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Advances in Function Geopolymer Materials—Second Edition
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Advances in Function Geopolymer Materials—Second Edition

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Construction and Building Materials".

Deadline for manuscript submissions: 20 November 2025 | Viewed by 3136

Special Issue Editors

Dr. Michał Łach

E-Mail Website
Guest Editor
1. Department of Materials Engineering, Faculty of Materials Engineering and Physics, Cracow University of Technology, Jana Pawła II 37, 31-864 Cracow, Poland
2. Interdisciplinary Center for Circular Economy, Cracow University of Technology, Warszawska 24, 31-155 Krakow, Poland
Interests: geopolymer; zeolites; recycling; circular economy; waste immobilization
Special Issues, Collections and Topics in MDPI journals
Dr. Kinga Korniejenko

E-Mail Website
Guest Editor
Institute of Material Engineering, Faculty of Material Engineering and Physics, Cracow University of Technology, Jana Pawła II 37, 31-864 Cracow, Poland
Interests: geopolymer; geopolymer composites; circular economy; additive manufacturing
Special Issues, Collections and Topics in MDPI journals
Dr. Aleksandar Nikolov

E-Mail Website
Guest Editor
Institute of Mineralogy and Crystallography, Bulgarian Academy of Science (IMC-BAS), Acad. G. Bonchev Str., bl. 107, 1113 Sofia, Bulgaria
Interests: geopolymer; geopolymer composites; zeolites; antibacterial coatings
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Geopolymer materials classified as inorganic polymers have been known for several decades, but there is currently an increased interest in this type of material. Because geopolymer production technology is sensitive to changes in raw material prices, it is difficult for geopolymers to compete with the prices of conventional mass-produced concretes. However, there is a lot of interest in many specialized, often niche, applications. One example is thermal insulation. Geopolymer materials have a number of unique properties and are classified as functional materials. Thanks to the properly designed syntheses of these materials, it is possible to control various properties. This Special Issue will present the latest achievements and research results on geopolymers as functional materials. We invite all scientists involved in the development of advanced geopolymer binders and concretes as well as advanced geopolymer composites to submit to this issue.

This Special Issue aims to attract original contributions in topics related to advanced functions of geopolymers. We believe that this collection will summarize the current state of the art and featured trends in this field and will thus be a source of new ideas for future research.

Dr. Michał Łach
Dr. Kinga Korniejenko
Dr. Aleksandar Nikolov
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Materials is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • geopolymer
  • functional material
  • modern insulation material
  • sustainable development
  • innovation in building materials

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Published Papers (4 papers)

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31 pages, 25510 KB  
Article
Geopolymer Foams Loaded with Diatomite/Paraffin Granules for Enhanced Thermal Energy Storage
by Agnieszka Przybek
Materials 2025, 18(19), 4512; https://doi.org/10.3390/ma18194512 - 28 Sep 2025
Abstract
This paper presents the development and characteristics of geopolymer foams modified with paraffin-based phase change materials (PCMs) encapsulated in diatomite. The aim was to increase both the thermal insulation and heat storage capacity of the foams while maintaining sufficient mechanical strength for construction [...] Read more.
This paper presents the development and characteristics of geopolymer foams modified with paraffin-based phase change materials (PCMs) encapsulated in diatomite. The aim was to increase both the thermal insulation and heat storage capacity of the foams while maintaining sufficient mechanical strength for construction applications. Eleven variants of composites with different PCM fractions (5–10% by mass) and grain sizes (<1.6 mm to >2.5 mm) were synthesized and tested. The inclusion of PCM encapsulated in diatomite modified the porous structure: the total porosity increased from 6.6% in the reference sample to 19.6% for the 1.6–1.8 mm_10% wt. variant, with pore diameters ranging from ~4 to 280 µm. Thermal conductivity (λ) ranged between 0.090–0.129 W/m·K, with the lowest values observed for composites 2.0–2.5 mm_5–10% wt. (≈0.090–0.091 W/m·K), which also showed high thermal resistance (R ≈ 0.287–0.289 m2·K/W). The specific heat (Cp) increased from 1.28 kJ/kg·K (reference value) to a maximum value of 1.87 kJ/kg·K for the 2.0–2.5 mm_10% mass variant, confirming the effective energy storage capacity of PCM-modified foams. Mechanical tests showed compressive strength values in the range of 0.7–3.1 MPa. The best structural performance was obtained for the 1.6–1.8 mm_10% wt. variant (3.1 MPa), albeit with a higher λ (≈0.129 W/m·K), illustrating the classic trade-off between porosity-based insulation and mechanical strength. SEM microstructural analysis and mercury porosimetry confirmed the presence of mesopores, which determine both thermal and mechanical properties. The results show that medium-sized PCM fractions (1.6–2.0 mm) with moderate content (≈10% by weight) offer the most favorable compromise between insulation and strength, while thicker fractions (2.0–2.5 mm) maximize thermal energy storage capacity. These findings confirm the possibility of incorporating natural PCMs into geopolymer foams to create multifunctional materials for sustainable and energy-efficient building applications. A unique contribution to this work is the use of diatomite as a natural PCM carrier, ensuring stability, compatibility, and environmental friendliness compared to conventional encapsulation methods. Full article
(This article belongs to the Special Issue Advances in Function Geopolymer Materials—Second Edition)
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24 pages, 3402 KB  
Article
Development of Multifunctional Slag and Bauxite Residue-Based Geopolymers with Heavyweight Aggregate Enhancement
by Andrie Harmaji, Reza Jafari and Guy Simard
Materials 2025, 18(17), 4087; https://doi.org/10.3390/ma18174087 - 1 Sep 2025
Viewed by 672
Abstract
The growing demand for sustainable and multifunctional construction materials, particularly those capable of addressing durability and energy challenges, has motivated the development of conductive and photothermally active geopolymers. This study investigated the use of an Fe-rich spinel aggregate (FSA) as a high-density filler [...] Read more.
The growing demand for sustainable and multifunctional construction materials, particularly those capable of addressing durability and energy challenges, has motivated the development of conductive and photothermally active geopolymers. This study investigated the use of an Fe-rich spinel aggregate (FSA) as a high-density filler in geopolymers composed of ground granulated blast furnace slag and bauxite residue, with a fixed addition of 1 wt% graphite (binder-based) to enhance electrical conductivity. The effects of different FSA replacement percentages (0–100%) on compressive strength, electrical conductivity, photothermal efficiency, and chemical resistance were evaluated. An increase in the FSA content translated to an increase in the final compressive strength, with 100% FSA replacement achieving the highest value of 45.5 ± 2.5 MPa at 28 days. As the FSA content increased, the electrical resistivity decreased to as low as 42 Ω·m at 100% replacement. Under simulated solar flux conditions (1 kW/m2), photothermal analysis revealed that the 100% FSA mixtures exhibited the highest surface temperature increase of 9.8 °C after 300 s, indicating their superior thermal responsiveness. Furthermore, acid immersion in 10% HCl for 28 days showed mass gain in all geopolymers, with the highest gain observed at 50% FSA (+11.51%). Similarly, the strength increased after acid exposure up to a 75% FSA content. These findings highlight the multifunctional potential of FSA-enhanced geopolymers for high-mechanical-performance, electrically conductive, photothermally active, and chemically durable materials as multifunctional construction materials. Full article
(This article belongs to the Special Issue Advances in Function Geopolymer Materials—Second Edition)
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30 pages, 10507 KB  
Article
Thermal Properties of Geopolymer Concretes with Lightweight Aggregates
by Agnieszka Przybek, Paulina Romańska, Kinga Korniejenko, Krzysztof Krajniak, Maria Hebdowska-Krupa and Michał Łach
Materials 2025, 18(13), 3150; https://doi.org/10.3390/ma18133150 - 3 Jul 2025
Cited by 1 | Viewed by 1131
Abstract
Despite the availability of various materials for chimney applications, ongoing research seeks alternatives with improved thermal and chemical resistance. Geopolymers are a promising solution, exhibiting exceptional resistance to high temperatures, fire, and aggressive chemicals. This study investigates fly ash-based lightweight geopolymer concretes that [...] Read more.
Despite the availability of various materials for chimney applications, ongoing research seeks alternatives with improved thermal and chemical resistance. Geopolymers are a promising solution, exhibiting exceptional resistance to high temperatures, fire, and aggressive chemicals. This study investigates fly ash-based lightweight geopolymer concretes that incorporate expanded clay aggregate (E.C.A.), perlite (P), and foamed geopolymer aggregate (F.G.A.). The composites were designed to ensure a density below 1200 kg/m3, reducing overall weight while maintaining necessary performance. Aggregate content ranged from 60 to 75 wt.%. Physical (density, thickness, water absorption), mechanical (flexural and compressive strength), and thermal (conductivity, resistance) properties were evaluated. F.G.A. 60 achieved a 76.8% reduction in thermal conductivity (0.1708 vs. 0.7366 W/(m·K)) and a 140.4% increase in thermal resistance (0.1642 vs. 0.0683). The F.G.A./E.C.A./P 60 mixture showed the highest compressive strength (18.069 MPa), reaching 52.7% of the reference concrete’s strength, with a 32.3% lower density (1173.3 vs. 1735.0 kg/m3). Water absorption ranged from 4.9% (REF.) to 7.3% (F.G.A. 60). All samples, except F.G.A. 70 and F.G.A. 75, endured heating up to 800 °C. The F.G.A./E.C.A./P 60 composite demonstrated well-balanced performance: low thermal conductivity (0.2052 W/(m·K)), thermal resistance up to 1000 °C, flexural strength of 4.386 MPa, and compressive strength of 18.069 MPa. The results confirm that well-designed geopolymer lightweight concretes are suitable for chimney and flue pipe linings operating between 500 and 1000 °C and exposed to acidic condensates and aggressive chemicals. This study marks the initial phase of a broader project on geopolymer-based prefabricated chimney systems. Full article
(This article belongs to the Special Issue Advances in Function Geopolymer Materials—Second Edition)
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Review

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43 pages, 4854 KB  
Review
The Role of Natural Fibers in the Building Industry—The Perspective of Sustainable Development
by Agnieszka Przybek
Materials 2025, 18(16), 3803; https://doi.org/10.3390/ma18163803 - 13 Aug 2025
Viewed by 1007
Abstract
Contemporary construction faces the need to reduce its negative impact on the environment, prompting designers, investors, and contractors to seek more sustainable materials and technologies. One area of dynamic development is the use of natural fibers as an alternative to conventional, often synthetic, [...] Read more.
Contemporary construction faces the need to reduce its negative impact on the environment, prompting designers, investors, and contractors to seek more sustainable materials and technologies. One area of dynamic development is the use of natural fibers as an alternative to conventional, often synthetic, building components. Plant- and animal-based fibers, such as hemp, flax, jute, straw, bamboo, and sheep’s wool, are characterized by low energy consumption in production, renewability, and biodegradability. Their use is in line with the concept of a circular economy and reduces the carbon footprint of buildings. Natural fibers offer a number of beneficial physical and functional properties, including good thermal and acoustic insulation parameters, as well as hygroscopicity, which allows for the regulation of indoor humidity, improving air quality and comfort of use. In recent years, there has also been a renaissance of traditional building techniques, such as straw construction, often combined with modern engineering standards. Their potential is particularly recognized in green and energy-efficient construction. The article provides an overview of the types of natural fibers available for use in construction and analyzes their technical, environmental, and economic properties. It also draws attention to current regulations, standards, and certifications (e.g., LEED, BREEAM) that promote the popularization of these solutions. In light of the analyzed data, the role of natural fibers as a viable alternative supporting the transformation of the construction sector towards sustainable development is considered. Full article
(This article belongs to the Special Issue Advances in Function Geopolymer Materials—Second Edition)
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