Search Results (1,573)

Turbot Scophthalmus maximus (Linnaeus, 1758) is one of the most valuable and economically important species for the Black Sea countries. In Bulgaria, their numbers are limited and stocks are depleted; therefore, monitoring development and health status is extremely important. Internal helminths are widespread among turbots on the Bulgarian Black Sea coast. However, description of this infection is relatively limited, and they have not been reported in scientific papers. For this purpose, a total of 36 hauls were made at depths from 15 to 90 m, and 65 turbots were examined for intestinal parasites. The present study represents the first report of internal helminths in turbot from Bulgarian marine waters through the spawning season, characterized morphologically based on a microscope observation and molecular identification. Evaluation of laboratory analyses revealed that two different parasites were determined: Bothriocephalus sp. (Müller, 1776) and Hysterothylacium aduncum (Rudolphi, 1802) and that 73.85% of the turbot were infected with one or more parasites. Based on the results, control measures and treatment for the wild population are unrealistic but should be considered for the containment and spread of diseases in aquaculture facilities. Full article

Background: Compared to the conventional method of machining granite, abrasive water jet machining (AWJM) offers several benefits, including flexible cutting mechanisms and machine efficiency, among other possible advantages. The high-speed particles carried by water remove the materials, preventing heat damage and maintaining the granite’s structure. Methods: Three types of granite with different compressive strengths are investigated in terms of the effects of pump pressure (P), traverse speed (T), and abrasive mass flow (A) on the cutting depth. Results: The results of the study demonstrated that the coarse-grained granite negatively affected the penetration depth, while the fine-grained granite produced a higher cutting depth. The value of an optimal depth of penetration was also generated; for example, the optimum depth obtained for Black Galaxy Granite, M1 (32.27 mm), was achieved at P = 300 MPa, T = 100 mm/min, and A = 180.59 g/min. Conclusions: In terms of processing parameters, the maximum penetration depth can be achieved in granite with a higher compressive strength. Full article

The incorporation of residues into rubber composites has gained attention as a sustainable strategy to address waste management challenges while replacing commercial fillers. In this study, we investigated the potential use of water filter cartridge residue after exhaustion, composed of activated carbon, as a reinforcing filler in vulcanized natural rubber composites. Samples were prepared with 5, 10, 15, and 20 phr (per hundred rubber) of residue and compared to unfilled natural rubber. Stress vs. strain tests reached 13.9 MPa of tension at rupture for composites containing 10 phr of carbon-activated residues, representing a 21.9% increase compared to natural rubber. Interestingly, the tension at rupture for NR/AC_10phr reached values close to those of NR/CB_5phr (with carbon black N330) attaining 14.4 MPa. These results indicate that, even at relatively low concentrations, the carbon filter can offer partial substitution for commercial fillers. Moreover, the use of activated carbon from filter cartridges as filler in rubber composites provides an environmentally favorable alternative to energy-intensive regeneration processes for activated carbon. Full article

Current work investigates the fabrication and performance of nanocomposite membranes, modified with varying concentrations of hybrid nanostructures comprising titanium nanowires coated with iron nanoparticles (TiO₂ NWs-Fe₂O₃), for the removal of Naphthol Blue Black (NBB) dye from industrial wastewater. A series of analytical tools were employed to confirm the successful modification including scanning electron microscopy and EDX analysis, porosity and hydrophilicity measurements, Fourier-transform infrared spectroscopy, and X-Ray Diffraction. The incorporation of TiO₂ NWs-Fe₂O₃ has enhanced membrane performance significantly by increasing the PWF and improving dye retention rates of nanocomposite membranes. At 0.7 g of nanostructure content, the modified membrane (M8) achieved a PWF of 93 L/m²·h and NBB dye rejection of over 98%. The flux recovery ratio (FRR) analysis disclosed improved antifouling properties, with the M8 membrane demonstrating a 73.4% FRR. This study confirms the potential of TiO₂ NWs-Fe₂O₃-modified membranes in enhancing water treatment processes, offering a promising solution for industrial wastewater treatment. These outstanding results highlight the potential of the novel PES-TiO₂ NWs-Fe₂O₃ membranes for dye removal and present adequate guidance for the modification of membrane physical properties in the field of wastewater treatment. Full article

Research on raw materials for Al₂O₃-SiC-C refractory castables used in blast furnace troughs is relatively well established. However, gaps remain in both laboratory and industrial trials concerning the performance of castables incorporating SiC-modified flake graphite and alternative carbon sources. This study investigated the sintering behavior, mechanical properties, and service performance of Al₂O₃-SiC-C castables utilizing varying contents of modified flake graphite, pitch, and carbon black as carbon sources. Samples were characterized using SEM, XRD, and EDS for phase composition and microstructural morphology analysis. Key findings revealed that the thermal expansion mismatch between the SiC coating and flake graphite in SiC-modified graphite generated a microcrack-toughening effect. This effect, combined with the synergistic reinforcement from both components, enhanced the mechanical properties. The SiC modification layer improved the wettability and oxidation resistance of the flake graphite. This modified graphite further contributed to enhanced erosion resistance through mechanisms of matrix pinning and crack deflection within the microstructure. However, the microcracks induced by thermal mismatch concurrently reduced erosion resistance, resulting in an overall limited net improvement in erosion resistance attributable to the modified graphite. Specimens containing 1 wt.% modified flake graphite exhibited the optimal overall performance. During industrial trials, this formulation unexpectedly demonstrated a water reduction mechanism requiring further investigation. Full article

Gully erosion refers to the landform formed by soil and water loss through gully development, which is a critical manifestation of soil degradation. However, research on the spatio-temporal variations in erosion gullies at the county scale remains insufficient, particularly regarding changes in gully aggregation and their driving factors. This study utilized high-resolution remote sensing imagery, gully interpretation information, topographic data, meteorological records, vegetation coverage, soil texture, and land use datasets to analyze the spatio-temporal patterns and influencing factors of erosion gully evolution in Bin County, Heilongjiang Province of China, from 2012 to 2022. Kernel density evaluation (KDE) analysis was also employed to explore these dynamics. The results indicate that the gully number in Bin County has significantly increased over the past decade. Gully development involves not only headward erosion of gully heads but also lateral expansion of gully channels. Gully evolution is most pronounced in slope intervals. While gentle slopes and slope intervals host the highest density of gullies, the aspect does not significantly influence gully development. Vegetation coverage exhibits a clear threshold effect of 0.6 in inhibiting erosion gully formation. Additionally, cultivated areas contain the largest number of gullies and experience the most intense changes; gully aggregation in forested and grassland regions shows an upward trend; the central part of the black soil region has witnessed a marked decrease in gully aggregation; and meadow soil areas exhibit relatively stable spatio-temporal variations in gully distribution. These findings provide valuable data and decision-making support for soil erosion control and transformation efforts. Full article

The rising demand for sustainable protein is driving interest in insects as a raw material for advanced food ingredients. This review collates and critically analyses over 300 studies on the conversion of crickets, mealworms, black soldier flies, and other farmed species into powders, protein isolates, oils, and chitosan-rich fibers with targeted techno-functional roles. This survey maps how thermal pre-treatments, blanch–dry–mill routes, enzymatic hydrolysis, and isoelectric solubilization–precipitation preserve or enhance the water- and oil-holding capacity, emulsification, foaming, and gelation, while also mitigating off-flavors, allergenicity, and microbial risks. A meta-analysis shows insect flours can absorb up to 3.2 g of water g⁻¹, stabilize oil-in-water emulsions for 14 days at 4 °C, and form gels with 180 kPa strength, outperforming or matching eggs, soy, or whey in specific applications. Case studies demonstrate a successful incorporation at 5–15% into bakery, meat analogs and dairy alternatives without sensory penalties, and chitin-derived chitosan films extend the bread shelf life by three days. Comparative life-cycle data indicate 45–80% lower greenhouse gas emissions and land use than equivalent animal-derived ingredients. Collectively, the evidence positions insect-based ingredients as versatile, safe, and climate-smart tools to enhance food quality and sustainability, while outlining research gaps in allergen mitigation, consumer acceptance, and regulatory harmonization. Full article

Objective: To investigate the effects of oat fiber on animal constipation and elucidate its underlying mechanisms. Methods: Male BALB/c mice were randomly allocated into five groups: control group (CON), model control group (MODEL), low dose group (LOW), middle dose group (MIDDLE), high dose group (HIGH). Constipation was induced in the mice by intragastric administration of loperamide. Subsequently, the mice (except those in the CON and MODEL groups) were administered oat fiber intragastrically for 21 consecutive days. Results: Compared with the MODEL group, oat fiber significantly increased the number of fecal pellets, fecal wet weight, and fecal water content (p < 0.05), shortened the time to first black stool excretion (p < 0.05), and enhanced the small intestinal propulsion rate in constipated mice. Additionally, oat fiber significantly upregulated motilin (MTL) and gastrin (GAS) levels (p < 0.05), while downregulating vasoactive intestinal peptide (VIP) and somatostatin (SS) levels (p < 0.05). It also significantly reduced the transcription level of Aquaporin 8 (AQP8) (p < 0.05), effectively alleviating intestinal mucosal injury and immune inflammation. The relative expression levels of TNF-α and IL-1β were significantly decreased in the oat fiber group (p < 0.05). Gut microbiota analysis revealed that oat fiber increased both the abundance and diversity of gut microbiota in constipated mice. Specifically, oat fiber was found to enhance the relative abundance of Firmicutes while reducing that of Bacteroidetes. At the genus level, it promoted the proliferation of Lachnospiraceae_NK4A136_group and Roseburia. Conclusions: Oat fiber alleviates constipation in mice by modulating gastrointestinal regulatory peptides, gut microbiota, aquaporin and mitigating intestinal barrier damage and immune-inflammatory responses. Full article

This study aimed to investigate the effect of wildfire episodes on air quality in terms of particulate matter (PM) and carbonaceous compound concentration in ambient air, and to assess deviations from typical annual patterns. The sampling was performed at a rural background site near the Adriatic coast in Croatia through 2024. To better understand contributions caused by fire events, the levels of organic carbon (OC), elemental carbon (EC), black carbon (BC), pyrolytic carbon (PyrC), optical carbon (OptC), water-soluble organic carbon (WSOC), levoglucosan (LG), mannosan (MNS), and galactosan (GA) were determined in PM₁₀ and PM_2.5 fractions (particles smaller than 10 µm and 2.5 µm, respectively). The annual mean concentrations of PM₁₀ and PM_2.5 were 14 µg/m³ and 8 µg/m³, respectively. During the fire episode, the PM_2.5 mass contribution to the total PM₁₀ mass exceeded 65%. Total carbon (TC) and OC increased by a factor of 7, EC and BC by 12, PyrC by 8, and WSOC by 12. The concentration of LG reached 1.219 μg/m³ in the PM₁₀ fractions and 0.954 μg/m³ in the PM_2.5 fractions, representing a 200-fold increase during the fire episode. Meteorological data were integrated to assess atmospheric conditions during the fire episode, and the specific ratios between fire-related compounds were analyzed. Full article

This study assessed the presence, abundance, and characteristics of microplastics (MPs) in farmed Pacific oysters (Crassostrea gigas) and evaluated the efficacy of depuration in reducing MPs under laboratory-controlled and commercial conditions. Oysters cultivated in the Lima estuary (NW Portugal) were sampled in autumn and winter, along with adjacent surface water and sediment, to investigate potential contamination sources. MP concentrations in oysters varied temporally, with higher levels in October 2023 (0.48 ± 0.34 MPs g⁻¹ ww) than in February 2024 (0.09 ± 0.07 MPs g⁻¹ ww), while the environmental levels remained stable across dates. All MPs were fibres, predominantly transparent, followed by blue and black. Fourier-Transform Infrared Spectroscopy (FTIR) confirmed cellulose and polyethylene terephthalate (PET) as dominant polymers in oysters and environmental samples. No clear correlation was found between MPs in oysters and surrounding compartments. Laboratory depuration reduced MPs by 78% within 48 h, highlighting its potential as a mitigation strategy. However, depuration was less effective under commercial conditions, possibly due to lower initial contamination levels. These findings suggest that oysters may act as a vector for human exposure to MPs via seafood consumption. While depuration shows promise in reducing contamination, further research is needed to optimise commercial protocols and enhance the safety of aquaculture products. Full article

Lithium-ion batteries (LiBs) are utilized in numerous applications due to advancements in technology, and the recovery of end-of-life (EoL) LiBs is imperative for environmental and economic reasons. Pyrometallurgical and hydrometallurgical methods have been used in the recovery of metals such as Li, Co, and Ni in the EoL LiBs. Hydrometallurgical methods, which have been demonstrated to exhibit higher recovery efficiency and reduced energy consumption, have garnered increased attention in recent research. Inorganic acids, including HCl, HNO₃, and H₂SO₄, as well as organic acids such as acetic acid and citric acid, are employed in the hydrometallurgical recovery of these metals. It is imperative to acknowledge the environmental hazards posed by these acids. Consequently, solvometallurgical processes, which involve the use of organic solvents with minimal or no water, are gaining increasing attention as alternative or complementary techniques to conventional hydrometallurgical processes. In the context of solvent systems that have been examined for a range of solvometallurgical methods, deep eutectic solvents (DESs) have garnered particular interest due to their low toxicity, biodegradable nature, tunable properties, and efficient metal recovery potential. In this study, the leaching process of black mass containing graphite, LCO, NMC, and LMO was carried out in a short time using the ternary DES system. The ternary DES system consists of choline chloride (ChCl), glycolic acid (GLY), and ascorbic acid (AA). As a result of the leaching process of cathode powders in the black mass without any pre-enrichment process, Li, Co, Ni, and Mn elements passed into solution with an efficiency of over 95% at 60 °C and within 1 h. Moreover, the kinetics of the leaching process was investigated, and Density Functional Theory (DFT) calculations were used to explain the leaching mechanism. Full article

Yogurt fortified with polyphenols, as a new type of functional yogurt, exhibits high quality and good antioxidant activity. However, the effects of black garlic polyphenols (BGP) on the quality of solidified yogurt have been scarcely reported. Therefore, the effects of different levels (0.1–0.4%) of BGP on the sensory scores, physicochemical properties, rheological properties, texture properties, antioxidant activity and polyphenol content of solidified yogurt were studied. The results showed that the total sensory scores of yogurt with 0.2% and 0.4% levels of BGP addition were both above 80. BGP addition significantly decreased the water-holding capacity and pH values of yogurt, compared with the yogurt without BGP addition. The yogurt with a 0.4% level of BGP had the highest titratable acidity of 89.84° T. In addition, the storage modulus (G’) and loss modulus (G”) of yogurt increased with the addition of BGP. The gel strength, chewiness and hardness of yogurt significantly decreased with an increase in BGP addition. The content of quercetin and caffeic acid in the yogurt with the addition of 0.1–0.4% BGP was 0.53–1.79 mg/g and 2.13–4.98 mg/g, respectively. The antioxidant activity and total phenolic acid content of yogurt significantly increased with an increment in BGP addition. The 2,2′-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) diammonium salt radical scavenging activity, ferric reducing antioxidant power and 1,1-diphenyl-2-picrylhydrazyl radical scavenging activity of yogurt with a 0.4% level of BGP increased by 52.79%, 57.31% and 42.51%, respectively, compared to the yogurt without BGP addition. This study provides a theoretical basis for the development of novel yogurt with high antioxidant activity. Full article

The spatial genes of rural settlements show a lot of different traditional settlement traits, which makes them a great starting point for studying rural spatial morphology. However, qualitative and macro-regional statistical indicators are usually used to find and extract rural settlement spatial genes. Taking Yubei Village in the Nanxi River Basin as an example, this study combined remote sensing images, real-time drone mapping, GIS (geographic information system), and space syntax, extracted 12 key indicators from five dimensions (landform and water features (environment), boundary morphology, spatial structure, street scale, and building scale), and quantitatively “decoded” the spatial genes of the settlement. The results showed that (1) the settlement is a “three mountains and one water” pattern, with cultivated land accounting for 37.4% and forest land accounting for 34.3% of the area within the 500 m buffer zone, while the landscape spatial diversity index (LSDI) is 0.708. (2) The boundary morphology is compact and agglomerated, and locally complex but overall orderly, with an aspect ratio of 1.04, a comprehensive morphological index of 1.53, and a comprehensive fractal dimension of 1.31. (3) The settlement is a “clan core–radial lane” network: the global integration degree of the axis to the holy hall is the highest (0.707), and the local integration degree R3 peak of the six-room ancestral hall reaches 2.255. Most lane widths are concentrated between 1.2 and 2.8 m, and the eaves are mostly higher than 4 m, forming a typical “narrow lanes and high houses” water town streetscape. (4) The architectural style is a combination of black bricks and gray tiles, gable roofs and horsehead walls, and “I”-shaped planes (63.95%). This study ultimately constructed a settlement space gene map and digital library, providing a replicable quantitative process for the diagnosis of Jiangnan water town settlements and heritage protection planning. Full article

The black-spotted frog (Pelophylax nigromaculatus) is a common economic species in the rice–frog ecological cropping mode. The present study investigated microbial community structures in paddy water and black-spotted frog’s guts across rice monoculture and low-/high-density rice–frog co-cropping systems at four rice growth stages. Proteobacteria dominate in paddy water, while frog guts are enriched in Firmicutes and Actinobacteriota. The frog density shows no impact on the α-diversity, but rice growth stages significantly alter the Shannon, Simpson, and Pielou_e indices (p < 0.01). Co-cropping may promote amino acid synthesis, elemental cycling, and stress tolerance in paddy water microbiota, which are more diverse than gut microbiota. Strong correlations exist between paddy water and gut microbiotas, with Limnohabitans being linked to gut diversity (p < 0.05). Low-density co-cropping enhances Xenorhabdus, which is beneficial for pest control and stabilizes gut microbiota. The results of this study offer insights for managing rice–frog systems based on rice growth stages. Full article

The polyvalent nature of water is one often explored in fiction by Caribbean writers, and this paper will consider the ways that the representations of mermaids act as an extension of this exploration. Mermaids are central to a number of folk traditions across the Caribbean region and its diaspora. On islands, including Trinidad, Martinique, Carriacou, and Haiti, with names such as Fairymaid, Mama Glo, and La Siren, mermaids are often regarded as mothers and protectresses of both the sea and the creatures within it. This paper will analyse the representation of the mermaid in Monique Roffey’s The Mermaid of Black Conch (2020) and consider how the novel utilises the mermaid and an aquatic poetics to explore Kamau Brathwaite’s conceptualisation of a submarine unity for the Caribbean. Full article