 Jul 2024
Cited by 2 | Viewed by 1319
Abstract
Hydraulic power take-off (PTO) is increasingly favored as energy regulation and transmission system in wave energy converters (WEC), significantly smoothing the inherent randomness and fluctuation of wave energy. This paper designed a novel hydraulic PTO system composition of a double-acting hydraulic cylinder pump [...] Read more.
Hydraulic power take-off (PTO) is increasingly favored as energy regulation and transmission system in wave energy converters (WEC), significantly smoothing the inherent randomness and fluctuation of wave energy. This paper designed a novel hydraulic PTO system composition of a double-acting hydraulic cylinder pump and accumulators. The dynamic process sub-division principle in an operating period of the hydraulic cylinder pump and accumulator and the mathematical model for explaining the fluctuations of pressure and flow rate in the hydraulic pump and accumulator circuit by means of the sub-division principle are put forward. The MATLAB/Simulink simulation model used to analyze pressure fluctuation in the hydraulic PTO system is established based on the mathematical model. The numerical results and MATLAB simulation results are mutually verified about the fine analysis of the accumulator smoothing fluctuation in the hydraulic PTO system. The results show that the pressure fluctuation amplitude of a hydraulic circuit is negatively correlated with the accumulator pre-charge pressure and the accumulator volume, and is positively correlated with the operating period of a hydraulic pump. The energy transfer efficiency of the hydraulic PTO system with accumulator fine compensation can be above 90%. The theory and model in this paper will serve as a valuable reference for designing fluctuation compensation parameters in hydraulic systems. Full article
(This article belongs to the Section Aerospace Actuators)
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12 pages, 4027 KiB  
Article
A Practical Superconducting DC Dynamo for Charging Conduction-Cooled HTS Magnet
by Yujia Zhai, Chunran Mu, Jinduo Wang, Litong Zhu, Tingkun Weng, Zhuo Li, Xingzheng Wu, Liufei Shen, Jianhua Liu and Qiuliang Wang
Energies 2024, 17(11), 2684; https://doi.org/10.3390/en17112684 - 31 May 2024
Cited by 1 | Viewed by 1359
Abstract
At present, HTS magnets cannot operate in the real closed-loop persistent current mode due to the existence of joint resistance, flux creep, and AC loss of the HTS tape. Instead of using a current source, HTS flux pumps are capable of injecting flux [...] Read more.
At present, HTS magnets cannot operate in the real closed-loop persistent current mode due to the existence of joint resistance, flux creep, and AC loss of the HTS tape. Instead of using a current source, HTS flux pumps are capable of injecting flux into closed HTS magnets without electrical contact. This paper presents a practical superconducting DC dynamo for charging a conduction-cooled HTS magnet system based on a flux-pumping technique. To minimize heat losses, the rotor is driven by a servo motor mounted outside the vacuum dewar by utilizing magnetic fluid dynamic sealing. Different parameters, such as air gap and rotating speed, have been tested to investigate the best pumping effect, and finally, it successfully powers a 27.3 mH HTS non-insulated double-pancake coil to the current of 54.2 A within 76 min. As a low-cost and compact substitute for the traditional current source, the realization of a contactless DC power supply can significantly improve the flexibility and mobility of the HTS magnet system and could be of great significance for the technological innovation of future HTS magnets used in offshore wind turbines, biomedical, aerospace, etc. Full article
(This article belongs to the Special Issue Emerging Trends in Superconductivity for Electric Power Technologies)
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23 pages, 2974 KiB  
Article
Pumped Storage Hydropower as a Part of Energy Storage Systems in Poland—Młoty Case Study
by Jarosław Kulpa, Michał Kopacz, Kinga Stecuła and Piotr Olczak
Energies 2024, 17(8), 1830; https://doi.org/10.3390/en17081830 - 11 Apr 2024
Cited by 4 | Viewed by 2820
Abstract
The increase in the share of renewable energy sources (RES) leads to a growing need for sources or systems/actions to stabilize the national energy grid. Such stabilizing actions include market tools, such as prices and demand-side response (DSR) tools, as well as flexible [...] Read more.
The increase in the share of renewable energy sources (RES) leads to a growing need for sources or systems/actions to stabilize the national energy grid. Such stabilizing actions include market tools, such as prices and demand-side response (DSR) tools, as well as flexible energy sources (e.g., gas). In addition, energy storage, where pumped storage hydroelectricity (PSH) accounts for 90% of global storage capacity, plays an important role. Therefore, the authors presented a detailed analysis of PSH in the context of the dynamic growth of installed capacity in renewable energy sources. They analyzed the economic viability of this type of power plant, with a particular emphasis on operational costs, energy production, and revenue. The Młoty case study and market data, including historical data on various PSH, were presented and analyzed. This study uses copulas, simulation, and statistical analysis. The authors proved that market prices and arbitrage actions alone are not sufficient to achieve profitability of the investment; however, additional benefits, such as fees for available power, enable the achievement of economic profitability. The reason for this is the fact that one of the main goals of PSH is to serve as a power reserve. In addition, this paper presents the analysis of the utilization of existing PSH in the form of full pumping and energy generation cycles (charging and discharging storage). Full article
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16 pages, 828 KiB  
Article
Coherent Spin Dynamics of Electrons in CdSe Colloidal Nanoplatelets
by Sergey R. Meliakov, Vasilii V. Belykh, Ina V. Kalitukha, Aleksandr A. Golovatenko, Alessio Di Giacomo, Iwan Moreels, Anna V. Rodina and Dmitri R. Yakovlev
Nanomaterials 2023, 13(23), 3077; https://doi.org/10.3390/nano13233077 - 4 Dec 2023
Cited by 4 | Viewed by 2146
Abstract
Coherent spin dynamics of electrons in CdSe colloidal nanoplatelets are investigated by time-resolved pump–probe Faraday rotation at room and cryogenic temperatures. We measure electron spin precession in a magnetic field and determine g-factors of 1.83 and 1.72 at low temperatures for nanoplatelets [...] Read more.
Coherent spin dynamics of electrons in CdSe colloidal nanoplatelets are investigated by time-resolved pump–probe Faraday rotation at room and cryogenic temperatures. We measure electron spin precession in a magnetic field and determine g-factors of 1.83 and 1.72 at low temperatures for nanoplatelets with a thickness of 3 and 4 monolayers, respectively. The dephasing time of spin precession T2* amounts to a few nanoseconds and has a weak dependence on temperature, while the longitudinal spin relaxation time T1 exceeds 10 ns even at room temperature. Observations of single and double electron spin–flips confirm that the nanoplatelets are negatively charged. The spin–flip Raman scattering technique reveals g-factor anisotropy by up to 10% in nanoplatelets with thicknesses of 3, 4, and 5 monolayers. In the ensemble with a random orientation of nanoplatelets, our theoretical analysis shows that the measured Larmor precession frequency corresponds to the in-plane electron g-factor. We conclude that the experimentally observed electron spin dephasing and its acceleration in the magnetic field are not provided by the electron g-factor anisotropy and can be related to the localization of the resident electrons and fluctuations of the localization potential. Full article
(This article belongs to the Special Issue Advances in Spin Physics in Semiconductor Nanostructures)
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13 pages, 1204 KiB  
Article
Modeling of Charge Injection, Recombination, and Diffusion in Complete Perovskite Solar Cells on Short Time Scales
by Krzysztof Szulc, Katarzyna Pydzińska-Białek and Marcin Ziółek
Materials 2023, 16(22), 7110; https://doi.org/10.3390/ma16227110 - 10 Nov 2023
Cited by 2 | Viewed by 2090
Abstract
A model of charge population decay upon ultrafast optical pulse excitation in complete, working perovskite solar cells is proposed. The equation, including charge injections (extractions) from perovskite to contact materials, charge diffusion, and charge recombination via first-, second-, and third-order processes, is solved [...] Read more.
A model of charge population decay upon ultrafast optical pulse excitation in complete, working perovskite solar cells is proposed. The equation, including charge injections (extractions) from perovskite to contact materials, charge diffusion, and charge recombination via first-, second-, and third-order processes, is solved using numerical simulations. Results of simulations are positively verified by broadband transient absorption results of mixed halide, triple-cation perovskite (FA0.76MA0.19Cs0.05Pb(I0.81Br0.19)3). The combined analytical and experimental findings reveal the best approaches for the proper determination of the crucial parameters that govern charge transfer dynamics in perovskite solar cells on picosecond and single nanosecond time scales. Measurements from both electron and hole transporting layer sides under different applied bias potentials (zero and close to open circuit potential) and different pump fluence (especially below 5 μJ/cm2), followed by fitting of parameters using numerical modeling, are proposed as the optimal methodology for describing the processes taking place in efficient devices. Full article
(This article belongs to the Special Issue Advances in Solar Cell Materials and Structures)
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18 pages, 3870 KiB  
Article
Optical Absorption, Photocarrier Recombination Dynamics and Terahertz Dielectric Properties of Electron-Irradiated GaSe Crystals
by Svetlana A. Bereznaya, Ruslan A. Redkin, Valentin N. Brudnyi, Yury S. Sarkisov, Xinyang Su and Sergey Yu. Sarkisov
Crystals 2023, 13(11), 1562; https://doi.org/10.3390/cryst13111562 - 1 Nov 2023
Cited by 2 | Viewed by 2025
Abstract
Optical absorption spectra of 9 MeV electron-irradiated GaSe crystals were studied. Two absorption bands with the low-photon-energy threshold at 1.35 and 1.73 eV (T = 300 K) appeared in the transparency region of GaSe after the high-energy-electron irradiation. The observed absorption bands [...] Read more.
Optical absorption spectra of 9 MeV electron-irradiated GaSe crystals were studied. Two absorption bands with the low-photon-energy threshold at 1.35 and 1.73 eV (T = 300 K) appeared in the transparency region of GaSe after the high-energy-electron irradiation. The observed absorption bands were attributed to the defect states induced by Ga vacancies in two charge states, having the energy positions at 0.23 and 0.61 eV above the valence band maximum at T = 300 K. The optical pump-terahertz probe technique (OPTP) was employed to study the dark and photoexcited terahertz conductivity and charge carrier recombination dynamics at two-photon excitation of as-grown and 9 MeV electron-irradiated GaSe crystals. The measured values of the differential terahertz transmission at a specified photoexcitation condition were used to extract the terahertz charge carrier mobilities. The determined terahertz charge carrier mobility values were ~46 cm2/V·s and ~14 cm2/V·s for as-grown and heavily electron-irradiated GaSe crystals, respectively. These are quite close to the values determined from the Lorentz–Drude–Smith fitting of the measured dielectric constant spectra. The photo-injection-level-dependent charge carrier lifetimes were determined from the measured OPTP data, bearing in mind the model injection-level dependencies of the recombination rates governed by interband and trap-assisted Auger recombination, bulk and surface Shockley–Read–Hall (SRH) recombination and interband radiative transitions in the limit of a high injection level. It was found that GaSe possesses a long charge carrier lifetime (a~1.9 × 10−6 ps−1, b~2.7 × 10−21 cm3ps−1 and c~1.3 × 10−37 cm6ps−1), i.e., τ~0.53 μs in the limit of a relatively low injection, when the contribution from SRH recombination is dominant. The electron irradiation of as-grown GaSe crystals reduced the charge carrier lifetime at a high injection level due to Auger recombination through radiation-induced defects. It was found that the terahertz spectra of the dielectric constants of as-grown and electron-irradiated GaSe crystals can be fitted with acceptable accuracy using the Lorentz model with the Drude–Smith term accounting for the free-carrier conductivity. Full article
(This article belongs to the Special Issue Advances of Nonlinear Optical Materials)
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20 pages, 7947 KiB  
Article
Superhydrophobic Microchannel Heat Exchanger for Electric Vehicle Heat Pump Performance Enhancement
by Yunren Sui, Zengguang Sui, Guangda Liang and Wei Wu
Sustainability 2023, 15(18), 13998; https://doi.org/10.3390/su151813998 - 21 Sep 2023
Cited by 4 | Viewed by 2184
Abstract
Battery-powered electric vehicles (EVs) have emerged as an environmentally friendly and efficient alternative to traditional internal combustion engine vehicles, while their single-charge driving distances under cold conditions are significantly limited due to the high energy consumption of their heating systems. Heat pumps can [...] Read more.
Battery-powered electric vehicles (EVs) have emerged as an environmentally friendly and efficient alternative to traditional internal combustion engine vehicles, while their single-charge driving distances under cold conditions are significantly limited due to the high energy consumption of their heating systems. Heat pumps can provide an effective heating solution for EVs, but their coefficient of performance (COP) is hampered by heat transfer deterioration due to frost accumulation. This study proposes a solution to this issue by introducing a microchannel heat exchanger (MHE) with superhydrophobic surface treatment (SHST) as a heat pump evaporator. A computational fluid dynamics MHE model and a dynamic heat pump model are developed and rigorously validated to examine the detrimental impact of frost accumulation on heat transfer, airflow resistance, and heat pump performance. When the frost layer thickness is 0.8 mm at a given air-side velocity of 1.0 m/s, the air-side heat transfer coefficient can be reduced by about 75%, and the air-side pressure drop sharply increases by 28.4 times. As frost thickness increases from 0 to 0.8 mm, the heating capacity drops from 3.97 to 1.82 kW, and the system COP declines from 3.17 to 2.30. Experimental results show that the frost thickness of the MHE with SHST reaches approximately 0.4 mm after 30 min, compared to that of 0.8 mm of the MHE without SHST, illustrating the defrosting capability of the superhydrophobic coating. The study concludes by comparing the performance of various heating methods in EVs to highlight the advantages of SHST technology. As compared to traditional heat pumps, the heating power consumption of the proposed system is reduced by 48.7% due to the defrosting effect of the SHST. Moreover, the single-charge driving distance is extended to 327.27 km, an improvement of 8.99% over the heat pump without SHST. Full article
(This article belongs to the Section Energy Sustainability)
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