Novel Electrocatalysts for CO2 Reduction

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Electrocatalysis".

Deadline for manuscript submissions: closed (30 November 2021) | Viewed by 2913

Special Issue Editor


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Guest Editor
Center for Sustainable Future Technologies @POLITO, Istituto Italiano di Tecnologia, Via Livorno 60, 10144 Turin, Italy
Interests: electrochemical analysis; membranes; electrocatalysis

Special Issue Information

Dear Colleagues,

The CO2 that comes from the use of fossil fuels accounts for about 65% of the global greenhouse gas emissions, and it plays a critical role in global climate change. Among the different strategies that have been used to address the storage and reutilization of CO2, the transformation of CO2 into chemicals or fuels with high added-value has been considered to be a winning approach. This transformation is capable of reducing carbon emissions and inducing a “fuel switching” that exploits renewable energy sources. However, the industrial utilization of CO2 to fuel is currently under development. Considerable emphasis has been placed on increasing the present low efficiency and low production rate. In fact, depending on the selected catalyst, reaction conditions and electrolyte, different products—such as carbon monoxide, formic acid, and hydrocarbons including methane, methanol, or mixtures thereof—can be obtained. Moreover, the CO2 is typically dissolved in aqueous media and, consequently, the hydrogen evolution reaction (HER) is in inevitable competition with CO2 reduction.

The scope of this issue is to exploit the possibility of novel nano structured non-noble materials to be used for the aforementioned applications, in high current densities and with high selectivity, toward the production of value added products. The thorough electrochemical analysis of the materials (from cyclic voltammetry to Impedance spectroscopy) is highly encouraged.

Dr. M. Amin Farkhondehfal
Guest Editor

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Keywords

  • Electrocatalyst
  • CO2 reduction
  • Formic Acid
  • Current density
  • Impedance spectroscopy
  • Electrochemistry
  • nano structures

Published Papers (1 paper)

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Research

13 pages, 5688 KiB  
Article
Effect of Calcium Doping Using Aqueous Phase Reforming of Glycerol over Sonochemically Synthesized Nickel-Based Supported ZrO2 Catalyst
by Ain Syuhada, Mariam Ameen, Farooq Sher, Mohammad Tazli Azizan, Aqsha Aqsha, Mohd Hizami Mohd Yusoff and Muhamad Syafiq Hazwan Ruslan
Catalysts 2021, 11(8), 977; https://doi.org/10.3390/catal11080977 - 16 Aug 2021
Cited by 14 | Viewed by 2317
Abstract
The aqueous phase reforming (APR) of glycerol was studied using sonochemically synthesized 10%Ni-x%Ca/ZrO2 catalysts (where x = 0, 0.5, 3, and 5) for the production of value-added liquid products. The APR reaction was performed in a batch reactor under the following conditions: [...] Read more.
The aqueous phase reforming (APR) of glycerol was studied using sonochemically synthesized 10%Ni-x%Ca/ZrO2 catalysts (where x = 0, 0.5, 3, and 5) for the production of value-added liquid products. The APR reaction was performed in a batch reactor under the following conditions: 20 bar, 230 °C 450 rpm, and 1 h of reaction time. The synthesized catalysts were characterized using XRD, FESEM, BET, and H2-TPR to observe the effect of Ca doping on the physio-chemical properties of the catalysts. The results revealed that, at higher Ca loading, the catalysts experienced serious particles’ agglomeration, which resulted in a larger particles’ size, smaller surface area, and smaller pore volume owing to uneven distribution of the particles. The characterization results of the catalysts confirmed that the Us catalysts have a slightly higher surface area, pore volume, and pore size, as well as highly reducible and fine crystalline structure, compared with WI catalysts. The catalytic performance of the catalysts shows that 1,3-propanediol (1,3-PDO) and 1,2-propanediol (1,2-PDO) were the two main liquid products produced from this reaction. The highest selectivity of 1,3-PDO (23.84%) was obtained over the 10%Ni/ZrO2 catalyst, while the highest selectivity of 1,2-PDO (25.87%) was obtained over the 10%Ni-5%Ca/ZrO2 catalyst. Full article
(This article belongs to the Special Issue Novel Electrocatalysts for CO2 Reduction)
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