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16 September 2026

Geological Records of a 1000-Yr-Old Extreme Tsunami Event Revealed by Drill Cores in Qiongzhou Strait

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1
Institute of Geomechanics, Chinese Academy of Geological Sciences, Beijing 100081, China
2
Key Laboratory of Active Tectonics and Geological Safety, Ministry of Natural Resources, Institute of Geomechanics, Chinese Academy of Geological Sciences, Beijing 100081, China
*
Author to whom correspondence should be addressed.

Abstract

In AD 1076, a super tsunami hit the South China Sea islands and the coasts of Guangdong and Vietnam. However, the impact on Hainan Island, situated farther from the tsunami source, remains unclear. Tsunami modeling indicates that seismic tsunamis from megathrust earthquakes in the Manila Subduction Zone may affect Guangdong, Hainan and Vietnam. This study found tsunami deposits in core HZK14 from southeastern Qiongzhou Strait, Hainan, characterized by increased grain-size anomalies, coexistence of young and old ages, and mixed microfossils from nearshore and middle-shelf settings. The youngest shell 14C age from the core is AD 1100, which is close to the age of the AD 1076 tsunami event. Combined with geological records and historical documents, we conclude that tsunamis from the Manila Subduction Zone can reach Hainan’s coast. This has significant implications for tsunami risk assessment and for the development of the Hainan Free Trade Zone. It also provides valuable constraints for tsunami simulations in the South China Sea.

1. Introduction

Tsunami hazards, triggered by submarine earthquakes, landslides, and volcanic eruptions, are considered among the deadliest marine disasters. Countries along the Pacific coast, including the United States, Canada, Chile, and Japan, have been repeatedly impacted by trans-Pacific tsunamis triggered by earthquakes and volcanic activities around the Pacific Rim [1,2,3,4,5,6,7,8,9]. The transoceanic tsunamis triggered by the 2004 Sumatra Mw 9.1 earthquake and the 2011 Japan Mw 9.0 earthquake caused significant damage to coastal residents and infrastructure, and also triggered environmental disasters [10,11,12]. These catastrophic marine events have attracted the attention of countries around the world to tsunami research.
Due to the physical conditions restricting tsunami generation, the eastern coast of China is minimally affected by tsunamis originating from the Pacific Ocean [13]. Meanwhile, the semi-enclosed tectonic environment of the South China Sea hinders the impact of external tsunami sources on its interior [14]. Tsunamis significantly impacting the Chinese coast primarily originate from earthquakes along the Manila subduction zone on the western side of the Philippines [15,16,17,18] and local tsunamis generated by earthquakes along the coastal fault zone in the northern South China Sea [19]. The occurrence of local tsunamis generated by earthquakes along the coastal fault zone is widely accepted [20,21]. Research on palaeotsunamis in the South China Sea indicates that tsunamis triggered by earthquakes in AD 1076 propagated to coastal countries in the South China Sea (Figure 1a). In addition to impacting the Philippines’ Luzon Island, located near the tsunami source [22], the tsunami also struck the Xisha Islands and impacted the coasts of Guangdong and Hong Kong in China, causing the destruction of Nan’ao Song City [23,24,25,26,27,28], and the tsunami wave could reach Yongshu Reef in a southwest direction [29]. Tsunami simulations show that regardless of whether the Manila subduction zone ruptures as a whole or in segments, the resulting tsunamis would have catastrophic impacts on the coastal areas of Guangdong, Fujian, and Hainan, as well as the islands within the South China Sea [19]. However, there has been a lack of evidence for tsunami strikes along the northeastern coastline of Hainan Island in the past. Based on analyses of sedimentary structures, radiocarbon (14C) and uranium-series (U-series) ages, geochemical proxies, and micropaleontological assemblages from core HZK14 in the southeastern Qiongzhou Strait (Figure 1b), this study confirms that the northeastern part of Hainan Island was struck by a tsunami approximately 1000 years ago. This finding provides crucial evidence for assessing the tsunami risk of Hainan Island and determining the extent of tsunami impact in the South China Sea.
Figure 1. Location map of the study area and boreholes. (a) Location of tsunami records in AD 1076 [27]; (b) location of boreholes in Qiongzhou Strait.

2. Geological Background

The Qiongzhou Strait is located in the south of China, between Hainan Island and the Leizhou Peninsula. During the Late Quaternary, the Late Pleistocene Basuo Formation, characterized by fluvial facies, was deposited in the southeast of the Qiongzhou Strait. Due to the significant sea-level fall during the Last Glacial Maximum, the Late Pleistocene sediments were exposed and subjected to weathering and erosion, resulting in the formation of a mottled weathering crust. During the Holocene Megathermal, nearly 20-m-thick coastal swamp facies strata were deposited in the Qiongzhou Strait and Puqian Bay. Around 4400 years ago, sea level began to drop by approximately 2 m [30,31,32], causing Puqian Bay to transition into a river delta, through which the paleo-Sanjiang River (flowing across Dongzhai Port) discharged into the Qiongzhou Strait via the bay. The AD 1605 Qiongzhou earthquake induced vertical coseismic displacement along the Puqian-Qinglan Fault, followed by long-term post-seismic creep, leading to a cumulative subsidence of up to 9 m in the southeast of Puqian Bay [21]. Consequently, geological records predating the AD 1605 earthquake have been well-preserved, minimally disturbed by subsequent human activities, making this area an ideal site for investigating historical tsunami events. Additionally, tsunami simulations indicate that this region is susceptible to tsunami wave inundation [19], suggesting a high potential for preserving tsunami deposits.

3. Methodology

3.1. Borehole Sediment Investigation

We drilled a core (HZK14) approximately 5.5 km from the coastline, at a site prior to paving, which was located on the southeastern margin of the Qiongzhou Strait at a water depth of about 8 m (Figure 2).
Figure 2. Stratigraphic columns and main geochemical indicators for the sediments of core HZK14. (a) Stratigraphic columns of rock cores from Borehole HZK14; (b) Trend of chemical element Rb variation along depth in Borehole HZK14; (c) Trend of Sr variation along depth in Borehole HZK14; (d) Trend of Ba variation along depth in Borehole HZK14; (e) Trend of Sr/Ba ratio variation along depth in Borehole HZK14; (f) Trend of Sr/Rb ratio variation along depth in Borehole HZK14.
The HZK14 core is composed of five sedimentary units arranged from top to bottom (Figure 2): Unit Ua (0~35 cm) comprises loose, uncemented gray silty sand, interspersed with ceramic fragments and shell fragments. Unit Ub (35~85 cm) consists of gray medium-fine sand containing shell, rip-up clasts, and coral fragments as well as subrounded quartzose gravels. Unit Ub is in erosional contact with the underlying Qiongshan Formation (Qh1–2q). Unit Uc (85~140 cm) consists of dark gray silty sand of the Qiongshan Formation. Prior to the AD 1605 Qiongzhou earthquake, the strata were exposed at the surface, and Unit Ub was subsequently deposited unconformably atop Unit Uc. Unit Ud (140~178 cm) is composed of yellowish-brown sand and gravel mixed with shell fragments, and is interpreted as an ancient tsunami or storm surge deposit. Unit Ue (178~200 cm) and Unit Uc have the same stratigraphic characteristics, and both are sedimentary strata of the Qiongshan Formation.

3.2. 14C and U-Series Dating

Thirteen AMS 14C dating samples were obtained from core HZK14 (Figure 2), spanning depths from 5 to 175 cm (Table 1). Of these, two samples originated from Unit Ua, five samples were derived from the coarse-grained event layer (Unit Ub), one from Unit Uc, and the remaining five from Unit Ud. Sample preparation was carried out by the Beijing Luminescence Laboratory Co., Ltd. The procedure involved the following steps: first, the outer and inner surfaces of each shell were mechanically abraded with a hand drill to remove adhered contaminants, followed by ultrasonic cleaning. The shells were then soaked in 1 M acetic acid for one day to eliminate any potential secondary carbonate contamination, after which they were rinsed with deionized water and oven-dried. An appropriate amount of each dried shell sample was weighed, and inorganic carbon was extracted using phosphoric acid and subsequently converted into elemental graphite using the CHS2-AGE3 system. The sample size was set to contain at least 1 mg of carbon to guarantee measurement reliability. After target preparation, the graphite targets were measured with a 200 kV MICADAS accelerator mass spectrometer (Ionplus AG, Dietikon, Switzerland) at the AMS 14C Laboratory of Lanzhou University. Radiocarbon ages were calibrated using the Calib 8.2 software and the Marine 20 calibration curve, which is an independent international curve for the global marine reservoir [33,34]. Six ΔR values, three from the Xisha Islands and one each from Ho Chi Minh City, Con Dao Island, and Hon Tre Island in Vietnam [35,36,37,38] were selected from the MARINE20 database to calculate the ΔR (−155 ± 36 a) used for age correction.
Table 1. AMS 14C ages of Shells in core HZK14.
One sample for U-series dating was taken from coral fragments at the bottom of Unit Ub of core HZK14 (Table 2). Samples analysis was conducted by the Key Laboratory of Active Tectonics and Geological Safety, Ministry of Natural Resources. Age correction was applied using a coral-specific initial 230Th/232Th ratio of 0.5 ± 0.2.
Table 2. U-series ages of corals from Unit Ub of core HZK14.

3.3. Geochemical Analysis

Based on the sediment grain size and fossil characteristics, eleven geochemical samples were collected from the core intervals of core HZK14 at depths of 5~125 cm (Table 3). All geochemical samples were analyzed at the National Research Center for Geoanalysis using a Rigaku-3080 X-ray Fluorescence Spectrometer (Rigaku Corporation, Akishima, Tokyo, Japan), with a precision of better than 0.5%. The trace elements Sr, Ba, Zn, and Rb were determined using a Rigaku-2100 spectrometer (Rigaku Corporation, Akishima, Tokyo, Japan), with analytical errors within 3–5%. The remaining trace elements were measured by a TJAPQ-ExCell ICP-MS (Beijing Haiguang Instrument Co., Ltd., Shunyi, Beijing, China), with analytical errors of less than 5% for elements with concentrations greater than 10 × 10−6.
Table 3. Geochemical Element Concentrations and Ratios in Drill Cores from Qiongzhou Strait.

3.4. Microfossil Analysis

Based on unit divisions and grain-size variations, seven samples were collected from core HZK14 for micropaleontological analysis. Samples analysis was conducted by the Institute of Hydrogeology and Environmental Geology, Chinese Academy of Geological Sciences.

4. Test Results and Analysis

4.1. AMS 14C and U-Series Dating Results

Tsunami waves, upon reaching the coast, often rapidly deposit heterogeneous marine sediments in coastal lowlands [39]. Tsunami deposits typically contain nearshore shell fragments, terrestrial animal remains, and deep-water marine microfossils [25,27,40,41]. To determine the deposition time of the tsunami layer, AMS 14C dating was performed on marine or terrestrial organisms within the event layer, as well as in situ shells from the overlying and underlying strata. The AMS 14C dating data and their calibration results for shells at 13 different depths from core HZK14 are presented in Table 1.
The AMS 14C ages of two shells from sedimentary Unit Ua of core HZK14 are 192 BC and 3378 BC, respectively. The 14C ages of five shells from sedimentary Unit Ub range from AD 1100 to 4835 BC, and exhibit age inversion and a phenomenon of mixed old and young ages within the same layer. The 14C age of shells from the normal sedimentary deposits of the underlying Qiongshan Formation (Unit Uc) is 4498 BC. In contrast, five shell samples from the event layer (Unit Ud) yield 14C ages of 4487 BC and 4661 BC, showing pronounced age inversions and a mixture of old and young materials, which probably represent a paleotsunami or storm surge event.
The U-series age of coral fragments from a depth of 80 cm at the base of Unit Ub in core HZK14 is 5.6 ± 1.2 ka (Table 2), which is close to the older 14C age of shells from the same layer.

4.2. Geochemical Indicators

Offshore marine shells or substitutes for marine saltwater are more enriched in elements such as Ca, Sr, P, Ba, Mg, and Br, while sediments from terrestrial sources or deposited in high-energy hydrodynamic environments often accumulate TiO2 and Zr, characterized by high contents of Al2O3 and Rb [27]. Therefore, element ratios and contents can serve as important indicators for identifying tsunami deposits [42].
Geochemical analysis of sediments from core HZK14 indicated that the Ti and Rb concentrations in Unit Ub are markedly lower than those in the underlying Unit Uc, but are comparable to those in the overlying sequence (Table 3, Figure 2). In contrast, Sr concentrations exhibit a positive anomaly in Unit Ub, whereas Ba concentrations remain similar to those in the overlying strata (Figure 2). Given that elemental concentrations are susceptible to grain-size variations, the Sr/Rb and Sr/Ba ratios can be used to correct for such grain-size effects, and thus the combined use of elemental ratios and absolute concentrations serves as a robust diagnostic proxy for paleo-tsunami events [43]. The average Sr/Ba ratio in four sediment samples from Unit Ub is 0.72 (Table 3), which is higher than the average Sr/Ba ratio of 0.56 in Chinese shallow sea sediments [27,44]. In contrast, the average Sr/Ba ratios in four samples from the underlying Unit Uc and three samples from the overlying Unit Ua are 0.49 and 0.58, respectively, lower than that in the Unit Ub deposit layer. The average Sr/Rb ratio in the Unit Ub is 2.35, also higher than the average Sr/Rb ratio of 1.72 in the Unit Uc sediments and the average Sr/Rb ratio of 1.99 in Unit Ua. These characteristics indicate that the Unit Ub layer was formed by the transport and accumulation of offshore sediments towards the shore, likely driven by tsunami waves. The average Ti content in the Unit Ub layer is 1871 μg/g, which is lower than the average Ti content of 2674 μg/g in the underlying Unit Uc sediments, as well as the average Ti content of 1882 μg/g in the overlying Unit Ua sediments.

4.3. Foraminiferal Records in the Deposits

In core HZK14, Unit Ua yields an abundance of 1232 specimens per 20 g of dry sediment. The dominant assemblage consists mainly of shallow-marine species, including A. beccarii (30.52%), E. advenum (12.34%), P. armata (7.79%), Q. semimula (5.84%), and Q. akneriana (5.84%).
The foraminiferal abundance in Unit Ub of core HZK14 reaches as high as 5344 specimens per 20 g, with 54 genera and 95 species identified. In Unit Ub, the predominant foraminifera fossil genera and species include A. beccarii (17.7%), A. globosa (2.1%), E. advenum (4.79%), E. hispidulum (1.8%), P. armata (11.98%), Q. akneriana (3.59%), Q. semimula (4.79%), M. laevigata (3.59%), and T. inflata (4.79%) (Figure 3), all indicative of shallow marine environments. Additionally, species typical of the middle continental shelf environment—including C. magellanicum (0.3%), Q. costata (5.09%), Q. lamarckiana (2.69%), T. trigonula (5.69%), and C. wuellerstorfi (3.59%)—occur in relatively high proportions. Unit Uc has an abundance of 1070 specimens per 20 g, with the dominant assemblage again dominated by shallow-marine forms: A. beccarii (31.06%), A. globosa (6.48%), A. tepida (4.78%), A. maruhasii (9.56%), E. advenum (5.46%), P. armata (7.17%), and T. inflata (4.44%). Only minor occurrences of middle-continental-shelf indicators (C. magellanicum at 1.02%, C. wuellerstorfi at 0.68%, and Q. lamarckiana at 0.68%) are observed in this unit.
Figure 3. Foraminiferal fossils in the sediments of core HZK14.
Unit Ud shows an abundance of 2344 specimens per 20 g. The dominant assemblage is composed of shallow-marine taxa, chiefly A. beccarii (32.9%), A. maruhasii (6.73%), E. advenum (3.74%), P. armata (5.23%), and T. inflata (2.99%). Notably, this unit also contains elevated abundances of middle-continental-shelf species, including A. takanabensis (6.73%), A. pulchella (2.24%), C. magellanicum (2.24%), P. tuberculatum (3.74%), Q. costata (4.49%), and T. trigonula (2.99%).

5. Discussion

5.1. The Origin of Event Sediments in Marine Cores

The differentiation of tsunami deposits from storm deposits has been identified as one of the most challenging aspects of palaeotsunami event reconstruction [45]. Based on extensive research findings on tsunamis in modern, historical, and geological periods, scholars both domestically and internationally have summarized diagnostic evidence for tsunami deposits, including stratigraphy and sedimentology, provenance types, geochemical indicators, and microfossil evidence [26,41,45,46,47,48,49,50]. They believe that tsunami events can be effectively identified through the study of sedimentary structures, grain size variations, biological species, depositional ages, and geochemical indicators of the event layers.
Reconstructions of the sedimentary environment in Puqian Bay indicate that sea level began to fall at around 4400 cal yr BP [32], when it stood approximately 2 m higher than present, leading to a transition from marine to terrestrial conditions [31]. The great AD 1605 Qiongzhou earthquake then triggered substantial subsidence of 6 to 9 m in Puqian Bay [51,52], converting the area back to a marine setting and renewing sedimentation. Core observations from borehole HZK14 reveal that the event layer (Unit Ub) overlies the Holocene marine strata of the Qiongshan Formation, which were deposited prior to 4498 BC, indicating that these strata were subaerially exposed at the time of the event. The event layer was thus emplaced by storm-surge or tsunami overwash in an inland setting above the contemporary coastline, and was subsequently buried by sediments accumulated after the AD 1605 Qiongzhou earthquake.
Distinguishing between tsunami deposits and storm surge deposits is crucial for identifying ancient tsunamis [39]. In the northeastern part of Hainan Island, geological evidence for prehistoric extreme typhoons includes a shell ridge at Puqian Bay dating to approximately 4400 years ago and overwash deposits in coastal dunes dating to 3400 years ago [53,54]. Historical records also document several severe typhoon events: in AD 968, a typhoon struck Qiongzhou, “destroying city gates and nearly all government offices and houses,” with similar events in AD 974 and AD 982 [55,56]. In AD 1501, a typhoon in Qiongshan caused storm surges with flooding and a water-level rise of about 2.2 m; in AD 1515, a strong northeast wind “swept seawater southwestward”; and in AD 1541, a gale “uprooted nearly all vegetation”; and in AD 1808, a severe typhoon generated storm surges that “extended from Puqian to Wushuling, more than ten li inland, killing over a dozen residents, and rendering the fields saline and uncultivable for years” (i.e., saltwater intrusion caused soil salinisation) [56]. These documentary accounts of typhoons are considered relatively reliable. Notably, the two major storm-surge events of AD 982 and AD 1808 are clearly recorded in cores HZK15 and HZK16 from Puqian Bay (data to be published elsewhere), whereas the smaller events have not yet been identified in the geological record.
In contrast, historical records of tsunamis are much scarcer, largely because tsunamis primarily affect coastal areas and ancient observers had limited understanding of such phenomena, potentially introducing biases in disaster documentation. Nevertheless, historical texts can still provide valuable clues for identifying past tsunamis. For example, the AD 1605 Qiongzhou earthquake caused seawater to inundate extensive areas that even the largest storm surges could not reach, and despite the event’s tsunami-like characteristics, local chronicles and genealogies lack detailed descriptions [57]. In comparison, the AD 1076 event—which has been substantiated by event deposits along the South China Sea coast—was historically recorded as a major flood or a suspected tsunami [58].
Radiocarbon ages of reworked shells in event layers often predate or coincide with the actual timing of the tsunami [59]; the youngest shell age within an event layer can therefore be used as a proxy for the event age [60]. In our cores from the Qiongzhou Strait, the youngest age obtained from the event layer approximates the age of the AD 1076 tsunami, suggesting that this layer most likely represents the geological record of the AD 1076 earthquake-induced tsunami that reached Hainan Island.
In core HZK14, the Unit Ub is in erosional contact with the underlying Qiongshan Formation, which consists of grayish-green silty layers. In core HZK14, the Unit Ub is 50 cm thick and comprises gray medium-fine sand containing shell and coral fragments as well as subrounded quartzose gravels. Five shell radiocarbon ages range from AD 1100 to 3756 BC. These chronological data show coexistence of young and old values and exhibit age inversions, indicating a rapid depositional event.
The Unit Ub deposits preserved in core HZK14 are characterized by poor sorting, rip-up clasts from the underlying layers, a significant increase in particle size compared to the surrounding in situ layers, and coexistence of young and old ages, mixed microfossils from nearshore and middle-shelf settings, and geochemical anomalies. Notably, the middle-shelf microfossils recovered from core HZK14 are completely different from those found in the storm surge deposits of Puqian Bay, which are dominated by relatively shallow-water taxa such as E. advenum, E. limpidum, A. beccarii, and A. maruhasii [53]. In addition, the presence of rip-up clasts from the underlying strata is a key criterion for identifying tsunami deposits [50]. All of these features are indicative of tsunami deposition [46,47,48,50].

5.2. Regional Evidence for the Timing of Tsunami Events

The median corrected ages of five shells from the tsunami layers in the core HZK14 in Qiongzhou Strait, obtained using AMS 14C dating, range from 4835 BC to AD 1100. Tsunami deposits are event layers formed by rapid sedimentation upon wave arrival at the coast. Consequently, pre-existing “old” shells are often transported and redeposited by tsunamis, resulting in a mixture of old and young shell ages [27], the youngest shell age within the event layer is closer to the deposition age of the event. The youngest median corrected 14C age of shells in the core HZK14 from Qiongzhou Strait is AD 1100. This age is close to the deposition ages of tsunami layers on Xisha East Island (AD 1017 to AD 1034), on Nan’ao Island (AD 1012 to AD 1072), and in the northern South China Sea (AD 1048 to AD 1108) [24,25,27].

5.3. Triggering Mechanisms of Tsunami Hazard Events

Studies have shown that most strong earthquakes in the coastal fault zone of the northern South China Sea are accompanied by tsunami phenomena. The Qiongzhou M 7½ earthquake that occurred near the Qiongzhou Strait in AD 1605 generated a local tsunami [57]. Sediments deposited after the earthquake-induced subsidence are present in Unit Ua (Figure 2), and further research is needed to determine whether these are tsunami deposits. Tsunamis that have had a significant impact on the Chinese coast originate from earthquakes in the Manila Subduction Zone [15,17]. Tsunami simulations indicate that earthquake-generated tsunamis originating from the Manila Subduction Zone are capable of striking the northeastern part of Hainan Island and the eastern entrance of the Qiongzhou Strait [19]. However, the impact of tsunamis triggered by the M 7½ earthquake in the Manila Subduction Zone on the southern coast of China is relatively low, with wave amplitudes generally not exceeding 30 cm [16,18]. Therefore, it can be inferred that the tsunami event in the southeast of Qiongzhou Strait, along with tsunami events recorded in the East Xisha Island, Nan’ao Island, and the northern waters of the South China Sea, was likely caused by a super tsunami triggered by a great earthquake of magnitude exceeding than M 7½ that occurred in the Manila Subduction Zone in AD 1076.

6. Conclusions

A tsunami deposit layer was identified in the core stratigraphy from the southeast of Qiongzhou Strait, Hainan Island. This layer is sharply differentiated from the underlying strata by its distinct sediment grain size, sedimentary structures, and facies. The deposit contains characteristic increased grain anomalies, shell fragments with mixed ages, mixed microfossils from nearshore and middle-shelf settings, indicating that the southeast of Qiongzhou Strait was situated on land above the contemporary coastline during the tsunami event. Both the land and tsunami layer exhibit subsidence of 8 to 10 m, attributed to the AD 1605 Qiongzhou earthquake. The youngest shell 14C age from the core HZK14 is AD 1100, which is close to the age of the AD 1076 tsunami event in the South China Sea islands and coasts, as well as historical accounts of a major tsunami event in the South China Sea in AD 1076. These findings suggest that the northeastern part of Hainan Island and the Qiongzhou Strait were impacted by a tsunami in AD 1076. Consequently, the potential risk of damage to major coastal infrastructure projects from tsunamis triggered by large earthquakes in the Manila subduction zone deserves serious consideration.

Author Contributions

Conceptualization, C.W. and D.H.; methodology, C.W. and X.Y.; validation, Y.Z., D.S. and D.H.; formal analysis, C.W., X.Y. and L.Z.; investigation, C.W., X.Y. and L.Z.; resources, C.W., X.Y. and L.Z.; data curation, C.W. and X.Y.; writing—original draft preparation, C.W. and X.Y.; writing—review and editing, C.W. and X.Y.; visualization, C.W. and X.Y.; supervision, D.H.; project administration, L.Z.; funding acquisition, L.Z. All authors have read and agreed to the published version of the manuscript.

Funding

This study is supported by Chinese Academy of Geological Sciences Basal Research Fund (No. JKYQN202412), the Institute of Geomechanics, Chinese Academy of Geological Sciences Basal Research Fund (No. DZLXJK202507) and Geological Survey project of China Geological Survey (No. DD202606201408).

Data Availability Statement

The raw data supporting the conclusions of this article will be made available by the authors on request.

Acknowledgments

We are grateful to the reviewers for their valuable comments.

Conflicts of Interest

The authors declare no conflicts of interest.

Abbreviations

The following abbreviations are used in this manuscript:
AMSAccelerator Mass Spectrometry
ICP-MSInductively Coupled Plasma Mass Spectrometry
U-series agesUranium-series ages
ADAnno Domini
BCBefore Christ

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