Powder Metallurgy of High-Entropy Alloy

A special issue of Metals (ISSN 2075-4701). This special issue belongs to the section "Powder Metallurgy".

Deadline for manuscript submissions: closed (1 August 2020) | Viewed by 7970

Special Issue Editors


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Guest Editor
Institute of Physics of Materials, Czech Academy of Sciences and Institute of Materials Science and Engineering, Brno University of Technology, Brno, Czech Republic
Interests: steels; intermetallics; light weight alloys and their composites; high entropy alloys; fracture resistance of metallic materials; ceramics and ceramic matrix composites; microstructure vs materials performance under mechanical loading
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Guest Editor
Institute of Physics of Materials, Czech Academy of Sciences, Brno, Czech Republic
Interests: powder shaping methods; powder metallurgy; mechanical alloying; ceramic matrix composites; dispersion strengthened alloys; high entropy alloys

Special Issue Information

Dear Colleagues,

Recently, the high-entropy alloys (HEAs), medium entropy alloys and/or multi-principal element alloys have attracted significant interest, mainly due to distinctive properties resulting from the novelty of their basic design concept. This is coming from stabilization of the disordered phase and, therefore, to suppression of ordered intermetallics formation by maximizing the configurational entropy. This strategy has, indeed, been shown to produce some stable single-phase fcc and bcc alloys solid solution. However, the majority of HEAs studied so far have been proven to form intermetallic phases in specific conditions.

The HEAs’ design concept opens potential for investigations on the unexplored compositional range of multi-component alloys. Up to date, HEAs have demonstrated promising capability for industrial applications, mainly thanks to some of their remarkable properties, such as unique high combination of strength and ductility even at low temperatures, high temperature strength, high wear resistance, quite good thermal stability, satisfying corrosion resistance, etc.

HEAs are generally fabricated by casting, however, this way is subjected to some processing problems which may be detrimental for the final material. Alternatively, powder metallurgy (PM) has been proven to be a reliable and not too expensive method capable of relatively easy and efficient production of HEAs. Compared to casting, PM requires lower temperatures for its processing, since it can be produced through solid state sintering. Nevertheless, there are open problems to be fixed, e.g. oxides and/or other secondary phase particles formation, routes to optimise microstructure relating to HEAs performance under mechanical loading etc.

In this Special Issue, articles will be invited that focus on separate steps of mechanical alloying and HEAs powder preparation and characterisation methods, their influence on sinterability by different techniques and the final materials’ performance both from the powder stage and/or compaction stadium. Fast and low-cost processes especially remain of interest, being fully controllable and with a high implementation potential.

Prof. Ivo Dlouhý
Dr. Hynek Hadraba
Guest Editors

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Keywords

  • High-entropy alloy
  • multicomponent alloy
  • mechanical alloying
  • microstructure
  • strength
  • fracture resistance
  • wear resistance
  • temperature effects
  • applications

Published Papers (2 papers)

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15 pages, 5273 KiB  
Article
The Origins of High-Entropy Alloy Contamination Induced by Mechanical Alloying and Sintering
by Igor Moravcik, Antonin Kubicek, Larissa Moravcikova-Gouvea, Ondrej Adam, Vaclav Kana, Vaclav Pouchly, Antonin Zadera and Ivo Dlouhy
Metals 2020, 10(9), 1186; https://doi.org/10.3390/met10091186 - 03 Sep 2020
Cited by 42 | Viewed by 3535
Abstract
One of the prevailing problems for materials produced by powder metallurgy is contamination from various sources. This work deals with the influence of process parameters and presence of process control agents (PCA) on the contamination level of materials produced by means of mechanical [...] Read more.
One of the prevailing problems for materials produced by powder metallurgy is contamination from various sources. This work deals with the influence of process parameters and presence of process control agents (PCA) on the contamination level of materials produced by means of mechanical alloying (MA) technology, densified with spark plasma sintering (SPS). The equiatomic CoCrFeNi high-entropy alloy (HEA) was manufactured by the said methodology. For clear comparison, the 316L austenitic steel powder was milled and densified with identical conditions as a reference material. Both materials were milled in argon and nitrogen atmospheres for various times from 5 to 30 h. Chemical analysis of contamination by carbon, oxygen, and nitrogen within the powder and bulk materials was carried out using combustion analyzers. The microstructural analysis of powders and bulk samples was carried out using scanning electron microscopy (SEM) with focus on contaminant phases. The results show that carbon contamination increases with milling time. It is caused by wear of milling vial and balls made from high-carbon steels. Increase of carbon content within consolidation using SPS was also observed. The oxygen contamination also increases with milling time. It is more pronounced in the CoCrFeNi alloy due to higher oxidation of powder surfaces prior to milling. Milling of powders using nitrogen atmosphere also causes an increase of nitrogen content in both HEA and AISI 316L. The use of PCA (ethanol) during milling even for a short time (30 min) causes significant increase of carbon and oxygen contamination. The ways to decrease contamination are discussed in the paper. Full article
(This article belongs to the Special Issue Powder Metallurgy of High-Entropy Alloy)
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18 pages, 4758 KiB  
Article
Microstructure and Mechanical Properties of Sintered and Heat-Treated HfNbTaTiZr High Entropy Alloy
by Jaroslav Málek, Jiří Zýka, František Lukáč, Jakub Čížek, Lenka Kunčická and Radim Kocich
Metals 2019, 9(12), 1324; https://doi.org/10.3390/met9121324 - 07 Dec 2019
Cited by 16 | Viewed by 3755
Abstract
High entropy alloys (HEAs) have attracted researchers’ interest in recent years. The aim of this work was to prepare the HfNbTaTiZr high entropy alloy via the powder metallurgy process and characterize its properties. The powder metallurgy process is a prospective solution for the [...] Read more.
High entropy alloys (HEAs) have attracted researchers’ interest in recent years. The aim of this work was to prepare the HfNbTaTiZr high entropy alloy via the powder metallurgy process and characterize its properties. The powder metallurgy process is a prospective solution for the synthesis of various alloys and has several advantages over arc melting (e.g., no dendritic structure, near net-shape, etc.). Cold isostatic pressing of blended elemental powders and subsequent sintering at 1400 °C for various time periods up to 64 h was used. Certain residual porosity, as well as bcc2 (Nb- and Ta-rich) and hcp (Zr- and Hf-rich) phases, remained in the bcc microstructure after sintering. The bcc2 phase was completely eliminated during annealing (1200 °C/1h) and subsequent water quenching. The hardness values of the sintered specimens ranged from 300 to 400 HV10. The grain coarsening during sintering was significantly limited and the maximum average grain diameter after 64 h of sintering was approximately 60 μm. The compression strength at 800 °C was 370 MPa and decreased to 47 MPa at 1200 °C. Porosity can be removed during the hot deformation process, leading to an increase in hardness to ~450 HV10. Full article
(This article belongs to the Special Issue Powder Metallurgy of High-Entropy Alloy)
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