Rubber-Based Composites: Challenges in Reusing Waste and Nanostructures as Fillers

A special issue of Journal of Composites Science (ISSN 2504-477X). This special issue belongs to the section "Polymer Composites".

Deadline for manuscript submissions: 20 March 2026 | Viewed by 222

Special Issue Editors


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Guest Editor
Department of Engineering, School of Engineering and Sciences, Sao Paulo State University (UNESP), Rosana 19272-100, SP, Brazil
Interests: rubber composites; waste management; nanostructures; rubber-based devices

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Guest Editor
Materials Engineering Department, Science and Technology Center of the Federal University of São Carlos, São Carlos 13565-905, Brazil
Interests: electroactive polymers; rheology; IPMC; deformation sensors; rubber recycling
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Special Issue Information

Dear Colleagues,

Rubber, classified as an elastomer, is a flexible material capable of being stretched multiple times its original length without undergoing plastic deformation. Due to its properties such as elasticity, and thermal and electrical insulation, it finds extensive applications across various industries. Notable uses include automotive components like tires, hoses, transmission belts, and cushions; industrial equipment (hydraulic and pneumatic systems) utilizing sealing rings and gaskets to prevent leaks; medical materials including gloves and catheters; footwear manufacturing for soles; rubber flooring in the construction industry; and electrical insulators for electronics and telecommunications.

To be utilized in these products, rubber undergoes vulcanization processes that enhance its mechanical strength and durability. Furthermore, the incorporation of reinforcing fillers can improve tensile and tear resistance. Commercial fillers, such as carbon black and silica, contribute to chemical and mechanical resistance, while the addition of fillers like calcium carbonate or talc reduces costs. These fillers decrease the polymer matrix mass without significantly compromising the material's properties. Other fillers can also enhance composite processing by reducing vulcanization time or improving molding and may impart new properties like electrical conductivity or flame resistance.

An alternative to replace—even partially—commercial fillers involves utilizing waste materials. Although many agricultural and industrial wastes are directed towards energy generation or by-products through pyrolysis processes, recycling and beneficiation methods remain complex, costly, and require improvement in product quality. Consequently, employing fillers in composites offers an environmental advantage by enabling proper disposal of these residues, reducing costs, and mitigating mineral resource exploitation.

However, challenges persist, such as ensuring that waste-derived fillers provide mechanical reinforcement surpassing that of commercial fillers, achieve homogeneous dispersion, promote cross-linking within the polymer matrix, and yield reproducible results. Reducing filler size to nanometric levels presents advantages in interaction with the polymer matrix, provided uniform distribution and phase compatibility are ensured. Nanoparticles, including graphene oxide, carbon nanotubes, nanoclays, titanates, and ceramics, have been integrated into composites. Future research correlating nanostructured with waste materials may facilitate the development of advanced engineering composites. With this, we are pleased to invite you to submit papers representing new reinforcing fillers, whether organic, fibrous or inorganic (industrial), originating from waste recycling or the synthesis of metallic or magnetic nanostructures, or prominent results with known commercial fillers such as carbon nanotubes, graphene oxide, etc.

This Special Issue aims to summarize recent advances regarding reinforcing fillers in rubber composites, reuse of waste as reinforcement, and nanostructures for the production of advanced engineering materials. Research articles and reviews are welcome.

Dr. Flávio Camargo Cabrera
Dr. Carlos Henrique Scuracchio
Guest Editors

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Keywords

  • recycling
  • waste management
  • nanomaterials
  • filler
  • reinforcement

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Published Papers (1 paper)

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Research

12 pages, 866 KiB  
Article
Reuse of Activated Carbon Filter Waste as Filler in Vulcanized Rubber Composites
by Viviane Chaves de Souza, Henrique Pina Cardim, Carlos Toshiyuki Hiranobe, Guilherme Pina Cardim, Iago William Zapelini, Leonardo Lataro Paim, Gleyson Tadeu Almeida Santos, Silvio Rainho Teixeira, Erivaldo Antônio da Silva, Renivaldo José dos Santos and Flávio Camargo Cabrera
J. Compos. Sci. 2025, 9(8), 406; https://doi.org/10.3390/jcs9080406 (registering DOI) - 1 Aug 2025
Viewed by 55
Abstract
The incorporation of residues into rubber composites has gained attention as a sustainable strategy to address waste management challenges while replacing commercial fillers. In this study, we investigated the potential use of water filter cartridge residue after exhaustion, composed of activated carbon, as [...] Read more.
The incorporation of residues into rubber composites has gained attention as a sustainable strategy to address waste management challenges while replacing commercial fillers. In this study, we investigated the potential use of water filter cartridge residue after exhaustion, composed of activated carbon, as a reinforcing filler in vulcanized natural rubber composites. Samples were prepared with 5, 10, 15, and 20 phr (per hundred rubber) of residue and compared to unfilled natural rubber. Stress vs. strain tests reached 13.9 MPa of tension at rupture for composites containing 10 phr of carbon-activated residues, representing a 21.9% increase compared to natural rubber. Interestingly, the tension at rupture for NR/AC10phr reached values close to those of NR/CB5phr (with carbon black N330) attaining 14.4 MPa. These results indicate that, even at relatively low concentrations, the carbon filter can offer partial substitution for commercial fillers. Moreover, the use of activated carbon from filter cartridges as filler in rubber composites provides an environmentally favorable alternative to energy-intensive regeneration processes for activated carbon. Full article
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