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Reactions, Volume 6, Issue 2 (June 2025) – 10 articles

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18 pages, 8106 KiB  
Article
Fischer–Tropsch Synthesis: Effect of CO Conversion over Ru/NaY Catalyst
by Wenping Ma, Jia Yang, Gary Jacobs and Dali Qian
Reactions 2025, 6(2), 31; https://doi.org/10.3390/reactions6020031 - 1 May 2025
Abstract
Unlike on Fe and Co catalysts, the CO conversion effect on Ru catalyst performance is little reported. This study is undertaken to explore the issue using a series of Ru/NaY catalysts under 200–230 °C, 2.0 MPa, H2/CO = 2, and 10–60% [...] Read more.
Unlike on Fe and Co catalysts, the CO conversion effect on Ru catalyst performance is little reported. This study is undertaken to explore the issue using a series of Ru/NaY catalysts under 200–230 °C, 2.0 MPa, H2/CO = 2, and 10–60% CO conversion in a 1 L continuous stirred tank reactor (CSTR). The results are comparatively studied with those of Fe and Co catalysts reported previously. The NaY support and four 1.0%, 2.5%, 5.0%, and 7.5% Ru/NaY catalysts were characterized by BET, H2 chemisorption, H2O-TPD, XRD, HRTEM, and XANES/EXAFS techniques. The BET and XRD results suggest a high surface area (730 m2/g), high degree of crystallinity of the NaY support, and high dispersion of Ru, while an hcp Ru structure and well-reduced Ru were reflected in the HR-TEM FFT and XANES/EXAFS results. The reaction results indicate that the CO conversion effect on CH4 and C5+ selectivities on the Ru is the same as that on the Fe and Co catalysts, with CH4 selectivity decreasing and C5+ selectivity increasing with increasing CO conversion. However, the CO conversion effect on olefin formation for the Ru catalyst was found to be opposite to that of the Fe and Co; increasing CO conversion enhanced olefin formation but suppressed secondary reactions of 1-olefins. The H2O cofeeding experiments showed that H2O impacted olefin formation by suppressing hydrogen adsorption and hydrogenation. The H2O-TPD experiment evidenced a much stronger H2O adsorption capacity (6.8 mmol/g-cat) on Ru followed by Co (1 mmol/g-cat), and then Fe (0.2 mmol/g-cat)., which showed only a very low H2O adsorption capacity.This finding may explain the opposite CO conversion effect on olefin formation observed on the Ru catalyst, and may also explain why low CH4 selectivity (i.e., 3%) occurred on the Ru catalyst and high CH4 selectivity (i.e., 6–8%) occurred on the Co catalyst, both of which possess low water gas shift (WGS) activity. Full article
(This article belongs to the Special Issue Fischer-Tropsch Synthesis: Bridging Carbon Sustainability)
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14 pages, 3335 KiB  
Article
Efficient Copolymerization of CO2 and Propylene Oxide via ZnGA/Zn-Co DMC Composite Catalysts: Synergistic Catalysis for High-Performance Polypropylene Carbonate
by Shuqin Miao, Xiaojiong Wu, Delong Ding, Chunliang Ge, Weihua Shen, Yi Yang and Yunjin Fang
Reactions 2025, 6(2), 30; https://doi.org/10.3390/reactions6020030 - 29 Apr 2025
Viewed by 183
Abstract
Polypropylene carbonate (PPC) is a biodegradable material derived from propylene oxide (PO) with the renewable resource CO2. In this study, PPC was prepared by the catalytic polymerization of CO2 with PO using a zinc glutarate/zinc cobalt double metal cyanide (ZnGA/DMC) [...] Read more.
Polypropylene carbonate (PPC) is a biodegradable material derived from propylene oxide (PO) with the renewable resource CO2. In this study, PPC was prepared by the catalytic polymerization of CO2 with PO using a zinc glutarate/zinc cobalt double metal cyanide (ZnGA/DMC) composite catalyst prepared from two heterogeneous catalysts, zinc glutarate (ZnGA) and zinc cobalt double metal cyanide (Zn-Co DMC). High selectivity of PPC was achieved among the polymer and propylene carbonate. The prepared PPC had high molecular weight. The thermal stability of the PPC product was obviously improved by the optimization of the reaction conditions. The catalytic effect of the composite catalyst was superior to that of individual ZnGA and Zn-Co DMC, overcoming the shortcomings of those two catalysts. And the composite catalyst also stimulated some synergistic effects between the two composites, which significantly improved the catalytic effect. Full article
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14 pages, 3577 KiB  
Article
Two-Dimensional Lamellar Stacked Bi2O3/CeO2 Type-II Heterojunctions Promote Carrier Separation to Enhance Ciprofloxacin Oxidation
by Lihong Chen, Xiufei Zhao, Kuo Zhang, Biyu Wu, Xiao Yang, Haonan Zou, Lei Zhang, Huahao Shao, Tianyi Ma, Hu Zhou and Yusheng Zhang
Reactions 2025, 6(2), 29; https://doi.org/10.3390/reactions6020029 - 23 Apr 2025
Viewed by 169
Abstract
The development of efficient and stable photocatalysts is critical for addressing water pollution challenges caused by persistent organic contaminants. However, single-component photocatalysts often suffer from rapid photogenerated carrier recombination and limited visible-light absorption. In this study, a two-dimensional lamellar stacked Bi2O [...] Read more.
The development of efficient and stable photocatalysts is critical for addressing water pollution challenges caused by persistent organic contaminants. However, single-component photocatalysts often suffer from rapid photogenerated carrier recombination and limited visible-light absorption. In this study, a two-dimensional lamellar stacked Bi2O3/CeO2 type-II heterojunction photocatalyst (BC) was successfully synthesized in situ by a topological transformation strategy induced by high-temperature oxidation of monolithic Bi. Transmission electron microscopy (TEM) and scanning electron microscopy (SEM) analyses confirmed the uniform distribution of Bi2O3 nanosheets on CeO2 surfaces, forming an intimate interfacial contact that enhances charge separation and transfer efficiency. Photoluminescence (PL) spectroscopy, UV–visible diffuse reflectance spectroscopy (DRS), and electrochemical characterization revealed extended visible-light absorption (up to 550 nm) and accelerated electron migration in the heterojunction. Under simulated sunlight, the optimized BOC (3:1) composite exhibited a ciprofloxacin (CIP) degradation rate constant 2.30 and 5.63 times higher than pure Bi2O3 and CeO2, respectively. Theoretical calculations validated the type-II band alignment with conduction and valence band offsets of 0.07 eV and 0.17 eV, which facilitated efficient spatial separation of photogenerated carriers. This work provides a rational strategy for designing heterojunction photocatalysts and advancing their application in water purification. Full article
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20 pages, 5240 KiB  
Article
Sustainable Reduction of Strontium Sulfate Using Bioethanol: A Pathway to Carbon-Neutral SrS Production
by Javier E. Morales-Mendoza, Jorge L. Domínguez-Arvizu, Alma B. Jasso-Salcedo, Blanca C. Hernández-Majalca, José L. Bueno-Escobedo, Alejandro López-Ortiz and Virginia H. Collins-Martínez
Reactions 2025, 6(2), 28; https://doi.org/10.3390/reactions6020028 - 21 Apr 2025
Viewed by 317
Abstract
Achieving net-zero carbon emissions, this study introduces a sustainable pathway for reducing strontium sulfate (SrSO4) and celestite ore to strontium sulfide (SrS) using biofuels (biomethane, bioethanol) derived from agro-industrial waste and green hydrogen. Traditional SrSO4 reduction methods, which rely on [...] Read more.
Achieving net-zero carbon emissions, this study introduces a sustainable pathway for reducing strontium sulfate (SrSO4) and celestite ore to strontium sulfide (SrS) using biofuels (biomethane, bioethanol) derived from agro-industrial waste and green hydrogen. Traditional SrSO4 reduction methods, which rely on fossil-derived reductants like coal and operate at energy-intensive temperatures (1100–1200 °C), generate significant greenhouse gases and toxic byproducts, highlighting the need for eco-friendly alternatives. Experimental results demonstrate that bioethanol outperformed other reductants, achieving 97% conversion of synthetic SrSO4 at 950 °C within 24 min and 74% conversion of natural celestite ore over 6 h. Remarkably, this bioethanol-driven process matches the energy efficiency of the conventional black ash method while enabling carbon neutrality through renewable feedstock utilization, reducing CO2 emissions by 30–50%. By valorizing agro-industrial waste streams, this strategy advances circular economy principles and aligns with Mexico’s national agenda for sustainable industrial practices, including its commitment to decarbonizing heavy industries. This study contributes to sustainable development goals and offers a scalable solution for decarbonizing strontium compound production in the chemical industry. Full article
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14 pages, 6104 KiB  
Article
Investigating the Ag–Support Interaction in Silver Catalysts for Soot Combustion: The Importance of Coordination of Al3+ Ions in the Support
by Ewa M. Iwanek (nee Wilczkowska), Aleksandra Goździk and Zbigniew Kaszkur
Reactions 2025, 6(2), 27; https://doi.org/10.3390/reactions6020027 - 18 Apr 2025
Viewed by 200
Abstract
This study shows how important the coordination of Al3+ ions in the silver support is for the overall activity in soot combustion. Five silver catalysts with a silver content of 14.7 wt.% were prepared using the following supports: α-Al2O3 [...] Read more.
This study shows how important the coordination of Al3+ ions in the silver support is for the overall activity in soot combustion. Five silver catalysts with a silver content of 14.7 wt.% were prepared using the following supports: α-Al2O3, which has only octahedrally coordinated Al3+, θ-Al2O3, which has both octahedrally and tetrahedrally coordinated Al3+, and zeolites, which contain only tetrahedrally coordinated Al3+: 10X, 13X, and 5A. The analysis of the diffraction patterns showed that silver on the surface of catalysts made with the first four supports was mainly in the metallic form, except for Ag/5A in which there was a lack of reflections from Ag0 in the XRD pattern. Nevertheless, the difference in the activity of the support and the catalyst as well as the EDX results indicate the presence of silver on the catalyst. The SEM-EDX analysis showed that the silver dispersion strongly depends on the support and that even the zeolites with large silver particles on the surface have silver evenly distributed across the surface. The activity of the catalysts decreased in the following series: Ag/Al 1200 > Ag/5A ≈ Ag/13X > Ag/10X ≈ Ag/Al 550. Time-of-Flight Secondary Ion Mass Spectrometry was used to delve into the reason why the catalyst with the low-surface area α-Al2O3 support yielded a better catalyst than that obtained using the high-surface area alumina support and showed that different ratios of secondary ions were emitted from the two surfaces. Full article
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15 pages, 7187 KiB  
Article
Hexoses Biorefinery: Driving Glucose Dehydration over Sulfonic Polymer and Hybrid Acid Catalysts
by Kryslaine M. A. Santos, Simone J. Canhaci, Rafael F. Perez and Marco A. Fraga
Reactions 2025, 6(2), 26; https://doi.org/10.3390/reactions6020026 - 12 Apr 2025
Viewed by 140
Abstract
Glucose is the most abundant monosaccharide as it is the primary unit of cellulose and starch, which are the more relevant feedstocks for biorefineries. Dehydration of glucose can lead to anhydroglucoses, whose interest has been increasing due to its potential industrial use. Commercial [...] Read more.
Glucose is the most abundant monosaccharide as it is the primary unit of cellulose and starch, which are the more relevant feedstocks for biorefineries. Dehydration of glucose can lead to anhydroglucoses, whose interest has been increasing due to its potential industrial use. Commercial sulfonic polymer resins and a synthesized organic–inorganic mesoporous material were taken as Brønsted acid catalysts. High hexose conversion (up to 98%) and selectivity to anhydroglucoses (~80%) could be reached, turning this process into an alternative route to carbohydrate pyrolysis that presents an energy-intensive downstream. Hexose conversion to anhydroglucoses was related to the amount of acid sites, and the removal of one molecule of water from hexoses to produce anhydroglucoses was found as the preferential dehydration route over a bare Brønsted acid catalyst in anhydrous polar aprotic solvent (DMF) at mild conditions. Product distribution changed dramatically upon catalyst deactivation with HMF and fructose emerging as relevant products. It was suggested that an additional Lewis surface is produced during the deactivation process, probably arising from the formation of insoluble high molecular weight compounds in acidic media. Full article
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28 pages, 12427 KiB  
Review
Photocatalytic Degradation of Methyl Orange in Wastewater Using TiO2-Based Coatings Prepared by Plasma Electrolytic Oxidation of Titanium: A Review
by Stevan Stojadinović
Reactions 2025, 6(2), 25; https://doi.org/10.3390/reactions6020025 - 8 Apr 2025
Viewed by 381
Abstract
This review analyzes TiO2-based coatings formed by the plasma electrolytic oxidation (PEO) process of titanium for the photocatalytic degradation of methyl orange (MO) under simulated solar irradiation conditions. PEO is recognized as a useful technique for creating oxide coatings on various [...] Read more.
This review analyzes TiO2-based coatings formed by the plasma electrolytic oxidation (PEO) process of titanium for the photocatalytic degradation of methyl orange (MO) under simulated solar irradiation conditions. PEO is recognized as a useful technique for creating oxide coatings on various metals, particularly titanium, to assist in the degradation of organic pollutants. TiO2-based photocatalysts in the form of coatings are more practical than TiO2-based photocatalysts in the form of powder because the photocatalyst does not need to be recycled and reused after wastewater degradation treatment, which is an expensive and time-consuming process. In addition, the main advantage of PEO in the synthesis of TiO2-based photocatalysts is its short processing time (a few minutes), as it excludes the annealing step needed to convert the amorphous TiO2 into a crystalline phase, a prerequisite for a possible photocatalytic application. Pure TiO2 coatings formed by PEO have a low photocatalytic efficiency in the degradation of MO, which is due to the rapid recombination of the photo-generated electron/hole pairs. In this review, recent advances in the sensitization of TiO2 with narrow band gap semiconductors (WO3, SnO2, CdS, Sb2O3, Bi2O3, and Al2TiO5), doping with rare earth ions (example Eu3+) and transition metals (Mn, Ni, Co, Fe) are summarized as an effective strategy to reduce the recombination of photo-generated electron/hole pairs and to improve the photocatalytic efficiency of TiO2 coatings. Full article
(This article belongs to the Special Issue Feature Papers in Reactions in 2025)
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16 pages, 3488 KiB  
Article
Study on the Anti-Photocorrosion Mechanism of Novel Self-Assembled Spherical Cu2O/FePO4 Z-Scheme Heterojunctions
by Kuo Zhang, Xiufei Zhao, Hang Qian, Lihong Chen, Biyu Wu, Xiao Yang, Haonan Zou, Yujiao Hu, Feng Chen, Borong Liao, Hu Zhou, Lei Zhang, Tianyi Ma and Yusheng Zhang
Reactions 2025, 6(2), 24; https://doi.org/10.3390/reactions6020024 - 7 Apr 2025
Viewed by 280
Abstract
Cu2O, a narrow-bandgap semiconductor with visible light absorption capabilities, faces limitations in photocatalytic applications due to photocorrosion from hole self-oxidation and insufficient light absorption. In this work, a series of novel spherical Cu2O/FePO4 Z-scheme heterojunctions were successfully synthesized [...] Read more.
Cu2O, a narrow-bandgap semiconductor with visible light absorption capabilities, faces limitations in photocatalytic applications due to photocorrosion from hole self-oxidation and insufficient light absorption. In this work, a series of novel spherical Cu2O/FePO4 Z-scheme heterojunctions were successfully synthesized via self-assembly to overcome these challenges. The photocurrent, electrical impedance spectroscopy (EIS), and photoluminescence (PL) tests showed that Cu2O/1.5FePO4 (CF1.5) had excellent electron hole separation efficiency. Subsequently, photocatalytic degradation was utilized as a probing technique to further confirm the above conclusions, with the kinetic reaction constants of CF1.5 being 2.46 and 11.23 times higher than those of Cu2O and FePO4, respectively. After five cycles of experiments and XPS analysis, it was found that the content of Cu(I) in CF1.5 did not significantly decrease after the reaction, indicating that it has superior anti-photocorrosion performance compared to single Cu2O, which is also due to the establishment of a Z-scheme heterojunction. Systematic studies using radical scavenging experiments and ESR tests identified ·OH and ·O2 as the main active species involved in photocatalysis. The formation of a Z-scheme heterojunction not only enhances the photocatalytic activity of the CF1.5 composite but also effectively suppresses the photocorrosion of Cu2O, thereby offering a promising approach for enhancing anti-photocorrosion of Cu2O. Full article
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28 pages, 6457 KiB  
Article
Photocatalytic and Photo-Fenton-like Degradation of Cationic Dyes Using SnFe2O4/g-C3N4 Under LED Irradiation: Optimization by RSM-BBD and Artificial Neural Networks (ANNs)
by Yassine Elkahoui, Fatima-Zahra Abahdou, Majda Ben Ali, Said Alahiane, Mohamed Elhabacha, Youssef Boutarba and Souad El Hajjaji
Reactions 2025, 6(2), 23; https://doi.org/10.3390/reactions6020023 - 28 Mar 2025
Viewed by 481
Abstract
The development of heterostructures incorporating photocatalysts optimized for visible-light activity represents a major breakthrough in the field of environmental remediation research, offering innovative and sustainable solutions for environmental purification. This study explores the photocatalytic capabilities of a SnFe2O4/g-C3 [...] Read more.
The development of heterostructures incorporating photocatalysts optimized for visible-light activity represents a major breakthrough in the field of environmental remediation research, offering innovative and sustainable solutions for environmental purification. This study explores the photocatalytic capabilities of a SnFe2O4/g-C3N4 heterojunction nanocomposite, successfully synthesized from graphitic carbon nitride (g-C3N4) and tin ferrate (SnFe2O4) and applied to the degradation of the cationic dye brilliant cresyl blue (BCB) in an aqueous solution. These two components are particularly attractive due to their low cost and ease of fabrication. Various characterization techniques, including XRD, FTIR, SEM, and TEM, were used to confirm the successful integration of SnFe2O4 and g-C3N4 phases in the synthesized catalysts. The photocatalytic and photo-Fenton-like activity of the heterojunction composites was evaluated by the degradation of brilliant cresyl blue under visible LED illumination. Compared to the pure components SnFe2O4 and g-C3N4, the SnFe2O4/g-C3N4 nanocomposite demonstrated a superior photocatalytic performance. Furthermore, the photo-Fenton-like performance of the composites is much higher than the photocatalytic performances. The significant improvement in photo-Fenton activity is attributed to the synergistic effect between SnFe2O4 and g-C3N4, as well as the efficient separation of photoexcited electron/hole pairs. The recyclability of the SnFe2O4/g-C3N4 composite toward BCB photo-Fenton like degradation was also shown. This study aimed to assess the modeling and optimization of photo-Fenton-like removal BCB using the SnFe2O4/g-C3N4 nanomaterial. The main parameters (photocatalyst dose, initial dye concentration, H2O2 volume, and reaction time) affecting this system were modeled by two approaches: a response surface methodology (RSM) based on a Box–Behnken design and artificial neural network (ANN). A comparison was made between the predictive accuracy of RSM for brilliant cresyl blue (BCB) removal and that of the artificial neural network (ANN) approach. Both methodologies provided satisfactory and comparable predictions, achieving R2 values of 0.97 for RSM and 0.99 for ANN. Full article
(This article belongs to the Special Issue Feature Papers in Reactions in 2025)
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19 pages, 6227 KiB  
Article
Comparative Study of Greener Alkene Epoxidation Using a Polymer-Supported Mo(VI) Complex: Performance Evaluation and Optimisation via Response Surface Methodology
by Md Masud Rana Bhuiyan and Basudeb Saha
Reactions 2025, 6(2), 22; https://doi.org/10.3390/reactions6020022 - 24 Mar 2025
Viewed by 244
Abstract
A heterogeneous polybenzimidazole-supported Mo(VI) catalyst and tert-butyl hydroperoxide (TBHP) as an oxidising reagent have been utilised to establish a more environmentally friendly and greener alkene epoxidation process. A polybenzimidazole-supported Mo(VI) complex (PBI.Mo) has been prepared, characterised and evaluated successfully. The stability and [...] Read more.
A heterogeneous polybenzimidazole-supported Mo(VI) catalyst and tert-butyl hydroperoxide (TBHP) as an oxidising reagent have been utilised to establish a more environmentally friendly and greener alkene epoxidation process. A polybenzimidazole-supported Mo(VI) complex (PBI.Mo) has been prepared, characterised and evaluated successfully. The stability and catalytic activity of the produced catalyst have been evaluated for the epoxidation of 1,7-octadiene and 1,5-hexadiene in a jacketed stirred batch reactor to assess its performance towards these alkenes. The suitability and efficiency of the catalyst have been compared by studying the effect of reaction temperature, feed mole ratio of alkene to TBHP, catalyst loading, and reaction time on the yield of 1,2-epoxy-5-hexene and 1,2-epoxy-7-octene. Response surface methodology (RSM) using Box–Behnken Design (BBD) has been employed to design experimental runs and study the catalytic performance of the PBI.Mo catalyst for all batch experimental results. A quadratic regression model has been developed representing an empirical relationship between reaction variables and response, which is the yield of epoxides. The numerical optimisation technique concluded that the maximum yield that can be reached is 66.22% for 1,7-octadiene and 64.2% for 1,5-hexadiene. The reactivity of alkenes was observed to follow the sequence 1,5-hexadiene > 1,7-octadiene. The findings of this study confirm that the optimal reaction conditions vary between the two reactions, indicating differences in catalytic performance for each alkene. Full article
(This article belongs to the Special Issue Feature Papers in Reactions in 2025)
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