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Novel Allyl Cobalt Phosphine Complexes: Synthesis, Characterization and Behavior in the Polymerization of Allene and 1,3-Dienes

  • Giovanni Ricci,
  • Antonella Caterina Boccia,
  • Giuseppe Leone and
  • Alessandra Forni
Catalysts2017, 7(12), 381;https://doi.org/10.3390/catal7120381

7 December 2017

Novel allyl cobalt complexes, i.e., (η3-C4H7)(η4-C4H6)Co(PCyPh2) (1), (η3-C4H7)(η4-C4H6)Co(PMePh2) (2) and (η3-C5H9)(η4-C5H8)Co(PMePh2) (3), were synthesized by reacting CoCl2(PRPh2)2 (R = methyl, cyclohexyl) with 1,3-butadiene or isoprene in presenc...

(This article belongs to the Special Issue Catalysts for the Controlled Polymerization of Conjugated Dienes)
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