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Porous Carbons for CO2 Adsorption and Capture

A special issue of Molecules (ISSN 1420-3049). This special issue belongs to the section "Materials Chemistry".

Deadline for manuscript submissions: 31 July 2025 | Viewed by 508

Special Issue Editors


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Guest Editor
State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan University of Technology, Taiyuan 030024, China
Interests: porous carbons; CO2 adsorption and capture; activated carbon; heteroatom doping; carbon nanotubes

E-Mail Website
Guest Editor
Institute of Applied Chemistry, Jiangxi Academy of Sciences, Nanchang, China
Interests: porous carbon; CO2 adsorption; CO2 capture; activated carbon; nitrogen doping

Special Issue Information

Dear Colleagues,

As the global community continues to tackle the urgent challenge of climate change, efficient CO2 capture and storage have become a key strategy for mitigating greenhouse gas emissions. The synthesis of porous carbons through a more sustainable, efficient, and controllable approach is being intensively pursued, as porous carbons have demonstrated competitive performances in many areas. Porous carbons have also been long studied as CO2 adsorbents due to their tunable properties, excellent stability, and low costs. An in-depth understanding of the correlations between adsorption performances and physicochemical properties can assist in tailoring synthesis strategies for enhanced CO2 adsorption. The current Special Issue aims to further bridge the gap between porous carbon synthesis and adsorption behaviors, achieving superior CO2 capture capabilities.

Scope and Topics of Interest:

We invite contributions on topics including (but not limited to) the following:

  1. Synthesis and Fabrication of Porous Carbons
    • Activated carbons from biomass, waste materials, and other precursors;
    • Carbon nanomaterials (e.g., carbon nanotubes, graphene oxide) for CO2 capture;
    • Template-assisted synthesis and porous carbon design;
    • Porous carbons from industrial by-products and sustainable sources.
  2. Surface Functionalization and Modification
    • Doping with heteroatoms (N, O, S) to enhance CO2 uptake;
    • Functionalization for selective adsorption and increased capacity;
    • Pore size engineering and control for optimized CO2
  3. Characterization Techniques
    • BET surface area and porosity analysis;
    • Microscopic and spectroscopic techniques (SEM, TEM, XPS, FTIR);
    • Characterization of CO2 adsorption isotherms, kinetics, and thermodynamics.
  4. CO2 Adsorption Mechanisms
    • Physisorption vs. chemisorption mechanisms for CO2 capture;
    • Effect of environmental factors (temperature, pressure, humidity) on CO2 uptake;
    • Adsorption selectivity for CO2 over other gasses (e.g., N2, CH4).
  5. Performance and Efficiency of CO2 Capture
    • Adsorption capacity and CO2 selectivity;
    • Regeneration and reusability of porous carbons for long-term performance;
    • Energy efficiency and environmental impact of CO2 capture processes.
  6. Applications of Porous Carbons in CO2 Capture Technologies
    • Direct air capture (DAC);
    • Post-combustion CO2 capture in power plants and industrial processes;
    • Carbon capture and utilization (CCU) and value-added products;
    • Integration with renewable energy systems for enhanced CO2
  7. Emerging Trends and Future Directions
    • Hybrid materials, combining porous carbons with other adsorbents (e.g., MOFs, COFs);
    • Machine learning and AI in material design and optimization for CO2 capture;

Prof. Dr. Guojie Zhang
Dr. Jinsong Shi
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Molecules is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • porous carbons
  • carbon nanotubes
  • graphene oxide
  • carbon nanomaterials
  • activated carbons
  • adsorbents
  • CO2 adsorption
  • CO2 capture
  • physisorption
  • chemical activation
  • physical activation
  • surface functionalization
  • pore structure design
  • carbon doping
  • nitrogen doping
  • CO2 capture efficiency
  • CO2 selectivity
  • direct air capture (DAC)
  • CO2 storage
  • industrial CO2 capture
  • carbon capture and utilization (CCU)
  • CO2 adsorption mechanisms
  • adsorption kinetics
  • sustainable materials
  • adsorbent regeneration
  • machine learning in material design

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Published Papers (1 paper)

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Research

20 pages, 3178 KiB  
Article
Progressive Conversion Model Applied to the Physical Activation of Activated Carbon from Palm Kernel Shells at the Pilot Scale in a Nichols Furnace and at the Industrial Scale in a Rotary Kiln
by Ernesto de la Torre, Alex S. Redrovan and Carlos F. Aragón-Tobar
Molecules 2025, 30(7), 1573; https://doi.org/10.3390/molecules30071573 - 31 Mar 2025
Viewed by 238
Abstract
Palm kernel shells, an abundant agro-industrial residue in countries like Ecuador, can be valorized through their conversion into activated carbon for industrial applications. This study investigates the physical activation of carbonized palm kernel shells using both a Nichols furnace at the pilot scale [...] Read more.
Palm kernel shells, an abundant agro-industrial residue in countries like Ecuador, can be valorized through their conversion into activated carbon for industrial applications. This study investigates the physical activation of carbonized palm kernel shells using both a Nichols furnace at the pilot scale and a rotary kiln at the industrial scale. The progressive conversion model was used to explain how the activation process works and to calculate the reaction rate constants for CO2 (krCO2) and H2O (krH2O). The experimental results demonstrated that activation in an H2O-rich atmosphere significantly enhanced porosity development and iodine index compared to CO2 alone. Additionally, the study confirmed that activation kinetics are primarily controlled by the chemical reaction rather than mass transport limitations, as indicated by the negligible effect of particle size on gasification rates. At 850 °C, the reaction rate constants were calculated to be krCO2 = 0.75 (mol·cm−3·s)−1 and krH2O = 8.91 (mol·cm−3·s)−1. The model’s predictions closely matched the experimental data, validating its applicability for process optimization at both the pilot and industrial scales. These findings provide valuable insights for improving the efficiency of activated carbon production from palm kernel shells in large-scale operations. Full article
(This article belongs to the Special Issue Porous Carbons for CO2 Adsorption and Capture)
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