Search Results (15)

Microencapsulated phase-change materials (MPCMs) with excellent thermal properties for low-temperature cold storage were developed in this study. Using 1-decanol as the core and methyl methacrylate as the shell precursor, the effects of emulsifier type and ultrasonic emulsification conditions were investigated. Styrene-maleic anhydride copolymer served effectively as a protective colloid emulsifier, producing MPCMs with high enthalpy and a well-defined, uniform microstructure. Under optimal conditions of 5 wt% emulsifier content relative to the oil phase, an ultrasonic power of 375 W, and an emulsification time of 12 min, the MPCMs exhibited a phase-change enthalpy of 126.7 kJ/kg. To further improve the thermal properties, a binary eutectic mixture was prepared by combining 1-decanol and 1-tetradecane at an optimal molar ratio (51.1:48.9). This binary-core MPCM showed a higher storage enthalpy (144.3 kJ/kg), with an increase of 13.9% compared to the single-core material (1-decanol). It also exhibited improved microstructural uniformity due to the stabilizing role of 1-tetradecane. These optimized MPCMs demonstrate phase-transition temperatures particularly suitable for low-temperature thermal storage, providing a practical and innovative technical solution for cold-chain logistics and vaccine refrigeration applications. Full article

The adoption of eco-friendly refrigerants in air conditioning systems is crucial for advancing low-carbon architecture. The current refrigerant R410A, with its high global warming potential, underscores the need for sustainable alternatives that balance cooling efficiency and environmental impact. This study investigates a binary mixture of R32 and R290 as a potential replacement for R410A. Using the Peng–Robinson equation of state, the thermodynamic properties of the mixed refrigerant were calculated post-temperature glide, analyzing variations across different mixing ratios. A specific ratio of 0.3:0.7 (R32:R290) was identified as optimal, offering a balance between safety and performance, closely matching R410A’s properties. Simulations of the refrigeration cycle were conducted to assess the effects of condensation and evaporation temperatures, as well as subcooling and superheating, on system performance. Key findings reveal that the 0.3:0.7 mixture not only meets safety standards for central air conditioning but also demonstrates efficiency comparable to R410A. These results provide a robust theoretical foundation for the development of low-carbon air conditioning technologies, highlighting the potential of R32/R290 mixtures in reducing environmental impact while maintaining performance. Full article

Characterizing the optimal operating parameters for a heat pump with a specific refrigerant is paramount, as it provides valuable guidance for refrigerant selection. The temperature mismatch between cold and hot fluids in the evaporator and condenser can lead to degraded thermal performance in heat pumps with large temperature variations. To address these two key issues, we selected several pure refrigerants with varying critical temperature levels for use in a large temperature variation heat pump configuration. The corresponding thermal performance was then investigated using the Ebsilon code under fixed temperature lift conditions as the operating temperature varied. It indicates that the maximum coefficient of performance (COP) is typically achieved when the deviation factors of temperature and pressure from their critical parameters fall within the ranges of 0.62~0.71 and 0.36~0.5, respectively. Our research recommends the binary refrigerant mixture of R152a/R1336mzz(z) (COP = 3.54) for the current operating conditions, as it significantly improves thermal performance compared to pure R1336mzz (z) (COP = 2.87) and R152a (COP = 3.01). Through research on the impact of the compositional ratio of R152a/R1336mzz(z) on the thermal performance of the heat pump, we found that that the optimal ratio of R1336mzz(z) component to R152a component is 0.5/0.5. This study offers valuable guidance for selecting the most suitable refrigerants for heat pumps in practical engineering design scenarios. Full article

The effect of essential oils (EOs) incorporated in their vapor phase combined with lactic acid immersion pretreatment was studied on fresh refrigerated chicken breast shelf life. Among the several EOs assayed, the in vitro results obtained from the vapor diffusion test allowed mustard, oregano, and garlic EOs to be selected due to their higher antimicrobial activity. In addition, it was possible to determine the EO minimum inhibitory concentrations against Pseudomonas aeruginosa and Escherichia coli and to identify EO binary mixtures showing synergistic or additive effects. Based on the obtained results, a ternary mixture constituted by 0.073, 0.292, and 0.146 µL/mL of headspace of mustard, oregano, and garlic, respectively, was proposed for its application to chicken breasts. The ternary mixture inhibitory action was confirmed in vitro against P. aeruginosa and E. coli. Furthermore, the presence of numerous compounds with recognized antimicrobial and antioxidant activity was found in its volatile phase through gas chromatography. When applying an EO mixture in its vapor phase in combination with 1.0% v/v of lactic acid immersion pretreatment on refrigerated chicken breast, a decrease in mesophilic microorganisms’ growth rate as well as in lipid oxidation was observed. Moreover, in a preliminary sensory test, the treated chicken breast was found to be acceptable to consumers and showed no significant differences compared to untreated chicken. In conclusion, the combined use of lactic acid immersion and EOs in their vapor phase was an effective alternative to increase chicken breast shelf life. Full article

The binary refrigerant mixtures containing 2,3,3,3-Tetrafluoroprop-1-ene are considered as excellent substitutes for traditional refrigerants. Weak hydrogen bonds exist in hydrofluorocarbons and hydrofluoroolefins. However, for several recently published binary refrigerant mixtures, there is no Vapor–Liquid Equilibrium calculation study considering hydrogen-bonding associations. This work presents a calculation work of the saturated properties of nine pure refrigerants using the Cubic-Plus-Association Equation of State, considering the hydrogen-bonding association in refrigerant fluids. The average relative deviations of the saturated vapor pressure, liquid, and vapor density are less than 1.0%, 1.5%, and 3.5%, respectively. The Vapor–Liquid Equilibrium of ten binary refrigerant mixtures containing 2,3,3,3-Tetrafluoroprop-1-ene is also calculated using the Cubic-Plus-Association Equation of State with the van der Waals mixing rule. The average relative deviations of the liquid-phase and vapor-phase mole fractions are less than 1.0% and 2.0%, respectively. Moreover, the Vapor–Liquid Equilibrium data and the model’s adaptability are analyzed and discussed. Full article

The interactions among agar, gellan gum, gelatin, and modified waxy corn starch in the formation of mixed gels were examined in five different ratios. Binary hydrocolloid gels were prepared using three ingredients: two hydrocolloids (total hydrocolloid concentration: 0.5 wt%, ratios of mixture: 0/0.5, 0.1/0.4, 0.2/0.3, 0.3/0.2, 0.4/0.1, and 0.5/0) and water. The textural properties of the hydrocolloid gels were studied by measuring the gel strength, rigidity, breaking force, breaking point, and syneresis as functions of the mixing ratio. The higher syneresis percentage of binary modified waxy corn starch and gum gels than that of mixed gum gels after cold storage was mainly due to the retrogradation of amylopectin. Agar was shown be the most influential with regards to increasing the gel strength, breaking force, and rigidity among the three kinds of gum, while gellan gum was more effective against syneresis than agar and gelatin for storage periods of 7 and 14 days. In the mixed gels, a dramatic increase in the breaking point from 0 to 0.5% was only exhibited for gellan gum. The results provided useful information, including gel strength, rigidity, breaking force, breaking point, and syneresis, for gum and modified corn starch ingredients selected from refrigerated binary gum gels such as pudding for food product development. Full article

These days, the low efficiency of solar-based thermal power plants results in uneconomical performance and high-cost uncompetitive industries compared with conventional fossil fuels. In order to overcome such issues, a novel combined cooling–power–heating (trigeneration) system is proposed and analyzed in this paper. This system uses an ammonia–water binary mixture as a working fluid and a solar heat source to produce diverse types of energy for a multi-unit building in a sustainable fashion. In addition to the basic cooling–power cogeneration cycle, a flashing chamber that will boost the flow rate of refrigerant without any additional heat supply is employed. By developing a mathematical model, the system performance is analyzed using varying parameters of solar irradiation, hot oil temperature, process heat pressure, and ambient temperature to investigate the influence on electrical power, cooling capacity, refrigeration exergy, energy utilization factor (EUF), and system exergy efficiency. Increasing direct normal irradiation (DNI) from 500 W/m² to 1000 W/m² reduces the system EUF and exergy efficiency from 53.62% to 43.12% and from 49.02% to 25.65%, respectively. Both power and refrigeration exergy increase with increasing DNI and ambient temperature, while heating exergy remains constant. It is demonstrated that of 100% solar energy supplied, 46.03% is converted into energetic output and 53.97% is recorded as energy loss. The solar exergy supplied is distributed into 8.34% produced exergy, 29.78% exergy loss, and the remaining 61.88% is the destructed exergy. The highest destruction of solar exergy (56.89%) occurs in the central receiver. Full article

The article presents the experimental results of combining a basic microstructure with partly closed pores and a mesh covering for heat transfer enhancement at the film flow of a refrigerant mixture. To reveal the effect of the combined structure, heat transfer on a microstructured surface without a covering as well as on a smooth surface with a mesh covering only has been studied. All experimental series were carried out using a binary mixture of R114 and R21 refrigerants. The mixture film flowed down the outer surface of a vertical cylinder in the undeveloped turbulence regime, when the film Reynolds number varied from 400 to 1300. It is shown that a microstructured surface with a fin pitch of 200 μm, fin height of 220 μm, and longitudinal knurling pitch of 160 μm, created by deformational cutting, demonstrates significant heat transfer enhancement: up to four times as compared to a smooth surface. However, adding a mesh covering with an aperture of 220 μm and a wire diameter of 100 μm reduces the intensification. The mesh covering overlaid on a smooth surface also does not provide heat transfer enhancement as compared to the smooth surface itself. The absence or even deterioration of heat transfer enhancement on surfaces with mesh covering can be primarily associated with the low thermal conductivity of the mesh material and shortcomings of the applied method of mesh mounting. The possibility of deteriorating vapor removal due to the incorrect selection of mesh covering parameters was also analyzed. The heat transfer coefficient values obtained for basic microstructured surfaces were compared with the dependencies available in the literature for predicting pool boiling heat transfer on microfinned surfaces. Full article

Regarding the use of SF₆ in medium voltage switchgear (MVS), a review of alternatives was encouraged by the European Parliament in Regulation No 517/2014. This is aimed at a new regulatory change, that is expected soon, which will include its prohibition, similar to what has happened with other fluorinated greenhouse gases in other fields, like refrigeration. Therefore, there is an urgent need to study the physical and chemical properties of alternative gas mixtures to determine if they are suitable to replace SF₆. In this context, this work addresses the difusional analysis of new gases. Binary and ternary mixtures made of 1,3,3,3-tetrafluoropropene (C₃F₄H₂) and heptafluoroisopropyl trifluoromethyl ketone (C₅F₁₀O), using dry air as a carrier gas, were studied. The mixtures were analyzed using original equipment, composed of UV-Vis spectroscopy technology in a sealed gas chamber, which is similar to MVS. Consequently, an experimental equipment that monitors the concentration of a gas mixture online and a model that predicts the mixing process were designed and tested. The concentration profiles were obtained concerning both the time and position in the gas chamber, and the diffusional and convectional parameters were numerically calculated and optimized in an algorithm created in Scilab. Full article

Screening for alternative refrigerants with high energy efficiency and low environmental impacts is one of the highest challenges of the refrigeration sector. This paper investigates the performance and refrigerant screening for single and two stages vapor compression refrigeration cycles. Several pure hydrocarbons, hydrofluorocarbons, hydrofluoroolefins, fluorinated ethers, and binary azeotropic mixtures are proposed as alternative refrigerants to substitute R22 and R134a due to their environmental impacts. The BACKONE equation of state is used to compute the thermodynamic properties of the candidates. The results show that the maximum coefficients of performance (COP) for single and two stage cycles using pure substances are achieved using cyclopentane with values of 4.14 and 4.35, respectively. On the other side, the maximum COP for the two cycles using azeotropic mixtures is accomplished using R134a + RE170 with values of 3.96 and 4.27, respectively. The two-stage cycle presents gain in COP between 5.1% and 19.6% compared with the single-stage cycle based on the used refrigerant. From the obtained results, among all investigated refrigerants, cyclopentane is the most suitable refrigerant for the two cycles from the viewpoint of energy efficiency. However, extra cautions should be taken due to its flammability. Full article

The most commonly used refrigerants are potent greenhouse gasses that can contribute to climate change. Hydro-Fluoro-Olefins are low Global Warming Potential fluids. A summary of our experimental research activity on the thermodynamic properties of two environmentally friendly Hydro-Fluoro-Olefins, namely R1234yf and R1234ze(E), is reported. In particular, the measurements were performed with an isochoric apparatus and the apparatus specifically built to reach temperatures down to about 100 K. The data elaboration confirms the validity of the choice and that R1234yf and R1234ze(E) can be adopted in many domestic applications. Moreover, considering the reduction of the flammability issues of R1234yf and R1234ze(E), the properties of binary systems containing these fluids and carbon dioxide were analyzed. The presented mixtures could be very interesting for low-temperature applications such as cascade cycles. Full article

Adsorption refrigeration has become an attractive technology due to the capability to exploit low-grade thermal energy for cooling power generation and the use of environmentally friendly refrigerants. Traditionally, these systems work with pure fluids such as water, ethanol, methanol, and ammonia. Nevertheless, the operating conditions make their commercialization still unfeasible, especially owing to safety and cost issues as a consequence of the working pressures, which are higher or lower than 1 atm. The present work represents the first thermodynamic insight in the use of mixtures for adsorption refrigeration and aims to assess the performance of a binary system of ammonia and ethanol. According to the Gibbs’ phase rule, the addition of a component introduces an additional degree of freedom, which allows to adjust the pressure of the system varying the composition of the mixture. The refrigeration process was simulated with isothermal- isochoric flash calculations to solve the phase equilibria, described by the Peng-Robinson-Stryjek-Vera (PRSV) equation of state for the vapor and liquid phases and by the ideal adsorbed solution theory (IAST) and the multicomponent potential theory of adsorption (MPTA) for the adsorbed phase. In operating condenser and evaporator, pressure levels around atmospheric pressure can be achieved using an ammonia/ethanol mixture with a mole fraction of ethanol in the range of 0.70−0.75. A good agreement in the predictions of the adsorbed phase composition was also reported using the IAST and the MPTA methods. Full article

This article is dedicated to the design, calculation and dimensioning of a small powered refrigeration system (132W) which produces ice bars (freezing) using solar thermal power, and resorts to an intermittent cycle absorption circuit with a water-ammonia mixture (H₂O-NH₃). The aim of this equipment is to minimize problems faced in places where there is no electric network to supply traditional refrigeration systems which preserve perishable products produced or stocked there, as well as drugs (vaccines), namely for specific regions of developing countries. The system developed can be divided into two parts. The intermittent cycle absorption refrigeration system uses a binary water-ammonia solution (H₂O-NH₃), where water is the absorber and the ammonia is the coolant and the thermal solar system. This is made up of CPC flat plate thermal collectors or vacuum tubes in which solar energy heats the water that circulates in the primary circuit. In the absorption circulation system, circulation occurs in a natural way due to the fluids affinity, and the temperature and pressure internal variations. This article shows the assumptions underlying the conception, calculation and dimensioning of the system’s construction. Full article

The performances of thermodynamics cycles are dependent on the properties of refrigerants. The performances of Vuilleumier (VM) cycle heat pump adopting mixture refrigerants are analyzed by MATLAB software using REFPROP programming. At given operating parameters and configuration, performances of the VM cycle adopting pure refrigerant, H₂, He or N₂ are compared. Thermodynamic properties of the four type mixtures, namely, He-H₂, He-N₂, H₂-N₂ and He-H₂-N₂, are obtained with total 16 mixing ratio, and the coefficient of performance and the exergy efficiency of these four mixture types in VM cycle heat pump are calculated. The results indicate that within the temperature of heat source 400–1000 K, helium is the best choice of pure refrigerant for VM cycle heat pump. The He-H₂ mixture is the best among all binary refrigerant mixtures; the recommended proportion is 1:2. For trinary refrigerant mixture, suggested proportion of helium, hydrogen and nitrogen is 2:2:1. For these recommended mixtures, system COPs (coefficient of performances) are close to 3.3 and exergy efficiencies are about 0.2, which are close to pure refrigerant helium. Full article

We present a thermo-economic evaluation of binary power plants based on the Organic Rankine Cycle (ORC) for geothermal power generation. The focus of this study is to analyse if an efficiency increase by using zeotropic mixtures as working fluid overcompensates additional requirements regarding the major power plant components. The optimization approach is compared to systems with pure media. Based on process simulations, heat exchange equipment is designed and cost estimations are performed. For heat source temperatures between 100 and 180 °C selected zeotropic mixtures lead to an increase in second law efficiency of up to 20.6% compared to pure fluids. Especially for temperatures about 160 °C, mixtures like propane/isobutane, isobutane/isopentane, or R227ea/R245fa show lower electricity generation costs compared to the most efficient pure fluid. In case of a geothermal fluid temperature of 120 °C, R227ea and propane/isobutane are cost-efficient working fluids. The uncertainties regarding fluid properties of zeotropic mixtures, mainly affect the heat exchange surface. However, the influence on the determined economic parameter is marginal. In general, zeotropic mixtures are a promising approach to improve the economics of geothermal ORC systems. Additionally, the use of mixtures increases the spectrum of potential working fluids, which is important in context of present and future legal requirements considering fluorinated refrigerants. Full article