Search Results (323)

In order to study how indigenous microorganisms can enhance the strength properties of granite residual soil in the Hanzhong area, two Bacillus species that produce urease were isolated from the local soil. The two Bacillus species are Bacillus subtilis and Bacillus tequilensis, and they were used for the solidification and improvement of the granite residual soil. Unconfined compressive strength tests, scanning electron microscope (SEM) and X-ray diffraction (XRD) analyses were systematically used to analyze the influence and mechanism of different cementation solution concentrations on the improvement effect. It has been found that with the growth of cementing fluid concentration, the unconfined compressive strength of improved soil specimens shows an increasing tendency, reaching its highest value when the cementing solution concentration is 2.0 mol/L. Among different bacterial species, curing results vary; Bacillus tequilensis demonstrates better performance across various cementing solution concentrations. The examination of failure strain in improved soil samples indicates that brittleness has been successfully alleviated, with optimal outcomes obtained at a cementing solution concentration of 1.0 mol/L. SEM and XRD analyses show that calcium carbonate precipitates (CaCO₃) are formed in soil samples treated by both strains. These precipitates effectively bond soil particles, verifying improvement effects on a microscopic level. The present study proposes an environmentally friendly and economical method for enhancing engineering applications of granite residual soil in Hanzhong area, which holds significant importance for projects such as artificial slope filling, subgrade filling, and foundation pit backfilling. Full article

The present article aims to develop a technological scheme for processing zinc ferrite residue, which typically forms during the leaching of zinc calcine. This semi-product is currently processed through the Waelz process, the main disadvantage of which is the loss of precious metals with the Waelz clinker. The experimental results of numerous experiments and analyses have verified a technological scheme including the following operations: sulfuric acid leaching of zinc ferrite residue under atmospheric conditions; autoclave purification of the resulting productive solution to obtain hematite; chloride leaching of lead and silver from the insoluble residue, which was produced in the initial operation; and cementation with zinc powder of lead and silver from the chloride solution. Utilizing such an advanced methodology, the degree of zinc leaching is 98.30% at a sulfuric acid concentration of 200 g/L, with a solid-to-liquid ratio of 1:10 and a temperature of 90 °C. Under these conditions, 96.40% Cu and 92.72% Fe form a solution. Trivalent iron in the presence of seeds at a temperature of 200 °C precipitates as hematite. In chloride extraction with 250 g/L NaCl, 1 M HCl, and a temperature of 60 °C, the leaching degree of lead is 96.79%, while that of silver is 84.55%. In the process of cementation with zinc powder, the degree of extraction of lead and silver in the cement precipitate is 98.72% and 97.27%, respectively. When implementing this scheme, approximately 15% of the insoluble residue remains, containing 1.6% Pb and 0.016% Ag. Full article

Phosphogypsum, a by-product of phosphate fertilizer production, was predominantly used as a supplementary additive in recycled construction materials. However, there are few detailed studies on utilizing phosphogypsum as the primary component in inorganic cementing materials while achieving cost-effective detoxification. This study aimed to develop a harmless phosphogypsum-based inorganic cementing material (PICM) mainly based on phosphogypsum, in which cement, quicklime, and a stabilizer were used as additives. Harmful ions and acidity were first detected through X-ray fluorescence and ion chromatography and then harmlessly treated with quicklime. Compaction parameters, mechanical performance, X-ray diffraction analysis, moisture, and freezing resistance were characterized successively. The results illustrated that fluoride and phosphate ions were the primary soluble contaminants, whose leaching solution concentration can be reduced to 15.31 mg/L and undetectable with 2% quicklime through the mass proportion of phosphogypsum added and mixed. Meanwhile, the corresponding pH value was also raised to over 8. Cement content and quicklime were positively correlated with PICM’s maximum dry density. PICM with 25% cement and 2.5% stabilizer presented the highest unconfined compression strength, and flexural strength did not show significant regularity. PICM was mainly composed of quartz, gypsum, ettringite, and calcite, whose content decreased as cement content and quicklime content increased. Stabilizer, quicklime and cement content were positively correlated with PICM’s freezing and moisture resistance. Full article

This study employed sodium laurate solution as the raw material to fabricate superhydrophobic coatings on cement-based substrates via a facile one-step spraying method. To optimize the processing parameters, the influence of solution concentration on substrate wettability was investigated, leading to the identification of the optimal concentration. Subsequently, superhydrophobic coatings were fabricated under these optimized conditions, and their wettability, mechanical durability, chemical corrosion resistance, and surface repairability were systematically characterized. The results revealed that the coating fabricated with a 0.3% sodium laurate solution exhibited an obvious regular, flaky, rough microstructure, achieving a water contact angle (WCA) of 154° ± 2° and a sliding angle (SA) of 2.9°. The coating demonstrated superhydrophobicity (WCA > 150° and SA < 10°), self-cleaning capability, mechanical durability, chemical corrosion resistance, and environmental stability; furthermore, the abraded surface can be restored to be superhydrophobic by simple and rapid repair. Full article

In the energy sector and in other types of industries (cement, iron/steel, chemical and petrochemical), highly roasted coffee ground residue can be used as a source material for producing bioadsorbents suitable for CO₂ capture. In this study, a bioadsorbent was produced in a two-step process involving biowaste carbonization and biocarbon activation within a KOH solution. The physicochemical properties of the bioadsorbent were assessed using LECO, TG, SEM, BET and FT-IR methods. Investigating the CO₂, O₂ and N₂ equilibrium adsorption capacity using an IGA analyzer allowed us to calculate CO₂ selectivity factors. We assessed the influence of exhaust gas carbon dioxide concentration (16%, 30%, 81.5% and 100% vol.) and adsorption step temperature (25 °C, 50 °C and 75 °C) on the CO₂ adsorption capacity of the bioadsorbent. We also investigated its stability and regenerability in multi-step adsorption–desorption using a TG-Vacuum system, simulating the VSA process and applying different pressures in the regeneration step (30, 60 and 100 mbar_abs). The tests conducted assessed the possibility of using a produced bioadsorbent for capturing CO₂ using the VSA technique. Full article

The utilization of steel slag (SS), fly ash (FA), and ground granulated blast furnace slag (GGBFS) as soil additives in construction represents a critical approach to achieving resource recycling of these industrial by-products. This study aims to activate the SS-FA-GGBFS composite with a NaOH solution and Na₂CO₃ and employ the activated solid waste blend as an admixture for lateritic clay modification. By varying the concentration of the NaOH solution and the dosage of Na₂CO₃ relative to the SS-FA-GGBFS composite, the effects of these parameters on the activation efficiency of the composite as a lateritic clay additive were investigated. Results indicate that the NaOH solution activates the SS-FA-GGBFS composite more effectively than Na₂CO₃. The NaOH solution significantly promotes the depolymerization of aluminosilicates in the solid waste materials and the generation of Calcium-Silicate-Hydrate and Calcium-Aluminate-Hydrate gels. In contrast, Na₂CO₃ relies on its carbonate ions to react with calcium ions in the materials, forming calcium carbonate precipitates. As a rigid cementing phase, calcium carbonate exhibits a weaker cementing effect on soil compared to Calcium-Silicate-Hydrate and Calcium-Aluminate-Hydrate gels. However, excessive NaOH leads to inefficient dissolution of the solid waste and induces a transformation of hydration products in the modified lateritic clay from Calcium-Silicate-Hydrate and Calcium-Aluminate-Hydrate to Sodium-Silicate-Hydrate and Sodium-Aluminate-Hydrate, which negatively impacts the strength and microstructural compactness of the alkali-activated solid waste composite-modified lateritic clay. Full article

Among the scour protection measures for pile foundations, the use of solidified mud has demonstrated effective protection against scour. However, research on the mechanical integrity of this protective measure is relatively scarce. Therefore, a series of experiments were performed on cement-solidified soil and Enzyme-Induced Carbonate Precipitation (ECIP) solidified soil to analyze fluidity, disintegration, and unconfined compressive strength, along with an analysis of influencing parameters. Test results show the following: for cement-solidified soil, fluidity decreases with higher cement content, while its disintegration rate decreases with more cement and its unconfined compressive strength increases with a longer curing time and higher cement content. For ECIP-solidified soil, fluidity decreases with higher soy powder concentration but increases with higher binder solution concentration. ECIP’s initial disintegration rate increases with binder concentration, but after 7 days curing, its disintegration rate decreases with both higher binder concentration and higher soy powder concentration. ECIP’s strength increases with higher soy powder concentration. Crucially, both types of solidified soil exhibit decreased unconfined compressive strength with higher initial water content. The research results can provide a reference for the construction of solidified soil in the field of scour protection. Full article

Microbially induced carbonate precipitation (MICP) offers an eco-friendly approach to stabilize porous materials. This study evaluates its feasibility for protecting agricultural drainage ditch slopes through laboratory tests. Liquid experiments assessed calcium carbonate (CaCO₃) precipitation rates under varying bacteria–cementation solution ratios (BCR), cementation solution concentrations (1–2 mol/L), and urease inhibitor (NBPT) contents (0–0.3%). Soil experiments further analyzed the effects of solidified layer thickness (4 cm vs. 8 cm) and curing cycles on soil stabilization. The results showed that CaCO₃ precipitation peaked at a BCR of 4:5 and declined when NBPT exceeded 0.1%. Optimal parameters (0.1% NBPT, 1 mol/L cementation solution, BCR 4:5) were applied to soil tests, revealing that multi-cycle treatments enhanced soil water retention and CaCO₃ content (up to 7.6%) and reduced disintegration rates (by 70%) and permeability (by 83%). A 4 cm solidified layer achieved higher Ca²⁺ utilization, while an 8 cm layer matched or exceeded 4 cm performance with shorter curing. Calcite crystals dominated CaCO₃ formation. Crucially, reagent dosage should approximate four times the target layer’s requirement to ensure efficacy. These findings demonstrate that MICP, when optimized, effectively stabilizes ditch slopes using minimal reagents, providing a sustainable strategy for agricultural soil conservation. Full article

The objective of this study is to examine the variations in the properties of cementitious materials subjected to bending loads in conjunction with dry and wet cycles of sulfate exposure. This investigation involved applying continuous bending loads at 0%, 20%, and 40% of the ultimate bending capacity to cementitious material specimens. Furthermore, three sets of mortars and concretes with differing water–cement ratios were formulated and analyzed using X-ray diffraction, scanning electron microscopy, and compressive strength tests. The findings indicated that while the flexural strength, compressive strength, and porosity of the specimens initially increased, they ultimately declined as the cementitious materials degraded over time within the sulfate solution. Additionally, it was observed that an increase in bending load corresponded with a decrease in flexural strength, alongside a rise in the internal sulfate ion concentration. By integrating an enhanced form of Fick’s second law with chemical reaction kinetics, a transport model for sulfate ions in cement-based materials was developed under the coupling effect of bending load and sulfate exposure, utilizing Comsol Multiphysics. The simulation results, which align well with the experimental observations, exhibit an error of approximately 5% at a depth of 5 mm. Full article

In arid and semi-arid areas, soil is blown up by the wind because of its loose structure. Wind erosion causes soil quality and fertility loss, land degradation, air pollution, disruption of ecological balance, and agricultural and livestock losses. Consequently, there is an immediate imperative for methods to mitigate the impacts of wind erosion. SICP (soybean urease-induced carbonate precipitation) has emerged as a promising biogeotechnical technology in mitigating wind erosion in arid and semi-arid regions. To enhance bio-cementation efficacy and treatment efficiency of SICP, aluminum chloride (AlCl₃) was employed as an additive to strengthen the SICP process. Multiple SICP treatment cycles with AlCl₃ additive were conducted on Tengger Desert sand specimens, with the specimens treated without AlCl₃ as the control group. The potential mechanisms by which AlCl₃ enhances SICP may have two aspects: (1) its flocculation effect accelerates the salting-out of proteinaceous organic matter in the SICP solution, retaining these materials as nucleation sites within soil pores; (2) the highly charged Al³⁺ cations adsorb onto negatively charged sand particle surfaces, acting as cores to attract and coalesce free CaCO₃ in solution, thereby promoting preferential precipitation at particle surfaces and interparticle contacts. This mechanism enhances CaCO₃ cementation efficiency, as evidenced by 2.69–3.89-fold increases in penetration resistance at the optimal 0.01 M AlCl₃ concentration, without reducing CaCO₃ production. Wind erosion tests showed an 88% reduction in maximum erosion rate (from 1142.6 to 135.3 g·m⁻²·min⁻¹), directly correlated with improved microstructural density observed via SEM (spherical CaCO₃ aggregates at particle interfaces). Economic analysis revealed a 50% cost reduction due to fewer treatment cycles, validating the method’s sustainability. These findings highlight AlCl₃-modified SICP as a robust, cost-effective strategy for wind erosion control in arid zones, with broad implications for biogeotechnical applications. Full article

The escalating disasters caused by the movement of shallow buried strata in China’s western mining areas are increasingly threatening operational safety. A critical issue in ensuring secure mining practices in these areas is the creep failure of weakly cemented soft rock under low-stress conditions. The unique particle contact mechanisms in weakly cemented mudstone, combined with the persistence of the cemented materials and the particulate matter they form, lead to mechanical responses that differ significantly from those of typical soft rocks during loading. Building on an existing multivariate linear regression equation for new similar materials, this study developed qualified weakly cemented medium similar materials, offering appropriate materials for long-term creep tests of weakly cemented formations. This was accomplished by employing orthogonal proportioning tests. The principal findings of our investigation are as follows: The new, similar material exhibits low strength and prominent creep characteristics, accurately simulating weakly cemented materials in western mining areas. The concentration of rosin–alcohol solution has a measurable impact on key parameters, such as σ_c, E, and γ in the weakly cemented similar material specimens. Furthermore, the creep characteristics of the specimens diminish progressively with an increase in the proportion of iron powder (I) and barite powder (B). The material was applied to a similar indoor model test simulating the weakly cemented material surrounding the auxiliary haulage roadway in Panel 20314 of the Gaojialiang Coal Mine, with speckle analysis employed for detailed examination. The experimental findings suggest that both the conventional mechanical properties and long-term creep characteristics of the material align with the required specifications, offering robust support for achieving optimal outcomes in the similar model test. Full article

To investigate the influence of the water–cement ratio and erosion patterns on the deterioration of concrete in a sulfate corrosion environment, concrete specimens with different water–cement ratios were immersed in Na₂SO₄ solutions of varying concentrations (0%, 5%, and 8%). The immersion times were set at 0 days, 30 days, 60 days, and 90 days. Macro-scale compressive strength tests and micro-scale performance tests were conducted to obtain the damage morphology, micro-scale elastic modulus, and hardness of eroded concrete. Additionally, K-means clustering analysis was used to analyze the micro-mineral phases of the specimens, and SEM and XRD were employed to reveal the degradation mechanisms of sulfate erosion on the microstructure of concrete. The results indicated that the erosion products of calcium aluminate and gypsum in concrete gradually increased with the increase in Na₂SO₄ solution concentration and immersion time. In the early stages of erosion, the compressive strength and corrosion resistance coefficient of concrete showed a temporary upward trend, which then decreased as the erosion depth increased. From a microstructural perspective, erosion had a significant impact on the internal structure of concrete, while the elastic modulus and hardness of hydrated calcium silicate and calcium hydroxide under erosion showed relatively minor changes, both exhibiting a gradual decrease. The volume fraction of microporous pores gradually increased, further exacerbating the depth and extent of erosion. Full article

This study evaluated the effects of mechanical agitation of Aloe vera Barbadensis Miller solution at different concentrations using passive ultrasonic irrigation (PUI), XP Endo Finisher (XPF), XP Clean (XPC), and Easy Clean (ECL), compared to conventional endodontic irrigation (CIE), on bond strength and adhesive failure patterns in the cervical, middle, and apical thirds of the root canal. Aloe vera solutions at 1%, 3%, and 5% were tested to reverse collagen fiber collapse induced by hypochlorous acid, a free radical released by 2.5% sodium hypochlorite, which impairs dentin hybridization and the light curing of resin cement. Fiberglass posts were cemented using an etch-and-rinse adhesive system (Ambar; FGM) and conventional dual resin cement (Allcem Core) in root dentin across all thirds. Human teeth underwent chemical–mechanical preparation, and the Aloe vera solution was agitated using the CIE, PUI, XPF, XPC, or ECL protocols. Slices from each root third were evaluated under a stereomicroscope at 10× magnification and subjected to the push-out test. Cytotoxicity was assessed by applying various Aloe vera concentrations to stem cells from the apical papilla (SCAPs) for 24 h, followed by analysis of cell metabolism (Alamar Blue), viability (Live/Dead), and proliferation (F-actin). Aloe vera demonstrated significant biological activity and enhanced bond strength, particularly at 3% and 5%, irrespective of the agitation method or root third. Thus, it can be concluded that using Aloe vera solution is an alternative for pre-treatment before the cementation of fiberglass posts with conventional dual-cure resin cement in endodontically treated dentin. Full article

This study explored the enzymatic formation of gel-like polymeric matrices through carbonate precipitation for dust suppression in Yellow River silt. The hydrogel-modified EICP method effectively enhanced the compressive strength and resistance to wind–rain erosion by forming a reinforced bio-cemented crust. The optimal cementation solution, consisting of urea and CaCl₂ at equimolar concentrations of 1.25 mol/L, was applied to improve CaCO₃ precipitation uniformity. A spraying volume of 4 L/m² (first urea-CaCl₂ solution, followed by urease solution) yielded a 14.9 mm thick hybrid gel-CaCO₃ crust with compressive strength exceeding 752 kPa. SEM analysis confirmed the synergistic interaction between CaCO₃ crystals and the gel matrix, where the hydrogel network acted as a nucleation template, enhancing crystal bridging and pore-filling efficiency. XRD analysis further supported the formation of a stable gel-CaCO₃ composite structure, which exhibited superior resistance to wind–rain erosion and mechanical wear. These findings suggest that gel-enhanced EICP represents a novel bio-gel composite technology for sustainable dust mitigation in silt soils. Full article

In this research, the effect of the addition of coconut fibers coated with hydrophobic substances as reinforcement material in mortars was evaluated. Fibers of different sizes (1, 2, and 5 cm) were pretreated with linseed oil and paraffin wax, in order to obtain a mortar/fiber ratio of 0.5% and 1% by weight. The chemical resistance of the fibers were evaluated before and after being exposed to a concentrated solution of Ca(OH)₂ in order to simulate the alkaline environment of the cement. The physicochemical characterization of the fibers was conducted by DTG (derivative thermogravimetry), TGA (thermogravimetric analysis), and FTIR (Fourier transform infrared spectrometry). The mechanical strength of the fiber-reinforced mortars was evaluated by compression and flexural tests. The effect of fiber degradation on mechanical behavior was evaluated between 28 days of processing. The results showed that the highest compressive and flexural strength were obtained with the composites reinforced with coconut fiber of 0.5% by weight, length of 1 cm, and paraffin wax as the impregnation substance. Full article