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Search Results (423)

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Keywords = TE01 mode

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10 pages, 3595 KiB  
Article
EM Characterization of a Compact RFQ Cold Model Prototype Employing a New Power Injection Scheme
by Marco A. López, Joaquín Portilla, Victor Etxebarria, Iñigo Arredondo and Jorge Feuchtwanger
Particles 2025, 8(3), 67; https://doi.org/10.3390/particles8030067 - 1 Jul 2025
Viewed by 351
Abstract
The experimental and computational characterization of a cold model prototype designed to test the electromagnetic properties of a new RFQ (Radio-Frequency Quadrupole) cavity is reported. This cavity is intended to be an essential part of a compact, high-gradient proton accelerator for medical purposes. [...] Read more.
The experimental and computational characterization of a cold model prototype designed to test the electromagnetic properties of a new RFQ (Radio-Frequency Quadrupole) cavity is reported. This cavity is intended to be an essential part of a compact, high-gradient proton accelerator for medical purposes. The RFQ’s design employs a novel RF power-coupler injection solution. One common way to couple the RF power in proton RFQs has been the use of loop-couplers inserted into the mid-section of the RFQ’s lobe sections. This technique has been demonstrated to be reliable and effective but introduces a significant perturbation into the lobe that can be more noticeable when dealing with compact structures. We propose a RF injection scheme that uses direct transition from a coaxial cable to the RFQ by connecting the inner coaxial conductor to the RFQ vane body. As a consequence, the lobe geometry is not perturbed, and the transversal electrical fields are directly excited through the vanes. Moreover, by using a pair of such couplers connected to opposite vanes at a given transversal plane of the RFQ, it is also possible to excite the desired quadrupolar TE210 modes while avoiding the excitation of dipolar TE110 modes. The resonances corresponding to different RFQ modes have been characterized, and the dependence of the amplitude of the modes on the relative phase of the field injected through the RF power ports has been demonstrated both by measurements and simulations. Full article
(This article belongs to the Section Experimental Physics and Instrumentation)
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20 pages, 1369 KiB  
Article
Numerical Modeling of Electromagnetic Modes in a Planar Stratified Medium with a Graphene Interface
by Eugen Smolkin
Computation 2025, 13(7), 157; https://doi.org/10.3390/computation13070157 - 1 Jul 2025
Viewed by 198
Abstract
Graphene interfaces in layered dielectrics can support unique electromagnetic modes, but analyzing these modes requires robust computational techniques. This work presents a numerical method for computing TE-polarized eigenmodes in a planar stratified dielectric slab with an infinitesimally thin graphene sheet at its interface. [...] Read more.
Graphene interfaces in layered dielectrics can support unique electromagnetic modes, but analyzing these modes requires robust computational techniques. This work presents a numerical method for computing TE-polarized eigenmodes in a planar stratified dielectric slab with an infinitesimally thin graphene sheet at its interface. The governing boundary-value problem is reformulated as coupled initial-value problems and solved via a customized shooting method, enabling accurate calculation of complex propagation constants and field profiles despite the discontinuity at the graphene layer. We demonstrate that the graphene significantly alters the modal spectrum, introducing complex leaky and surface waves with attenuation due to graphene’s conductivity. Numerical results illustrate how the layers’ inhomogeneity and the graphene’s surface conductivity influence mode confinement and loss. These findings confirm the robustness of the proposed computational approach and provide insights relevant to the design and analysis of graphene-based waveguiding devices. Full article
(This article belongs to the Section Computational Engineering)
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20 pages, 3470 KiB  
Article
Hydrogen Supplementation in SI Engines: Enhancing Efficiency and Reducing Emissions with a Focus on Knock Phenomena
by Saugirdas Pukalskas, Alfredas Rimkus, Tadas Vipartas, Saulius Stravinskas, Donatas Kriaučiūnas, Gabrielius Mejeras and Andrius Ušinskas
Machines 2025, 13(7), 571; https://doi.org/10.3390/machines13070571 - 1 Jul 2025
Viewed by 317
Abstract
This study investigates the impact of hydrogen supplementation on the performance, efficiency, and emissions of a spark-ignition internal combustion engine, with a specific focus on knock phenomena. A Nissan HR16DE engine was modified to operate in a dual-fuel mode using gasoline (E95) and [...] Read more.
This study investigates the impact of hydrogen supplementation on the performance, efficiency, and emissions of a spark-ignition internal combustion engine, with a specific focus on knock phenomena. A Nissan HR16DE engine was modified to operate in a dual-fuel mode using gasoline (E95) and high-purity hydrogen. Hydrogen was injected via secondary manifold injectors and managed through a reprogrammable MoTeC ECU, allowing precise control of ignition timing and fuel delivery. Experiments were conducted across various engine speeds and loads, with hydrogen mass fractions ranging from 0% to 30%. Results showed that increasing hydrogen content enhanced combustion intensity, thermal efficiency, and stability. Brake specific fuel consumption decreased by up to 43.4%, while brake thermal efficiency improved by 2–3%. CO, HC, and CO2 emissions were significantly reduced. However, NOx emissions increased with higher hydrogen concentrations due to elevated combustion temperatures. Knock tendency was effectively mitigated by retarding ignition timing, ensuring peak in-cylinder pressure occurred at 14–15° CAD aTDC. These findings demonstrate the potential of hydrogen supplementation to reduce fossil fuel use and greenhouse gas emissions in spark ignition engines, while highlighting the importance of precise combustion control to address challenges such as knock and NOx formation. Full article
(This article belongs to the Special Issue Advanced Engine Energy Saving Technology)
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18 pages, 2131 KiB  
Article
Numerical Study of a Dual-Mode Optical Sensor for Temperature and Refractive Index Sensing with Enhanced Temperature Range
by Muhammad Favad Qadir, Muhammad Zakwan, Saleem Shahid, Ahsan Sarwar Rana, Muhammad Mahmood Ali and Wolfgang Bösch
Sensors 2025, 25(13), 3999; https://doi.org/10.3390/s25133999 - 26 Jun 2025
Viewed by 321
Abstract
This study presents a photonic integrated optical sensor based on a dual-polarization microring resonator with angular gratings on a silicon-on-insulator (SOI) waveguide, enabling simultaneous and precise refractive index (RI) and temperature measurements. Due to the distinct energy distributions for transverse electric (TE [...] Read more.
This study presents a photonic integrated optical sensor based on a dual-polarization microring resonator with angular gratings on a silicon-on-insulator (SOI) waveguide, enabling simultaneous and precise refractive index (RI) and temperature measurements. Due to the distinct energy distributions for transverse electric (TE) and transverse magnetic (TM) modes in SOI waveguides, these modes show distinct sensitivity responses to the variation in ambient RI and temperature. Simultaneous measurements of both temperature and RI are enabled by exciting both these transverse modes in the microring resonator structure. Furthermore, incorporating angular gratings into the microring resonator’s inner sidewall extends the temperature measurement range by mitigating free spectral range limitations. This work presents a novel approach to dual-polarization microring resonators with angular gratings, offering an enhanced temperature measurement range and detection limit in optical sensing applications requiring an extended temperature range. The proposed structure is able to yield a simulated temperature measurement range of approximately 35 nm with a detection limit as low as 2.99×105. The achieved temperature sensitivity is 334 pm/°C and RI sensitivity is 13.33 nm/RIU for the TE0 mode, while the TM0 mode exhibits a temperature sensitivity of 260 pm/°C and an RI sensitivity of 76.66 nm/RIU. Full article
(This article belongs to the Section Optical Sensors)
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20 pages, 6267 KiB  
Article
Study on Quasi-Open Microwave Cavity Sensor Measuring Pulverized Coal Mass Concentration in Primary Air Pipe
by Yiguang Yang, Lianyong Zhang, Chenlong Wang, Lijun Chen, Hao Xu and Shihao Song
Sensors 2025, 25(12), 3657; https://doi.org/10.3390/s25123657 - 11 Jun 2025
Viewed by 377
Abstract
Pulverized coal mass concentration in the primary air pipe is one of the essential parameters for promoting furnace combustion efficiency. However, attaining accurate, real-time, and online detection for pulverized coal mass concentration remains challenging due to factors such as large pipe diameter and [...] Read more.
Pulverized coal mass concentration in the primary air pipe is one of the essential parameters for promoting furnace combustion efficiency. However, attaining accurate, real-time, and online detection for pulverized coal mass concentration remains challenging due to factors such as large pipe diameter and high flow rate. This study introduces a quasi-open microwave resonant cavity sensor. The principle and model were analyzed using the perturbation method, and the design and optimization were conducted with the simulation. A prototype and its test system were constructed, and the test results demonstrated good agreement between the simulations and experiments. The simulation revealed that the resonant frequency decreased monotonically from 861 to 644 MHz as mass concentration increased within 20%~80%, resulting in a change of about 3.62 MHz/1% under static mixture. The resonant frequency showed a drop from 21 MHz to 9 MHz with an increase in mass concentration under pulverized coal flow. Prediction models were developed and validated, showing the absolute values of the relative errors to be within 4% under operational scenarios. Additionally, the impact of the sensor on pulverized coal flow was evaluated, and it was found that the sensor structure had minimal impact on the flow in terms of velocity and the distribution of continuous flow. Finally, the long-term stability was assessed by examining the wear of the antennas and barriers. With inner barriers experiencing up to 2/3d wear, the resonant frequency drift ratio remained below 1.5%, corresponding to a mass concentration deviation of less than 3.2%. Full article
(This article belongs to the Section Physical Sensors)
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16 pages, 7546 KiB  
Article
Differential-Fed Wideband Circularly Polarized SIW Cavity-Backed Slot Antenna Array
by Chao Wang, Xiao-Chun Li and David Keezer
Electronics 2025, 14(12), 2389; https://doi.org/10.3390/electronics14122389 - 11 Jun 2025
Viewed by 389
Abstract
This paper presents a wideband circularly polarized (CP) substrate-integrated waveguide (SIW) cavity-backed slot antenna array arranged in a 2 × 2 configuration with differential feeding structures. The design features arc-shaped microstrips within the SIW cavity to excite the TE011x/ [...] Read more.
This paper presents a wideband circularly polarized (CP) substrate-integrated waveguide (SIW) cavity-backed slot antenna array arranged in a 2 × 2 configuration with differential feeding structures. The design features arc-shaped microstrips within the SIW cavity to excite the TE011x/TE101y and TE211y/TE121x modes. By overlapping the center frequencies of the two modes, wideband CP radiation is achieved. The introduction of four modified ring couplers composes a simple but efficient differential feeding network, eliminating the need for balanced resistors like baluns, making it more suitable for millimeter wave or even higher frequency applications. Experimental results show that the antenna array achieves a −10 dB impedance bandwidth of 32.6% (from 17.28 to 24.00 GHz), a 3 dB axial ratio (AR) bandwidth of 13.8% (from 17.05 to 19.57 GHz), a 3 dB gain bandwidth of 41.8% (from 15.39 to 23.51 GHz) and a peak gain of 10.6 dBi, with results closely matching simulation data. This study enhances the development of differential CP SIW cavity-backed slot antenna arrays, offering a potential solution for creating compact integrated front-end circuits in the millimeter wave or Terahertz frequency range. Full article
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20 pages, 5354 KiB  
Article
Platinum Group Minerals in Sulfide Droplets of the Zhelos Intrusion, Eastern Sayn, Russia: First Data
by Tatiana B. Kolotilina, Alexander V. Nikolaev, Alexander L. Finkelstein, Alexey S. Mekhonoshin and Olga Yu. Belozerova
Minerals 2025, 15(6), 612; https://doi.org/10.3390/min15060612 - 5 Jun 2025
Viewed by 350
Abstract
The composition of platinum group minerals localized in sulfide droplets from peridotites of the Zhelos intrusion was studied on a scanning electron microscope and on an electron probe microanalyzer. As part of this study, also an analytical approach based on the variation in [...] Read more.
The composition of platinum group minerals localized in sulfide droplets from peridotites of the Zhelos intrusion was studied on a scanning electron microscope and on an electron probe microanalyzer. As part of this study, also an analytical approach based on the variation in accelerating voltage, electron beam intensity and probe diameter is considered in order to estimate the X-ray generation region, when analyzing PGM microinclusions comparable in size to the radiation generation region or smaller. Estimates were made of the possibility of reducing the size of the local analysis area when the accelerating voltage was reduced. The influence of the matrix composition on the results of the local analysis of PGM microphases and accuracy of the Pd and Pt content determination was also evaluated. The findings of the experiments conducted allowed for the successful identification of elements belonging to the PGM microphases and the host matrix. This approach enabled the estimation of the precise levels of impurity elements in their composition. Using a scanning electron microscope in the automatic scanning mode for the detection of heavy elements, 10 single and composite grains of three platinum group minerals larger than 5 µm and 22 microphases ranging in size from 0.3 to 4 µm were detected in the sulfide droplets. The large phases are merenskyite, omeiite and michenerite, with merenskyite being predominant. Among the microscopic inclusions were identified Pd-Bi-Te, Os-Ru-As and Rh-As-S phases. The composition of the studied palladium bismuthotelluride samples indicates a formation temperature range of 489–700 °C. Full article
(This article belongs to the Section Mineral Deposits)
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18 pages, 1670 KiB  
Article
Non-Bosonic Damping of Spin Waves in van der Waals Ferromagnetic Monolayers
by Michael G. Cottam and Bushra Hussain
Nanomaterials 2025, 15(10), 768; https://doi.org/10.3390/nano15100768 - 20 May 2025
Viewed by 311
Abstract
The spin wave renormalization processes in two-dimensional van der Waals ferromagnetic monolayers are investigated using an established non-bosonic diagram technique based on the drone-fermion perturbation method. The aim is to evaluate the damping of the long-wavelength spin wave modes at temperatures below the [...] Read more.
The spin wave renormalization processes in two-dimensional van der Waals ferromagnetic monolayers are investigated using an established non-bosonic diagram technique based on the drone-fermion perturbation method. The aim is to evaluate the damping of the long-wavelength spin wave modes at temperatures below the Curie temperature. In addition to the multi-magnon scattering processes, which typically dominate at low temperatures, an additional mechanism is found here that becomes important at elevated temperatures. This spin disorder damping mechanism, which was mainly studied previously in bulk magnetic materials and thicker films, features a spin wave or magnon being scattered by the magnetic disorder that is present when a longitudinal spin component undergoes large thermal fluctuations. The magnetic ordering in the monolayers is stabilized by an out-of-plane single-ion or Ising-type anisotropy, which influences the damping properties. Numerical results are derived for monolayer films of the van der Waals ferromagnet Cr2Ge2Te6. Full article
(This article belongs to the Section Theory and Simulation of Nanostructures)
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13 pages, 12842 KiB  
Article
Strong Coupling Based on Quasibound States in the Continuum of Nanograting Metasurfaces in Near-Infrared Region
by Yulun Zhao, Junqiang Li, Yuchang Liu, Yadong Yue, Yongchuan Dang, Yilin Wang, Kun Liang and Li Yu
Photonics 2025, 12(5), 508; https://doi.org/10.3390/photonics12050508 - 19 May 2025
Viewed by 566
Abstract
Quasibound states in the continuum (qBICs) have aroused much attention as a feasible stage to investigate optical strong coupling due to their extremely high-quality factors (Q-factors) and extraordinary electromagnetic field enhancement. However, current demonstrations of strong coupling based on qBICs have primarily focused [...] Read more.
Quasibound states in the continuum (qBICs) have aroused much attention as a feasible stage to investigate optical strong coupling due to their extremely high-quality factors (Q-factors) and extraordinary electromagnetic field enhancement. However, current demonstrations of strong coupling based on qBICs have primarily focused on the visible spectral range, while research in the near-infrared (NIR) regime remains scarce. In this work, we design a nanograting metasurface supporting Friedrich–Wintgen bound states in the continuum (FW BICs). We demonstrate that FW BIC formation stems from destructive interference between Fabry–Pérot cavity modes and metal–dielectric hybrid guided-mode resonances. To investigate the qBIC–exciton coupling system, we simulated the interaction between MoTe2 excitons and nanograting metasurfaces. A Rabi splitting of 55.4 meV was observed, which satisfies the strong coupling criterion. Furthermore, a chiral medium layer is modeled inside the nanograting metasurface by rewriting the weak expression and boundary conditions. A mode splitting of the qBIC–chiral medium system in the circular dichroism (CD) spectrum demonstrates that the chiral response successfully transferred from the chiral medium layer to the exciton–polaritons systems through strong coupling. In comparison to the existing studies, our work demonstrates a significantly larger CD signal under the same Pascal parameters and with a thinner chiral dielectric layer. Our work provides a new ideal platform for investigating the strong coupling based on quasibound states in the continuum, which exhibits promising applications in near-infrared chiral biomedical detection. Full article
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10 pages, 2567 KiB  
Article
A TM01-TE11 Circular Waveguide Mode Converter on the Basis of Dielectric Filling
by Zibin Weng, Ziming Lv, Liupeng Zan, Sihan Xiao and Chen Liang
Micromachines 2025, 16(5), 585; https://doi.org/10.3390/mi16050585 - 16 May 2025
Viewed by 568
Abstract
In this paper, a dielectric-filled circular waveguide TM01-TE11 mode converter is proposed, which has high conversion efficiency and a wide operating bandwidth. Filling the circular waveguide with dielectric material changes the local propagation characteristics, thus achieving a [...] Read more.
In this paper, a dielectric-filled circular waveguide TM01-TE11 mode converter is proposed, which has high conversion efficiency and a wide operating bandwidth. Filling the circular waveguide with dielectric material changes the local propagation characteristics, thus achieving a phase difference between the TE11 modes in the two halves of the circular waveguide during propagation. This, in turn, facilitates the completion of mode conversion with high efficiency. Compared with the conventional radial dielectric plate, this paper improves the method of filling the dielectric inside the circular waveguide by transforming it into a coaxial structure. This is followed by the incorporation of a radial dielectric plate, a modification that has been proven to enhance the conversion efficiency and extend the operational bandwidth. The mode converter operates at 9.7 GHz, and when the dielectric filler material is polytetrafluoroethylene (PTFE), both simulation and practical studies are carried out. The simulation results demonstrate that the maximum conversion efficiency of this mode converter is 99.2%, and the bandwidth with conversion efficiency greater than 90% is nearly 21.1%. The maximum conversion efficiency in the actual test is essentially consistent with the simulation results. The validity of the design scheme of this converter and the accuracy of the simulation study are demonstrated. Full article
(This article belongs to the Section E:Engineering and Technology)
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16 pages, 5820 KiB  
Article
Mechanical, Antibacterial, and Physico-Chemical Properties of Three Different Polymer-Based Direct Restorative Materials: An In Vitro Study
by Chloé Laporte, Rim Bourgi, Hamdi Jmal, Teissir Ben Ammar, Sandy Hazko, Frédéric Addiego, Salvatore Sauro, Youssef Haïkel and Naji Kharouf
Polymers 2025, 17(9), 1272; https://doi.org/10.3390/polym17091272 - 6 May 2025
Viewed by 793
Abstract
A novel resin-based bulk-fill restorative material (ST; Stela SDI, Bayswater, Victoria, Australia) has been recently introduced as a self-curing alternative to traditional light-cured composites. Promoted for its unlimited depth of cure, enhanced aesthetics, and unique primer composition, it aims to address challenges associated [...] Read more.
A novel resin-based bulk-fill restorative material (ST; Stela SDI, Bayswater, Victoria, Australia) has been recently introduced as a self-curing alternative to traditional light-cured composites. Promoted for its unlimited depth of cure, enhanced aesthetics, and unique primer composition, it aims to address challenges associated with amalgam and light-curing composites. Thus, the aim of this in vitro study was to investigate the performance of the new self-curing polymer-based restorative material, ST, compared to two conventional light-cured composites for direct restoration. The study evaluated compressive strength with and without aging, antibacterial activity, mineral deposition in contact with Phosphate-Buffered Saline (PBS) and artificial saliva, porosity, and wettability of ST (Tetric EvoCeram (TE; Ivoclar Vivadent, Schaan, Liechtenstein) and Clearfil Majesty ES-2 (CM; Kuraray Noritake Dental, Tokyo, Japan)). The data was statistically analyzed (α = 0.05) through one-way and two-way analysis of variance (ANOVA). ST demonstrated significantly higher compressive strength than TE and CM at baseline and after aging (p < 0.001), while aging significantly reduced compressive strength across all materials (p < 0.001). Fracture mode analysis revealed brittle fractures for TE and CM, whereas ST fractured in multiple smaller fragments. CM showed the highest void volume and diameter, significantly differing from ST and TE (p < 0.001). Scanning electron microscopy (SEM) analysis revealed cubical-like crystalline formations on ST’s surface after 28 days of immersion in PBS and saliva, indicating some level of bioactivity, whereas no changes were observed for TE and CM. Wettability testing showed ST had the lowest contact angle (12.24° ± 2.1°) compared to TE (62.78° ± 4.68°) and CM (64.64° ± 3.72°) (p < 0.001). Antibacterial activity testing displayed a significant decrease in bacterial growth for CM compared to ST (p = 0.001) and TE (p = 0.002); however, ST and TE showed no significant differences (p = 0.950). To conclude, ST Automix demonstrated promising results across several key parameters, making it a potential candidate for long-lasting restorative applications. Future studies should explore its long-term clinical performance and investigate formulations that enhance its antibacterial properties. Moreover, the bond strength of these materials to dentin and the cytotoxicity should be evaluated. Full article
(This article belongs to the Special Issue Physicochemical Properties of Polymer Composites)
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22 pages, 1447 KiB  
Article
Optimization of a Nuclear–CSP Hybrid Energy System Through Multi-Objective Evolutionary Algorithms
by Chenxiao Ji, Xueying Nie, Shichao Chen, Maosong Cheng and Zhimin Dai
Energies 2025, 18(9), 2189; https://doi.org/10.3390/en18092189 - 25 Apr 2025
Viewed by 595
Abstract
Combining energy storage with base-load power sources offers an effective way to cover the fluctuation of renewable energy. This study proposes a nuclear–solar hybrid energy system (NSHES), which integrates a small modular thorium molten salt reactor (smTMSR), concentrating solar power (CSP), and thermal [...] Read more.
Combining energy storage with base-load power sources offers an effective way to cover the fluctuation of renewable energy. This study proposes a nuclear–solar hybrid energy system (NSHES), which integrates a small modular thorium molten salt reactor (smTMSR), concentrating solar power (CSP), and thermal energy storage (TES). Two operation modes are designed and analyzed: constant nuclear power (mode 1) and adjusted nuclear power (mode 2). The nondominated sorting genetic algorithm II (NSGA-II) is applied to minimize both the deficiency of power supply probability (DPSP) and the levelized cost of energy (LCOE). The decision variables used are the solar multiple (SM) of CSP and the theoretical storage duration (TSD) of TES. The criteria importance through inter-criteria correlation (CRITIC) method and the technique for order preference by similarity to ideal solution (TOPSIS) are utilized to derive the optimal compromise solution. The electricity curtailment probability (ECP) is calculated, and the results show that mode 2 has a lower ECP compared with mode 1. Furthermore, the configuration with an installed capacity of nuclear and CSP (100:100) has the lowest LCOE and ECP when the DPSP is satisfied with certain conditions. Optimizing the NSHES offers an effective approach to mitigating the mismatch between energy supply and demand. Full article
(This article belongs to the Special Issue Smart Energy Storage and Management)
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12 pages, 9413 KiB  
Article
Design of a Miniaturized and Polarization-Independent Frequency-Selective Surface for Targeted EMI Shielding
by Muhammad Idrees, Yejun He, Youquan Wen and Abdul Majeed
Appl. Sci. 2025, 15(8), 4534; https://doi.org/10.3390/app15084534 - 20 Apr 2025
Cited by 1 | Viewed by 670
Abstract
In this article, a miniaturized frequency-selective surface (FSS)-based electromagnetic shield is investigated for EMI mitigation in the X-band. The FSS comprises a convoluted conducting loop designed over an FR-4 substrate. It operates at 10 GHz X-band frequency and offers an effective shielding of [...] Read more.
In this article, a miniaturized frequency-selective surface (FSS)-based electromagnetic shield is investigated for EMI mitigation in the X-band. The FSS comprises a convoluted conducting loop designed over an FR-4 substrate. It operates at 10 GHz X-band frequency and offers an effective shielding of at least 33 dB. It reveals rejection bandwidths of 26% for the TE and TM wave modes at normal incidence. Moreover, it accomplishes polarization-insensitive and angularly stable spectral responses owing to its structural symmetry and compact size. In addition, an equivalent circuit model (ECM) and a finite prototype of the shield are developed to verify EM simulations. A comparison of the results indicates that the FSS offers wide angular stability and excellent shielding performance, which makes it a suitable candidate for applications requiring targeted EMI mitigation. Full article
(This article belongs to the Special Issue Recent Advances in Magnetic Shielding)
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9 pages, 1898 KiB  
Communication
Hybrid Crown Ether Ligands with Disiloxane Units and Their Complexes with Small s-Block Ions
by Roman-Malte Richter, Daniel James Stauf, Anna Lena Rauchel, Lutz Ruppach, Kevin Bania, Annalena Duncker and Carsten von Hänisch
Compounds 2025, 5(2), 11; https://doi.org/10.3390/compounds5020011 - 11 Apr 2025
Viewed by 581
Abstract
Herein, we present hybrid crown ether ligands with siloxane and ethylene oxide units and their coordination with the cations Li+, Na+, Mg2+ and Ca2+. The compounds prepared are (SiMe2O)2(C2H4 [...] Read more.
Herein, we present hybrid crown ether ligands with siloxane and ethylene oxide units and their coordination with the cations Li+, Na+, Mg2+ and Ca2+. The compounds prepared are (SiMe2O)2(C2H4O)3 (1, TrEGDS = Triethylenglycoldisiloxane) and (SiMe2O)2(C2H4O)4 (2, TeEGDS = Tetraethylenglycoldisiloxane)), as well as the metal complexes [Li(TrEGDS][GaI4] (3), [Na(TeEGDS)][GaI4] (4), [Mg(TrEGDS)][GaI4]2 (5) and [Ca(TeEGDS)][GaI4]2 (6). Single-crystal X-ray diffraction was used to study the prepared complexes and coordination modes in the solid state. Full article
(This article belongs to the Special Issue Feature Papers in Compounds (2025))
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13 pages, 3845 KiB  
Article
Ultra-Compact Multimode Micro-Racetrack Resonator Based on Cubic Spline Curves
by Zhen Li, Chuang Cheng, Xin Fu and Lin Yang
Photonics 2025, 12(4), 326; https://doi.org/10.3390/photonics12040326 - 31 Mar 2025
Viewed by 483
Abstract
Micro-racetrack resonators have become one of the key components for realizing signal processing, generation, and integration in microwave photonics, owing to their high Q factor, compact footprint, and tunability. However, most of the reported micro-racetrack resonators are confined to the single-mode regime. In [...] Read more.
Micro-racetrack resonators have become one of the key components for realizing signal processing, generation, and integration in microwave photonics, owing to their high Q factor, compact footprint, and tunability. However, most of the reported micro-racetrack resonators are confined to the single-mode regime. In this paper, we designed an ultra-compact multimode micro-racetrack resonator (MMRR) based on shape-optimized multimode waveguide bends (MWBs). Cubic spline curves were used to represent the MWB boundary and adjoint methods were utilized for inverse optimization, achieving an effective radius of 8 μm. Asymmetric directional couplers (ADCs) were designed to independently couple three modes into a multimode micro-racetrack, according to phase-matching conditions and transmission analysis. The MMRR was successfully fabricated on a commercial platform using a 193 nm dry lithography process. The device exhibited high loaded Q factors of 2.3 × 105, 4.1 × 104, and 2.9 × 104, and large free spectral ranges (FSRs) of 5.4, 4.7, and 4.2 nm for TE0, TE1, and TE2 modes, with about a 19 × 55 μm2 footprint. Full article
(This article belongs to the Special Issue Recent Advancement in Microwave Photonics)
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