Search Results (70)

This case study presents a comparative analysis of real-world operation of two residential domestic hot water (DHW) preparation methods both connected to their own air-to-water heat pump (HP) located in Central Europe. One system employs a conventional configuration with separate tanks and an internal heating coil (HP-B), while the other features a compact tank-in-tank setup where DHW is heated via an integrated buffer tank (HP-A). Both systems were monitored under real operational conditions, with seasonal and annual coefficients of performance (COP, SCOP) calculated to evaluate efficiency. In the absence of complete thermal output data for one system, a reconstruction method based on the other’s performance and known heat losses was applied. The findings confirm that DHW system design significantly affects seasonal efficiency, particularly during summer operation when heating DHW dominates the energy load. The energy cost savings on heating during summer months could reach 44%. The tank-in-tank system showed higher electrical consumption and lower SCOP due to internal heat transfer dynamics and dual-function operation. The study further shows associated energy and cost differences and demonstrates a practical approach to comparing real-world systems offering insights for design optimisation and operational strategy. The authors of the article used the results of their research and experience from implementations as very effective feedback for further research and development. The novelty and uniqueness of the article lie in the energy comparison of two different connections of the hot water and heating water storage tanks with heat source systems using an “air-to-water” heat pump. The benefit of the solution in question is evident from the technical and economic evaluation. Full article

This systematic review synthesizes passive and passive-first cooling strategies for greenhouses in hot–arid climates, organizing evidence across four domains: Airflow & Ventilation, Shading & Radiative Control, Thermal Storage & Ground Coupling, and Structural Design & Geometry. Drawing on the project corpus, we analyze 10–13 distinct techniques including ridge and side natural ventilation, windcatchers and solar chimneys, external shade nets, NIR-selective and transparent radiative-cooling films, and dynamic PV shading; earth-to-air heat exchangers (EAHE/GAHT), rock-bed sensible storage, phase-change materials (PCMs), and sunken or buried envelopes; as well as roof slope and shape, span number, and orientation. Across studies, cooling outcomes are reported as peak or daytime indoor air temperature reductions, defined relative either to outdoor conditions or to a control greenhouse, with the reference frame and temporal aggregation specified in the synthesis. Typical outcomes include ≈3–7 °C daytime reduction for optimized ventilation, ≈2–4 °C for shading and spectral covers while preserving PAR, ≈5–7 °C intake cooling for EAHE with winter pre-heating, and up to ≈14 °C peak attenuation for rock-bed storage under favorable conditions. Structural choices consistently amplify these effects by sustaining pressure head and limiting thermal heterogeneity. Performance is strongly context-dependent—governed by wind regime, diurnal amplitude, dust and UV exposure, and crop-specific light and temperature thresholds—and the most robust results arise from stacked, site-specific designs that combine skin-level radiative rejection, buoyancy-supportive geometry, and ground or latent buffering with minimal active backup. Smart controllers that modulate vents, shading, and targeted fogging or fans based on VPD or temperature differentials improve stability and reduce water and energy use by engaging actuation only when passive capacity is exceeded. We recommend standardized composite metrics encompassing temperature moderation, humidity stability, PAR availability, and water and energy use per unit yield to enable fair cross-study comparison, multi-season validation, and policy adoption. Collectively, the synthesized techniques provide a practical palette for improved greenhouse climate management under hot and arid conditions. Full article

Cerium oxide (CeO₂) nanozymes, also known as nanoceria have emerged as a versatile class of catalytic nanomaterials capable of mimicking key redox enzymes, including oxidases and peroxidases. Their tunable Ce³⁺/Ce⁴⁺ redox cycling, high density of oxygen vacancies, and exceptional resistance to thermal, pH, and storage stress distinguish CeO₂ from conventional enzyme labels, such as horseradish peroxidase (HRP). In immunoassays, CeO₂ enables H₂O₂-free TMB (3,3′,5,5′-tetramethylbenzidine) oxidation, generating strong chromogenic signals with minimal background. Although CeO₂ nanozymes have been explored in colorimetric, chemiluminescent, and photoactive immunoassays, their integration into lateral flow immunoassays (LFIAs) remains limited, with only a few hybrid CeO₂-containing systems reported to date. This mini-review highlights the limitations of conventional peroxidase-based formats and explains how CeO₂’s redox cycling (Ce³⁺/Ce⁴⁺) and oxygen-vacancy-driven catalysis deliver stable, reagent-free signal amplification. Emphasis is placed on the synthetic control of CeO₂, conjugation chemistry with antibodies, and integration into LFIA architectures. CeO₂ enables hydrogen-peroxide-free colorimetric detection with improved robustness and sensitivity, positioning it as a promising catalytic label for point-of-care testing. However, it may aggregate in high-ionic-strength buffers, and its synthesis cost increases for highly uniform, vacancy-engineered materials. Surface functionalization with polymers or dopants and optimized dispersion strategies can mitigate these issues, guiding future practical implementations. Full article

Photovoltaic thermal systems are capable of simultaneously generating electricity and recovering thermal energy from the rear surface of photovoltaic modules. When integrated with an air-source heat pump, the thermal energy recovered from an air-based photovoltaic thermal system can be utilized as an auxiliary heat source, thereby improving heating performance and reducing electricity consumption. In this study, a demonstration-scale performance assessment of an air-based photovoltaic thermal-assisted air-source heat pump system was conducted in a real building located in Asan, South Korea. Performance analysis was based on measured operational data collected over a one-month period in March 2024, corresponding to late-winter to early-spring conditions when heating demand was still present. During the measurement period, the average plane-of-array solar irradiance was approximately 600 W/m², with peak values reaching up to 1000 W/m². Under these conditions, the air-based photovoltaic thermal collector provided average electrical and thermal power outputs of 1.96 kW and 2.2 kW, respectively, while peak outputs reached 3.3 kW for electricity generation and 3.8 kW for thermal energy recovery. The daily thermal energy production remained relatively stable, ranging from 17.8 to 21.7 kWh. Furthermore, approximately 45–60% of the recovered thermal energy was effectively transferred to a buffer tank through an air-to-water heat exchanger, indicating stable solar heat recovery and storage performance. When the recovered thermal energy was supplied to the air-source heat pump during daytime heating operation, a preheating effect was observed, resulting in reduced electricity consumption and improved heating performance. The coefficient of performance increased from 2.24 during nighttime operation to 2.81 under solar-assisted daytime conditions, corresponding to a notable reduction in electricity consumption under solar-assisted daytime operation, compared with nighttime operation without PVT preheating. Overall, the results indicate that, under the tested late-winter to early-spring heating conditions, the integrated air-based photovoltaic thermal and air-source heat pump system can enhance heating performance and reduce electricity consumption, demonstrating its practical feasibility as a solar-assisted heating solution rather than representing generalized annual performance. Full article

Decarbonisation of the aviation sector is essential for achieving global-climate targets, with hydrogen propulsion emerging as a viable alternative to battery–electric systems for vertical flight. Unlike previous studies focusing on clean-sheet eVTOL concepts or fixed-wing platforms, this work provides a comprehensive retrofit evaluation of a two-seat light helicopter (Cabri G2/Robinson R22 class) to a hydrogen–electric hybrid powertrain built around a Toyota TFCM2-B PEM fuel cell (85 kW net), a 30 kg lithium-ion buffer battery, and 700 bar Type-IV hydrogen storage totalling 5 kg, aligned with the Vertical Flight Society (VFS) mission profile. The mass breakdown, mission energy equations, and segment-wise hydrogen use for a 100 km sortie are documented using a single main rotor with a radius of R = 3.39 m, with power-by-segment calculations taken from the team’s final proposal. Screening-level simulations are used solely for architectural assessment; no experimental validation is performed. Mission analysis indicates a 100 km operational range with only 3.06 kg of hydrogen consumption (39% fuel reserve). The main contribution is a quantified demonstration of a practical retrofit pathway for light rotorcraft, showing approximately 1.8–2.2 times greater range (100 km vs. 45–55 km battery-only baseline, including respective safety reserves). The Hawk demonstrates a 28% reduction in total propulsion system mass (199 kg including PEMFC stack and balance-of-plant 109 kg, H₂ storage 20 kg, battery 30 kg, and motor with gearbox 40 kg) compared to a battery-only configuration (254.5 kg battery pack, plus equivalent 40 kg motor and gearbox), representing approximately 32% system-level mass savings when thermal-management subsystems (15 kg) are included for both configurations. Full article

The development of multifunctional polymer composites capable of both heat conduction and latent heat storage is of great interest for advanced thermal management applications. In this work, thermoplastic polyurethane (TPU) nanocomposites containing microencapsulated paraffin-based phase change materials (PCMs) and multi-walled carbon nanotubes (MWCNTs) were systematically investigated. The microstructure, thermal stability, specific heat capacity, thermal diffusivity and conductivity of these composites were analyzed as a function of the PCM and MWCNTs content. SEM observations revealed the homogeneous dispersion of PCM microcapsules and the presence of localized MWCNT aggregates in PCM-rich domains. Thermal diffusivity measurements indicated a monotonic decrease with increasing temperature for all compositions, from 0.097 mm²·s⁻¹ at 5 °C to 0.091 mm²·s⁻¹ at 25 °C for neat TPU, and from 0.186 mm²·s⁻¹ to 0.173 mm²·s⁻¹ for TPU with 5 vol.% MWCNTs. Distinct non-linear behavior was observed around 25 °C, i.e., in correspondence to the paraffin melting, where the apparent diffusivity temporarily decreased due to latent heat absorption. The trend of the thermal conductivity (λ) was determined by the competing effects of PCM and MWCNTs: PCM addition reduced λ at 25 °C from 0.162 W·m⁻¹·K⁻¹ (neat TPU) to 0.128 W·m⁻¹·K⁻¹ at 30 vol.% PCM, whereas the incorporation of 5 vol.% of MWCNTs increased λ up to 0.309 W·m⁻¹·K⁻¹. In PCM-containing nanocomposites, MWCNT networks efficiently bridged the polymer–microcapsule interfaces, creating continuous conductive pathways that mitigated the insulating effect of the encapsulated paraffin and ensured stable heat transfer even across the solid–liquid transition. A one-dimensional transient heat-transfer model confirmed that increasing the matrix thermal conductivity accelerates the melting of the PCM, improving the dynamic thermal buffering capacity of these materials. Therefore, these results underlined the potential of TPU/MWCNT/PCM composites as versatile materials for applications requiring both rapid heat dissipation and effective thermal management. Full article

Latent heat thermal energy storage (LHTES) using inorganic salt hydrates is a promising technology for buffering renewable energy fluctuations; however, phase-dependent heat transfer remains insufficiently understood for design optimization. In this study, a shell-and-tube storage module with a circular-finned tube was constructed and filled with 13.17 kg of barium hydroxide octahydrate (BHO). Discharge tests were conducted with heat transfer fluid (HTF) inlet temperatures ranging from 20 °C to 50 °C and flow rates of 10–25 L/min, while charging was performed at 90 °C. The overall heat transfer coefficient (${\mathrm{U}}_{\mathrm{o}}$) was derived using the logarithmic mean temperature difference method, the inside coefficient (h_i) was calculated by the Petukhov correlation, and the outside coefficient (h_o) was obtained via thermal-resistance network. Results show that the average discharge energy was approximately 1.027 kWh (except 0.859 kWh at 50 °C inlet), with a mean utilization efficiency of 79.25%. The ${\mathrm{U}}_{\mathrm{o}}$ was consistently highest in the liquid phase, followed by the latent and solid phases, with ranges of 0.257–0.863, 0.025–0.072, and 0.015–0.044 kW/m²·°C, respectively. Sensitivity analysis revealed that the HTF flow rate strongly influenced U_o across all phases, whereas inlet temperature played only a minor role. The outside coefficient ${\mathrm{h}}_{\mathrm{o}}$ was 0.033–0.162 kW/m²·°C in the latent regime and 0.018–0.064 kW/m²·°C in the solid regime, with a notable peak around Reynolds number 1.3 × 10⁴ in the latent phase. These findings provide detailed phase-resolved ${\mathrm{U}}_{\mathrm{o}}$ and ${\mathrm{h}}_{\mathrm{o}}$ data for inorganic salt hydrate storage and highlight design insights such as the diminishing returns of flow rate increase beyond a threshold, offering valuable guidelines for sizing and operation of LHTES in Power-to-Heat applications. Full article

In the continuous demand for high-performance lithium-ion batteries (LIBs), thermal management control is, these days, crucial with respect to safety, performance, and longevity. As a promising passive solution, Phase Change Materials (PCMs) have been implemented to overcome the conventional battery thermal management (BTM) approaches, including air cooling, liquid cooling, or refrigerant-based systems. Their ability to transfer the heat during phase change processes makes them ideal candidates for further thermal buffers, thus allowing compact and energy-efficient temperature control without extra power consumption. This work encompasses the recent progress in PCM-based battery thermal management systems, with a particular focus on material selection, structural design, and experimental validation. Current advances in composite PCMs, including the use of high-conductivity additives, porous supports, and encapsulation methods, are here appraised in terms of their thermal conductivity, cycling stability, leakage prevention, and overall safety. Comparisons between organic, inorganic, and hybrid PCM types demonstrate the benefits and drawbacks of each class. Ongoing discussion is also directed towards challenges that include low thermal conductivity, limited heat storage capacity, scalability, cost, and flammability. Future development opportunities are also identified in the areas of multifunctional PCMs, hybrid passive–active cooling approaches, scalable processing, and life-cycle considerations. Full article

Coal mine gas with methane concentrations below 8% cannot sustain stable self-combustion, posing significant challenges for safe utilization and greenhouse gas mitigation. To address this limitation, we developed a large-scale industrial square rotary regenerative thermal oxidizer (RTO) capable of high-efficiency oxidation under ultra-low methane conditions. This work integrates multi-scale computational fluid dynamics (CFD) modeling, laboratory and pilot-scale physical experiments, and multi-physics coupled simulations to capture the complex interactions of fluid flow, species transport, and thermal response in regenerative ceramics. Compared with conventional circular or three-bed RTOs, the proposed square rotating design achieves 13% higher heat storage utilization, 15% smaller floor area, and enhanced spatial uniformity of the temperature field. Multi-scale simulations reveal that increasing methane molar fraction (CH₄) from 0.012 to 0.017 raises the peak temperature from 1280 K to 1350 K, reduces the burnout height from 1.18 m to 1.15 m, and, under constant oxygen supply, extends the high-temperature zone to 1450 K with a stabilized burnout position at 1.06 ± 0.01 m. Incorporating a 15° conical expansion combustion chamber increases local turbulent kinetic energy by 17.4%, accelerating oxidation while maintaining methane removal rates > 98% within an optimized bottom blowing time of 30–90 s. This study not only provides validated design thresholds for ultra-low concentration methane oxidation—such as temperature windows, buffer zones, and switching cycles—but also offers an engineering framework for scaling RTO systems to industrial coal mine applications. This advances both energy recovery efficiency and methane emission control, demonstrating clear advantages over existing RTO configurations. Full article

Sand-based thermal energy storage systems represent a paradigm shift in sustainable energy solutions, leveraging Earth’s most abundant mineral resource through advanced nanocomposite engineering. This review examines sand-based phase change materials (PCM) systems with emphasis on integration with human-powered energy generation (HPEG). Silicon-based hierarchical pore structures provide multiscale thermal conduction pathways while achieving PCM loading capacities exceeding 90%. Carbon-based nanomaterial doping enhances thermal conductivity by up to 269%, reaching 3.1 W/m·K while maintaining phase change enthalpies above 130 J/g. This demonstrated cycling stability exceeds 1000 thermal cycles with <8% capacity degradation. Thermal energy storage costs reach ~$20 kWh⁻¹—60% lower than lithium-ion systems when normalized by usable heat capacity. Integration with triboelectric nanogenerators achieves 55% peak mechanical-to-electrical conversion efficiency for direct pathways, while thermal-buffered systems provide 8–12% end-to-end efficiency with temporal decoupling between intermittent human power input and stable electrical output. Miniaturized systems target off-grid communities, offering 5–10× cost advantages over conventional batteries for resource-constrained deployments. Levelized storage costs remain competitive despite efficiency penalties versus lithium-ion alternatives. Critical challenges, including thermal cycling degradation, energy-power density trade-offs, and environmental adaptability, are systematically analyzed. Future directions explore biomimetic multi-level pore designs, intelligent responsive systems, and distributed microgrid implementations. Full article

The increasing adoption of electric vehicles has driven the development of charging technologies that meet growing demands for power, efficiency, and grid compatibility. This review presents a comprehensive analysis of the EV charging ecosystem, covering Level 3 DC charging stations, power converter topologies, and the role of energy storage systems in supporting grid integration. Commercial solutions and academic prototypes are compared across key parameters such as voltage, current, power, efficiency, and communication protocols. The study highlights trends in charger architectures—including buck, boost, buck–boost, LLC resonant, and full-bridge configurations—while also addressing the integration of stationary storage as a buffer for fast charging stations. Special attention is given to wide-bandgap semiconductors like SiC and GaN, which enhance efficiency and thermal performance. A significant gap persists between the technical transparency of commercial systems and the ambiguity often observed in prototypes, highlighting the urgent need for standardized research reporting. Although converter efficiency is no longer a primary constraint, substantial challenges remain regarding infrastructure availability and the integration of storage with charging stations. This paper seeks to offer a comprehensive perspective on the design and deployment of smart, scalable, and energy-efficient charging systems, with particular emphasis on cascaded and bidirectional topologies, as well as hybrid storage solutions, which represent promising pathways for the advancement of future EV charging infrastructure. Full article

The influence of minor components on leaching molecular iodine (I₂) through polypropylene (PP)-based packaging from a povidone iodine-based (PVP-I) formulation, simulating an ophthalmic application, was evaluated. I₂ is a cheap, broad-spectrum, and multi-target antiseptic. Nevertheless, it is volatile, and the prolonged storage of I₂-based formulations is demanding in plastic packaging because of transmission through the material. Therefore, we explored the possibility of moderating the loss of I₂ from an iodophor formulation by introducing small amounts of molecular iodine into the polymer material commonly used in eyedropper caps, i.e., PP. Thus, PP was blended via an extrusion process with a polymeric complex containing iodine (such as PVP-I) or with a second polymeric component able to complex the I₂ released from an iodophor solution. The aim of this work was to introduce I₂ into PP-based polymer matrices without using organic solvents and indirectly, i.e., through the addition of components that could generate molecular iodine or complex it in the solid phase, as I₂ is heat-sensitive. To increase the miscibility between PP and PVP-I, poly(N-vinylpyrrolidone) (PVP) or a vinyl pyrrolidone vinyl acetate copolymer 55/45 (Sokalan) were added as compatibilizers. The PP-based binary and ternary blends, in granular or sheet form, were characterized thermally (Differential Scanning Calorimetry, DSC, and Thermogravimetric analysis, TGA), mechanically (tensile tests), morphologically (scanning electron microscopy (SEM)), and chemically (attenuated total reflectance Fourier transform infrared (ATR-FTIR)). Additionally, the variation in wettability induced by the introduction of the hydrophilic minority components was determined by static contact angle measurements (static contact angle (SCA)), and tests were carried out to determine the barrier properties against oxygen (oxygen transmission rate (OTR)) and molecular iodine. The I₂ leaching of the different blends was compared with that of PP by monitoring the I₂ retention in a buffered PVP-I solution via UV-vis spectroscopy. Overall, the experimental data showed the capability of the minority components in the blends to increase thermal stability as well as act as a barrier to oxygen. Additionally, the PP blend with PVP-I induced a reduction in molecular iodine leaching in comparison with PP. Full article

Andrographolide (ADG) is a typical poorly water-soluble drug, and a co-amorphous strategy was used here to improve its aqueous solubility. Co-amorphous systems of ADG and amino acids with a 1:1 molar ratio were screened via the neat ball milling method. L-lysine (Lys) and L-tryptophan (Trp) can be used as co-formers with ADG, forming a co-amorphous phase, which was confirmed by powder X-ray diffraction, IR and Raman spectroscopy. ADG-Trp showed poor solubility at 37 °C, which was close to that of raw ADG (0.08 mg·mL⁻¹). ADG-Lys showed unexpectedly enhanced solubility, at 0.5 mg·mL⁻¹ in the media of water and PBS (pH 7.4) and 0.3 mg·mL⁻¹ in the medium of HCl buffer (pH 1.2) at 37 °C. ADG-Lys showed good storage stability for 5 months, but its thermal stability was poor and it could recrystallize at 100 °C. Compared with ADG-Trp, ADG-Lys has weaker hydrogen bonding interactions and stronger hydrophobic interactions related to ADG molecules, which might cause the unusual enhancement in solubility. To our knowledge, ADG-Lys prepared in this work shows the maximum ADG content (70 wt.%) and the highest ADG solubility among the reported ADG amorphous solid dispersions and co-amorphous systems. Full article

Solid–liquid phase change materials (PCMs) have attracted significant attention due to their high enthalpy, which enables superior energy storage density. However, it is difficult to maintain their original shapes in a molten state. Therefore, confining PCMs within porous materials is an important method, either through mixing molten polymers and PCMs or confining PCMs in pre-prepared porous materials (e.g., aerogels). The former method is straightforward and easy to execute but its stability is severely limited, and the latter is exactly the opposite. Herein, aerogel-confined functional liquid made via in situ solid–liquid host–guest composite strategy is reported. As a proof of concept, Nylon 66 and 1,6-hexanediol are selected as the solid and liquid phases, respectively. 1,6-hexanediol not only serves as a solvent to dissolve Nylon 66 but also induces sol–gel transition during the cooling process and acts as a PCM to store energy. Unlike aerogel-supported systems requiring multi-step processing, this approach integrates porous host formation and PCM encapsulation in one step. The resulting shape-stabilized PCMs (ss-PCMs) exhibit obscure leakage, high latent heat (160 J/g), mechanical robustness (compressive modulus of 3.6 MPa), and low thermal conductivity (0.081 W/(m·K)) above 75 wt% loading of 1,6-hexanediol. These ss-PCMs enable infrared stealth by delaying thermal detection and passive thermal buffering that suppress temperature fluctuations. The in situ solid–liquid host–guest composite strategy is straightforward, being achievable through a one-pot method involving heating and cooling cycles, with high raw material utilization and minimal waste generation, thus maximizing the conversion rate of raw materials into the final product. By combining the excellent liquid retention capability of aerogels with process simplicity, this methodology opens new avenues for the development of ss-PCMs. Full article

Notoginsenoside Rb1 (Rb1), a bioactive saponin from Panax notoginseng, exerts cardio-cerebrovascular protective, anti-inflammatory, antioxidant, and glucose homeostasis-regulating effects. However, its oral bioavailability is limited by gastric degradation and poor intestinal permeability. This study presents a food-grade bigel system for encapsulating Rb1 to enhance its stability and controlled-release performance. Oleogels were structured using monoglycerides (8%, w/w) in soybean oil. Rb1-loaded binary hydrogels (gellan gum/xanthan gum, 12:1 w/w) were emulsified in 10% Tween-80 (w/w). Bigels were formulated at varying hydrogel-to-oleogel ratios, and a ratio of 4:6 was identified as optimal. Stress-sweep rheological analysis revealed a dense gel structure with a peak storage modulus (G′) of 290.64 Pa—the highest among all tested ratios—indicating superior structural integrity. Confocal microscopy confirmed homogeneous encapsulation of Rb1 within the continuous hydrogel phase, effectively preventing payload leakage. Differential scanning calorimetry (DSC) analysis detected a distinct endothermic transition at 55 °C (ΔH = 6.25 J/g), signifying energy absorption that enables thermal buffering during food processing. The system achieved an encapsulation efficiency of 99.91% and retains both water and oil retention. Effective acid protection and colon-targeted delivery were observed in the digestion test. Effective acid protection and colon-targeted delivery were observed in the digestion test. Less than 5% of Rb1 was released in the gastric phase, and over 90% sustained intestinal release occurred at 4 h. The optimized bigel effectively protected Rb1 from gastric degradation and enabled sustained intestinal release. Its food-grade composition, thermal stability, and tunable rheology offer significant potential for use in functional foods and nutraceuticals. Full article