Special Issue "Catalysis in Heterocyclic and Organometallic Synthesis"
Deadline for manuscript submissions: 30 November 2020.
Interests: Heterocyclic chemistry; Organometallic chemistry of transition metals; NMR spectroscopy; Stereochemistry; Molecular modelling; Antiproliferative compounds; Cross coupling reactions; Organocatalysis
Special Issues and Collections in MDPI journals
In the last decades, diverse methods of catalysis, including transition metal catalysis, organocatalysis, their homogenous and heterogenous versions as well as biocatalysis, witnessed an extremely rapid development in a variety of chemical transformations utilised in chemical, fuel, pharmaceutical and agricultural industries to afford a wide range of products having impact on daily life. As a results of intensive research a number of well-established concepts and tools are now available to get a deeper insight into the mechanisms of catalytic reactions allowing to develop more and more sophisticated catalytic systems and conditions capable of governing the elementary steps of a multistep transformation to proceed via a rationally designed pathway. Although in the chemistry of heterocyclic and organometallic compounds, representing two large and partly overlapping domains of chemical research, the most efficient, robust and often environmentally benign synthetic strategies are based on catalysis, there is a constant need to develop further superior systems of higher catalytic activity and specificity and to elaborate catalytic versions of extensively used stoichiometric organic syntheses with particular regards to asymmetric transformations.
Prof. Dr. Antal Csámpai
Manuscript Submission Information
Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All papers will be peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.
Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Catalysts is an international peer-reviewed open access monthly journal published by MDPI.
Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 1800 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.
- Heterocyclic synthesis
- Synthesis of organometallics
- Metal catalysis
- Chemoselective transformations
- Asymmetric synthesis
- Catalytic annulation reactions
- Enantioselective syntheses
- Reaction mechanism
The below list represents only planned manuscripts. Some of these manuscripts have not been received by the Editorial Office yet. Papers submitted to MDPI journals are subject to peer-review.
Title: Recent Advances in Oxidative Synthesis of Quinolines
Author: Liang-Hua Zou
Abstract: The research on the synthesis of quinolines has been extensively investigated during the past years due to their significant properties and applications in pharmaceuticals, useful ligands and materials. The traditional synthesis of quinolines, such as Friedländer quinoline synthesis and Combes quinoline synthesis, could date back to one century ago. So far, many methods have been developed to construction of structurally diverse and complex quinolines. Despite these advances, many of these procedures often suffered from strong acidic conditions, highly explosive, low yields, and expensive reagents. Therefore, the development of more efficient alternatives is still highly desirable.
Oxidative protocols have become an important means of synthesis of quinolines in the past years. Recently, significant advances in this field have witnessed a myriad of elegant reports on transition-metal catalyzed or transition-metal free reactions. These reactions indicate there are a great potential in exploiting the inherent reactivity of molecules through the combination use of an efficient catalyst, base, oxidant and solvent. This mini-review will focus on the synthesis of quinolines via oxidative annulation with or without the catalyst of transition-metals.
Title: Selective hydration of nitriles to amides in air with Rh(I)-N-heterocyclic catalysts
Authors: Csilla Enikő Czégéni, Sourav De, Antal Udvardy, Nóra Judit Derzsi, Gergely Papp, Gábor Papp, and Ferenc Joó
Abstract: Although catalytic hydration of nitriles to amides is an often studied reaction, most of the catalysts are based on ruthenium, in contrast to rhodium complexes which are much less frequently applied as catalysts in this process. In this work we demonstrate that several easily available Rh(I)-NHC catalysts efficiently furnish the desired amides selectively, in air and under mild conditions.
Title: Non-K region disubstituted pyrenes (1,3-, 1,6- and 1,8-) by (hetero)aryl groups
Abstract: Disubstituted pyrenes at the non-K region by the same or different (hetero)aryl groups are in the increasing interest of scientists during the last decade due to their optical and photophysical properties. However, in that area, there is no systematization of the structures and synthesis methods and their limitations. Taking all into account I wrote the review article of the reported in the literature approaches to their synthesis starting from commercially available pyrene. Herein, the ways of obtaining of disubstituted intermediates based on bromination and acylation reaction were presented what is crucial in the determination of the possibility of further functionalization by using coupling, cycloaddition, condensation, etc. reactions. Moreover, the application of disubstituted pyrenes in the synthesis of 1,3,6,8-tetrasubstituted was also reviewed. The whole review demonstrates the direction in the chemistry of disubstituted pyrenes.
Author: Dawid Zych