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Inorganics, Volume 7, Issue 10 (October 2019)
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Cover Story (view full-size image) Defective Zr- based metal–organic framework UiO-66 was prepared by adding a large amount of formic [...] Read more. Defective Zr- based metal–organic framework UiO-66 was prepared by adding a large amount of formic acid as a monocarboxylic modulator. Then, it was employed as support for anchoring, with an exchange reaction, an Ir(III)–HEDTA complex by means of post-synthetic defect functionalization. The catalytic properties of the hybrid system for the water oxidation reaction, with Ce(IV) as the oxidant, were evaluated. View this paper.