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20 pages, 780 KiB  
Article
A Semantic Behavioral Sequence-Based Approach to Trajectory Privacy Protection
by Ji Xi, Weiqi Zhang, Zhengwang Xia, Li Zhao and Huawei Tao
Symmetry 2025, 17(8), 1266; https://doi.org/10.3390/sym17081266 (registering DOI) - 7 Aug 2025
Abstract
Trajectory data contain numerous sensitive attributes. Unauthorized disclosure of precise user trajectory information generates persistent privacy and security concerns that significantly impact daily life. Most existing trajectory privacy protection schemes focus on geographic trajectories while neglecting the critical importance of semantic trajectories, resulting [...] Read more.
Trajectory data contain numerous sensitive attributes. Unauthorized disclosure of precise user trajectory information generates persistent privacy and security concerns that significantly impact daily life. Most existing trajectory privacy protection schemes focus on geographic trajectories while neglecting the critical importance of semantic trajectories, resulting in ongoing privacy vulnerabilities. To address this limitation, we propose the Semantic Behavior Sequence-based Trajectory Privacy Protection method (SBS-TPP). Our approach integrates short-term and long-term behavioral patterns within a user behavior modeling layer to identify user preferences. A dual-model framework (geographic and semantic) generates noise-injected trajectories with maximized noise potential. This methodology applies symmetric noise addition to both geographic trajectory fragments and semantic trajectory segments, optimizing trajectory data utility while ensuring robust protection of sensitive information. The SBS-TPP framework operates in the following two phases: firstly, behavior modeling, which comprises interest extraction from behavioral trajectory sequences, and secondly, noise generation, which creates synthetic noise locations with maximal semantic expectation from original locations, yielding privacy-enhanced trajectories for publication. Experimental results demonstrate that our interest extraction model achieves 93.7% accuracy while maintaining 81.6% data utility under strict privacy guarantees. The proposed method significantly enhances data usability and enables effective recommendation services without compromising user privacy or security. Full article
(This article belongs to the Section Computer)
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14 pages, 2209 KiB  
Article
Effect of Different Deodorants on SBS-Modified Asphalt Fume Emissions, Asphalt Road Performance, and Mixture Performance
by Zhaoyan Sheng, Ning Yan and Xianpeng Zhao
Processes 2025, 13(8), 2485; https://doi.org/10.3390/pr13082485 - 6 Aug 2025
Abstract
During large-scale pavement construction, the preparation of SBS-modified asphalt typically produces large amounts of harmful fumes. The emergence of deodorants can effectively alleviate the problem of smoke emissions during the asphalt manufacturing process. On the basis of ensuring the original road performance, exploring [...] Read more.
During large-scale pavement construction, the preparation of SBS-modified asphalt typically produces large amounts of harmful fumes. The emergence of deodorants can effectively alleviate the problem of smoke emissions during the asphalt manufacturing process. On the basis of ensuring the original road performance, exploring more suitable dosages and types of deodorant is urgently needed. Five commercial deodorants were evaluated using an asphalt smoke collection system, and UV-visible spectrophotometry (UV) was employed to screen the deodorants based on smoke concentration. Gas chromatography–mass spectrometry (GC-MS) was used to quantitatively analyze changes in harmful smoke components before and after adding two deodorants. Subsequently, the mechanisms of action of the two different types of deodorants were analyzed microscopically using fluorescence microscopy. Finally, the performance of bitumen and asphalt mixtures after adding deodorants was evaluated. The results showed that deodorant A (reactive type) and D (adsorption type) exhibited the best smoke suppression effects, with optimal addition rates of 0.6% and 0.5%, respectively. Deodorant A reduced benzene homologues by nearly 50% and esters by approximately 40%, while deodorant D reduced benzene homologues by approximately 70% and esters by approximately 60%, without producing new toxic gases. Both deodorants had a minimal impact on the basic properties of bitumen and the road performance of asphalt mixtures, with all indicators meeting technical specifications. This research provides a theoretical basis for the effective application of deodorants in the future, truly enabling a transition from laboratory research to large-scale engineering applications in the construction of environmentally friendly roads. Full article
(This article belongs to the Section Materials Processes)
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12 pages, 1530 KiB  
Article
Effect of Aggregate Type on Asphalt–Aggregate Adhesion and Its Quantitative Characterization
by Liuxiao Chen, Junlin Li, Hao Xiang, Jun Zhang, Enlin Feng and Lin Kong
Materials 2025, 18(15), 3696; https://doi.org/10.3390/ma18153696 - 6 Aug 2025
Abstract
To study the effect of aggregate type on the adhesion between asphalt and aggregate, limestone, basalt, diabase, and 70# asphalt with SBS asphalt were selected. The mineral phase composition of the aggregates was analyzed by X-ray diffraction. The surface energy theory was used [...] Read more.
To study the effect of aggregate type on the adhesion between asphalt and aggregate, limestone, basalt, diabase, and 70# asphalt with SBS asphalt were selected. The mineral phase composition of the aggregates was analyzed by X-ray diffraction. The surface energy theory was used to calculate the adhesion work and the work of flaking. The modified water boiling method combined with image processing technology was used to quantitatively characterize the flaking behavior of the asphalt. The results show that the aggregate type is closely related to the asphalt–aggregate adhesion. The mineral compositions of different types of aggregates vary significantly, with limestone, being a strongly alkaline aggregate predominantly comprising CaCO3, exhibiting better adhesion with asphalt. The contact angle test and modified boiling method also yielded the same results, and the adhesion relationship with asphalt was limestone > basalt > diabase. Image processing technology effectively characterizes the spalling situation of asphalt and conducts quantitative analysis. Full article
(This article belongs to the Section Construction and Building Materials)
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17 pages, 2393 KiB  
Article
Impact of Cu-Site Dopants on Thermoelectric Power Factor for Famatinite (Cu3SbS4) Nanomaterials
by Jacob E. Daniel, Evan Watkins, Mitchel S. Jensen, Allen Benton, Apparao Rao, Sriparna Bhattacharya and Mary E. Anderson
Electron. Mater. 2025, 6(3), 10; https://doi.org/10.3390/electronicmat6030010 - 6 Aug 2025
Abstract
Famatinite (Cu3SbS4) is an earth-abundant, nontoxic material with potential for thermoelectric energy generation applications. Herein, rapid, energy-efficient, and facile one-pot modified polyol synthesis was utilized to produce gram-scale quantities of phase-pure famatinite (Cu2.7M0.3SbS4, [...] Read more.
Famatinite (Cu3SbS4) is an earth-abundant, nontoxic material with potential for thermoelectric energy generation applications. Herein, rapid, energy-efficient, and facile one-pot modified polyol synthesis was utilized to produce gram-scale quantities of phase-pure famatinite (Cu2.7M0.3SbS4, M = Cu, Zn, Mn) nanoparticles (diameter 20–30 nm) with controllable and stoichiometric incorporation of transition metal dopants on the Cu-site. To produce pellets for thermoelectric characterization, the densification process by spark plasma sintering was optimized for individual samples based on thermal stability determined using differential scanning calorimetry and thermogravimetric analysis. Electronic transport properties of undoped and doped famatinite nanoparticles were studied from 225–575 K, and the thermoelectric power factor was calculated. This is the first time electronic transport properties of famatinite doped with Zn or Mn have been studied. All famatinite samples had similar resistivities (>0.8 mΩ·m) in the measured temperature range. However, the Mn-doped famatinite nanomaterials exhibited a thermoelectric power factor of 10.3 mW·m−1·K−1 at 575 K, which represented a significant increase relative to the undoped nanomaterials and Zn-doped nanomaterials engendered by an elevated Seebeck coefficient of ~220 µV·K−1 at 575 K. Future investigations into optimizing the thermoelectric properties of Mn-doped famatinite nanomaterials are promising avenues of research for producing low-cost, environmentally friendly, high-performing thermoelectric materials. Full article
(This article belongs to the Special Issue Feature Papers of Electronic Materials—Third Edition)
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12 pages, 2764 KiB  
Article
AlxCoCrFeNi High-Entropy Alloys Enable Simultaneous Electrical and Mechanical Robustness at Thermoelectric Interfaces
by Xiaoxia Zou, Wangjie Zhou, Xinxin Li, Yuzeng Gao, Jingyi Yu, Linglu Zeng, Guangteng Yang, Li Liu, Wei Ren and Yan Sun
Materials 2025, 18(15), 3688; https://doi.org/10.3390/ma18153688 - 6 Aug 2025
Abstract
The interface between high-performance thermoelectric materials and electrodes critically governs the conversion efficiency and long-term reliability of thermoelectric generators under high-temperature operation. Here, we propose AlxCoCrFeNi high-entropy alloys (HEA) as barrier layers to bond Cu-W electrodes with p-type skutterudite (p-SKD) thermoelectric [...] Read more.
The interface between high-performance thermoelectric materials and electrodes critically governs the conversion efficiency and long-term reliability of thermoelectric generators under high-temperature operation. Here, we propose AlxCoCrFeNi high-entropy alloys (HEA) as barrier layers to bond Cu-W electrodes with p-type skutterudite (p-SKD) thermoelectric materials. The HEA/p-SKD interface exhibited excellent chemical bonding with a stable and controllable reaction layer, forming a dense, defect-free (Fe,Ni,Co,Cr)Sb phase (thickness of ~2.5 μm) at the skutterudites side. The interfacial resistivity achieved a low value of 0.26 μΩ·cm2 and remained at 7.15 μΩ·cm2 after aging at 773 K for 16 days. Moreover, the interface demonstrated remarkable mechanical stability, with an initial shear strength of 88 MPa. After long-term aging for 16 days at 773 K, the shear strength retained 74 MPa (only 16% degradation), ranking among the highest reported for thermoelectric materials/metal joints. Remarkably, the joint maintained a shear strength of 29 MPa even after 100 continuous thermal cycles (623–773 K), highlighting its outstanding thermo-mechanical stability. These results validate the AlxCoCrFeNi high-entropy alloys as an ideal interfacial material for thermoelectric generators, enabling simultaneous optimization of electrical and mechanical performance in harsh environments. Full article
(This article belongs to the Section Metals and Alloys)
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20 pages, 1831 KiB  
Article
Saccharomyces boulardii CNCM I-745 Supernatant Improves Markers of Gut Barrier Function and Inflammatory Response in Small Intestinal Organoids
by Louisa Filipe Rosa, Steffen Gonda, Nadine Roese and Stephan C. Bischoff
Pharmaceuticals 2025, 18(8), 1167; https://doi.org/10.3390/ph18081167 - 6 Aug 2025
Abstract
Objectives: Saccharomyces boulardii CNCM I-745, a probiotic yeast, is effectively used for the treatment of acute diarrhea as well as for the prevention and treatment of traveller‘s diarrhea and diarrhea under tube feeding. The underlying mechanisms are not fully elucidated. Both antitoxic [...] Read more.
Objectives: Saccharomyces boulardii CNCM I-745, a probiotic yeast, is effectively used for the treatment of acute diarrhea as well as for the prevention and treatment of traveller‘s diarrhea and diarrhea under tube feeding. The underlying mechanisms are not fully elucidated. Both antitoxic and regulatory effects on the intestinal barrier, mediated either by the yeast or yeast-derived substrates, have been discussed. Methods: To examine the effects of Saccharomyces boulardii released substrates (S.b.S) on gastrointestinal (GI) barrier function, a murine small intestinal organoid cell model under stress was used. Stress was induced by lipopolysaccharide (LPS) exposure or withdrawal of growth factors from cell culture medium (GFRed). Stressed organoids were treated with S.b.S (200 µg/mL), and markers of GI barrier and inflammatory response were assessed. Results: GFRed-induced stress was characterized by disturbances in selected tight junction (TJ) (p < 0.05), adherent junction (AJ) (p < 0.001), and mucin (Muc) formation (p < 0.01), measured by gene expressions, whereby additional S.b.S treatment was found to reverse these effects by increasing Muc2 (from 0.22 to 0.97-fold change, p < 0.05), Occludin (Ocln) (from 0.37 to 3.5-fold change, p < 0.0001), and Claudin (Cldn)7 expression (from 0.13 ± 0.066-fold change, p < 0.05) and by decreasing Muc1, Cldn2, Cldn5, and junctional adhesion molecule A (JAM-A) expression (all p < 0.01). Further, S.b.S normalized expression of nucleotide binding oligomerization domain (Nod)2- (from 44.5 to 0.51, p < 0.0001) and matrix metalloproteinase (Mmp)7-dependent activation (from 28.3 to 0.02875 ± 0.0044 ** p < 0.01) of antimicrobial peptide defense and reduced the expression of several inflammatory markers, such as myeloid differentiation primary response 88 (Myd88) (p < 0.01), tumor necrosis factor α (Tnfα) (p < 0.01), interleukin (IL)-6 (p < 0.01), and IL-1β (p < 0.001). Conclusions: Our data provide new insights into the molecular mechanisms by which Saccharomyces boulardii CNCM I-745-derived secretome attenuates inflammatory responses and restores GI barrier function in small intestinal organoids. Full article
(This article belongs to the Topic Probiotics: New Avenues)
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24 pages, 1671 KiB  
Article
Sustainability in Purpose-Driven Businesses Operating in Cultural and Creative Industries: Insights from Consumers’ Perspectives on Società Benefit
by Gesualda Iodice and Francesco Bifulco
Sustainability 2025, 17(15), 7117; https://doi.org/10.3390/su17157117 - 6 Aug 2025
Abstract
This study intends to provide insights and challenges for the shape of the B movement, an emerging paradigm that fosters cross-sectoral partnerships and encourages ethical business practices through so-called purpose-driven businesses. Focusing on Italy, the first European country to adopt this managerial model, [...] Read more.
This study intends to provide insights and challenges for the shape of the B movement, an emerging paradigm that fosters cross-sectoral partnerships and encourages ethical business practices through so-called purpose-driven businesses. Focusing on Italy, the first European country to adopt this managerial model, the research investigates Italian Benefit Corporations, known as Società Benefit (SB), and their most appealing sustainability claims from a consumer perspective. The analysis intends to inform theory development by assuming the cultural and creative industry (CCI) as a field of interest, utilizing a within-subjects experimental design to analyze data from a diverse consumer sample across various contexts. The results indicate that messaging centered on economic sustainability emerged as the most effective in generating positive consumer responses, highlighting a prevailing inclination toward pragmatic factors such as affordability, economic accessibility, and tangible benefits rather than social issues. While sustainable behaviors are not yet widespread, latent ethical sensitivity for authentic, value-driven businesses suggests that economic and ethical dimensions can be strategically synthesized to enhance consumer engagement. This insight highlights the role of BCs in catalyzing a shift in consumption patterns within ethical-based and creative-driven sectors. Full article
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23 pages, 4361 KiB  
Article
Novel Visible Light-Driven Ho2InSbO7/Ag3PO4 Photocatalyst for Efficient Oxytetracycline Contaminant Degradation
by Jingfei Luan and Tiannan Zhao
Molecules 2025, 30(15), 3289; https://doi.org/10.3390/molecules30153289 - 6 Aug 2025
Abstract
In this study, a Z-scheme Ho2InSbO7/Ag3PO4 (HAO) heterojunction photocatalyst was successfully fabricated for the first time by ultrasound-assisted solvothermal method. The structural features, compositional components and morphological characteristics of the synthesized materials were thoroughly characterized by [...] Read more.
In this study, a Z-scheme Ho2InSbO7/Ag3PO4 (HAO) heterojunction photocatalyst was successfully fabricated for the first time by ultrasound-assisted solvothermal method. The structural features, compositional components and morphological characteristics of the synthesized materials were thoroughly characterized by a series of techniques, including X-ray diffraction, Fourier transform infrared spectroscopy, Raman spectrum, X-ray photoelectron spectroscopy, transmission electron microscopy, scanning electron microscopy and energy-dispersive X-ray spectroscopy. A comprehensive array of analytical techniques, including ultraviolet-visible diffuse reflectance absorption spectra, photoluminescence spectroscopy, time-resolved photoluminescence spectroscopy, photocurrent testing, electrochemical impedance spectroscopy, electron paramagnetic resonance, and ultraviolet photoelectron spectroscopy, was employed to systematically investigate the optical, chemical, and photoelectronic properties of the materials. Using oxytetracycline (OTC), a representative tetracycline antibiotic, as the target substrate, the photocatalytic activity of the HAO composite was assessed under visible light irradiation. Comparative analyses demonstrated that the photocatalytic degradation capability of the HAO composite surpassed those of its individual components. Notably, during the degradation process, the application of the HAO composite resulted in an impressive removal efficiency of 99.89% for OTC within a span of 95 min, along with a total organic carbon mineralization rate of 98.35%. This outstanding photocatalytic performance could be ascribed to the efficient Z-scheme electron-hole separation system occurring between Ho2InSbO7 and Ag3PO4. Moreover, the adaptability and stability of the HAO heterojunction were thoroughly validated. Through experiments involving the capture of reactive species and electron paramagnetic resonance analysis, the active species generated by HAO were identified as hydroxyl radicals (•OH), superoxide anions (•O2), and holes (h+). This identification provides valuable insights into the mechanisms and pathways associated with the photodegradation of OTC. In conclusion, this research not only elucidates the potential of HAO as an efficient Z-scheme heterojunction photocatalyst but also marks a significant contribution to the advancement of sustainable remediation strategies for OTC contamination. Full article
(This article belongs to the Special Issue Nanomaterials in Photochemical Devices: Advances and Applications)
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16 pages, 2071 KiB  
Article
Mapping QTL and Identifying Candidate Genes for Resistance to Brown Stripe in Highly Allo-Autopolyploid Modern Sugarcane
by Wei Cheng, Zhoutao Wang, Fu Xu, Yingying Yang, Jie Fang, Jianxiong Wu, Junjie Pan, Qiaomei Wang and Liping Xu
Horticulturae 2025, 11(8), 922; https://doi.org/10.3390/horticulturae11080922 - 5 Aug 2025
Abstract
Disease resistance is one of the most important target traits for sugarcane genetic improvement. Sugarcane brown stripe (SBS) caused by Helminthosporium stenospilum is one of the most destructive foliar diseases, which not only reduces harvest cane yield but also sugar content. This study [...] Read more.
Disease resistance is one of the most important target traits for sugarcane genetic improvement. Sugarcane brown stripe (SBS) caused by Helminthosporium stenospilum is one of the most destructive foliar diseases, which not only reduces harvest cane yield but also sugar content. This study aimed to identify quantitative trait loci (QTL) and candidate genes associated with SBS resistance. Here, the phenotypic investigation in six field habitats showed a continuous normal distribution, revealing that the SBS resistance trait is a quantitative trait. Two high-density linkage maps based on the single-dose markers calling from the Axiom Sugarcane100K SNP chip were constructed for the dominant sugarcane cultivars YT93-159 (SBS-resistant) and ROC22 (SBS-susceptible) with a density of 2.53 cM and 2.54 cM per SNP marker, and mapped on 87 linkage groups (LGs) and 80 LGs covering 3069.45 cM and 1490.34 cM of genetic distance, respectively. A total of 32 QTL associated with SBS resistance were detected by QTL mapping, which explained 3.73–11.64% of the phenotypic variation, and the total phenotypic variance explained (PVE) in YT93-159 and ROC22 was 107.44% and 79.09%, respectively. Among these QTL, four repeatedly detected QTL (qSBS-Y38-1, qSBS-Y38-2, qSBS-R8, and qSBS-R46) were considered stable QTL. Meanwhile, two major QTL, qSBS-Y38 and qSBS-R46, could account for 11.47% and 11.64% of the PVE, respectively. Twenty-five disease resistance candidate genes were screened by searching these four stable QTL regions in their corresponding intervals, of which Soffic.01G0010840-3C (PR3) and Soffic.09G0017520-1P (DND2) were significantly up-regulated in YT93-159 by qRT-PCR, while Soffic.01G0040620-1P (EDR2) was significantly up-regulated in ROC22. These results will provide valuable insights for future studies on sugarcane breeding in combating this disease. Full article
(This article belongs to the Special Issue Disease Diagnosis and Control for Fruit Crops)
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10 pages, 335 KiB  
Article
On the Probability of the Astrometric Resolution of Spectroscopic Binaries into Components
by Dugasa Belay Zeleke, Alexey Yu. Sytov, Seblu Humne Negu, Arseniy M. Sachkov, Solomon Belay Tessema and Oleg Yu. Malkov
Galaxies 2025, 13(4), 87; https://doi.org/10.3390/galaxies13040087 - 5 Aug 2025
Abstract
Resolved spectroscopic binaries (RSBs) are an extremely valuable class of objects, being the only (apart from trigonometric) supplier of dynamical stellar parallaxes. This circumstance, as well as the comparative paucity of studied RSBs, makes the problem of identifying binary systems potentially capable of [...] Read more.
Resolved spectroscopic binaries (RSBs) are an extremely valuable class of objects, being the only (apart from trigonometric) supplier of dynamical stellar parallaxes. This circumstance, as well as the comparative paucity of studied RSBs, makes the problem of identifying binary systems potentially capable of being added to the list of known RSBs extremely urgent. In this paper, we propose a methodology for estimating the probability of a spectroscopic binary system to be resolved into components, perform the first step of its application to the SB9 catalogue, and present preliminary results, in particular, a list of the most promising RSB candidates. Full article
(This article belongs to the Special Issue Stellar Spectroscopy, Molecular Astronomy and Atomic Astronomy)
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13 pages, 4326 KiB  
Article
MBE Growth of High-Quality HgCdSe for Infrared Detector Applications
by Zekai Zhang, Wenwu Pan, Gilberto A. Umana Membreno, Shuo Ma, Lorenzo Faraone and Wen Lei
Materials 2025, 18(15), 3676; https://doi.org/10.3390/ma18153676 - 5 Aug 2025
Abstract
HgCdSe has recently been proposed as a potential alternative material to HgCdTe for fabricating high-performance infrared detectors. This work presents a study on the growth of high-crystalline-quality HgCdSe materials on GaSb (211)B substrates via molecular beam epitaxy and demonstration of the first prototype [...] Read more.
HgCdSe has recently been proposed as a potential alternative material to HgCdTe for fabricating high-performance infrared detectors. This work presents a study on the growth of high-crystalline-quality HgCdSe materials on GaSb (211)B substrates via molecular beam epitaxy and demonstration of the first prototype HgCdSe-based mid-wave infrared detectors. By optimizing the MBE growth parameters, and especially the thermal cleaning process of the GaSb substrate surface prior to epitaxial growth, high-quality HgCdSe material was achieved with a record XRD full width at half maximum of ~65 arcsec. At a temperature of 77 K, the mid-wave infrared HgCdSe n-type material demonstrated a minority carrier lifetime of ~1.19 µs, background electron concentration of ~2.2 × 1017 cm−3, and electron mobility of ~1.6 × 104 cm2/Vs. The fabricated mid-wave infrared HgCdSe photoconductor presented a cut-off wavelength of 4.2 µm, a peak responsivity of ~40 V/W, and a peak detectivity of ~1.2 × 109 cmHz1/2/W at 77 K. Due to the relatively high background electron concentration, the detector performance is lower than that of state-of-the-art low-doped HgCdTe counterparts. However, these preliminary results indicate the great potential of HgCdSe materials for achieving next-generation IR detectors on large-area substrates with features of lower cost and larger array format size. Full article
(This article belongs to the Section Optical and Photonic Materials)
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22 pages, 7171 KiB  
Article
Distribution Characteristics, Mobility, and Influencing Factors of Heavy Metals at the Sediment–Water Interface in South Dongting Lake
by Xiaohong Fang, Xiangyu Han, Chuanyong Tang, Bo Peng, Qing Peng, Linjie Hu, Yuru Zhong and Shana Shi
Water 2025, 17(15), 2331; https://doi.org/10.3390/w17152331 - 5 Aug 2025
Abstract
South Dongting Lake is an essential aquatic ecosystem that receives substantial water inflows from the Xiangjiang and Zishui Rivers. However, it is significantly impacted by human activities, including mining, smelting, and farming. These activities have led to serious contamination of the lake’s sediments [...] Read more.
South Dongting Lake is an essential aquatic ecosystem that receives substantial water inflows from the Xiangjiang and Zishui Rivers. However, it is significantly impacted by human activities, including mining, smelting, and farming. These activities have led to serious contamination of the lake’s sediments with heavy metals (HMs). This study investigated the distribution, mobility, and influencing factors of HMs at the sediment–water interface. To this end, sediment samples were analyzed from three key regions (Xiangjiang River estuary, Zishui River estuary, and northeastern South Dongting Lake) using traditional sampling methods and Diffusive Gradients in Thin Films (DGT) technology. Analysis of fifteen HMs (Pb, Bi, Ni, As, Se, Cd, Sb, Mn, Zn, V, Cr, Cu, Tl, Co, and Fe) revealed significant spatial heterogeneity. The results showed that Cr, Cu, Pb, Bi, Ni, As, Se, Cd, Sb, Mn, Zn, and Fe exhibited high variability (CV > 0.20), whereas V, Tl, and Co demonstrated stable concentrations (CV < 0.20). Concentrations were found to exceed background values of the upper continental crust of eastern China (UCC), Yangtze River sediments (YZ), and Dongting Lake sediments (DT), particularly at the Xiangjiang estuary (XE) and in the northeastern regions. Speciation analysis revealed that V, Cr, Cu, Ni, and As were predominantly found in the residual fraction (F4), while Pb and Co were concentrated in the oxidizable fraction (F3), Mn and Zn appeared primarily in the exchangeable fractions (F1 and F2), and Cd was notably dominant in the exchangeable fraction (F1), suggesting a high potential for mobility. Additionally, DGT results confirmed a significant potential for the release of Pb, Zn, and Cd. Contamination assessment using the Pollution Load Index (PLI) and Geoaccumulation Index (Igeo) identified Pb, Bi, Ni, As, Se, Cd, and Sb as major pollutants. Among these, Bi and Cd were found to pose the highest risks. Furthermore, the Risk Assessment Code (RAC) and the Potential Ecological Risk Index (PERI) highlighted Cd as the primary ecological risk contributor, especially in the XE. The study identified sediment grain size, pH, electrical conductivity, and nutrient levels as the primary influencing factors. The PMF modeling revealed HM sources as mixed smelting/natural inputs, agricultural activities, natural weathering, and mining/smelting operations, suggesting that remediation should prioritize Cd control in the XE with emphasis on external inputs. Full article
(This article belongs to the Section Water Quality and Contamination)
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11 pages, 1037 KiB  
Article
Bonding to Demineralized Dentin: Impact of Immediate and Delayed Dentin Sealing over Time
by Erika Pérez-Soto, Rim Bourgi, Louis Hardan, Carlos Enrique Cuevas-Suarez, Ana Josefina Monjáras-Ávila, Miguel Ángel Fernández-Barrera, Nicolas Nassar, Monika Lukomska-Szymanska, Rima Daoui, Naji Kharouf and Youssef Haikel
Dent. J. 2025, 13(8), 354; https://doi.org/10.3390/dj13080354 - 5 Aug 2025
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Abstract
Background/Objectives: Immediate dentin sealing (IDS) has been widely investigated in sound dentin; however, its efficacy on demineralized dentin remains insufficiently explored. This in vitro experimental study aimed to evaluate the shear bond strength (SBS) of indirect composite resin restorations bonded to demineralized dentin [...] Read more.
Background/Objectives: Immediate dentin sealing (IDS) has been widely investigated in sound dentin; however, its efficacy on demineralized dentin remains insufficiently explored. This in vitro experimental study aimed to evaluate the shear bond strength (SBS) of indirect composite resin restorations bonded to demineralized dentin using IDS, assessed at 24 h and after 6 months of aging. Methods: Twenty-five extracted premolars were randomly divided into five groups: (1) control (no sealing), (2) IDS applied to sound dentin (sound-IDS), (3) IDS applied to demineralized dentin (carious-IDS), (4) delayed dentin sealing (DDS) on sound dentin (sound-DDS), and (5) DDS on demineralized dentin (carious-DDS). SBS values were analyzed using a three-way analysis of variance (ANOVA) with dentin condition (sound vs. demineralized), aging time (24 h vs. 6 months), and sealing strategy (control, IDS, DDS) as independent variables. Statistical analyses were performed using SigmaPlot 12.0, with significance set at p < 0.05. Results: The results showed that IDS led to significantly higher SBS than DDS (p < 0.05). Bond strength was significantly influenced by dentin condition (p < 0.05), and all interactions between variables—particularly between dentin condition and sealing strategy, and between aging time and treatment—were statistically significant (p < 0.001). Overall, bond strength was higher at 24 h than after 6 months. IDS showed optimal performance in sound dentin, while DDS resulted in better long-term outcomes in demineralized dentin. Conclusions: These findings suggest that DDS may be the more effective approach in cases of carious or demineralized dentin. Full article
(This article belongs to the Section Restorative Dentistry and Traumatology)
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11 pages, 1709 KiB  
Article
Beam Profile Prediction of High-Repetition-Rate SBS Pulse Compression Using Convolutional Neural Networks
by Hongli Wang, Chaoshuai Liu, Panpan Yan and Qinglin Niu
Photonics 2025, 12(8), 784; https://doi.org/10.3390/photonics12080784 - 4 Aug 2025
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Abstract
Fast prediction of beam quality in SBS pulse compression for high-repetition-rate operation is urgently important for SBS experimental parameter acquisition. In this study, a fast computational prediction model for SBS beam profiles is developed using a convolutional neural network (CNN) method, which is [...] Read more.
Fast prediction of beam quality in SBS pulse compression for high-repetition-rate operation is urgently important for SBS experimental parameter acquisition. In this study, a fast computational prediction model for SBS beam profiles is developed using a convolutional neural network (CNN) method, which is trained and validated using experimental data from SBS pulse compression experiments. The CNN method can predict beam spot images for experimental conditions in the range of 100–500 Hz repetition rates and 5–40 mJ injection energy. The proposed CNN-based SBS beam profile prediction model has a fast convergence of the loss function and an average error of 15% with respect to the experimental results, indicating a high accuracy of the model. The CNN-based prediction model achieves an average error of 11.8% for beam profile prediction across various experimental conditions, demonstrating its potential for SBS beam profile characterization. The CNN method could provide a fast means for predicting the characteristic law of the beam intensity distribution in high-repetition-rate SBS pulse compression systems. Full article
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Article
The Pulmonary Manifestation of Mastocytosis: Experiences of the National Reference Centre of Excellence
by Marlena Sztormowska, Aleksandra Górska, Maciej Piskunowicz, Lucyna Górska, Wojciech Nazar, Marta Chełmińska, Krzysztof Kuziemski, Ewa Jassem and Marek Niedoszytko
J. Clin. Med. 2025, 14(15), 5455; https://doi.org/10.3390/jcm14155455 - 3 Aug 2025
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Abstract
Background: Patients with mastocytosis may present with exacerbated respiratory symptoms and lung diseases resulting from mast cell mediator release. However, their prevalence and severity level remain under debate. The study aims to analyze the prevalence of respiratory symptoms and the usefulness of lung [...] Read more.
Background: Patients with mastocytosis may present with exacerbated respiratory symptoms and lung diseases resulting from mast cell mediator release. However, their prevalence and severity level remain under debate. The study aims to analyze the prevalence of respiratory symptoms and the usefulness of lung function tests like spirometry, diffusing capacity of the lung for carbon monoxide (DLCO), and high-resolution computed tomography (HRCT) of the chest in mastocytosis patients presenting with dyspnea, cough, and exercise intolerance. Methods: We included 104 patients with mastocytosis and 71 healthy controls. Data collection encompassed patient interview, clinical examination, spirometry, DLCO, and chest HRCT. Diagnosis of mastocytosis included bone marrow biopsies and serum tryptase measurements. Results: Compared to controls, patients with mastocytosis exhibited significantly lower values in FEV1/VC ratio, absolute DLCO/VA, predicted DLCO/VA, absolute DLCOcSB, and predicted DLCOcSB (p < 0.001). Commonly reported respiratory symptoms included dyspnea (36.5%), chest tightness (22.1%), and wheezing (9.6%). Airway obstruction was identified in 7.7% of patients; however, it appeared to be independent of the mastocytosis subtype. A decreased DLCO/VA ratio was observed in 4.8% of patients, but HRCT did not reveal any evidence of underlying lung disease. Conclusions: Mastocytosis appears to be a risk factor for the occurrence and exacerbation of respiratory symptoms. However, airway obstruction and impairment of the alveolar–capillary membrane seem to occur independently of the clinical subtype of mastocytosis. Additionally, the causal relationship between pulmonary involvement, mast cell infiltration of the alveolar–capillary membrane, and the systemic circulation of mast cell mediators remains unclear and requires further research. Full article
(This article belongs to the Section Respiratory Medicine)
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