Pre-Crosslinked Gel Particles Enhanced by Amphiphilic Nanocarbon Dots in Harsh Reservoirs: Synthesis and Deep Stimulation Mechanism

To address the issues of easy degradation, dehydration, and insufficient deep plugging strength of traditional pre-crosslinked gel particles (PPGs) in high-temperature and high-salinity reservoirs, this study innovatively introduced amphiphilic carbon dots (CDs) with both hydrophilic and hydrophobic structures as multifunctional modifiers. The carbon dot-reinforced PPGs (CD-PPGs) were successfully prepared through in situ polymerization. Through systematic characterization, microscopic visualization experiments, and macroscopic oil displacement evaluation, the performance enhancement mechanism and profile control behavior were deeply explored. The results show that the amphiphilic carbon dots significantly enhanced the material’s temperature resistance (up to 110 °C), salt resistance (up to 15 × 10⁴ mg/L salinity), and mechanical properties by constructing a “hydrogen bond-hydrophobic association” dual crosslinking system within the PPG network. More importantly, it was found that CD-PPGs exhibit a unique “self-aggregation” ability in deep reservoirs, which enables the in situ formation of high-strength plugging micelles at the target location while ensuring excellent injectability. At a permeability range of 539.0–2988.6 mD, the sealing rate of 0.5 PV nano-SiO₂ nuclear gel particles was greater than 95%. With permeabilities of 490.1 mD and 3020.5 mD under heterogeneous reservoir simulation conditions, the total recovery degree after the nanoparticle-based SiO₂ solid core gel was displaced was 52.6%, which was 20.5% higher than that of single water flooding. This study not only developed a high-performance profile control nanomaterial but also elucidated its strengthening mechanism, providing new insights and a theoretical basis for advancing deep profile control technology.