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Electrochem, Volume 5, Issue 4

December 2024 - 13 articles

Cover Story: The synergistic effects of co-doping titanium (Ti) and vanadium (V) on P2-type Na0.67Fe0.5Mn0.5O2 cathode is investigated in this study to address the structural instability arising from the destructive Jahn-Teller (JT) distortion effect of Mn3+/ Mn4+ during cycling. The Ti and V co-doping improved the crystallinity of the cathode structure, and it also enhanced the structural stability and mitigated the phase transition from P2 to OP4 at higher voltages. The investigation involved a comprehensive analysis of structural properties and an evaluation of electrochemical performance. The co-doping enhanced the energy density, ion transport, stability, and capacity retention. The research findings revealed an avenue toward the enhanced performance and longevity in sodium-ion batteries for advanced energy storage applications. View this paper
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Articles (13)

  • Article
  • Open Access
1,871 Views
14 Pages

Influence of Cigarette Butt Extract on the Suppression of Metal Corrosion

  • Verena Šućurović,
  • Nives Vladislavić and
  • Ivana Škugor Rončević

21 December 2024

Cigarette butts are an increasing environmental burden worldwide, and the quantities discarded each year could continue to rise. The chemical composition of cigarette butts, which comprises about 4000 different toxic chemicals, as well as their persi...

  • Article
  • Open Access
1 Citations
2,057 Views
11 Pages

Electrochemical Characterization of Recast Nafion® Film-Modified Electrodes in Acetonitrile with Various Electrolytes

  • Anna F. Claire,
  • Peter Zacher,
  • Danielle Lehto,
  • Daysha Krahn and
  • Krysti L. Knoche Gupta

17 December 2024

Nafion® is a cation exchange polymer that is commonly used in aqueous energy applications such as fuel cells due to its ability to exclude anions and neutral molecules and increase apparent diffusion of cationic redox molecules. However, this beh...

  • Article
  • Open Access
1 Citations
2,618 Views
14 Pages

Enhanced Performance with Nano-Porous Silicon in TiFeSi2/C Composite Anode for Lithium-Ion Batteries

  • Alhamdu Nuhu Bage,
  • Olusola Bamisile,
  • Humphrey Adun,
  • Paul Takyi-Aninakwa,
  • Destina Godwin Ekekeh and
  • Qingsong Howard Tu

5 December 2024

The innovative design of the microstructure of silicon-based composite anodes in Li-ion batteries holds great potential for overcoming inherent limitations, such as the significant volume change experienced by silicon particles. In this study, TiFeSi...

  • Article
  • Open Access
2,473 Views
14 Pages

Full Tailored Metal Content NCM Regeneration from Spent Lithium-Ion Battery Mixture Under Mild Condition

  • Alpha Chi Him Tsang,
  • Shaobo Ouyang,
  • Yang Lv,
  • Chi Chung Lee,
  • Chi-Wing Tsang and
  • Xiao-Ying Lu

2 December 2024

Mild conditioned, second-life ternary nickel–cobalt–manganese (NCM) black powder regeneration from spent lithium-ion batteries’ (LIBs) black powder mixture was demonstrated after mild conditioned p-toluenesulphuric acid (PTA)-assist...

  • Article
  • Open Access
1 Citations
1,789 Views
16 Pages

18 November 2024

This work describes the development of an electrochemical biosensor method based on bacterial consortia to determine antioxidant capacity. The bacterial consortium used is a combination of bacteria from the genera Bacillus and Pseudomonas which can p...

  • Article
  • Open Access
1 Citations
1,521 Views
30 Pages

15 November 2024

For the first time, carbon-particle-supported palladium-based cobalt composite electrocatalysts (abbreviated as PdxCoy/CPs) were prepared using a calcination–hydrothermal process–hydrothermal process (denoted as CHH). The catalysts of Pdx...

  • Article
  • Open Access
1,615 Views
24 Pages

A Nitrogen- and Carbon-Present Tin Dioxide-Supported Palladium Composite Catalyst (Pd/N-C-SnO2)

  • Keqiang Ding,
  • Weijia Li,
  • Mengjiao Li,
  • Mengyao Di,
  • Ying Bai,
  • Xiaoxuan Liang and
  • Hui Wang

13 November 2024

For the first time, nitrogen- and carbon-present tin dioxide-supported palladium composite catalysts (denoted as Pd/N-C-SnO2) were prepared via an HCH method (HCH is the abbreviation for the hydrothermal process–calcination–hydrothermal p...

  • Article
  • Open Access
1 Citations
3,128 Views
12 Pages

8 November 2024

In this study, vanadium (3.5+) electrolyte was prepared for vanadium redox flow batteries (VRFBs) through a reduction reaction using a batch-type hydrothermal reactor, differing from conventional production methods that utilize VOSO4 and V2O5. The st...

  • Article
  • Open Access
3 Citations
2,169 Views
15 Pages

24 October 2024

This study investigates the underlying mechanisms of hydrogen peroxide (H₂O₂) sensing using a composite material of bismuth oxide and bismuth oxyselenide (Bi2OxSey). The antagonistic effect of tungsten (W)-doping on the electrochemical be...

  • Article
  • Open Access
3 Citations
4,885 Views
18 Pages

Enhanced Performance of Sodium-Ion Battery Cathodes with Ti and V Co-Doped P2-Type Na0.67Fe0.5Mn0.5O2 Materials

  • Trapa Banik,
  • Indranil Bhattacharya,
  • Kirankumar Venkatesan Savunthari,
  • Sanjeev Mukerjee,
  • Webster Adepoju and
  • Abiodun Olatunji

18 October 2024

Manganese- and iron-rich P2-type Na0.67Fe0.5Mn0.5O2 (NFM) has garnered significant interest as a promising cathode candidate due to the natural abundance of Fe and Mn along with a high redox couple of Fe3+/Fe4+ and Mn3+/Mn4+. Despite all these m...

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Electrochem - ISSN 2673-3293