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Keywords = CO2-storage

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15 pages, 882 KiB  
Article
Effects of Modified Atmosphere Packaging on Postharvest Physiology and Quality of ‘Meizao’ Sweet Cherry (Prunus avium L.)
by Jianchao Cui, Xiaohui Jia, Wenhui Wang, Liying Fan, Wenshi Zhao, Limin He and Haijiao Xu
Agronomy 2025, 15(8), 1774; https://doi.org/10.3390/agronomy15081774 - 24 Jul 2025
Abstract
Sweet cherry (Prunus avium L.) is becoming increasingly popular in China, but its postharvest quality deteriorates significantly during harvest storage and transport. Here, we investigated the efficiency of different modified atmosphere packaging (MAP) treatments on the quality and physiology of ‘Meizao’ sweet [...] Read more.
Sweet cherry (Prunus avium L.) is becoming increasingly popular in China, but its postharvest quality deteriorates significantly during harvest storage and transport. Here, we investigated the efficiency of different modified atmosphere packaging (MAP) treatments on the quality and physiology of ‘Meizao’ sweet cherry during 60 days of cold storage (0 ± 0.5 °C). Fruits were sealed in four types of MAP low-density polyethylene (LDPE) liners (PE20, PE30, PE40, and PE50), with unsealed 20 μm LDPE packaging bags used as the control. Our findings demonstrated that PE30 packaging established an optimal gas composition (7.0~7.7% O2 and 3.6~3.9% CO2) that effectively preserved ‘Meizao’ sweet cherry quality. It maintained the fruit color, firmness, soluble solid content (SSC), titratable acidity (TA), and vitamin C (Vc) content while simultaneously delaying deteriorative processes such as weight loss, pedicel browning, and fruit decay. These results indicate that PE30 was the most suitable treatment for preserving the quality of ‘Meizao’ sweet cherries during cold storage. Furthermore, physiological research showed that significant inhibition of respiration rate was achieved by PE30, accompanied by maintained activities of antioxidant enzymes (CAT, POD, and SOD), which consequently led to reduced accumulations of ethanol and malondialdehyde (MDA) during cold storage. To date, no systematic studies have investigated the physiological and biochemical responses of ‘Meizao’ to different thickness-dependent LDPE-MAP conditions. These observations highlight the power of the optimized PE30 packaging as an effective method for extending the fruit storage life, delaying postharvest senescence, and maintaining fruit quality of ‘Meizao’ sweet cherry. Full article
(This article belongs to the Section Horticultural and Floricultural Crops)
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13 pages, 2088 KiB  
Article
Assessment of Effects of Storage Time on Fermentation Profile, Chemical Composition, Bacterial Community Structure, Co-Occurrence Network, and Pathogenic Risk in Corn Stover Silage
by Zhumei Du, Ying Meng, Yifan Chen, Shaojuan Cui, Siran Wang and Xuebing Yan
Fermentation 2025, 11(8), 425; https://doi.org/10.3390/fermentation11080425 - 23 Jul 2025
Abstract
In order to achieve the efficient utilization of agricultural by-products and overcome the bottleneck of animal feed shortages in dry seasons, this study utilized corn stover (CS; Zea mays L.) as a material to systematically investigate the dynamic changes in the fermentation quality, [...] Read more.
In order to achieve the efficient utilization of agricultural by-products and overcome the bottleneck of animal feed shortages in dry seasons, this study utilized corn stover (CS; Zea mays L.) as a material to systematically investigate the dynamic changes in the fermentation quality, bacterial community structure, and pathogenic risk of silage under different fermentation times (0, 3, 7, 15, and 30 days). CS has high nutritive value, including crude protein and sugar, and can serve as a carbon source and a nitrogen source for silage fermentation. After ensiling, CS silage (CSTS) exhibited excellent fermentation quality, characterized by relatively high lactic acid content, low pH, and ammonia nitrogen content within an acceptable range. In addition, neither propionic acid nor butyric acid was detected in any of the silages. CS exhibited high α-diversity, with Serratia marcescens being the dominant bacterial species. After ensiling, the α-diversity significantly (p < 0.05) decreased, and Lactiplantibacillus plantarum was the dominant species during the fermentation process. With the extension of fermentation days, the relative abundance of Lactiplantibacillus plantarum significantly (p < 0.05) increased, reaching a peak and stabilizing between 15 and 30 days. Ultimately, lactic acid bacteria dominated and constructed a microbial symbiotic network system. In the bacterial community of CSTS, the abundance of “potential pathogens” was significantly (p < 0.01) lower than that of CS. These results provide data support for establishing a microbial regulation theory for silage fermentation, thereby improving the basic research system for the biological conversion of agricultural by-products and alleviating feed shortages in dry seasons. Full article
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20 pages, 2546 KiB  
Article
Positive Relationships Between Soil Organic Carbon and Tree Physical Structure Highlights Significant Carbon Co-Benefits of Beijing’s Urban Forests
by Rentian Xie, Syed M. H. Shah, Chengyang Xu, Xianwen Li, Suyan Li and Bingqian Ma
Forests 2025, 16(8), 1206; https://doi.org/10.3390/f16081206 - 22 Jul 2025
Abstract
Increasing soil carbon storage is an important strategy for achieving sustainable development. Enhancing soil carbon sequestration capacity can effectively reduce the concentration of atmospheric carbon dioxide, which not only contributes to the carbon neutrality goal but also helps maintain ecosystem stability. Based on [...] Read more.
Increasing soil carbon storage is an important strategy for achieving sustainable development. Enhancing soil carbon sequestration capacity can effectively reduce the concentration of atmospheric carbon dioxide, which not only contributes to the carbon neutrality goal but also helps maintain ecosystem stability. Based on 146 soil samples collected at plot locations selected across Beijing, we examined relationships between soil organic carbon (SOC) and key characteristics of urban forests, including their spatial structure and species complexity. The results showed that SOC in the topsoil with a depth of 20 cm was highest over forested plots (6.384 g/kg–20.349 g/kg) and lowest in soils without any vegetation cover (5.586 g/kg–6.783 g/kg). The plots with herbaceous/shrub vegetation but no tree cover had SOC values in between (5.586 g/kg–15.162 g/kg). The plot data revealed that SOC was better correlated with the physical structure than the species diversity of Beijing’s urban trees. The correlation coefficients (r) between SOC and five physical structure indicators, including average diameter at breast height (DBH), average tree height, basal area density, and the diversity of DBH and tree height, ranged from 0.32 to 0.52, whereas the r values for four species diversity indicators ranged from 0.10 to 0.25, two of which were not statistically different from 0. Stepwise linear regression analyses revealed that the species diversity indicators were not very sensitive to SOC variations among a large portion of the plots and were about half as effective as the physical structure indicators for explaining the total variance of SOC. These results suggest that urban planning and greenspace management policies could be tailored to maximize the carbon co-benefits of urban land. Specifically, trees should be planted in urban areas wherever possible, preferably as densely as what can be allowed given other urban planning considerations. Protection of large, old trees should be encouraged, as these trees will continue to sequester and store large quantities of carbon in above- and belowground biomass as well as in soil. Such policies will enhance the contribution of urban land, especially urban forests and other greenspaces, to nature-based solutions (NBS) to climate change. Full article
(This article belongs to the Special Issue Ecosystem Services of Urban Forest)
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23 pages, 6480 KiB  
Article
Mechanism Analysis and Evaluation of Formation Physical Property Damage in CO2 Flooding in Tight Sandstone Reservoirs of Ordos Basin, China
by Qinghua Shang, Yuxia Wang, Dengfeng Wei and Longlong Chen
Processes 2025, 13(7), 2320; https://doi.org/10.3390/pr13072320 - 21 Jul 2025
Viewed by 272
Abstract
Capturing CO2 emitted by coal chemical enterprises and injecting it into oil reservoirs not only effectively improves the recovery rate and development efficiency of tight oil reservoirs in the Ordos Basin but also addresses the carbon emission problem constraining the development of [...] Read more.
Capturing CO2 emitted by coal chemical enterprises and injecting it into oil reservoirs not only effectively improves the recovery rate and development efficiency of tight oil reservoirs in the Ordos Basin but also addresses the carbon emission problem constraining the development of the region. Since initiating field experiments in 2012, the Ordos Basin has become a significant base for CCUS (Carbon capture, Utilization, and Storage) technology application and demonstration in China. However, over the years, projects have primarily focused on enhancing the recovery rate of CO2 flooding, while issues such as potential reservoir damage and its extent have received insufficient attention. This oversight hinder the long-term development and promotion of CO2 flooding technology in the region. Experimental results were comprehensively analyzed using techniques including nuclear magnetic resonance (NMR), X-ray diffraction (XRD), scanning electron microscopy (SEM), inductively coupled plasma (ICP), and ion chromography (IG). The findings indicate that under current reservoir temperature and pressure conditions, significant asphaltene deposition and calcium carbonate precipitation do not occur during CO2 flooding. The reservoir’s characteristics-high feldspar content, low carbon mineral content, and low clay mineral content determine that the primary mechanism affecting physical properties under CO2 flooding in the Chang 4 + 5 tight sandstone reservoir is not, as traditional understand, carbon mineral dissolution or primary clay mineral expansion and migration. Instead, feldspar corrosion and secondary particles migration are the fundamental reasons for the changes in reservoir properties. As permeability increases, micro pore blockage decreases, and the damaging effect of CO2 flooding on reservoir permeability diminishes. Permeability and micro pore structure are therefore significant factors determining the damage degree of CO2 flooding inflicts on tight reservoirs. In addition, temperature and pressure have a significant impact on the extent of reservoir damage caused by CO2 flooding in the study region. At a given reservoir temperature, increasing CO2 injection pressure can mitigate reservoir damage. It is recommended to avoid conducting CO2 flooding projects in reservoirs with severe pressure attenuation, low permeability, and narrow pore throats as much as possible to prevent serious damage to the reservoir. At the same time, the production pressure difference should be reasonably controlled during the production process to reduce the risk and degree of calcium carbonate precipitation near oil production wells. Full article
(This article belongs to the Section Energy Systems)
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27 pages, 2736 KiB  
Article
Estimation of Tree Diameter at Breast Height (DBH) and Biomass from Allometric Models Using LiDAR Data: A Case of the Lake Broadwater Forest in Southeast Queensland, Australia
by Zibonele Mhlaba Bhebhe, Xiaoye Liu, Zhenyu Zhang and Dev Raj Paudyal
Remote Sens. 2025, 17(14), 2523; https://doi.org/10.3390/rs17142523 - 20 Jul 2025
Viewed by 332
Abstract
Light Detection and Ranging (LiDAR) provides three-dimensional information that can be used to extract tree parameter measurements such as height (H), canopy volume (CV), canopy diameter (CD), canopy area (CA), and tree stand density. LiDAR data does not directly give diameter at breast [...] Read more.
Light Detection and Ranging (LiDAR) provides three-dimensional information that can be used to extract tree parameter measurements such as height (H), canopy volume (CV), canopy diameter (CD), canopy area (CA), and tree stand density. LiDAR data does not directly give diameter at breast height (DBH), an important input into allometric equations to estimate biomass. The main objective of this study is to estimate tree DBH using existing allometric models. Specifically, it compares three global DBH pantropical models to calculate DBH and to estimate the aboveground biomass (AGB) of the Lake Broadwater Forest located in Southeast (SE) Queensland, Australia. LiDAR data collected in mid-2022 was used to test these models, with field validation data collected at the beginning of 2024. The three DBH estimation models—the Jucker model, Gonzalez-Benecke model 1, and Gonzalez-Benecke model 2—all used tree H, and the Jucker and Gonzalez-Benecke model 2 additionally used CD and CA, respectively. Model performance was assessed using five statistical metrics: root mean squared error (RMSE), mean absolute error (MAE), mean absolute percentage error (MAPE), percentage bias (MBias), and the coefficient of determination (R2). The Jucker model was the best-performing model, followed by Gonzalez-Benecke model 2 and Gonzalez-Benecke model 1. The Jucker model had an RMSE of 8.7 cm, an MAE of −13.54 cm, an MAPE of 7%, an MBias of 13.73 cm, and an R2 of 0.9005. The Chave AGB model was used to estimate the AGB at the tree, plot, and per hectare levels using the Jucker model-calculated DBH and the field-measured DBH. AGB was used to estimate total biomass, dry weight, carbon (C), and carbon dioxide (CO2) sequestered per hectare. The Lake Broadwater Forest was estimated to have an AGB of 161.5 Mg/ha in 2022, a Total C of 65.6 Mg/ha, and a CO2 sequestered of 240.7 Mg/ha in 2022. These findings highlight the substantial carbon storage potential of the Lake Broadwater Forest, reinforcing the opportunity for landholders to participate in the carbon credit systems, which offer financial benefits and enable contributions to carbon mitigation programs, thereby helping to meet national and global carbon reduction targets. Full article
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25 pages, 1661 KiB  
Article
The Public Acceptance of Power-to-X Technologies—Results from Environmental–Psychological Research Using a Representative German Sample
by Jan Hildebrand, Timo Kortsch and Irina Rau
Sustainability 2025, 17(14), 6574; https://doi.org/10.3390/su17146574 - 18 Jul 2025
Viewed by 259
Abstract
Power-to-X (ptx) technologies are considered a promising solution for enabling the storage and sectoral integration of renewable energy, playing a vital role in the sustainable transition of industrialized energy systems. This study investigates the public acceptance of ptx technologies in Germany using a [...] Read more.
Power-to-X (ptx) technologies are considered a promising solution for enabling the storage and sectoral integration of renewable energy, playing a vital role in the sustainable transition of industrialized energy systems. This study investigates the public acceptance of ptx technologies in Germany using a quantitative, environmental–psychological framework. Key influencing factors such as social and personal norms, environmental awareness, and openness to innovation are analyzed. A particular focus is placed on generational differences, comparing the perceptions of youth (16–25 years) and adults (>25 years) through a representative online survey. The results reveal a general lack of knowledge about ptx technologies yet a positive assessment of their decarbonization potential. Ecological impact—particularly the ability to reduce CO2 emissions—emerges as the strongest predictor of acceptance. This is closely tied to conditions such as the use of renewable electricity and sustainable sourcing of carbon and water. Notably, acceptance among youth is also influenced by environmental awareness, prior knowledge, and perceived behavioral control. The results show that, in general, there is still a need for improved science communication to address the existing uncertainties in the population. At the same time, age-specific approaches are required, as perceptions and acceptance factors differ significantly between younger and older age groups. Full article
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18 pages, 9956 KiB  
Article
Hydrogen Storage Vessel for a Proton-Exchange Membrane (PEM) Fuel Cell Auxiliary Power Unit for Commercial Aircraft
by Anto Nickhil Antony Ramesh, Aliyu M. Aliyu, Nick Tucker and Ibrahim M. Albayati
Appl. Sci. 2025, 15(14), 8006; https://doi.org/10.3390/app15148006 - 18 Jul 2025
Viewed by 169
Abstract
Approximately 20% of emissions from air travel are attributed to the auxiliary power units (APUs) carried in commercial aircraft. This paper proposes to reduce greenhouse gas emissions in international air transport by adopting proton-exchange membrane (PEM) fuel cells to replace APUs in commercial [...] Read more.
Approximately 20% of emissions from air travel are attributed to the auxiliary power units (APUs) carried in commercial aircraft. This paper proposes to reduce greenhouse gas emissions in international air transport by adopting proton-exchange membrane (PEM) fuel cells to replace APUs in commercial aircraft: we consider the design of three compressed hydrogen storage vessels made of 304 stainless steel, 6061-T6 aluminium, and Grade 5 (Ti-6Al-4V) titanium and capable of delivering 440 kW—enough for a PEM fuel cell for a Boeing 777. Complete structural analyses for pressures from 35 MPa to 70 MPa and wall thicknesses of 25, 50, 100, and 150 mm are used to determine the optimal material for aviation applications. Key factors such as deformation, safety factors, and Von Mises equivalent stress are evaluated to ensure structural integrity under a range of operating conditions. In addition, CO2 emissions from a conventional 440 kW gas turbine APU and an equivalent PEM fuel cell are compared. This study provides insights into optimal material selection for compressed hydrogen storage vessels, emphasising safety, reliability, cost, and weight reduction. Ultimately, this research aims to facilitate the adoption of fuel cell technology in aviation, contributing to greenhouse emissions reduction and hence sustainable air transport. Full article
(This article belongs to the Section Transportation and Future Mobility)
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17 pages, 2166 KiB  
Article
Effects of Fertilizer Application on Growth and Stoichiometric Characteristics of Nitrogen, Phosphorus, and Potassium in Balsa Tree (Ochroma lagopus) Plantations at Different Slope Positions
by Jialan Chen, Weisong Zhu, Yuanxi Liu, Gang Chen, Juncheng Han, Wenhao Zhang and Junwen Wu
Plants 2025, 14(14), 2221; https://doi.org/10.3390/plants14142221 - 18 Jul 2025
Viewed by 186
Abstract
Ochroma lagopus, a fast-growing tropical tree species, faces fertilization challenges due to slope heterogeneity in plantations. This study examined 3-year-old Ochroma lagopus at upper and lower slope positions under five treatments: CK (no fertilizer), F1 (600 g/plant), F2 (800 g/plant), F3 (1000 [...] Read more.
Ochroma lagopus, a fast-growing tropical tree species, faces fertilization challenges due to slope heterogeneity in plantations. This study examined 3-year-old Ochroma lagopus at upper and lower slope positions under five treatments: CK (no fertilizer), F1 (600 g/plant), F2 (800 g/plant), F3 (1000 g/plant), and F4 (1200 g/plant) of secondary macronutrient water-soluble fertilizer. Growth parameters and N-P-K stoichiometry were analyzed. Key results: (1) Height increased continuously with fertilizer dosage at both slopes, while DBH peaked and then declined. (2) At upper slopes (nutrient-poor soil), fertilization elevated leaf P but reduced branch N/K and increased root P/K. At lower slopes (nutrient-rich soil), late-stage leaf N increased significantly, with roots accumulating P/K via a “storage strategy”. Stoichiometric thresholds indicated N-K co-limitation (early-mid stage) shifting to P limitation (late stage) on upper slopes and persistent N-K co-limitation on lower slopes. (3) PCA identified F4 (1200 g/plant) and F1 (600 g/plant) as optimal for upper and lower slopes, respectively. This research provides a theoretical basis for precision fertilization in Ochroma lagopus plantations, emphasizing slope-specific nutrient status and element interactions for dosage optimization. Full article
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23 pages, 6606 KiB  
Article
Clove Oil-Based Nanoemulsion Containing Amphotericin B as a Therapeutic Approach to Combat Fungal Infections
by Marcel Lucas de Almeida, Ana Paula dos Santos Matos, Veronica da Silva Cardoso, Tatielle do Nascimento, Ralph Santos-Oliveira, Leandro Machado Rocha, Francisco Paiva Machado, Franklin Chimaobi Kenechukwu, Alane Beatriz Vermelho and Eduardo Ricci-Júnior
Pharmaceutics 2025, 17(7), 925; https://doi.org/10.3390/pharmaceutics17070925 - 17 Jul 2025
Viewed by 273
Abstract
Background/Objectives: Candidiasis, primarily caused by Candida albicans, and sporotrichosis, mainly caused by Sporothrix schenckii, are skin fungal infections that pose serious threats to global health. The Candida auris is a great concern in immunocompromised individuals, and while Sporothrix brasiliensis cause sporotrichosis, [...] Read more.
Background/Objectives: Candidiasis, primarily caused by Candida albicans, and sporotrichosis, mainly caused by Sporothrix schenckii, are skin fungal infections that pose serious threats to global health. The Candida auris is a great concern in immunocompromised individuals, and while Sporothrix brasiliensis cause sporotrichosis, an infection commonly found in cats, this disease can be transmitted to humans through scratches or bites. Existing treatments for these fungal infections often cause problems related to resistance and significant side effects. Consequently, development of alternative therapeutic approaches such as nanotechnology-based topical lipid-based formulations is interesting. Thus, the objectives of this study were to prepare clove oil (CO)-in-water nanoemulsions (NEs) containing amphotericin B (AmB) and characterize them with respect to stability, release profile, and in vitro cytotoxic activity against Candida and Sporothrix strains. As a future alternative for the treatment of fungal skin diseases. Methods: Chemical analysis of clove oil was obtained by GC-MS. The NEs were produced using an ultrasound (sonicator) method with varying proportions of CO, Pluronic® F-127, and AmB. The NEs were characterized by droplet size, morphology, stability and in vitro release profile. The antifungal and cytotoxic activity against C. albicans, C. auris, S. schenckii, and S. brasiliensis were ascertained employing agar diffusion and colorimetric MTT assay methods. A checkerboard assay was carried out using clove oil and amphotericin B against C. auris. Results: Eugenol was the major compound identified in CO at a concentration of 80.09%. AmB-loaded NEs exhibited particle sizes smaller than 50 nm and a polydispersity index below 0.25. The optimal Ne (NEMLB-05) remained stable after 150 days of storage at 4 °C. It exhibited rapid release within the first 24 h, followed by a slow and controlled release up to 96 h. NEMLB-05 more effectively inhibited C. auris compared to free AmB and also demonstrated greater activity against C. albicans, S. schenckii, and S. brasiliensis. Clove oil and amphotericin B presented synergism inhibiting the growth of C. auris. Conclusions: The selected CO-in-water NEs containing AmB demonstrated promising potential as a topical therapeutic alternative for treating fungal infections. Full article
(This article belongs to the Special Issue Nanotechnology in the Treatment of Neglected Parasitic Diseases)
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23 pages, 3031 KiB  
Article
Climbing the Pyramid: From Regional to Local Assessments of CO2 Storage Capacities in Deep Saline Aquifers of the Drava Basin, Pannonian Basin System
by Iva Kolenković Močilac, Marko Cvetković, David Rukavina, Ana Kamenski, Marija Pejić and Bruno Saftić
Energies 2025, 18(14), 3800; https://doi.org/10.3390/en18143800 - 17 Jul 2025
Viewed by 112
Abstract
Deep saline aquifers in the eastern part of Drava Basin were screened for potential storage sites. The input dataset included three seismic volumes, a rather extensive set of old seismic sections and 71 wells. Out of all identified potential storage objects, only two [...] Read more.
Deep saline aquifers in the eastern part of Drava Basin were screened for potential storage sites. The input dataset included three seismic volumes, a rather extensive set of old seismic sections and 71 wells. Out of all identified potential storage objects, only two sites were found to be situated in the favorable geological settings, meaning that the inspected wells drilled through structural traps had a seal at least 20 m thick which was intersected by only a few faults with rather limited displacement. Many more closed structures in the area were tested by exploration wells, but in all other wells, various problems were encountered, including inadequate reservoir properties, inadequate seal or inadequate depth of the identified trap. Analysis was highly affected by the insufficient quality and spatial distribution of the seismic input data, as well as in places with insufficient quality of input well datasets. An initial characterization of identified storage sites was performed, and their attributes were compared, with potential storage object B recognized as the one that should be further developed. However, given the depth and increased geothermal gradient of the potential storage object B, it is possible that it will be developed as a geothermal reservoir, and this brings forward the problem of concurrent subsurface use. Full article
(This article belongs to the Collection Feature Papers in Carbon Capture, Utilization, and Storage)
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35 pages, 2895 KiB  
Review
Ventilated Facades for Low-Carbon Buildings: A Review
by Pinar Mert Cuce and Erdem Cuce
Processes 2025, 13(7), 2275; https://doi.org/10.3390/pr13072275 - 17 Jul 2025
Viewed by 410
Abstract
The construction sector presently consumes about 40% of global energy and generates 36% of CO2 emissions, making facade retrofits a priority for decarbonising buildings. This review clarifies how ventilated facades (VFs), wall assemblies that interpose a ventilated air cavity between outer cladding [...] Read more.
The construction sector presently consumes about 40% of global energy and generates 36% of CO2 emissions, making facade retrofits a priority for decarbonising buildings. This review clarifies how ventilated facades (VFs), wall assemblies that interpose a ventilated air cavity between outer cladding and the insulated structure, address that challenge. First, the paper categorises VFs by structural configuration, ventilation strategy and functional control into four principal families: double-skin, rainscreen, hybrid/adaptive and active–passive systems, with further extensions such as BIPV, PCM and green-wall integrations that couple energy generation or storage with envelope performance. Heat-transfer analysis shows that the cavity interrupts conductive paths, promotes buoyancy- or wind-driven convection, and curtails radiative exchange. Key design parameters, including cavity depth, vent-area ratio, airflow velocity and surface emissivity, govern this balance, while hybrid ventilation offers the most excellent peak-load mitigation with modest energy input. A synthesis of simulation and field studies indicates that properly detailed VFs reduce envelope cooling loads by 20–55% across diverse climates and cut winter heating demand by 10–20% when vents are seasonally managed or coupled with heat-recovery devices. These thermal benefits translate into steadier interior surface temperatures, lower radiant asymmetry and fewer drafts, thereby expanding the hours occupants remain within comfort bands without mechanical conditioning. Climate-responsive guidance emerges in tropical and arid regions, favouring highly ventilated, low-absorptance cladding; temperate and continental zones gain from adaptive vents, movable insulation or PCM layers; multi-skin adaptive facades promise balanced year-round savings by re-configuring in real time. Overall, the review demonstrates that VFs constitute a versatile, passive-plus platform for low-carbon buildings, simultaneously enhancing energy efficiency, durability and indoor comfort. Future advances in smart controls, bio-based materials and integrated energy-recovery systems are poised to unlock further performance gains and accelerate the sector’s transition to net-zero. Emerging multifunctional materials such as phase-change composites, nanostructured coatings, and perovskite-integrated systems also show promise in enhancing facade adaptability and energy responsiveness. Full article
(This article belongs to the Special Issue Sustainable Development of Energy and Environment in Buildings)
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21 pages, 1897 KiB  
Article
Simulation of Conventional WWTPs Acting as Mediators in H2/CO2 Conversion into Methane
by Rubén González and Xiomar Gómez
Environments 2025, 12(7), 245; https://doi.org/10.3390/environments12070245 - 16 Jul 2025
Viewed by 303
Abstract
CO2-biomethanation was studied in the present manuscript by considering the direct injection of hydrogen into a conventional anaerobic digester treating sewage sludge within a simulated wastewater treatment plant (WWTP). The plant was simulated using the Python 3.12.4 software, and a Monte [...] Read more.
CO2-biomethanation was studied in the present manuscript by considering the direct injection of hydrogen into a conventional anaerobic digester treating sewage sludge within a simulated wastewater treatment plant (WWTP). The plant was simulated using the Python 3.12.4 software, and a Monte Carlo simulation was conducted to account for the high variability in the organic content of the wastewater and the methane potential of the sludge. Two modes of operation were studied. The first mode involves the use of an anaerobic digester to upgrade biogas, and the second mode considers using the digester as a CO2 utilization unit, transforming captured CO2. Upgrading biogas and utilizing the extra methane to generate electricity within the same plant leads to a negative economic balance (first scenario). A hydrogen injection of 1 L of H2/Lr d (volumetric H2 injection per liter of reactor per day) was required to transform the CO2 present in the biogas into methane. The benefits associated with this approach resulted in lower savings regarding heat recovery from the electrolyzer, increased electricity production, and an additional oxygen supply for the waste-activated sludge treatment system. Increasing the injection rate to values of 5 and 30 L of H2/Lr d was also studied by considering the operation of the digester under thermophilic conditions. The latter assumptions benefited from the better economy of scale associated with larger installations. They allowed for enough savings to be obtained in terms of the fuel demand for sludge drying, in addition to the previous categories analyzed in the biogas upgrading case. However, the current electricity price makes the proposal unfeasible unless a lower price is set for hydrogen generation. A standard electricity price of 7.6 c€/kWh was assumed for the analysis, but the specific operation of producing hydrogen required a price below 3.0 c€/kWh to achieve profitability. Full article
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15 pages, 4059 KiB  
Article
Surface Fluorination for the Stabilization in Air of Garnet-Type Oxide Solid Electrolyte for Lithium Ion Battery
by Michael Herraiz, Saida Moumen, Kevin Lemoine, Laurent Jouffret, Katia Guérin, Elodie Petit, Nathalie Gaillard, Laure Bertry, Reka Toth, Thierry Le Mercier, Valérie Buissette and Marc Dubois
Batteries 2025, 11(7), 268; https://doi.org/10.3390/batteries11070268 - 16 Jul 2025
Viewed by 160
Abstract
After reviewing the state of the art of the fluorination of inorganic solid electrolytes, an application of gas/solid fluorination is given and how it can be processed. Garnet-type oxide has been chosen. These oxides with an ideal structure of chemical formula A3 [...] Read more.
After reviewing the state of the art of the fluorination of inorganic solid electrolytes, an application of gas/solid fluorination is given and how it can be processed. Garnet-type oxide has been chosen. These oxides with an ideal structure of chemical formula A3B2(XO4)3 are mainly known for their magnetic and dielectric properties. Certain garnets may have a high enough Li+ ionic conductivity to be used as solid electrolyte of lithium ion battery. The surface of LLZO may be changed in contact with the moisture and CO2 present in the atmosphere that results in a change of the conductivity at the interface of the solid. LiOH and/or lithium carbonate are formed at the surface of the garnet particles. In order to allow for handling and storage under normal conditions of this solid electrolyte, surface fluorination was performed using elemental fluorine. When controlled using mild conditions (temperature lower or equal to 200 °C, either in static or dynamic mode), the addition of fluorine atoms to LLZO with Li6,4Al0,2La3Zr2O12 composition is limited to the surface, forming a covering layer of lithium fluoride LiF. The effect of the fluorination was evidenced by IR, Raman, and NMR spectroscopies. If present in the pristine LLZO powder, then the carbonate groups disappear. More interestingly, contrary to the pristine LLZO, the contents of these groups are drastically reduced even after storage in air up to 45 days when the powder is covered with the LiF layer. Surface fluorination could be applied to other solid electrolytes that are air sensitive. Full article
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28 pages, 5586 KiB  
Article
Vertical Equilibrium Model Analysis for CO2 Storage
by Mohammadsajjad Zeynolabedini and Ashkan Jahanbani Ghahfarokhi
Gases 2025, 5(3), 16; https://doi.org/10.3390/gases5030016 - 16 Jul 2025
Viewed by 162
Abstract
This work uses the MATLAB Reservoir Simulation Toolbox (MRST) to reduce the 3D reservoir model into a 2D version in order to investigate CO2 storage in the Aurora model using the vertical equilibrium (VE) model. For this purpose, we used an open-source [...] Read more.
This work uses the MATLAB Reservoir Simulation Toolbox (MRST) to reduce the 3D reservoir model into a 2D version in order to investigate CO2 storage in the Aurora model using the vertical equilibrium (VE) model. For this purpose, we used an open-source reservoir simulator, MATLAB Reservoir Simulation Toolbox (MRST). MRST is an open-source reservoir simulator, with supplementary modules added to enhance its versatility in addition to a core set of procedures. A fully implicit discretization is used in the numerical formulation of MRST-co2lab enabling the integration of simulators with vertical equilibrium (VE) models to create hybrid models. This model is then compared with the Eclipse model in terms of properties and simulation results. The relative permeability of water and gas can be compared to verify that the model fits the original Eclipse model. Comparing the fluid viscosities used in MRST and Eclipse also reveals comparable tendencies. However, reservoir heterogeneity is the reason for variations in CO2 plume morphologies. The upper layers of the Eclipse model have lower permeability than the averaged MRST model, which has a substantial impact on CO2 transport. According to the study, after 530 years, about 17 MT of CO2 might be stored, whereas 28 MT might escape the reservoir, since after 530 years CO2 plume reaches completely the open northern boundary. Additionally, a sensitivity analysis study has been conducted on permeability, porosity, residual gas saturation, rock compressibility, and relative permeability curves which are the five uncertain factors in this model. Although plume migration is highly sensitive to permeability, porosity, and rock compressibility variation, it shows a slight change with residual gas saturation and relative permeability curve in this study. Full article
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37 pages, 2969 KiB  
Review
Carbon Aerogels: Synthesis, Modification, and Multifunctional Applications
by Liying Li, Guiyu Jin, Jian Shen, Mengyan Guo, Jiacheng Song, Yiming Li and Jian Xiong
Gels 2025, 11(7), 548; https://doi.org/10.3390/gels11070548 - 15 Jul 2025
Viewed by 392
Abstract
Amidst global imperatives for sustainable energy and environmental remediation, carbon aerogels (CAs) present a transformative alternative to conventional carbon materials (e.g., activated carbon, carbon fibers), overcoming limitations of disordered pore structures, unmodifiable surface chemistry, and functional inflexibility. This review systematically examines CA-based electrochemical [...] Read more.
Amidst global imperatives for sustainable energy and environmental remediation, carbon aerogels (CAs) present a transformative alternative to conventional carbon materials (e.g., activated carbon, carbon fibers), overcoming limitations of disordered pore structures, unmodifiable surface chemistry, and functional inflexibility. This review systematically examines CA-based electrochemical systems as its primary focus, analyzing fundamental charge-storage mechanisms and establishing structure–property–application relationships critical to energy storage performance. We critically assess synthesis methodologies, emphasizing how stage-specific parameters govern structural/functional traits, and detail multifunctional modification strategies (e.g., heteroatom doping, composite engineering) that enhance electrochemical behavior through pore architecture optimization, surface chemistry tuning, and charge-transfer kinetics acceleration. Electrochemical applications are extensively explored, including the following: 1. Energy storage: supercapacitors (dual EDLC/pseudocapacitive mechanisms) and battery hybrids. 2. Electrocatalysis: HER, OER, ORR, and CO2 reduction reaction (CO2RR). 3. Electrochemical processing: capacitive deionization (CDI) and electrosorption. Beyond this core scope, we briefly acknowledge CA versatility in ancillary domains: environmental remediation (heavy metal removal, oil/water separation), flame retardancy, microwave absorption, and CO2 capture. Full article
(This article belongs to the Section Gel Applications)
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