Special Issue "Coordination Polymers: Synthesis, Crystal Structure and Multifunctional Applications"

A special issue of Materials (ISSN 1996-1944).

Deadline for manuscript submissions: 31 December 2020.

Special Issue Editor

Prof. Andrei S. Potapov
Website
Guest Editor
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of SciencesTomsk Polytechnic University, Tomsk, Russia
Interests: nitrogen ligands; metal-organic frameworks; luminescence

Special Issue Information

Dear Colleagues,

Coordination polymers are constructed from metal ions and bridging ligands, which join them into infinite 1D chains or 2D and 3D networks. Chemistry coordination polymers is a vibrant field of modern science, which is confirmed by an exponential increase in the number of scientific articles, reviews, and thematic issues in the best journals. A wide variety of possible coordination arrangements of metal ions and geometries of linkers provides almost unlimited possibilities for constructing coordination polymers of various topologies. The functional properties of coordination polymers can be modified by introducing various functional groups into organic linkers, which affect sorption, catalytic, photophysical, and other properties. The presence of a developed system of pores and channels in the structure of coordinatin polymers provides high values of sorption capacity and selectivity for industrially important gases and their mixtures—hydrogen, carbon dioxide, water vapor, methane, ethane, ethylene, and acetylene. Another important characteristic of coordination polymers is their luminescent properties, which can be associated with various types of electronic transitions—intraligand, metal-centered, metal–ligand, and ligand–metal charge transfer. Electronic transitions in guest molecules included in the pores of the framework are also possible. The photophysical properties of coordination polymers are used to create electroluminescent materials for LEDs, as contrast agents in biomedical imaging, theranostics, and photodynamic therapy.

The aim of current Specail Issue is to cover various aspects of the synthesis, structural characterization, and study of functinal properties of both inorganic and metal-organic coordination polymers. It is our pleasure to invite you to submitt communications, full papers, and reviews for this Special Issue.

Prof. Andrei S. Potapov
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All papers will be peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Materials is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2000 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • coordination network
  • metal-organic framework
  • catalysis
  • luminescence
  • topology
  • gas sorption
  • coordination polymer

Published Papers (1 paper)

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Research

Open AccessFeature PaperArticle
Transition Metal Coordination Polymers with Trans-1,4-Cyclohexanedicarboxylate: Acidity-Controlled Synthesis, Structures and Properties
Materials 2020, 13(2), 486; https://doi.org/10.3390/ma13020486 - 19 Jan 2020
Abstract
Five trans-1,4-cyclohexanedicarboxylate (chdc2−) metal–organic frameworks of transition metals were synthesized in aqueous systems. A careful control of pH, reaction temperature and solvent composition were shown to direct the crystallization of a particular compound. Isostructural [Co(H2O)4(chdc)]n ( [...] Read more.
Five trans-1,4-cyclohexanedicarboxylate (chdc2−) metal–organic frameworks of transition metals were synthesized in aqueous systems. A careful control of pH, reaction temperature and solvent composition were shown to direct the crystallization of a particular compound. Isostructural [Co(H2O)4(chdc)]n (1) and [Fe(H2O)4(chdc)]n (2) consist of one-dimensional hydrogen-bonded chains. Compounds [Cd(H2O)(chdc)]n∙0.5nCH3CN (3), [Mn4(H2O)3(chdc)4]n (4) and [Mn2(Hchdc)2(chdc)]n (5) possess three-dimensional framework structures. The compounds 1, 4 and 5 were further characterized by magnetochemical analysis, which reveals paramagnetic nature of these compounds. A presence of antiferromagnetic exchange at low temperatures is observed for 5 while the antiferromagnetic coupling in 4 is rather strong, even at ambient conditions. The thermal decompositions of 1, 4 and 5 were investigated and the obtained metal oxide (cubic Co3O4 and MnO) samples were analyzed by X-ray diffraction and scanning electron microscopy. Full article
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Planned Papers

The below list represents only planned manuscripts. Some of these manuscripts have not been received by the Editorial Office yet. Papers submitted to MDPI journals are subject to peer-review.

1. Title: Coordination polymers based on highly emissive ligands: structure and functional properties

Author: Prof. Andrei S. Potapov

Email: [email protected]

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