Performance of High-Fluidity Cementitious Grouting Materials with Recycled Waste Glass in Semi-Flexible Pavement Mixture
Abstract
1. Introduction
- (a)
- To show the advantages of Glcement grouts in terms of performance and engineering properties.
- (b)
- To highlight the benefits of Glcement-based SFP mixture in terms of durability and mechanical properties.
- (c)
- To demonstrate that the CGM can be designed for enhanced durability and economy by incorporating RWG.
2. Materials and Methods
2.1. Ordinary Portland Cement
2.2. Recycled Waste Glass
2.3. Granite Aggregates
2.4. MasterEase 3003 Superplasticizer
2.5. Bitumen Binder
2.6. Design and Performance Test Methods of Glass-Cementitious Grouting Materials
2.6.1. Design of Glcement Grouts
2.6.2. Flowability Test
2.6.3. Compressive Strength Test
2.6.4. Dry Density Test
2.6.5. Drying Shrinkage Test
2.6.6. Water Absorption Test
2.7. Performance Test Methods of the Optimized Glass-Cementitious Grouting Material
2.7.1. Wet Density Test
2.7.2. Flexural Strength Test
2.7.3. Porosity Test
2.7.4. Microstructure Analysis
2.8. Design and Performance Test Methods of the Glcement-Based SFP Mixture
2.8.1. Design of of the Glcement-Based SFP Mixture
2.8.2. Degree of Saturation Test
2.8.3. Indirect Tensile Strength Test
2.8.4. Compressive Strength Test
2.8.5. Cantabro Abrasion Loss Test
2.8.6. Marshall Stability Test
3. Results and Analysis
3.1. Optimum Water Content
3.2. Optimum Superplasticizer Content
3.3. Flowability
3.4. Compressive Strength
3.5. Dry Density
3.6. Drying Shrinkage
3.7. Water Absorption
3.8. Performance of Optimized Glass-Cementitious Grout
3.8.1. Performance Ranking
3.8.2. Engineering Properties
3.8.3. Microstructure
3.9. Mechanical Performance of Glcement-Based SFP Mixture
4. Conclusions
- The flowability values of CGMs decreased slightly with increasing RWG concentration as an FGA replacement. Additionally, the flowability decreased as the RWG particle size increased. In contract, the compressive strength of CGMs significantly improved with increasing RWG concentration and particle size, attributed to enhanced pozzolanic reactivity and CSH formation.
- As the RWG concentration increased, the density of CGMs decreased due to the lower bulk density of RWG. Similarly, the drying shrinkage and water absorption of CGMs containing RWG were lower than those of the Base grouts. This behavior is attributed to the smooth surface and negligible surface water retention of RWG particles compared to FGA, as well as the improved microstructure of the CGM. Moreover, both water absorption and drying shrinkage decreased further with increasing RWG particle size.
- Compared to RWG concentration, RWG particle size had a larger effect on the overall engineering properties of CGMs. Consequently, Glcement II grout proved more suitable as a CGM than Glcement I grout. Among all CGMs, Glcement II-70 grout exhibited optimal performance, demonstrating superior void-filling capacity, fluidity, and mechanical properties. Furthermore, the SFP mixture injected with Glcement II-70 met all performance requirements, showing excellent mechanical behavior due to enhanced interlocking within the voids.
- Comparing environmental pollution indicators of CGMs with and without RWG, the optimized and rational application of 70% RWG significantly reduces adverse effects on the ecological environment. This approach is a feasible, eco-friendly technology for disposing of waste glass and promotes the socioeconomic sustainable development of cities.
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
Abbreviations
SFP | Semi-flexible pavement |
CGM | Cementitious grouting material |
RWG | Recycled waste glass |
FGA | Fine granite aggregate |
Glcement | Glass-cementitious |
OAS | Open-graded asphalt skeleton |
OPC | Ordinary Portland cement |
CSH | Calcium silicate hydrate |
W/C | Water-to-cement ratio |
FESEM | Field emission scanning electron microscopy |
ITS | Indirect tensile strength |
MES03 | Master ease 3003 superplasticizer |
REAM | Road Engineering Association of Malaysia |
S/C | Sand-to-cement ratio |
MES03/C | MasterEase 3003 superplasticizer-to-cement ratio |
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Property | Normal Consistency | Initial Set Time | Final Set Time | Specific Gravity | Compressive Strength (3 Days) | Compressive Strength (7 Days) | Compressive Strength (28 Days) |
---|---|---|---|---|---|---|---|
Reference | ASTM C187-11 [35] | ASTM C191-21 [36] | ASTM C191-21 [36] | ASTM C188-17 [37] | ASTM C109-20 [38] | ASTM C109-20 [38] | ASTM C109-20 [38] |
Unit | % | minute | minute | - | N/mm2 | N/mm2 | N/mm2 |
Requirement | - | min. 45 | max. 600 | - | min. 23 | min. 27 | min. 41 |
Result | 30.00 | 117.45 | 306.22 | 3.119 | 26.691 | 29.570 | 42.019 |
Chemical Compound (%) | CaO | SiO2 | Al2O3 | Fe2O3 | Ag2O | SO3 | I | K2O | P2O5 | PbO | Others |
---|---|---|---|---|---|---|---|---|---|---|---|
OPC | 62.52 | 16.26 | 5.81 | 5.56 | 3.96 | 2.04 | 1.89 | 0.55 | 0.11 | - | 1.31 |
RWG | 24.05 | 63.71 | 3.08 | 1.04 | - | 0.25 | - | 1.02 | 5.49 | 0.54 | 0.82 |
Property | Reference | Unit | Requirement | RWG Result | FGA Result | Coarse Result |
---|---|---|---|---|---|---|
Color | - | - | - | Green, brown, colorless | White to grayish | White to grayish |
Soundness | ASTM C088-13 [39] | % | max. 10 | 5.074 | 3.263 | 4.270 |
Fineness modulus | ASTM C125-20 [40] | - | - | 2.939 | 2.810 | - |
Water absorption | BS 812:Part 107 [41] | % | max. 2 | 0.597 | 0.932 | 1.092 |
Specific gravity | BS 812:Part 107 [41] | - | - | 2.478 | 2.586 | 2.559 |
Abrasion loss | ASTM C131-14 [42] | % | max. 25 | - | - | 19.476 |
Impact value | BS 812:Part 112 [43] | % | max. 15 | - | - | 9.124 |
Sieve Size (mm) | 0.425 | 0.300 | 0.150 | 0.075 | Pan |
---|---|---|---|---|---|
% Passing for cementitious grouting I materials | 100 | 100 | 100 | 50 | 0 |
% Passing for cementitious grouting II materials | 100 | 75 | 50 | 25 | 0 |
Chemical Property | Result | Physical Property | Result |
---|---|---|---|
pH at 25 °C | 6.5 | Form | Liquid |
Flammability | Non-flammable | Color | Brown to yellowish |
Self-ignition | Not self-igniting | Freezing temperature | −3 °C |
Chemical stability | Stable | Viscosity at 25 °C | 0.15 Pa·s |
Chemical nature | Polymer in water | Solubility | Soluble |
Oxidization | Not fire-propagating | Specific gravity | 1.095 |
Property | Test Reference | Unit | Requirement | Result |
---|---|---|---|---|
Penetration at 25 °C | ASTM D5-06 [46] | 0.1 mm | 60–70 | 64.9 |
Softening point | ASTM D36-09 [47] | °C | 48–56 | 51.8 |
Viscosity at 135 °C | ASTM D4402-15 [48] | Pa·s | max. 3 | 0.49 |
Grout Design | Max. Grain Size (mm) | S/C Ratio (%) | RWG/FGA Ratio (%) | W/C Ratio (%) | MES03/C Ratio (%) | Grout Designation |
---|---|---|---|---|---|---|
Grout I | 0.075 | 30 | 0 | 50, 45, 40, 35, 30, 25, 20 | 2.5 | Base I-W |
Grout I | 0.075 | 30 | 0 | 30 | 2.5, 2, 1.5, 1 | Base I-SP |
Grout I | 0.075 | 30 | 0 | 26 | 2.5 | Base I |
Grout I | 0.075 | 30 | 30 | 26 | 2.5 | Glcement I-30 |
Grout I | 0.075 | 30 | 50 | 26 | 2.5 | Glcement I-50 |
Grout I | 0.075 | 30 | 70 | 26 | 2.5 | Glcement I-70 |
Grout I | 0.075 | 30 | 100 | 26 | 2.5 | Glcement I-100 |
Grout II | 0.30 | 30 | 0 | 30, 25, 20 | 2.5 | Base II-W |
Grout II | 0.30 | 30 | 0 | 30 | 2.5, 2, 1.5, 1 | Base II-SP |
Grout II | 0.30 | 30 | 0 | 26 | 2.5 | Base II |
Grout II | 0.30 | 30 | 30 | 26 | 2.5 | Glcement II-30 |
Grout II | 0.30 | 30 | 50 | 26 | 2.5 | Glcement II-50 |
Grout II | 0.30 | 30 | 70 | 26 | 2.5 | Glcement II-70 |
Grout II | 0.30 | 30 | 100 | 26 | 2.5 | Glcement II-100 |
Parameter | Test Reference | Unit | Requirement | Result |
---|---|---|---|---|
Drainage | ASTM D6390-11 [59] | % | max. 0.30 | 0.117 |
Cantabro loss | EN 12697-17 [60] | % | max. 25 | 21.04 |
Air voids | ASTM D3203-05 [61] | % | 25–30 | 26.08 |
Cementitious Grout | Flowability (Second) | Compressive Strength (MPa) | Dry Density (kg/m3) | Drying Shrinkage (%) | Water Absorption (%) | |||||
---|---|---|---|---|---|---|---|---|---|---|
Result | Ni * | Result | Ni | Result | Ni | Result | Ni | Result | Ni | |
Base I | 14.28 | 1.000 | 107.8 | 1.000 | 2245 | 1.000 | 0.058 | 1.000 | 3.24 | 1.000 |
Glcement I-30 | 14.05 | 0.984 | 108.9 | 1.010 | 2231 | 0.994 | 0.054 | 0.931 | 3.12 | 0.963 |
Glcement I-50 | 14.30 | 1.001 | 110.6 | 1.026 | 2216 | 0.987 | 0.052 | 0.897 | 3.03 | 0.935 |
Glcement I-70 | 14.68 | 1.028 | 106.5 | 0.988 | 2200 | 0.980 | 0.045 | 0.897 | 2.70 | 0.833 |
Glcement I-100 | 13.60 | 0.952 | 105.9 | 0.982 | 2179 | 0.971 | 0.040 | 0.690 | 2.63 | 0.812 |
Base II | 12.24 | 1.000 | 111.1 | 1.000 | 2307 | 1.000 | 0.053 | 1.000 | 2.32 | 1.000 |
Glcement II-30 | 12.50 | 1.020 | 108.1 | 0.973 | 2296 | 0.995 | 0.047 | 0.887 | 2.24 | 0.966 |
Glcement II-50 | 12.40 | 1.012 | 114.4 | 1.030 | 2295 | 0.995 | 0.043 | 0.820 | 2.05 | 0.884 |
Glcement II-70 | 11.83 | 0.965 | 121.9 | 1.097 | 2301 | 0.997 | 0.041 | 0.774 | 1.89 | 0.815 |
Glcement II-100 | 11.35 | 0.927 | 106.9 | 0.962 | 2275 | 0.986 | 0.036 | 0.679 | 1.72 | 0.741 |
Property | Grouting Material | ||||
---|---|---|---|---|---|
Base II | Glcement II-30 | Glcement II-50 | Glcement II-70 | Glcement II-100 | |
Flowability | 3 | 5 | 4 | 2 | 1 |
Compressive strength | 3 | 4 | 2 | 1 | 5 |
Dry density | 1 | 3 | 4 | 2 | 5 |
Drying shrinkage | 5 | 4 | 3 | 2 | 1 |
Water absorption | 5 | 4 | 3 | 2 | 1 |
Relative index * | 0.52 | 0.40 | 0.56 | 0.84 | 0.68 |
Overall ranking | 4 | 5 | 3 | 1 | 2 |
Property | Flowability | Compressive Strength | Flexural Strength | Porosity | Wet Density | Dry Density | Drying Shrinkage | Water Absorption |
---|---|---|---|---|---|---|---|---|
Unit | Seconds | MPa | MPa | % | g/cm3 | g/cm3 | % | % |
Requirement | 11–16 | min. 105 | min. 7 | max. 15 | - | min. 2.2 | - | - |
Result | 11.80 | 121.92 | 13.94 | 5.36 | 2.151 | 2.301 | 0.04 | 1.89 |
Property | Air Voids | ITS | Cantabro Loss | Marshall Stability | Compressive Strength |
---|---|---|---|---|---|
Unit | % | kPa | % | kN | MPa |
Requirement | 3–6 | - | max. 15 | - | min. 7 |
Result | 3.9 | 1953.73 | 10.94 | 38.27 | 9.34 |
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AL-Qudah, A.H.; Koting, S.; Ibrahim, M.R.; Alibrahim, M.M.; Al-Mansour, A.I. Performance of High-Fluidity Cementitious Grouting Materials with Recycled Waste Glass in Semi-Flexible Pavement Mixture. Coatings 2025, 15, 1223. https://doi.org/10.3390/coatings15101223
AL-Qudah AH, Koting S, Ibrahim MR, Alibrahim MM, Al-Mansour AI. Performance of High-Fluidity Cementitious Grouting Materials with Recycled Waste Glass in Semi-Flexible Pavement Mixture. Coatings. 2025; 15(10):1223. https://doi.org/10.3390/coatings15101223
Chicago/Turabian StyleAL-Qudah, Ayman Hassan, Suhana Koting, Mohd Rasdan Ibrahim, Muna M. Alibrahim, and Abdullah I. Al-Mansour. 2025. "Performance of High-Fluidity Cementitious Grouting Materials with Recycled Waste Glass in Semi-Flexible Pavement Mixture" Coatings 15, no. 10: 1223. https://doi.org/10.3390/coatings15101223
APA StyleAL-Qudah, A. H., Koting, S., Ibrahim, M. R., Alibrahim, M. M., & Al-Mansour, A. I. (2025). Performance of High-Fluidity Cementitious Grouting Materials with Recycled Waste Glass in Semi-Flexible Pavement Mixture. Coatings, 15(10), 1223. https://doi.org/10.3390/coatings15101223