Phase Transformations and Grain Boundaries of Metals and Alloys

A special issue of Metals (ISSN 2075-4701). This special issue belongs to the section "Crystallography and Applications of Metallic Materials".

Deadline for manuscript submissions: closed (30 June 2022) | Viewed by 2938

Special Issue Editor


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Guest Editor
Centre des Matériaux, MINES ParisTech, PSL University, Paris, France
Interests: diffusion; diffusion-controlled phase transformations; microstructure–properties relationship; steels; nickel-base superalloys; aluminum alloys; Ti2AlNb alloys

Special Issue Information

Dear Colleagues,

Despite intensive and increasing decarburization of different industrial sectors, metallic materials play a crucial role in a number of applications, especially when high mechanical resistance at elevated temperatures is required to guarantee the integrity of parts. Since the first use of metals when a customer had to adapt the intended application to the “fixed and natural” material properties, the performances of metals have been continuously evolving and are now carefully controlled via appropriate choice of alloys chemical compositions and processing routes. The direct microstructure–properties relationship in metallic materials is now well established—in other words, a “good” microstructure consisting of “good” phases results in “good” properties. Together with chemical composition, grain size, size, morphology, and distribution of second phase precipitates, grain boundaries (GBs) represent a unique and intrinsic parameter which can be used to control the properties of metallic polycrystalline materials. Due to the global tendency toward miniaturization (in nanoelectronics, for example) and intensive research on nanograined metals, GBs have manifested a multitude of features to act on properties, as they are preferential nucleation sites, part of matter with different composition and significantly increased rate of diffusion and, more recently, with specific phase transitions, as compared to the bulk. The objective of the present Special Issue is to present recent achievements in the investigation of interaction between phase transformations and grain boundaries in metallic alloys. Experimental and theoretical (and/or modeling) aspects are both covered.

Dr. Vladimir A. Esin
Guest Editor

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Keywords

  • phase transformations
  • grain boundaries
  • diffusion
  • segregation
  • precipitation
  • martensitic transformation
  • spinodal decomposition
  • modeling
  • metallic alloys
  • properties

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Published Papers (1 paper)

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Research

12 pages, 3847 KiB  
Article
Influence of Yttrium on the Phase Composition of the Ti-Al System Obtained by the ‘Hydride Technology’
by Natalia Karakchieva, Alina Artemenko, Olga Lepakova, Victor Sachkov and Irina Kurzina
Metals 2022, 12(9), 1481; https://doi.org/10.3390/met12091481 - 6 Sep 2022
Cited by 2 | Viewed by 2435
Abstract
In this study, the influence of yttrium on the formation of the structural-phase state of the Ti-Al alloy, obtained by the “hydride technology” (GT) method, has been analyzed. Using transmission electron microscopy (TEM) and X-ray spectral microanalysis, the authors of the work have [...] Read more.
In this study, the influence of yttrium on the formation of the structural-phase state of the Ti-Al alloy, obtained by the “hydride technology” (GT) method, has been analyzed. Using transmission electron microscopy (TEM) and X-ray spectral microanalysis, the authors of the work have established the following phases formed in the sample volume and on the surface: Ti3Al, TiAl, Al, α-Ti, Ti3Al5, Y2Al, Y5Al3, YAl3, YAl, and Y6Ti4Al43. The lamellar structure has been formed in the alloy volume. The average width of the Al-rich lamellae was 0.36 µm and that of the Ti-rich lamellae was 0.21 µm. The formation of a triple Y6Ti4Al43 phase, which is localized along the boundaries of the lamellar structure, has been recorded. The localization scheme of the formed phases of the TAY alloy has been proposed. Full article
(This article belongs to the Special Issue Phase Transformations and Grain Boundaries of Metals and Alloys)
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