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Search Results (423)

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Keywords = recycled waste glass

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27 pages, 565 KiB  
Review
Review of the Use of Waste Materials in Rigid Airport Pavements: Opportunities, Benefits and Implementation
by Loretta Newton-Hoare, Sean Jamieson and Greg White
Sustainability 2025, 17(15), 6959; https://doi.org/10.3390/su17156959 - 31 Jul 2025
Viewed by 160
Abstract
The aviation industry is under increasing pressure to reduce its environmental impact while maintaining safety and performance standards. One promising area for improvement lies in the use of sustainable materials in airport infrastructure. One of the issues preventing uptake of emerging sustainable technologies [...] Read more.
The aviation industry is under increasing pressure to reduce its environmental impact while maintaining safety and performance standards. One promising area for improvement lies in the use of sustainable materials in airport infrastructure. One of the issues preventing uptake of emerging sustainable technologies is the lack of guidance relating to the opportunities, potential benefits, associated risks and an implementation plan specific to airport pavements. This research reviewed opportunities to incorporate waste materials into rigid airport pavements, focusing on concrete base slabs. Commonly used supplementary cementitious materials (SCMs), such as fly ash and ground granulated blast furnace slag (GGBFS) were considered, as well as recycled aggregates, including recycled concrete aggregate (RCA), recycled crushed glass (RCG), and blast furnace slag (BFS). Environmental Product Declarations (EPDs) were also used to quantify the potential for environmental benefit associated with various concrete mixtures, with findings showing 23% to 50% reductions in embodied carbon are possible for selected theoretical concrete mixtures that incorporate waste materials. With considered evaluation and structured implementation, the integration of waste materials into rigid airport pavements offers a practical and effective route to improve environmental outcomes in aviation infrastructure. It was concluded that a Triple Bottom Line (TBL) framework—assessing financial, environmental, and social factors—guides material selection and can support sustainable decision-making, as does performance-based specifications that enable sustainable technologies to be incorporated into airport pavement. The study also proposed a consequence-based implementation hierarchy to facilitate responsible adoption of waste materials in airside pavements. The outcomes of this review will assist airport managers and pavement designers to implement practical changes to achieve more sustainable rigid airport pavements in the future. Full article
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22 pages, 3056 KiB  
Article
Recycled Glass and Plastic Waste in Sustainable Geopolymer Systems for Affordable Housing Solutions
by Zhao Qing Tang, Yat Choy Wong, Yali Li and Eryadi Kordi Masli
Recycling 2025, 10(4), 147; https://doi.org/10.3390/recycling10040147 - 27 Jul 2025
Viewed by 356
Abstract
The increasing demand for sustainable construction materials has driven research into low-carbon geopolymers that mitigate both cement-related emissions and plastic and glass waste accumulation. This study explores the development of geopolymer concrete incorporating fly ash (FA), slag (S), and FA + S blends, [...] Read more.
The increasing demand for sustainable construction materials has driven research into low-carbon geopolymers that mitigate both cement-related emissions and plastic and glass waste accumulation. This study explores the development of geopolymer concrete incorporating fly ash (FA), slag (S), and FA + S blends, with 10% recycled crushed glass (RCG) and recycled plastic waste (RPW) as partial coarse aggregate replacements. Compressive strength testing revealed that FA + S-based geopolymers (25FA + S) with 100% ordinary Portland cement (OPC) replacement achieved a 7-day strength of 24.6 MPa, representing a 98% improvement over control specimens. Slag-based geopolymers demonstrated water absorption properties comparable to OPC, indicating enhanced durability. Microstructural analyses using SEM, XRD, and EDS confirmed the formation of a dense aluminosilicate matrix, with slag promoting FA reactivity and reinforcing interfacial transition zone (ITZ). These effects contributed to superior mechanical performance and water resistance. Despite minor shrinkage-induced cracking, full OPC replacement with S or FA + S geopolymers outperformed control specimens, consistently exceeding the target strength of 15 MPa required for low-impact, single-story housing applications within seven days. These findings underscore the potential of geopolymer systems for rapid and sustainable construction, offering an effective solution for reducing carbon footprints and repurposing industrial waste. Full article
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27 pages, 6279 KiB  
Article
Investigation of the Performance and Fuel Oil Corrosion Resistance of Semi-Flexible Pavement with the Incorporation of Recycled Glass Waste
by Ayman Hassan AL-Qudah, Suhana Koting, Mohd Rasdan Ibrahim and Muna M. Alibrahim
Materials 2025, 18(15), 3442; https://doi.org/10.3390/ma18153442 - 22 Jul 2025
Viewed by 294
Abstract
Semi-flexible pavement (SFP) is a durable and cost-effective alternative to conventional rigid and flexible pavement and is formed by permeating an open-graded asphalt (OGA) layer with high-fluidity cement grout. The degradation of SFP mattresses due to fuel oil spills can result in significant [...] Read more.
Semi-flexible pavement (SFP) is a durable and cost-effective alternative to conventional rigid and flexible pavement and is formed by permeating an open-graded asphalt (OGA) layer with high-fluidity cement grout. The degradation of SFP mattresses due to fuel oil spills can result in significant maintenance costs. Incorporating glass waste (GW) into the construction of SFPs offers an eco-friendly solution, helping to reduce repair costs and environmental impact by conserving natural resources and minimizing landfill waste. The main objective of this research is to investigate the mechanical performance and fuel oil resistance of SFP composites containing different levels of glass aggregate (GlaSFlex composites). Fine glass aggregate (FGA) was replaced with fine virgin aggregate at levels of 0%, 20%, 40%, 60%, 80%, and 100% by mass. The results indicated the feasibility of utilizing FGA as a total replacement (100%) for fine aggregate in the OGA structural layer of SFPs. At 100% FGA, the composite exhibited excellent mechanical performance and durability, including a compressive strength of 8.93 MPa, a Marshall stability exceeding 38 kN, and a stiffness modulus of 19,091 MPa. Furthermore, the composite demonstrated minimal permanent deformation (0.04 mm), a high residual stability of 94.7%, a residual compressive strength of 83.3%, and strong resistance to fuel spillage with a mass loss rate of less than 1%, indicating excellent durability. Full article
(This article belongs to the Special Issue Advanced Materials for Pavement and Road Infrastructure)
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18 pages, 2652 KiB  
Article
The Use of a Composite of Modified Construction Aggregate and Activated Carbon for the Treatment of Groundwater Contaminated with Heavy Metals and Chlorides
by Katarzyna Pawluk, Marzena Lendo-Siwicka, Grzegorz Wrzesiński, Sylwia Szymanek and Osazuwa Young Osawaru
Materials 2025, 18(15), 3437; https://doi.org/10.3390/ma18153437 - 22 Jul 2025
Viewed by 225
Abstract
The treatment of contaminants from road infrastructure poses significant challenges due to their variable composition and the high concentrations of chloride ions, heavy metals, and oil-derived substances. Traditional methods for protecting groundwater environments are often insufficient. A promising alternative is permeable reactive barrier [...] Read more.
The treatment of contaminants from road infrastructure poses significant challenges due to their variable composition and the high concentrations of chloride ions, heavy metals, and oil-derived substances. Traditional methods for protecting groundwater environments are often insufficient. A promising alternative is permeable reactive barrier (PRB) technology, which utilizes recycled materials and construction waste as reactive components within the treatment zone of the ground. This paper delves into the potential of employing a composite (MIX) consisting of modified construction aggregate (as recycled material) and activated carbon (example of reactive material) to address environmental contamination from a mixture of heavy metals and chloride. The research involved chemical modifications of the road aggregate, activated carbon, and their composite, followed by laboratory tests in glass reactors and non-flow batch tests to evaluate the kinetics and chemical equilibrium of the reactions. The adsorption process was stable and conformed to the pseudo-second-order kinetics and Langmuir, Toth, and Redlich–Peterson isotherm models. Studies using MIX from a heavy metal model solution showed that monolayer adsorption was a key mechanism for removing heavy metals, with strong fits to the Langmuir (R2 > 0.80) and Freundlich models, and optimal efficiencies for Cd and Ni (R2 > 0.90). The best fit, at Cd, Cu, Ni = 0.96, however, was with the Redlich–Peterson isotherm, indicating a mix of physical and chemical adsorption on heterogeneous surfaces. The Toth model was significant for all analytes, fitting Cl and Cd well and Pb and Zn moderately. The modifications made to the composite significantly enhanced its effectiveness in removing the contaminant mixture. The test results demonstrated an average reduction of chloride by 85%, along with substantial removals of heavy metals: lead (Pb) by 90%, cadmium (Cd) by 86%, nickel (Ni) by 85%, copper (Cu) by 81%, and zinc (Zn) by 79%. Further research should focus on the removal of other contaminants and the optimization of magnesium oxide (MgO) dosage. Full article
(This article belongs to the Special Issue Recovered or Recycled Materials for Composites and Other Materials)
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15 pages, 677 KiB  
Article
Zero-Shot Learning for Sustainable Municipal Waste Classification
by Dishant Mewada, Eoin Martino Grua, Ciaran Eising, Patrick Denny, Pepijn Van de Ven and Anthony Scanlan
Recycling 2025, 10(4), 144; https://doi.org/10.3390/recycling10040144 - 21 Jul 2025
Viewed by 302
Abstract
Automated waste classification is an essential step toward efficient recycling and waste management. Traditional deep learning models, such as convolutional neural networks, rely on extensive labeled datasets to achieve high accuracy. However, the annotation process is labor-intensive and time-consuming, limiting the scalability of [...] Read more.
Automated waste classification is an essential step toward efficient recycling and waste management. Traditional deep learning models, such as convolutional neural networks, rely on extensive labeled datasets to achieve high accuracy. However, the annotation process is labor-intensive and time-consuming, limiting the scalability of these approaches in real-world applications. Zero-shot learning is a machine learning paradigm that enables a model to recognize and classify objects it has never seen during training by leveraging semantic relationships and external knowledge sources. In this study, we investigate the potential of zero-shot learning for waste classification using two vision-language models: OWL-ViT and OpenCLIP. These models can classify waste without direct exposure to labeled examples by leveraging textual prompts. We apply this approach to the TrashNet dataset, which consists of images of municipal solid waste organized into six distinct categories: cardboard, glass, metal, paper, plastic, and trash. Our experimental results yield an average classification accuracy of 76.30% with Open Clip ViT-L/14-336 model, demonstrating the feasibility of zero-shot learning for waste classification while highlighting challenges in prompt sensitivity and class imbalance. Despite lower accuracy than CNN- and ViT-based classification models, zero-shot learning offers scalability and adaptability by enabling the classification of novel waste categories without retraining. This study underscores the potential of zero-shot learning in automated recycling systems, paving the way for more efficient, scalable, and annotation-free waste classification methodologies. Full article
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17 pages, 1651 KiB  
Article
Compositional Analysis of Municipal Solid Waste from Tshwane Metropolitan Landfill Sites in South Africa for Potential Sustainable Management Strategies
by Khanyisile Lepota, Kasturie Premlall and Major Mabuza
Waste 2025, 3(3), 22; https://doi.org/10.3390/waste3030022 - 15 Jul 2025
Viewed by 368
Abstract
The modern world has brought extensive socioeconomic and ecological changes. Urbanization in developing nations has significantly increased municipal solid waste, necessitating in-depth understanding of waste composition particularly in developing nations for sustainable management practices. This study aimed to classify and characterize waste while [...] Read more.
The modern world has brought extensive socioeconomic and ecological changes. Urbanization in developing nations has significantly increased municipal solid waste, necessitating in-depth understanding of waste composition particularly in developing nations for sustainable management practices. This study aimed to classify and characterize waste while evaluating potential waste management methods. Mixed methods were used to examine landfilled waste from Soshanguve and Hatherley sites in Tshwane Metropolitan, South Africa, using techniques such as Fourier transform infrared spectroscopy, X-ray fluorescence, proximate, and ultimate analysis. Seasonal variations in waste components were analysed over two seasons. The study identified that both sites are predominantly composed of organic waste, accounting for over 42 wt.%, with moisture content of ~50 wt.%, and minimal recyclables (<5 wt.%). Seasonal variations in MSW were significant for glass (<4% increase), organic waste (<5% increase), while plastic decreased by ~7% during spring. The biodegradable waste showed high carbon (>50%) and oxygen (>40%) levels, low ash content (<18%), and calorific values of 15–19 MJ/kg. Biodegradables mainly contained oxides of calcium, silicon, iron (III), and potassium with chemical composition indicating functional groups that emphasize composting and energy recovery benefits. The research provides insights into sustainable waste management, revealing waste composition at Tshwane landfills, aiding informed decision-making for resource usage and environmental conservation. Full article
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21 pages, 1615 KiB  
Article
Fostering a Sustainable Campus: A Successful Selective Waste Collection Initiative in a Brazilian University
by Geovana Dagostim Savi-Bortolotto, Ana Carolina Pescador, Tiago Bortolotto, Camila Garbin Sandi, Alícia Viana de Oliveira, Matheus Rodrigues Pereira Mendes, Kátia Cilene Rodrigues Madruga and Afonso Henrique da Silva Júnior
Sustainability 2025, 17(14), 6377; https://doi.org/10.3390/su17146377 - 11 Jul 2025
Viewed by 459
Abstract
This study reports a successful selective waste collection initiative led by UFSC’s Araranguá campus in a municipality without a recycling system. The initiative, named “Recicla UFSC Ara”, was structured around three main components: (i) the installation of color-coded bins for recyclable waste (including [...] Read more.
This study reports a successful selective waste collection initiative led by UFSC’s Araranguá campus in a municipality without a recycling system. The initiative, named “Recicla UFSC Ara”, was structured around three main components: (i) the installation of color-coded bins for recyclable waste (including paper, plastic, metals, and polystyrene) and non-recyclable waste in indoor and common areas; (ii) the establishment of a Voluntary Delivery Point (PEV) to gather specific recyclable materials, such as glass, electronics waste, plastic bottles, writing instruments, and bottle caps; and (iii) the execution of periodic educational community-focused campaigns aimed at encouraging participation from both the university and the broader local community. Recyclables were manually sorted and weighed during regular collection rounds, and contamination rates were calculated. Quantitative data collected from 2022 to 2025 were analyzed using descriptive statistics and one-way ANOVA to assess waste generation and contamination trends. Gathered recyclables were directed to appropriate partner institutions, including local “Ecoponto”, non-profit organizations, and corporate recycling programs. The study also conducted a literature review of similar university-led waste management programs to identify standard practices and regional specificities, providing a comparative analysis that highlights both shared elements and distinctive contributions of the UFSC model. Results demonstrate a significant volume of waste diverted from landfills and a gradual improvement in waste disposal practices among the university community. Targeted communication and operational changes mitigated key challenges, improper disposal, and logistical issues. This case underscores the role of universities as agents of environmental education and local sustainable development. Full article
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18 pages, 1316 KiB  
Article
Economy-Wide Material Flow Accounting: Application in the Italian Glass Industry
by Salik Ahmed, Marco Ciro Liscio, Andrea Pelaggi, Paolo Sospiro, Irene Voukkali and Antonis A. Zorpas
Sustainability 2025, 17(13), 6180; https://doi.org/10.3390/su17136180 - 5 Jul 2025
Viewed by 526
Abstract
Italy supplies about one-seventh of the European Union’s total glass production, and the sector’s sizeable resource demands make it a linchpin of national industrial strategy. With growing environmental regulations and the push for resource efficiency, Material Flow Accounting has become essential for companies [...] Read more.
Italy supplies about one-seventh of the European Union’s total glass production, and the sector’s sizeable resource demands make it a linchpin of national industrial strategy. With growing environmental regulations and the push for resource efficiency, Material Flow Accounting has become essential for companies to stay compliant and advance sustainability. The investigation concentrates on Italy’s glass industry to clarify its material requirements, ecological footprint, and overall sustainability performance. STAN software v2, combined with an Economy-Wide Material Flow Accounting (EW-MFA) framework, models the national economy as a single integrated input–output system. By tracking each material stream from initial extraction to end-of-life, the analysis delivers a cradle-to-grave picture of the sector’s environmental impacts. During the 2021 production year, Italy’s glass makers drew on a total of 10.5 million tonnes (Mt) of material inputs, supplied 76% (7.9 Mt) from domestic quarries, and 24% (2.6 Mt) via imports. Outbound trade in finished glass removed 1.0 Mt, leaving 9.5 Mt recorded as Domestic Material Consumption (DMC). Within that balance, 6.6 Mt (63%) was locked into long-lived stock, whereas 2.9 Mt (28%) left the system as waste streams and airborne releases, including roughly 2.1 Mt of CO2. At present, the post-consumer cult substitutes only one-third of the furnace batch, signalling considerable scope for improved circularity. When benchmarked against EU-27 aggregates for 2021, Italy registers a NAS/DMI ratio of 0.63 (EU median 0.55) and a DPO/DMI ratio of 0.28 (EU 0.31), indicating a higher share of material retained in stock and slightly lower waste generated per ton of input. A detailed analysis of glass production identifies critical stages, environmental challenges, and areas for improvement. Quantitative data on material use, waste generation, and recycling rates reveal the industry’s environmental footprint. The findings emphasise Economy-Wide Material Flow Accounting’s value in evaluating and improving sustainability efforts, offering insights for policymakers and industry leaders to drive resource efficiency and sustainable resource management. Results help scholars and policymakers in the analysis of the Italian glass industry context, supporting in the data gathering, while also in the use of this methodology for other sectors. Full article
(This article belongs to the Collection Waste Management towards a Circular Economy Transition)
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24 pages, 5049 KiB  
Article
Sustainable Mortar with Waste Glass and Fly Ash: Impact of Glass Aggregate Size and Life-Cycle Assessment
by Vimukthi Fernando, Weena Lokuge, Hannah Seligmann, Hao Wang and Chamila Gunasekara
Recycling 2025, 10(4), 133; https://doi.org/10.3390/recycling10040133 - 4 Jul 2025
Viewed by 363
Abstract
This study investigates the use of Glass Fine Aggregate (GFA) and Fly Ash (FA) in mortar for Alkali–Silica Reaction (ASR) mitigation through a multidimensional evaluation. GFA was used to replace river sand in 20% increments up to 100%, while FA replaced cement at [...] Read more.
This study investigates the use of Glass Fine Aggregate (GFA) and Fly Ash (FA) in mortar for Alkali–Silica Reaction (ASR) mitigation through a multidimensional evaluation. GFA was used to replace river sand in 20% increments up to 100%, while FA replaced cement at 10%, 20%, and 30%. Three GFA size ranges were considered: <1.18 mm, 1.18–4.75 mm, and a combined fraction of <4.75 mm. At 100% replacement, <1.18 mm GFA reduced ASR expansion to 0.07%, compared to 0.2% for <4.75 mm and 0.46% for 1.18–4.75 mm GFA. It also improved long-term strength by 25% from 28 days to 6 months due to pozzolanic activity. However, refining GFA to below 1.18 mm increased environmental impacts and resulted in a 4.2% increase in energy demand due to the additional drying process. Incorporating 10% FA reduced ASR expansion to 0.044%, had no significant effect on strength, and decreased key environmental burdens such as toxicity by up to 18.2%. These findings indicate that FA utilisation offers greater benefits for ASR mitigation and environmental sustainability than further refining GFA size. Therefore, combining <4.75 mm GFA with 10% FA is identified as the optimal strategy for producing durable and sustainable mortar with recycled waste glass. Full article
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13 pages, 1634 KiB  
Article
Physico-Mechanical Properties of Geopolymers Based on Fly Ashes and Waste Broken Glass
by Krzysztof Cendrowski, Elżbieta Horszczaruk and Jarosław Strzałkowski
Appl. Sci. 2025, 15(13), 7495; https://doi.org/10.3390/app15137495 - 3 Jul 2025
Viewed by 232
Abstract
This paper presents the results of testing the insulation performance of geopolymers based on fly ashes with the addition of waste broken glass. The waste glass was dried and ground to a maximum of 1 mm grain size. The proportions of broken glass [...] Read more.
This paper presents the results of testing the insulation performance of geopolymers based on fly ashes with the addition of waste broken glass. The waste glass was dried and ground to a maximum of 1 mm grain size. The proportions of broken glass in the total binder’s mass were 0%, 10%, 20%, and 30%. Sodium hydroxide and sodium silicate were the activators of the alkaline reaction. The obtained geopolymer materials were characterised by determining the basic physico-mechanical properties. The chemical composition, density, and thermal conductivity coefficient were determined. The mechanical performance, including compressive and flexural strength, was investigated after 28 days of curing. The morphological analysis was also carried out using microphotographs obtained from optical and scanning microscopes. A significant effect of the waste glass on the tested geopolymers’ mechanical performance was observed. Proportions of 10% and 20% broken glass in the binder led to more than a four-fold increase in the compressive strength and a two-fold increase in the flexural strength compared to the geopolymer without the waste glass. All tested geopolymers had excellent insulation ability compared to the reference mortar (more than 80% higher than cement mortar). However, the problem is potential alkali–silica reaction, which can occur when the waste glass content is high. Full article
(This article belongs to the Section Civil Engineering)
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20 pages, 3571 KiB  
Article
Mechanical Properties and Thermal Degradation Behaviour of Polyurethane Composites Incorporating Waste-Glass Particles
by Nathaphon Buddhacosa, Edwin Baez, Thevega Thevakumar, Everson Kandare and Dilan Robert
Polymers 2025, 17(13), 1734; https://doi.org/10.3390/polym17131734 - 21 Jun 2025
Viewed by 497
Abstract
This study investigated the effect of hot-pressing conditions, including the curing temperature, curing time and the applied pressure, on the flexural properties of polyurethane (PU) composites incorporating 88 wt.% (Glass/PU-88/12) and 95 wt.% (Glass/PU-95/5) recycled glass particles. Hot-pressing (cure) temperatures between 100 °C [...] Read more.
This study investigated the effect of hot-pressing conditions, including the curing temperature, curing time and the applied pressure, on the flexural properties of polyurethane (PU) composites incorporating 88 wt.% (Glass/PU-88/12) and 95 wt.% (Glass/PU-95/5) recycled glass particles. Hot-pressing (cure) temperatures between 100 °C and 180 °C were investigated with the objective to shorten the cure cycle, thereby increasing the production rate of the glass/PU composites to match industrial scales. The hot-pressing time varied between 1 min and 30 min, while the pressure varied between 1.1 MPa and 6.6 MPa. Further to investigating the hot-pressing conditions, the effect of post-curing on the flexural properties of glass/PU composites was also investigated. Microstructural analysis was used to identify the interactions between the glass particles and the PU matrix, explore the void content and establish the relationship between the microstructure and the mechanical properties of the resultant glass/PU composites. Glass/PU composites incorporating 5 wt.% (Glass/PU-95/5), 10 wt.% (Glass/PU-90/10) and 12 wt.% (Glass/PU-88/12) were manufactured under optimised hot-pressing conditions (temperature = 100 °C; cure time = 1 min; pressure = 6.6 MPa) and evaluated under flexural, tensile and compression loadings. Furthermore, the high-temperature stability of the composites was evaluated using thermogravimetric analysis. This study demonstrates the feasibility of upcycling glass waste into value-added materials for potential use in the construction and building industry. Full article
(This article belongs to the Section Polymer Processing and Engineering)
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17 pages, 6242 KiB  
Article
Eco-Efficient Mortars with High-Content Construction, Waste-Derived Aggregates Functionalized via Nano-TiO2 for NOx Abatement
by Xiu-Cheng Zhang and Xue-Fei Chen
Processes 2025, 13(6), 1944; https://doi.org/10.3390/pr13061944 - 19 Jun 2025
Viewed by 286
Abstract
This study elucidates the photocatalytic NOx abatement efficacy of eco-efficient mortars incorporating construction waste-derived aggregates functionalized with nano-TiO2. The research findings demonstrate a positive correlation between NOx abatement efficiency and nano-TiO2 substitution ratio, with recycled glass sand (RG)-based panels exhibiting [...] Read more.
This study elucidates the photocatalytic NOx abatement efficacy of eco-efficient mortars incorporating construction waste-derived aggregates functionalized with nano-TiO2. The research findings demonstrate a positive correlation between NOx abatement efficiency and nano-TiO2 substitution ratio, with recycled glass sand (RG)-based panels exhibiting superior performance compared to standard sand and recycled clay brick sand (RCBS)-based counterparts. The employment of ultrasonic dispersion as a nano-TiO2 incorporation method yields enhanced abatement efficiency relative to direct mixing, attributable to improved photocatalyst dispersion and surface area accessibility. The loading capacity of nano-TiO2 on recycled aggregates is observed to be positively influenced by the concentration of nano-TiO2 solution, with recycled clay brick sand demonstrating the highest loading capacity. RG-RCBS panels are shown to exhibit higher NOx abatement efficiency than standard sand (SS)-RCBS panels, with an optimal substitution ratio of 40% glass sand identified for maximizing abatement efficacy in RG-RCBS systems. A decline in NOx abatement efficiency is observed with increasing NOx flow rate and concentration, attributable to reduced pollutant residence time and excess pollutant load exceeding the panels’ processing capacity. Prolonged curing time also results in diminished abatement efficiency, due to microstructural alterations within the mortar matrix and the accumulation of photocatalytic reaction byproducts. Collectively, these findings underscore the potential of recycled aggregate-based mortars, in conjunction with nano-TiO2, as a viable eco-efficient strategy for NOx abatement, highlighting the critical influence of material selection, photocatalyst loading, and operational parameters on system performance. Full article
(This article belongs to the Section Materials Processes)
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15 pages, 1366 KiB  
Article
Predicting the Hydration of Ground Granulated Blast Furnace Slag and Recycled Glass Blended Cements
by Mark Tyrer, Mark Richardson, Niall Holmes, John Newell, Marcus Yio and Hong Wong
Appl. Sci. 2025, 15(12), 6872; https://doi.org/10.3390/app15126872 - 18 Jun 2025
Viewed by 391
Abstract
The use of recycled glass powder (RCGP) is investigated as a partial replacement for ground granulated blast furnace slag in blended CEM II/A-LL cements using thermodynamic modelling to simulate cement paste hydration at a water-to-cement (w/c) ratio of 0.5. This study allows a [...] Read more.
The use of recycled glass powder (RCGP) is investigated as a partial replacement for ground granulated blast furnace slag in blended CEM II/A-LL cements using thermodynamic modelling to simulate cement paste hydration at a water-to-cement (w/c) ratio of 0.5. This study allows a rapid means of examining the likely evolution of these materials over the first two to three years, allowing experimental work to focus on promising formulations. A comparison is made between the evolving solid phase and solution chemistries of four materials: a standard Portland-limestone (CEM II/A-LL), a ‘control’ blend, comprising equal quantities of CEM II/A-LL with GGBS and two novel blended cements containing RCGP. These represent 15% replacement (by mass) of GGBS by RCGP blended with either 40% or 60% CEM II/A-LL. The simulations were performed using the code HYDCEM, a cement hydration simulator, which calls on the thermodynamic model PHREEQC to sequentially simulate the evolution of the four cements. The results suggest that partial replacement of GGBS by 15% RCGP results in no significant change in system chemistry. The partial replacement of cementitious slag by waste container glass provides a route by which this material can be diverted from the landfill inventory, and the mass-balance and energy balance implications will be reported elsewhere. Full article
(This article belongs to the Special Issue Recent Advances in Sustainable Construction Materials and Structures)
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13 pages, 2406 KiB  
Article
First Test and Characterizations on Urban Glass Waste with Waste-Derived Carbon Fiber Treated to Realize Foam Glass for Possible Construction Applications
by Zakim Hussain, Seyed Mostafa Nouri, Matteo Sambucci and Marco Valente
Ceramics 2025, 8(2), 73; https://doi.org/10.3390/ceramics8020073 - 17 Jun 2025
Viewed by 472
Abstract
Urban glass waste is a significant by-product of residential areas, while scrap carbon fiber is a prevalent industrial by-product. This study explores an innovative approach to valorize these materials by producing foam glass (FG) for versatile applications, particularly in construction. A key challenge [...] Read more.
Urban glass waste is a significant by-product of residential areas, while scrap carbon fiber is a prevalent industrial by-product. This study explores an innovative approach to valorize these materials by producing foam glass (FG) for versatile applications, particularly in construction. A key challenge in FG production is enhancing its properties to meet increasingly stringent application-specific standards. The properties of FG are intrinsically linked to its porous structure, which depends on factors such as the foaming process. The oxidation of carbon fibers at high temperatures can induce a foaming effect, creating a porous matrix in the glass. This research investigates the effect of powdered recycled carbon fiber (PRCF)—an alternative method for recovering waste carbon fiber as a foaming agent for FG. PRCF was added at concentrations of 0.5%, 1%, and 1.5% by mass relative to powdered waste glass. Increasing PRCF content enhanced foaming and improved porosity, with total porosity rising from 47.18% at 0.5% PRCF to 65.54% at 1.5% PRCF, accompanied by a 50% reduction in compressive strength and a 68% decrease in thermal conductivity. The results demonstrate the feasibility of large-scale FG production with enhanced properties, achieved without substantial additional investment and by recovering two waste materials. This process supports sustainable development by promoting waste valorization and advancing circular economy principles. Full article
(This article belongs to the Special Issue Ceramics in the Circular Economy for a Sustainable World)
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22 pages, 4653 KiB  
Article
Recycled Clay Brick Powder as a Dual-Function Additive: Mitigating the Alkali–Silica Reaction (ASR) and Enhancing Strength in Eco-Friendly Mortar with Hybrid Waste Glass and Clay Brick Aggregates
by Xue-Fei Chen, Xiu-Cheng Zhang and Ying Peng
Materials 2025, 18(12), 2838; https://doi.org/10.3390/ma18122838 - 16 Jun 2025
Viewed by 461
Abstract
The construction industry’s escalating environmental footprint, coupled with the underutilization of construction waste streams, necessitates innovative approaches to sustainable material design. This study investigates the dual functionality of recycled clay brick powder (RCBP) as both a supplementary cementitious material (SCM) and an alkali–silica [...] Read more.
The construction industry’s escalating environmental footprint, coupled with the underutilization of construction waste streams, necessitates innovative approaches to sustainable material design. This study investigates the dual functionality of recycled clay brick powder (RCBP) as both a supplementary cementitious material (SCM) and an alkali–silica reaction (ASR) inhibitor in hybrid mortar systems incorporating recycled glass (RG) and recycled clay brick (RCB) aggregates. Leveraging the pozzolanic activity of RCBP’s residual aluminosilicate phases, the research quantifies its influence on mortar durability and mechanical performance under varying substitution scenarios. Experimental findings reveal a nonlinear relationship between RCBP dosage and mortar properties. A 30% cement replacement with RCBP yields a 28-day activity index of 96.95%, confirming significant pozzolanic contributions. Critically, RCBP substitution ≥20% effectively mitigates ASRs induced by RG aggregates, with optimal suppression observed at 25% replacement. This threshold aligns with microstructural analyses showing RCBP’s Al3+ ions preferentially reacting with alkali hydroxides to form non-expansive gels, reducing pore solution pH and silica dissolution rates. Mechanical characterization reveals trade-offs between workability and strength development. Increasing RCBP substitution decreases mortar consistency and fluidity, which is more pronounced in RG-RCBS blends due to glass aggregates’ smooth texture. Compressively, both SS-RCBS and RG-RCBS mortars exhibit strength reduction with higher RCBP content, yet all specimens show accelerated compressive strength gain relative to flexural strength over curing time. Notably, 28-day water absorption increases with RCBP substitution, correlating with microstructural porosity modifications. These findings position recycled construction wastes and glass as valuable resources in circular economy frameworks, offering municipalities a pathway to meet recycled content mandates without sacrificing structural integrity. The study underscores the importance of waste synergy in advancing sustainable mortar technology, with implications for net-zero building practices and industrial waste valorization. Full article
(This article belongs to the Section Construction and Building Materials)
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